In order to research the sulfate attack resistance of shotcrete, the sulfate attack of shotcrete in the presence and absence of steel fiber was experimentally studied by using dry-wet cycle method. Meanwhile, compared...In order to research the sulfate attack resistance of shotcrete, the sulfate attack of shotcrete in the presence and absence of steel fiber was experimentally studied by using dry-wet cycle method. Meanwhile, compared with ordinary concrete by the same mixture, the difference of sulfate attack resistance of shotcrete was studied. The experimental results showed that, with dry-wet cycles increasing, the changes of loss rate of relative dynamic elastic modulus and mass loss rate of specimens included three stages: initial descent stage, stable stage, and rapid descent stage, respectively. However, the changes of mechanical properties first increased and then decreased. Furthermore, the corrosion products of shotcrete after sulfate attack were observed by using the method of XRD, thermal analysis, and SEM, respectively, and the failure mode of shotcrete turned from ettringite destruction to ettringite-gypsum comprehensive failure. Meanwhile, the contents of ettringite and gypsum increased with increasing dry-wet cycle. Simultaneously, the stratified powders drilled from shotcrete under 150's dry-wet cycle were analyzed for the mineral phase composition and thermal analysis. With the drywet cycle increasing, the content of ettringite first increased and then decreased and tended to stable. However, the determination of gypsum decreased gradually and even to 0 when the depth was more than 12 mm.展开更多
In order to study the effect of different recycled fine aggregate and recycled coarse aggregate substitution rate on the sulfate resistance of recycled concrete under dry-wet cycle conditions,the substitution rate of ...In order to study the effect of different recycled fine aggregate and recycled coarse aggregate substitution rate on the sulfate resistance of recycled concrete under dry-wet cycle conditions,the substitution rate of recycled fine aggregate and recycled coarse aggregate was designed to be 0%/0%,10%/0%,0%/25%,10%/25%,0%/50%and 10%/50%of the six groups of mixture ratio.The mass loss rate and relative dynamic modulus of each group of test blocks were tested respectively and the optimal ratio was selected.The Wiener distribution probability method was used to establish the reliability function to optimize the remaining life of the ratio.The results show that the dynamic elastic modulus and mass show a trend of increasing first and then decreasing during the dry-wet cycles of sulfate.The recycled concrete has the strongest resistance to sulfate attack under the substitution rate of recycled fine aggregate and recycled coarse aggregate is 10%and 0%,and the test blocks will be damaged after being subjected to 182 times of dry-wet cycles of sulfate.The effect of recycled coarse aggregate on the sulfate attack resistance of the test block is more obvious than that of the recycled fine aggregate,which leads to the durability of the concrete being greatly reduced.展开更多
Saline soil is widely distributed in the marine sediments along the coast of the world and the arid-semi-arid areas of the Middle East and Iraq,and calcium sulfate erosion has become one of the important factors affec...Saline soil is widely distributed in the marine sediments along the coast of the world and the arid-semi-arid areas of the Middle East and Iraq,and calcium sulfate erosion has become one of the important factors affecting the durability of concrete in this area.In order to clarify the mechanism of sulfate ion damage to concrete,this paper mainly takes saline soil with high sulfate content in coastal area as well as arid-semi-arid area as the research object,and uses indoor geotechnical test,field test and numerical simulation to study the influence of different dry-wet cycle times on the unconfined compressive strength of concrete test blocks,and puts forward the relationship between the erosion arrival depth and time of sulfate ion in concrete,so as to predict the long-term erosion depth by using the erosion depth of sulfate ion in concrete in short time.The results show that the shorter the erosion time when the erosion reaches a certain depth,and the larger the erosion reaches when the erosion time is the same,the faster the erosion reaches the depth with the increase of erosion time.Compared with rectangular section concrete,circular section concrete penetrates faster.The results of this study can provide a reference for the durability design of concrete in saline soil sites containing sulfate.展开更多
The experiments of concrete attacked by sulfate solution under freeze-thaw cycles were investigated. The sulfate solution includes two types of 5% Na2SO4 and 5% MgSO4. Through the experiment, microstructural analyses ...The experiments of concrete attacked by sulfate solution under freeze-thaw cycles were investigated. The sulfate solution includes two types of 5% Na2SO4 and 5% MgSO4. Through the experiment, microstructural analyses such as SEM, XRD and TGA measurements were performed on the selected samples after freeze-thaw cycles. The corrosion products of the concrete were distinguished and quantitatively compared by the thermal analysis. Besides, the damage mechanism considering the dynamic modulus of elastically of concrete under the coupling effect was also investigated. The experimental results show that, under the action of freeze-thaw cycles and sulfate attack, the main attack products in concrete are ettringite and gypsum. The corrosion products exposed to MgSO4 solution are more than those to Na2SO4 solution. Furthermore, the content of gypsum in concrete is less than that of ettringite in test, and some of gypsum can be observed only after a certain corrosion extent. It is also shown that MgSO4 solution has a promoting effect to the damage of concrete under freeze-thaw cycles. Whereas for Na:SO4 solution, the damage of concrete has restrained before 300 freeze-thaw cycles, but the sulfate attack accelerates the deterioration process in its further test period.展开更多
基金Funded by the National Natural Science Foundation of China(No.51278403)the Program for Changjiang Scholars and Innovative Research Team in University(IRT 13089)the Doctor Innovation Foundation of Xi’an University of Architecture and Technology
文摘In order to research the sulfate attack resistance of shotcrete, the sulfate attack of shotcrete in the presence and absence of steel fiber was experimentally studied by using dry-wet cycle method. Meanwhile, compared with ordinary concrete by the same mixture, the difference of sulfate attack resistance of shotcrete was studied. The experimental results showed that, with dry-wet cycles increasing, the changes of loss rate of relative dynamic elastic modulus and mass loss rate of specimens included three stages: initial descent stage, stable stage, and rapid descent stage, respectively. However, the changes of mechanical properties first increased and then decreased. Furthermore, the corrosion products of shotcrete after sulfate attack were observed by using the method of XRD, thermal analysis, and SEM, respectively, and the failure mode of shotcrete turned from ettringite destruction to ettringite-gypsum comprehensive failure. Meanwhile, the contents of ettringite and gypsum increased with increasing dry-wet cycle. Simultaneously, the stratified powders drilled from shotcrete under 150's dry-wet cycle were analyzed for the mineral phase composition and thermal analysis. With the drywet cycle increasing, the content of ettringite first increased and then decreased and tended to stable. However, the determination of gypsum decreased gradually and even to 0 when the depth was more than 12 mm.
基金Supported by the National Natural Science Foundation of China(51468039,51868044)。
文摘In order to study the effect of different recycled fine aggregate and recycled coarse aggregate substitution rate on the sulfate resistance of recycled concrete under dry-wet cycle conditions,the substitution rate of recycled fine aggregate and recycled coarse aggregate was designed to be 0%/0%,10%/0%,0%/25%,10%/25%,0%/50%and 10%/50%of the six groups of mixture ratio.The mass loss rate and relative dynamic modulus of each group of test blocks were tested respectively and the optimal ratio was selected.The Wiener distribution probability method was used to establish the reliability function to optimize the remaining life of the ratio.The results show that the dynamic elastic modulus and mass show a trend of increasing first and then decreasing during the dry-wet cycles of sulfate.The recycled concrete has the strongest resistance to sulfate attack under the substitution rate of recycled fine aggregate and recycled coarse aggregate is 10%and 0%,and the test blocks will be damaged after being subjected to 182 times of dry-wet cycles of sulfate.The effect of recycled coarse aggregate on the sulfate attack resistance of the test block is more obvious than that of the recycled fine aggregate,which leads to the durability of the concrete being greatly reduced.
基金supported by the Fundamental Research Funds for the Central Universities(No.201962011)the Laboratory for Marine Geology,Qingdao National Labo-ratory for Marine Science and Technology(No.MGQN LM-KF201804)the National Natural Science Foundation of China(No.41672272).
文摘Saline soil is widely distributed in the marine sediments along the coast of the world and the arid-semi-arid areas of the Middle East and Iraq,and calcium sulfate erosion has become one of the important factors affecting the durability of concrete in this area.In order to clarify the mechanism of sulfate ion damage to concrete,this paper mainly takes saline soil with high sulfate content in coastal area as well as arid-semi-arid area as the research object,and uses indoor geotechnical test,field test and numerical simulation to study the influence of different dry-wet cycle times on the unconfined compressive strength of concrete test blocks,and puts forward the relationship between the erosion arrival depth and time of sulfate ion in concrete,so as to predict the long-term erosion depth by using the erosion depth of sulfate ion in concrete in short time.The results show that the shorter the erosion time when the erosion reaches a certain depth,and the larger the erosion reaches when the erosion time is the same,the faster the erosion reaches the depth with the increase of erosion time.Compared with rectangular section concrete,circular section concrete penetrates faster.The results of this study can provide a reference for the durability design of concrete in saline soil sites containing sulfate.
基金Funded by the Durability and Life Forecast of Shotcrete Tunnel Structure Fund(No.51278403)the Program for Changjiang Scholars and Innovative Research Team in University
文摘The experiments of concrete attacked by sulfate solution under freeze-thaw cycles were investigated. The sulfate solution includes two types of 5% Na2SO4 and 5% MgSO4. Through the experiment, microstructural analyses such as SEM, XRD and TGA measurements were performed on the selected samples after freeze-thaw cycles. The corrosion products of the concrete were distinguished and quantitatively compared by the thermal analysis. Besides, the damage mechanism considering the dynamic modulus of elastically of concrete under the coupling effect was also investigated. The experimental results show that, under the action of freeze-thaw cycles and sulfate attack, the main attack products in concrete are ettringite and gypsum. The corrosion products exposed to MgSO4 solution are more than those to Na2SO4 solution. Furthermore, the content of gypsum in concrete is less than that of ettringite in test, and some of gypsum can be observed only after a certain corrosion extent. It is also shown that MgSO4 solution has a promoting effect to the damage of concrete under freeze-thaw cycles. Whereas for Na:SO4 solution, the damage of concrete has restrained before 300 freeze-thaw cycles, but the sulfate attack accelerates the deterioration process in its further test period.