This paper models the giraffe’s jugular veins as a uniform collapsible tube from a rigid skull. The equations governing one-dimensional steady flow through such a tube for various conditions have been developed. The ...This paper models the giraffe’s jugular veins as a uniform collapsible tube from a rigid skull. The equations governing one-dimensional steady flow through such a tube for various conditions have been developed. The effects of inertial and inclination angles that have not been discussed previously have been included. It has been shown that different flows for a uniform tube (vein) are possible. However, this flow matches that of a jugular vein which is supercritical, and the steady solution has been given by the balance between the driving forces of gravity and the viscous resistance to the flow at the right atrium of the heart must be sub-critical for a fixed right-atrium pressure which means that an elastic jump is required to return the flow to sub-critical from the supercritical flow upstream this type of relationship gives rise to flow limitation at the same time given any right atrium fixed pressure there exists a maximum flow rate which when exceeded the boundary conditions of the flow do not hold boundary conditions at the right atrium are not satisfied hence making the steady flow impossible this mechanism of flow limitation is slightly different from the other one in that causes airways through forced expiration from the observation made it is clearly shown that there is an intravascular pressure difference with a change in height.展开更多
Gamma-emitting radionuclide ^(99m)Tc is globally used for the diagnosis of various pathological conditions owing to its ideal single-photon emission computed tomography (SPECT) characteristics.However,the short half-l...Gamma-emitting radionuclide ^(99m)Tc is globally used for the diagnosis of various pathological conditions owing to its ideal single-photon emission computed tomography (SPECT) characteristics.However,the short half-life of ^(99m)Tc (T_(1/2)=6 h)makes it difficult to store or transport.Thus,the production of ^(99m)Tc is tied to its parent radionuclide ^(99)Mo (T_(1/2)=66 h).The major production paths are based on accelerators and research reactors.The reactor process presents the potential for nuclear proliferation owing to its use of highly enriched uranium (HEU).Accelerator-based methods tend to use deuterium–tritium(D–T) neutron sources but are hindered by the high cost of tritium and its challenging operation.In this study,a new ^(99)Mo production design was developed based on a deuterium–deuterium (D–D) gas dynamic trap fusion neutron source (GDT-FNS) and a subcritical blanket system (SBS) assembly with a low-enriched uranium (LEU) solution.GDT-FNS can provide a relatively high-neutron intensity,which is one of the advantages of ^(99)Mo production.We provide a Monte Carlo-based neutronics analysis covering the calculation of the subcritical multiplication factor (k_(s)) of the SBS,optimization design for the reflector,shielding layer,and ^(99)Mo production capacity.Other calculations,including the neutron flux and nuclear heating distributions,are also provided for an overall evaluation of the production system.The results demonstrated that the SBS meets the nuclear critical safety design requirement (k_(s)<0.97) and maintained a high ^(99)Mo production capacity.The proposed system can generate approximately 157 Ci ^(99)Mo for a stable 24 h operation with a neutron intensity of 1×10^(14) n/s,which can meet 50%of China’s demand in 2025.展开更多
The effects of sulfuric acid-associated mechanical pretreatment on the hydrolysis behavior of pine sawdust were investigated in this study.Sulfuric acid could act as an acidic catalyst to depolymerize holocellulose th...The effects of sulfuric acid-associated mechanical pretreatment on the hydrolysis behavior of pine sawdust were investigated in this study.Sulfuric acid could act as an acidic catalyst to depolymerize holocellulose through cleavage of the glycosidic bonds,the dissociation energies of which were supplied by the impact of a ball on pine sawdust,during milling.The destruction of glycosidic and hydrogen bonds in pine sawdust resulted in a decrease of crystallinity and an increase of water solubility.The sulfuric acid could promote the hydrolysis of holocellulose and its hydrolysis products.It also destroyed the chemical linkages between holocellulose and lignin during ball milling.The cleavage of chemical linkages with holocellulose made lignin more difficult to hydrolyze in subcritical water,and higher activation energy was needed to hydrolyze pretreated pine sawdust at higher reaction temperatures.It also led to the formation of glucose char and aromatic-linked polymer char from the hydrolysis products of holocellulose.展开更多
In this letter,the effect of slip boundary on the origin of subcritical transition in two-dimensional chan-nel flows is studied numerically and theoretically.It is shown that both the positive and the negative slip le...In this letter,the effect of slip boundary on the origin of subcritical transition in two-dimensional chan-nel flows is studied numerically and theoretically.It is shown that both the positive and the negative slip lengths will increase the critical Reynolds number of localized wave packet and hence postpone the transition.By applying a variable transformation and expanding the variables about a small slip length,it is illustrated that the slip boundary effect only exists in the second and higher order modulations of the no-slip solution,and hence explains the power law found in simulations,i.e.the relative increment of the critical Reynolds number due to the slip boundary is proportional to the square of the slip length.展开更多
In this paper, a system of Lorenz-type ordinary differential equations is considered and, under some assumptions about the parameter space, the presence of the supercritical non-degenerate Hopf bifurcation is demonstr...In this paper, a system of Lorenz-type ordinary differential equations is considered and, under some assumptions about the parameter space, the presence of the supercritical non-degenerate Hopf bifurcation is demonstrated. The technical tool used consists of the Central Manifold theorem, a well-known formula to calculate the Lyapunov coefficient and Hopf’s Theorem. For particular values of the parameters in the parameter space established in the main result of this work, a graph is presented that describes the evolution of the trajectories, obtained by means of numerical simulation.展开更多
High-level waste is an important safety issue in the development of nuclear power.A proposed solution is the transmutation of waste in fast reactors.The exclusion of the risk of supercriticality by using subcritical r...High-level waste is an important safety issue in the development of nuclear power.A proposed solution is the transmutation of waste in fast reactors.The exclusion of the risk of supercriticality by using subcritical reactors is currently under development.Controlling the subcriticality level in such reactors presents difficulties.A problem is posed by the so-called space effect observed when using in reactors many neutron detectors in different locations of the core and reflector.Reactivity obtained from measure-ments,for example,by the Sjo¨strand method,differs by nonnegligible values.Numerical corrections can partially improve this situation.The use of a monoisotopic fission chamber set,designed for a given reactor,when each chamber is intended for a specific position in the system,can improve the situation.A question arises about the sensitivity of the results to reactivity changes.This issue is analyzed by computer simulation for possible fissionable and fissile nuclides for the total range of control rod insertion,changes in reactor fuel enrichment,and fuel temperature.The tested sensitivity was satisfactory at most levels from several dozen to several hundred pcm.A case study was conducted using the VENUS-F core model.展开更多
Effect of cryogenic treatment on the microstructure, hardening behavior and abrasion resistance of 14Cr2Mn2V high chromium cast iron (HCCI) subjected to subcritical treatment was investigated. The results show that ...Effect of cryogenic treatment on the microstructure, hardening behavior and abrasion resistance of 14Cr2Mn2V high chromium cast iron (HCCI) subjected to subcritical treatment was investigated. The results show that cryogenic treatment after subcritical treatment can obviously improve the hardness and abrasion resistance of HCCI because abundant retained austenite is transformed into martensite and fine secondary carbides E(Fe, Cr)23 C6 ] precipitate. The amount of martensite and precipitated secondary carbide in HCCI experiencing subcritical treatment followed by cryogenic treatment was more than that experiencing the subcritical treatment followed by air cooling. When the abrasion resistance of HCCI reaches the maximum, its microstructure contains about 15 % retained austenite. Cryogenic treatment can further reduce the austenite content but the retained austenite cannot be transformed in to martensite completely.展开更多
The accelerator-driven subcritical system (ADS) with a hard neutron energy spectrum was used to study transmutation of minor actinides (MAs). The aim of the study was to improve the efficiency of MA transmutation whil...The accelerator-driven subcritical system (ADS) with a hard neutron energy spectrum was used to study transmutation of minor actinides (MAs). The aim of the study was to improve the efficiency of MA transmutation while ensuring that variations in the effective multiplication factor (keff) remained within safe margins during reactor operation. All calculations were completed using code COUPLE3.0. The subcritical reactor was operated at a thermal power level of 800 MW, and a mixture of mononitrides of MAs and plutonium (Pu) was used as fuel. Zirconium nitride (ZrN) was used as an inert matrix in the fuel elements. The initial mass composition in terms of weight percentages in the heavy metal component (IHM) was 30.6% Pu/IHM and 69.4% MA/IHM. To verify the feasibility of this MA loading scheme, variations in keff, the amplification factor of the core, maximum power density and the content of MAs and Pu were calculated over six refueling cycles. Each cycle was of 600 days duration, and therefore, there were 3600 effective full power days. Results demonstrated that the effective transmutation support ratio of MAs was approximately 28, and the ADS was able to efficiently transmute MAs. The changes in other physical parameters were also within their normal ranges.It is concluded that the proposed MA transmutation scheme for an ADS core is reasonable.展开更多
This paper studies the local dynamics of an SDOF system with quadratic and cubic stiffness terms,and with linear delayed velocity feedback.The analysis indicates that for a sufficiently large velocity feedback gain,th...This paper studies the local dynamics of an SDOF system with quadratic and cubic stiffness terms,and with linear delayed velocity feedback.The analysis indicates that for a sufficiently large velocity feedback gain,the equilibrium of the system may undergo a number of stability switches with an increase of time delay,and then becomes unstable forever.At each critical value of time delay for which the system changes its stability,a generic Hopf bifurcation occurs and a periodic motion emerges in a one-sided neighbourhood of the critical time delay.The method of Fredholm alternative is applied to determine the bifurcating periodic motions and their stability.It stresses on the effect of the system parameters on the stable regions and the amplitudes of the bifurcating periodic solutions.展开更多
Effects of reaction parameter on yield of benzaldehyde produced from toluene oxidization using hydrogen peroxide in subcritical water are investigated. The experimental results show that if the molar ratio of hydrogen...Effects of reaction parameter on yield of benzaldehyde produced from toluene oxidization using hydrogen peroxide in subcritical water are investigated. The experimental results show that if the molar ratio of hydrogen peroxide to toluene is controlled within a reasonable range, the by-products may be neglected. The optimum technology of toluene oxidization to benzaldehyde is reaction time 60 min, reaction temperature 350℃, molar ratio of hydrogen peroxide to toluene 3.5. The yield of benzaldehyde can reach 17.2 % under the optimum condition. Research results of chemical reaction kinetics show that the consecutive reaction consists of two first-order reaction, and activation energy of these two reactions are 89 kJ·mol^-1 and 76 kJ·mol^-1 respectively,展开更多
The utilization of neutrons markedly affects the medical isotope yield of a subcritical system driven by an external D-T neutron source.The general methods to improve the utilization of neutrons include moderating mul...The utilization of neutrons markedly affects the medical isotope yield of a subcritical system driven by an external D-T neutron source.The general methods to improve the utilization of neutrons include moderating multiplying,and reflecting neutrons,which ignores the use of neutrons that backscatter to the source direction.In this study,a stacked structure was formed by assembling the multiplier and the low-enriched uranium solution to enable the full use of neutrons that backscatter to the source direction and further improve the utilization of neutrons.A model based on SuperMC was used to evaluate the neutronics and safety behavior of the subcritical system,such as the neutron effective multiplication factor,neutron energy spectrum,medical isotope yield,and heat deposition.Based on the calculation results,when the intensity of the neutron source was 59×10^(13)n/s,the optimized design with a stacked structure could increase the yield of ^(99)Mo to182 Ci/day,which is approximately 16% higher than that obtained with a single-layer structure.The inlet H_(2)O coolant velocity of 1.0 m/s and initial temperature of 20℃ were also found to be sufficient to prevent boiling of the fuel solution.展开更多
In this paper Hopf bifurcation control is implemented in order to change the bifurcation from supercritical to subcritical in a differential equations system of Lorenz type. To achieve this purpose: first, a region of...In this paper Hopf bifurcation control is implemented in order to change the bifurcation from supercritical to subcritical in a differential equations system of Lorenz type. To achieve this purpose: first, a region of parameters is identified where the system has a supercritical Hopf bifurcation;second, a class of non-linear feedback control laws is proposed;finally, it is shown that there are control laws which the disturbed system undergoes subcritical Hopf bifurcation.展开更多
Subcritical and supercritical water gasification of petroleum coke and asphaltene was performed at variable temperatures(350–650°C),feed concentrations(15–30 wt%)and reaction times(15–60 min).Nickel-impregnate...Subcritical and supercritical water gasification of petroleum coke and asphaltene was performed at variable temperatures(350–650°C),feed concentrations(15–30 wt%)and reaction times(15–60 min).Nickel-impregnated activated carbon(Ni/AC)was synthesized as a catalyst for enhancing syngas yields at optimal gasification conditions(650°C,15 wt%and 60 min).Structural chemistry of precursors and chars developed at different gasification temperatures was studied using physicochemical and synchrotronbased approaches such as carbon–hydrogen–nitrogen–sulfur(CHNS)analysis,thermogravimetric and differential thermogravimetric analysis(TGA/DTA),scanning electron microscopy(SEM),Fourier-Transform Infrared spectroscopy(FTIR),Raman spectroscopy,X-ray diffraction(XRD)and X-ray absorption spectroscopy(XAS).Asphaltene testified to be a better precursor for catalytic hydrothermal gasification leading to 11.97 mmol/g of total gas yield compared to petroleum coke(8.04 mmol/g).In particular,supercritical water gasification using 5 wt%Ni/AC at 650°C with 15 wt%feed concentration for 60 min resulted in 4.17 and 2.98 mmol/g of H_2from asphaltene and petroleum coke,respectively.Under the same conditions,the respective CH_4yields from catalytic gasification of asphaltene and petroleum coke were 2.54and 1.07 mmol/g.Nonetheless,asphaltene also seemed to an attractive feedstock for the production of highly aromatic chars through hydrothermal gasification.展开更多
The analysis of the fuel depletion behavior is critical for maintaining the safety of accelerator-driven subcritical systems(ADSs). The code COUPLE2.0 coupling 3-D neutron transport and point burnup calculation was de...The analysis of the fuel depletion behavior is critical for maintaining the safety of accelerator-driven subcritical systems(ADSs). The code COUPLE2.0 coupling 3-D neutron transport and point burnup calculation was developed by Tsinghua University. A Monte Carlo method is used for the neutron transport analysis, and the burnup calculation is based on a deterministic method. The code can be used for the analysis of targets coupled with a reactor in ADSs. In response to additional ADS analysis requirements at the Institute of Modern Physics at the Chinese Academy of Sciences, the COUPLE3.0 version was developed to include the new functions of(1) a module for the calculation of proton irradiation for the analysis of cumulative behavior using the residual radionuclide operating history,(2) a fixed-flux radiation module for hazard assessment and analysis of the burnable poison, and(3) a module for multi-kernel parallel calculation, which improves the radionuclide replacement for the burnup analysis to balance the precision level and computational efficiency of the program. This paper introduces thevalidation of the COUPLE3.0 code using a fast reactor benchmark and ADS benchmark calculations. Moreover,the proton irradiation module was verified by a comparison with the analytic method of calculating the210 Po accumulation results. The results demonstrate that COUPLE3.0 is suitable for the analysis of neutron transport and the burnup of nuclides for ADSs.展开更多
By direct numerical simulations of the plane Couette flow (PCF) in a large computational domain, it is shown that an isolated turbulent band decays monotonically at low Reynolds numbers but experiences transient growt...By direct numerical simulations of the plane Couette flow (PCF) in a large computational domain, it is shown that an isolated turbulent band decays monotonically at low Reynolds numbers but experiences transient growth before the eventual relaminarization at moderate Reynolds numbers. The lower bound Reynolds number of the transient-growth regime is determined as 286. The width, length, and tilt angle of the iso- lated band structure are defined based on the disturbance kinetic energy in the mid-plane, and the geometric characteristics of the band can be described with a tilted rectangle. It is illustrated that before its eventual fragmentation, the isolated turbulent band decays in a style of longitudinal contraction, where the center, width, and tilt angle of the band keep almost constant but the band length contracts with a statistically constant velocity.展开更多
The Hopf bifurcations of an airfoil flutter system with a cubic nonlinearity are investigated, with the flow speed as the bifurcation parameter. The center manifold theory and complex normal form method are Used to ob...The Hopf bifurcations of an airfoil flutter system with a cubic nonlinearity are investigated, with the flow speed as the bifurcation parameter. The center manifold theory and complex normal form method are Used to obtain the bifurcation equation. Interestingly, for a certain linear pitching stiffness the Hopf bifurcation is both supercritical and subcritical. It is found, mathematically, this is caused by the fact that one coefficient in the bifurcation equation does not contain the first power of the bifurcation parameter. The solutions of the bifurcation equation are validated by the equivalent linearization method and incremental harmonic balance method.展开更多
We analyze the exponential decay property of solutions of the semilinear wave equation in bounded domain Ω of R^N with a damping term which is effective on the exterior of a ball and boundary conditions of the Cauchy...We analyze the exponential decay property of solutions of the semilinear wave equation in bounded domain Ω of R^N with a damping term which is effective on the exterior of a ball and boundary conditions of the Cauchy-Ventcel type. Under suitable and natural assumptions on the nonlinearity, we prove that the exponential decay holds locally uniformly for finite energy solutions provided the nonlinearity is subcritical at infinity. Subcriticality means, roughly speaking, that the nonlinearity grows at infinity at most as a power p 〈 5. The results obtained in R^3 and RN by B. Dehman, G. Lebeau and E. Zuazua on the inequalities of the classical energy (which estimate the total energy of solutions in terms of the energy localized in the exterior of a ball) and on Strichartz's estimates, allow us to give an application to the stabilization controllability of the semilinear wave equation in a bounded domain of R^N with a subcritical nonlinearity on the domain and its boundary, and conditions on the boundary of Cauchy-Ventcel type.展开更多
For the first time,the solubility ofβ-carotene in pure and ethanol-modified subcritical water(SW)using the static method was determined.The experimental runs were performed at a temperature ranging from 298.15 to 403...For the first time,the solubility ofβ-carotene in pure and ethanol-modified subcritical water(SW)using the static method was determined.The experimental runs were performed at a temperature ranging from 298.15 to 403.15 K and 0–10%(w/w)of ethanol as a modifier at a constant pressure of 5 MPa.Samples were analyzed by UV–vis spectrophotometer.The solubility ofβ-carotene was found to range from 1.084×10^-8 to 227.1×10^-8 mol fractions in the subcritical water in above mentioned conditions.The obtainedβ-carotene solubility data were correlated using the linear model and modified Apelblat model.The obtained results showed the modified Apelblat model was better for estimating the solubility ofβ-carotene in SW.The values of the rootmean-square deviation(RMSD)between experimental and correlated data were calculated and used as the index of validity and accuracy for the model.Also,thermodynamic properties of the solution such as the Gibbs free energy of solution,enthalpy,and entropy of solution were estimated.展开更多
Flow around an oscillating cylinder in a subcritical region are numerically studied with a lattice Boltzmann method(LBM). The effects of the Reynolds number,oscillation amplitude and frequency on the vortex wake modes...Flow around an oscillating cylinder in a subcritical region are numerically studied with a lattice Boltzmann method(LBM). The effects of the Reynolds number,oscillation amplitude and frequency on the vortex wake modes and hydrodynamics forces on the cylinder surface are systematically investigated. Special attention is paid to the phenomenon of resonance induced by the cylinder oscillation. The results demonstrate that vortex shedding can be excited extensively under subcritical conditions, and the response region of vibration frequency broadens with increasing Reynolds number and oscillation amplitude. Two distinct types of vortex shedding regimes are observed. The first type of vortex shedding regime(VSR I) is excited at low frequencies close to the intrinsic frequency of flow, and the second type of vortex shedding regime(VSR II)occurs at high frequencies with the Reynolds number close to the critical value. In the VSR I, a pair of alternately rotating vortices are shed in the wake per oscillation cycle,and lock-in/synchronization occurs, while in the VSR II, two alternately rotating vortices are shed for several oscillation cycles, and the vortex shedding frequency is close to that of a stationary cylinder under the critical condition. The excitation mechanisms of the two types of vortex shedding modes are analyzed separately.展开更多
The long-term stability of the roof is particularly important in designing underground rock structures.To estimate the durability of roof strata in underground excavation,a computation scheme of subcritical crack grow...The long-term stability of the roof is particularly important in designing underground rock structures.To estimate the durability of roof strata in underground excavation,a computation scheme of subcritical crack growth is proposed in this study.By adopting the proposed method,the potential collapse location of strata is derivable in accordance with a static model,the durability of roof strata can be estimated,a dynamic time step control strategy is achieved to balance the accuracy and speed of computing,and the initial crack size of rock can be estimated.In addition to the above,a mechanical model of underground excavation with non-uniformly distributed loads and partially yielded foundation is presented as the prototypical case.A set of case studies is carried out that showcase a power correlation between applied stress and roof durability.The allowable applied tensile stress for a 100-year life cycle is about 76%of the tensile strength.By using the proposed subcritical crack growth computation scheme,the roof stability in an underground excavation can be identified not only from the spatial view but also from the temporal perspective.展开更多
文摘This paper models the giraffe’s jugular veins as a uniform collapsible tube from a rigid skull. The equations governing one-dimensional steady flow through such a tube for various conditions have been developed. The effects of inertial and inclination angles that have not been discussed previously have been included. It has been shown that different flows for a uniform tube (vein) are possible. However, this flow matches that of a jugular vein which is supercritical, and the steady solution has been given by the balance between the driving forces of gravity and the viscous resistance to the flow at the right atrium of the heart must be sub-critical for a fixed right-atrium pressure which means that an elastic jump is required to return the flow to sub-critical from the supercritical flow upstream this type of relationship gives rise to flow limitation at the same time given any right atrium fixed pressure there exists a maximum flow rate which when exceeded the boundary conditions of the flow do not hold boundary conditions at the right atrium are not satisfied hence making the steady flow impossible this mechanism of flow limitation is slightly different from the other one in that causes airways through forced expiration from the observation made it is clearly shown that there is an intravascular pressure difference with a change in height.
基金supported by Anhui Provincial Key R&D Program (202104g0102007)Hefei Municipal Natural Science Foundation (2022011)+2 种基金Collaborative Innovation Program of Hefei Science CenterChinese Academy of Sciences(2022HSC CIP024)International Partnership Program of Chinese Academy of Sciences (116134KYSB20200001)。
文摘Gamma-emitting radionuclide ^(99m)Tc is globally used for the diagnosis of various pathological conditions owing to its ideal single-photon emission computed tomography (SPECT) characteristics.However,the short half-life of ^(99m)Tc (T_(1/2)=6 h)makes it difficult to store or transport.Thus,the production of ^(99m)Tc is tied to its parent radionuclide ^(99)Mo (T_(1/2)=66 h).The major production paths are based on accelerators and research reactors.The reactor process presents the potential for nuclear proliferation owing to its use of highly enriched uranium (HEU).Accelerator-based methods tend to use deuterium–tritium(D–T) neutron sources but are hindered by the high cost of tritium and its challenging operation.In this study,a new ^(99)Mo production design was developed based on a deuterium–deuterium (D–D) gas dynamic trap fusion neutron source (GDT-FNS) and a subcritical blanket system (SBS) assembly with a low-enriched uranium (LEU) solution.GDT-FNS can provide a relatively high-neutron intensity,which is one of the advantages of ^(99)Mo production.We provide a Monte Carlo-based neutronics analysis covering the calculation of the subcritical multiplication factor (k_(s)) of the SBS,optimization design for the reflector,shielding layer,and ^(99)Mo production capacity.Other calculations,including the neutron flux and nuclear heating distributions,are also provided for an overall evaluation of the production system.The results demonstrated that the SBS meets the nuclear critical safety design requirement (k_(s)<0.97) and maintained a high ^(99)Mo production capacity.The proposed system can generate approximately 157 Ci ^(99)Mo for a stable 24 h operation with a neutron intensity of 1×10^(14) n/s,which can meet 50%of China’s demand in 2025.
基金supported by the National Natural Science Foundation of China(22078225)the Natural Science Foundation of Zhejiang Province(LGF22E080025 and LHY22E080005)。
文摘The effects of sulfuric acid-associated mechanical pretreatment on the hydrolysis behavior of pine sawdust were investigated in this study.Sulfuric acid could act as an acidic catalyst to depolymerize holocellulose through cleavage of the glycosidic bonds,the dissociation energies of which were supplied by the impact of a ball on pine sawdust,during milling.The destruction of glycosidic and hydrogen bonds in pine sawdust resulted in a decrease of crystallinity and an increase of water solubility.The sulfuric acid could promote the hydrolysis of holocellulose and its hydrolysis products.It also destroyed the chemical linkages between holocellulose and lignin during ball milling.The cleavage of chemical linkages with holocellulose made lignin more difficult to hydrolyze in subcritical water,and higher activation energy was needed to hydrolyze pretreated pine sawdust at higher reaction temperatures.It also led to the formation of glucose char and aromatic-linked polymer char from the hydrolysis products of holocellulose.
基金The present research is financially supported by the National Natural Science Foundation of China(Grants No.91752203).
文摘In this letter,the effect of slip boundary on the origin of subcritical transition in two-dimensional chan-nel flows is studied numerically and theoretically.It is shown that both the positive and the negative slip lengths will increase the critical Reynolds number of localized wave packet and hence postpone the transition.By applying a variable transformation and expanding the variables about a small slip length,it is illustrated that the slip boundary effect only exists in the second and higher order modulations of the no-slip solution,and hence explains the power law found in simulations,i.e.the relative increment of the critical Reynolds number due to the slip boundary is proportional to the square of the slip length.
文摘In this paper, a system of Lorenz-type ordinary differential equations is considered and, under some assumptions about the parameter space, the presence of the supercritical non-degenerate Hopf bifurcation is demonstrated. The technical tool used consists of the Central Manifold theorem, a well-known formula to calculate the Lyapunov coefficient and Hopf’s Theorem. For particular values of the parameters in the parameter space established in the main result of this work, a graph is presented that describes the evolution of the trajectories, obtained by means of numerical simulation.
基金This research was supported by the Polish Ministry of Science and Higher Education,and in part by the PL Grid Infrastructure available at Academic Computer Center CYFRONET AGH.APC was funded by the AGH-University of Science and Technology,Cracow,Poland.
文摘High-level waste is an important safety issue in the development of nuclear power.A proposed solution is the transmutation of waste in fast reactors.The exclusion of the risk of supercriticality by using subcritical reactors is currently under development.Controlling the subcriticality level in such reactors presents difficulties.A problem is posed by the so-called space effect observed when using in reactors many neutron detectors in different locations of the core and reflector.Reactivity obtained from measure-ments,for example,by the Sjo¨strand method,differs by nonnegligible values.Numerical corrections can partially improve this situation.The use of a monoisotopic fission chamber set,designed for a given reactor,when each chamber is intended for a specific position in the system,can improve the situation.A question arises about the sensitivity of the results to reactivity changes.This issue is analyzed by computer simulation for possible fissionable and fissile nuclides for the total range of control rod insertion,changes in reactor fuel enrichment,and fuel temperature.The tested sensitivity was satisfactory at most levels from several dozen to several hundred pcm.A case study was conducted using the VENUS-F core model.
文摘Effect of cryogenic treatment on the microstructure, hardening behavior and abrasion resistance of 14Cr2Mn2V high chromium cast iron (HCCI) subjected to subcritical treatment was investigated. The results show that cryogenic treatment after subcritical treatment can obviously improve the hardness and abrasion resistance of HCCI because abundant retained austenite is transformed into martensite and fine secondary carbides E(Fe, Cr)23 C6 ] precipitate. The amount of martensite and precipitated secondary carbide in HCCI experiencing subcritical treatment followed by cryogenic treatment was more than that experiencing the subcritical treatment followed by air cooling. When the abrasion resistance of HCCI reaches the maximum, its microstructure contains about 15 % retained austenite. Cryogenic treatment can further reduce the austenite content but the retained austenite cannot be transformed in to martensite completely.
基金supported by the Strategic Priority Research Program of The Chinese Academy of Sciences(No.XDA21010202)
文摘The accelerator-driven subcritical system (ADS) with a hard neutron energy spectrum was used to study transmutation of minor actinides (MAs). The aim of the study was to improve the efficiency of MA transmutation while ensuring that variations in the effective multiplication factor (keff) remained within safe margins during reactor operation. All calculations were completed using code COUPLE3.0. The subcritical reactor was operated at a thermal power level of 800 MW, and a mixture of mononitrides of MAs and plutonium (Pu) was used as fuel. Zirconium nitride (ZrN) was used as an inert matrix in the fuel elements. The initial mass composition in terms of weight percentages in the heavy metal component (IHM) was 30.6% Pu/IHM and 69.4% MA/IHM. To verify the feasibility of this MA loading scheme, variations in keff, the amplification factor of the core, maximum power density and the content of MAs and Pu were calculated over six refueling cycles. Each cycle was of 600 days duration, and therefore, there were 3600 effective full power days. Results demonstrated that the effective transmutation support ratio of MAs was approximately 28, and the ADS was able to efficiently transmute MAs. The changes in other physical parameters were also within their normal ranges.It is concluded that the proposed MA transmutation scheme for an ADS core is reasonable.
基金The project supported by the National Natural Science Foundation of China (19972025)
文摘This paper studies the local dynamics of an SDOF system with quadratic and cubic stiffness terms,and with linear delayed velocity feedback.The analysis indicates that for a sufficiently large velocity feedback gain,the equilibrium of the system may undergo a number of stability switches with an increase of time delay,and then becomes unstable forever.At each critical value of time delay for which the system changes its stability,a generic Hopf bifurcation occurs and a periodic motion emerges in a one-sided neighbourhood of the critical time delay.The method of Fredholm alternative is applied to determine the bifurcating periodic motions and their stability.It stresses on the effect of the system parameters on the stable regions and the amplitudes of the bifurcating periodic solutions.
文摘Effects of reaction parameter on yield of benzaldehyde produced from toluene oxidization using hydrogen peroxide in subcritical water are investigated. The experimental results show that if the molar ratio of hydrogen peroxide to toluene is controlled within a reasonable range, the by-products may be neglected. The optimum technology of toluene oxidization to benzaldehyde is reaction time 60 min, reaction temperature 350℃, molar ratio of hydrogen peroxide to toluene 3.5. The yield of benzaldehyde can reach 17.2 % under the optimum condition. Research results of chemical reaction kinetics show that the consecutive reaction consists of two first-order reaction, and activation energy of these two reactions are 89 kJ·mol^-1 and 76 kJ·mol^-1 respectively,
基金supported by the Natural Science Foundation of Anhui Province(No.1808085MA10)Anhui Provincial Key R&D Program(No.202104g0102007)the National Natural Science Foundation of China(No.21805283)。
文摘The utilization of neutrons markedly affects the medical isotope yield of a subcritical system driven by an external D-T neutron source.The general methods to improve the utilization of neutrons include moderating multiplying,and reflecting neutrons,which ignores the use of neutrons that backscatter to the source direction.In this study,a stacked structure was formed by assembling the multiplier and the low-enriched uranium solution to enable the full use of neutrons that backscatter to the source direction and further improve the utilization of neutrons.A model based on SuperMC was used to evaluate the neutronics and safety behavior of the subcritical system,such as the neutron effective multiplication factor,neutron energy spectrum,medical isotope yield,and heat deposition.Based on the calculation results,when the intensity of the neutron source was 59×10^(13)n/s,the optimized design with a stacked structure could increase the yield of ^(99)Mo to182 Ci/day,which is approximately 16% higher than that obtained with a single-layer structure.The inlet H_(2)O coolant velocity of 1.0 m/s and initial temperature of 20℃ were also found to be sufficient to prevent boiling of the fuel solution.
文摘In this paper Hopf bifurcation control is implemented in order to change the bifurcation from supercritical to subcritical in a differential equations system of Lorenz type. To achieve this purpose: first, a region of parameters is identified where the system has a supercritical Hopf bifurcation;second, a class of non-linear feedback control laws is proposed;finally, it is shown that there are control laws which the disturbed system undergoes subcritical Hopf bifurcation.
基金the Natural Sciences and Engineering Research Council of Canada (NSERC)Canada Research Chair program for funding this bioenergy research
文摘Subcritical and supercritical water gasification of petroleum coke and asphaltene was performed at variable temperatures(350–650°C),feed concentrations(15–30 wt%)and reaction times(15–60 min).Nickel-impregnated activated carbon(Ni/AC)was synthesized as a catalyst for enhancing syngas yields at optimal gasification conditions(650°C,15 wt%and 60 min).Structural chemistry of precursors and chars developed at different gasification temperatures was studied using physicochemical and synchrotronbased approaches such as carbon–hydrogen–nitrogen–sulfur(CHNS)analysis,thermogravimetric and differential thermogravimetric analysis(TGA/DTA),scanning electron microscopy(SEM),Fourier-Transform Infrared spectroscopy(FTIR),Raman spectroscopy,X-ray diffraction(XRD)and X-ray absorption spectroscopy(XAS).Asphaltene testified to be a better precursor for catalytic hydrothermal gasification leading to 11.97 mmol/g of total gas yield compared to petroleum coke(8.04 mmol/g).In particular,supercritical water gasification using 5 wt%Ni/AC at 650°C with 15 wt%feed concentration for 60 min resulted in 4.17 and 2.98 mmol/g of H_2from asphaltene and petroleum coke,respectively.Under the same conditions,the respective CH_4yields from catalytic gasification of asphaltene and petroleum coke were 2.54and 1.07 mmol/g.Nonetheless,asphaltene also seemed to an attractive feedstock for the production of highly aromatic chars through hydrothermal gasification.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA03030102)
文摘The analysis of the fuel depletion behavior is critical for maintaining the safety of accelerator-driven subcritical systems(ADSs). The code COUPLE2.0 coupling 3-D neutron transport and point burnup calculation was developed by Tsinghua University. A Monte Carlo method is used for the neutron transport analysis, and the burnup calculation is based on a deterministic method. The code can be used for the analysis of targets coupled with a reactor in ADSs. In response to additional ADS analysis requirements at the Institute of Modern Physics at the Chinese Academy of Sciences, the COUPLE3.0 version was developed to include the new functions of(1) a module for the calculation of proton irradiation for the analysis of cumulative behavior using the residual radionuclide operating history,(2) a fixed-flux radiation module for hazard assessment and analysis of the burnable poison, and(3) a module for multi-kernel parallel calculation, which improves the radionuclide replacement for the burnup analysis to balance the precision level and computational efficiency of the program. This paper introduces thevalidation of the COUPLE3.0 code using a fast reactor benchmark and ADS benchmark calculations. Moreover,the proton irradiation module was verified by a comparison with the analytic method of calculating the210 Po accumulation results. The results demonstrate that COUPLE3.0 is suitable for the analysis of neutron transport and the burnup of nuclides for ADSs.
基金Project supported by the National Natural Science Foundation of China(Nos.91752203,11490553,and 11602148)
文摘By direct numerical simulations of the plane Couette flow (PCF) in a large computational domain, it is shown that an isolated turbulent band decays monotonically at low Reynolds numbers but experiences transient growth before the eventual relaminarization at moderate Reynolds numbers. The lower bound Reynolds number of the transient-growth regime is determined as 286. The width, length, and tilt angle of the iso- lated band structure are defined based on the disturbance kinetic energy in the mid-plane, and the geometric characteristics of the band can be described with a tilted rectangle. It is illustrated that before its eventual fragmentation, the isolated turbulent band decays in a style of longitudinal contraction, where the center, width, and tilt angle of the band keep almost constant but the band length contracts with a statistically constant velocity.
基金Project supported by the National Natural Science Foundation of China (No.10772202)the Doctoral Foundation of Ministry of Education of China (No.20050558032)the Natural Science Foundation of Guangdong Province (Nos.07003680 and 05003295)
文摘The Hopf bifurcations of an airfoil flutter system with a cubic nonlinearity are investigated, with the flow speed as the bifurcation parameter. The center manifold theory and complex normal form method are Used to obtain the bifurcation equation. Interestingly, for a certain linear pitching stiffness the Hopf bifurcation is both supercritical and subcritical. It is found, mathematically, this is caused by the fact that one coefficient in the bifurcation equation does not contain the first power of the bifurcation parameter. The solutions of the bifurcation equation are validated by the equivalent linearization method and incremental harmonic balance method.
文摘We analyze the exponential decay property of solutions of the semilinear wave equation in bounded domain Ω of R^N with a damping term which is effective on the exterior of a ball and boundary conditions of the Cauchy-Ventcel type. Under suitable and natural assumptions on the nonlinearity, we prove that the exponential decay holds locally uniformly for finite energy solutions provided the nonlinearity is subcritical at infinity. Subcriticality means, roughly speaking, that the nonlinearity grows at infinity at most as a power p 〈 5. The results obtained in R^3 and RN by B. Dehman, G. Lebeau and E. Zuazua on the inequalities of the classical energy (which estimate the total energy of solutions in terms of the energy localized in the exterior of a ball) and on Strichartz's estimates, allow us to give an application to the stabilization controllability of the semilinear wave equation in a bounded domain of R^N with a subcritical nonlinearity on the domain and its boundary, and conditions on the boundary of Cauchy-Ventcel type.
基金The authors tend to appreciate for the partial financial support from Semnan University Science and Technology Park.
文摘For the first time,the solubility ofβ-carotene in pure and ethanol-modified subcritical water(SW)using the static method was determined.The experimental runs were performed at a temperature ranging from 298.15 to 403.15 K and 0–10%(w/w)of ethanol as a modifier at a constant pressure of 5 MPa.Samples were analyzed by UV–vis spectrophotometer.The solubility ofβ-carotene was found to range from 1.084×10^-8 to 227.1×10^-8 mol fractions in the subcritical water in above mentioned conditions.The obtainedβ-carotene solubility data were correlated using the linear model and modified Apelblat model.The obtained results showed the modified Apelblat model was better for estimating the solubility ofβ-carotene in SW.The values of the rootmean-square deviation(RMSD)between experimental and correlated data were calculated and used as the index of validity and accuracy for the model.Also,thermodynamic properties of the solution such as the Gibbs free energy of solution,enthalpy,and entropy of solution were estimated.
基金Project supported by the National Natural Science Foundation of China(No.11402129)the Zhejiang Provincial Natural Science Foundation of China(No.LY17A020002)
文摘Flow around an oscillating cylinder in a subcritical region are numerically studied with a lattice Boltzmann method(LBM). The effects of the Reynolds number,oscillation amplitude and frequency on the vortex wake modes and hydrodynamics forces on the cylinder surface are systematically investigated. Special attention is paid to the phenomenon of resonance induced by the cylinder oscillation. The results demonstrate that vortex shedding can be excited extensively under subcritical conditions, and the response region of vibration frequency broadens with increasing Reynolds number and oscillation amplitude. Two distinct types of vortex shedding regimes are observed. The first type of vortex shedding regime(VSR I) is excited at low frequencies close to the intrinsic frequency of flow, and the second type of vortex shedding regime(VSR II)occurs at high frequencies with the Reynolds number close to the critical value. In the VSR I, a pair of alternately rotating vortices are shed in the wake per oscillation cycle,and lock-in/synchronization occurs, while in the VSR II, two alternately rotating vortices are shed for several oscillation cycles, and the vortex shedding frequency is close to that of a stationary cylinder under the critical condition. The excitation mechanisms of the two types of vortex shedding modes are analyzed separately.
基金China Scholarship Council(CSC)The University of Queensland for a Ph D fellowship。
文摘The long-term stability of the roof is particularly important in designing underground rock structures.To estimate the durability of roof strata in underground excavation,a computation scheme of subcritical crack growth is proposed in this study.By adopting the proposed method,the potential collapse location of strata is derivable in accordance with a static model,the durability of roof strata can be estimated,a dynamic time step control strategy is achieved to balance the accuracy and speed of computing,and the initial crack size of rock can be estimated.In addition to the above,a mechanical model of underground excavation with non-uniformly distributed loads and partially yielded foundation is presented as the prototypical case.A set of case studies is carried out that showcase a power correlation between applied stress and roof durability.The allowable applied tensile stress for a 100-year life cycle is about 76%of the tensile strength.By using the proposed subcritical crack growth computation scheme,the roof stability in an underground excavation can be identified not only from the spatial view but also from the temporal perspective.