Attempts have been made to generate euchlorine gas by chlorate-chloride process and to utilize it further to clean up SO2 and NOx from the flue gas in a lab scale bubbling reactor. Preliminary experiments were carded ...Attempts have been made to generate euchlorine gas by chlorate-chloride process and to utilize it further to clean up SO2 and NOx from the flue gas in a lab scale bubbling reactor. Preliminary experiments were carded out to determine the gas and liquid phase mass transfer coefficients and their correlation equations have been established. Simultaneous removal of SO2 and NOx from the simulated flue gas using aqueous euchlorine scrubbing solution has been investigated. Euchlorine oxidized NO into NO2 completely and the later subsequently absorbed into the scrubbing solution in the form of nitrate. SO2 removal efficiency around 100% and NOx removal efficiency around 72% were achieved under optimal conditions. Mass balance has been confirmed by analyzing the sulfate, nitrate, euchlorine and chloride ion using ion chromatograph/auto-titrator and comparing it with their corresponding calculated values.展开更多
喷雾烟气脱硫过程中液滴在流场中运动时,在表面剪切力的作用下形成内部循环流动,影响液滴内部传质特性,进而影响雾滴吸收SO_2的过程.以单个悬浮液滴为研究对象,采用VOF(volume of fluid)方法计算了不同雷诺数下雾滴内部流动特性和SO_2...喷雾烟气脱硫过程中液滴在流场中运动时,在表面剪切力的作用下形成内部循环流动,影响液滴内部传质特性,进而影响雾滴吸收SO_2的过程.以单个悬浮液滴为研究对象,采用VOF(volume of fluid)方法计算了不同雷诺数下雾滴内部流动特性和SO_2气体在水雾雾滴内部的扩散,探讨了不同雷诺数下雾滴表面的速度分布以及雾滴内部循环流动对雾滴内部SO_2浓度分布的影响.数值计算结果表明:气流流场中的液滴与气流存在相对运动时,在表面剪切力的作用下液滴内部会产生2个相互对称的涡流,涡心距离液滴中心的距离为2/3R_d,涡流速度随着雷诺数的增加而增大.雾滴对SO_2的吸收过程受到2种机理的控制:一种是在浓度梯度推动下向雾滴内部的径向扩散;另一种是雾滴内部循环流动诱发的扩散传质.通过SO_2在雾滴中径向扩散时间与涡流形成的特征时间、内部循环流动诱发SO_2传质的特征时间的对比,表明在雾滴内部,循环涡流流动对吸附传质过程具有重要的影响,随着雷诺数的不断增加,雾滴内部循环流动对SO_2传质影响逐渐增大.展开更多
In this paper the rotating packed bed, a new type of absorber, which has high mass-transfer characteristic by means of centrifugal field instead of gravity field, is used to study on stimulated flue gas desulfurizatio...In this paper the rotating packed bed, a new type of absorber, which has high mass-transfer characteristic by means of centrifugal field instead of gravity field, is used to study on stimulated flue gas desulfurization. Based on experimental data,a model of mass-transfer and reaction of the sulfur dioxide chemical absorption in the rotating packed bed reactor is proposed according to the film-theory. It can be used to predict the performance of the total absorption rate and the enhancement factor of the sulfur dioxide and oxygen simultaneous absorption in the rotating packed bed reactor.The prediction of the model is consistent with the experimental result varying operating conditions, and the relative error between experimental result and predicted result is below 12%. Some interesting potential projects of simultaneous absorption of sulfur dioxide and oxygen in the rotating packed bed reactor are also discussed.展开更多
文摘Attempts have been made to generate euchlorine gas by chlorate-chloride process and to utilize it further to clean up SO2 and NOx from the flue gas in a lab scale bubbling reactor. Preliminary experiments were carded out to determine the gas and liquid phase mass transfer coefficients and their correlation equations have been established. Simultaneous removal of SO2 and NOx from the simulated flue gas using aqueous euchlorine scrubbing solution has been investigated. Euchlorine oxidized NO into NO2 completely and the later subsequently absorbed into the scrubbing solution in the form of nitrate. SO2 removal efficiency around 100% and NOx removal efficiency around 72% were achieved under optimal conditions. Mass balance has been confirmed by analyzing the sulfate, nitrate, euchlorine and chloride ion using ion chromatograph/auto-titrator and comparing it with their corresponding calculated values.
文摘喷雾烟气脱硫过程中液滴在流场中运动时,在表面剪切力的作用下形成内部循环流动,影响液滴内部传质特性,进而影响雾滴吸收SO_2的过程.以单个悬浮液滴为研究对象,采用VOF(volume of fluid)方法计算了不同雷诺数下雾滴内部流动特性和SO_2气体在水雾雾滴内部的扩散,探讨了不同雷诺数下雾滴表面的速度分布以及雾滴内部循环流动对雾滴内部SO_2浓度分布的影响.数值计算结果表明:气流流场中的液滴与气流存在相对运动时,在表面剪切力的作用下液滴内部会产生2个相互对称的涡流,涡心距离液滴中心的距离为2/3R_d,涡流速度随着雷诺数的增加而增大.雾滴对SO_2的吸收过程受到2种机理的控制:一种是在浓度梯度推动下向雾滴内部的径向扩散;另一种是雾滴内部循环流动诱发的扩散传质.通过SO_2在雾滴中径向扩散时间与涡流形成的特征时间、内部循环流动诱发SO_2传质的特征时间的对比,表明在雾滴内部,循环涡流流动对吸附传质过程具有重要的影响,随着雷诺数的不断增加,雾滴内部循环流动对SO_2传质影响逐渐增大.
文摘In this paper the rotating packed bed, a new type of absorber, which has high mass-transfer characteristic by means of centrifugal field instead of gravity field, is used to study on stimulated flue gas desulfurization. Based on experimental data,a model of mass-transfer and reaction of the sulfur dioxide chemical absorption in the rotating packed bed reactor is proposed according to the film-theory. It can be used to predict the performance of the total absorption rate and the enhancement factor of the sulfur dioxide and oxygen simultaneous absorption in the rotating packed bed reactor.The prediction of the model is consistent with the experimental result varying operating conditions, and the relative error between experimental result and predicted result is below 12%. Some interesting potential projects of simultaneous absorption of sulfur dioxide and oxygen in the rotating packed bed reactor are also discussed.
