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Effect of boron addition on the MoO_3/CeO_2–Al_2O_3 catalyst in the sulfur-resistant methanation 被引量:2
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作者 Baowei Wang Wenxia Yu +3 位作者 Weihan Wang Zhenhua Li Yan Xu Xinbin Ma 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第3期509-513,共5页
The effect of boron on the performance of MoO_3/CeO_2–Al_2O_3 catalysts, which were prepared with impregnation method, was investigated. The catalysts were characterized with N_2 adsorption–desorption, XRD, H_2-TPR,... The effect of boron on the performance of MoO_3/CeO_2–Al_2O_3 catalysts, which were prepared with impregnation method, was investigated. The catalysts were characterized with N_2 adsorption–desorption, XRD, H_2-TPR, and NH_3-TPD, and were tested in sulfur-resistant methanation. The results indicated that the MoO_3/CeO_2–Al_2O_3 catalysts modified by boron showed higher catalytic performance in sulfur-resistant methanation. The CO conversion increased from 47% to 62% with 0.5 wt% boron content. When the content of boron was under 0.5 wt%, the results suggested there was an increase in the amorphous form of MoO_3 caused by the generation of weak and intermediate acid sites, which had weakened the interaction between the active components and supports. While, the catalyst added 2.0 wt% boron showed the strong acid sites and the largest crystalline size resulting in the uneven distribution of ceria. 展开更多
关键词 Boron sulfur-resistant Methanation Mo-based catalyst Composite support
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Strong metal-support interactions between highly dispersed Cu^(+) species and ceria via mix-MOF pyrolysis toward promoted water-gas shift reaction
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作者 Xiao-Chen Sun Xing-Chi Li +7 位作者 Ze-Wei Xie Chen-Yue Yuan De-Jiu Wang Qian Zhang Xiao-Yu Guo Hao Dong Hai-Chao Liu Ya-Wen Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期475-483,共9页
The modulation of metal-support interfacial interaction is significant but challenging in the design of high-efficiency and high-stability supported catalysts.Here,we report a synthetic strategy to upgrade Cu-CeO_(2)i... The modulation of metal-support interfacial interaction is significant but challenging in the design of high-efficiency and high-stability supported catalysts.Here,we report a synthetic strategy to upgrade Cu-CeO_(2)interfacial interaction by the pyrolysis of mixed metal-organic framework(MOF)structure.The obtained highly dispersed Cu/CeO_(2)-MOF catalyst via this strategy was used to catalyze water-gas shift reaction(WGSR),which exhibited high activity of 40.5μmolCOgcat^(-1).s^(-1)at 300℃and high stability of about 120 h.Based on comprehensive studies of electronic structure,pyrolysis strategy has significant effect on enhancing metal-support interaction and then stabilizing interfacial Cu^(+)species under reaction conditions.Abundant Cu^(+)species and generated oxygen vacancies over Cu/CeO_(2)-MOF catalyst played a key role in CO molecule activation and H2O molecule dissociation,respectively.Both collaborated closely and then promoted WGSR catalytic performance in comparison with traditio nal supported catalysts.This study shall offer a robust approach to harvest highly dispersed catalysts with finely-tuned metal-support interactions for stabilizing the most interfacial active metal species in diverse heterogeneous catalytic reactions. 展开更多
关键词 Cu-based catalyst MOF derivative Water-gas shift reaction Metal-support interaction
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Effect of Mg/Al atom ratio of support on catalytic performance of Co-Mo/MgO-Al_2O_3 catalyst for water gas shift reaction 被引量:6
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作者 Yixin Lian Huifang Wang Quanxing Zheng Weiping Fang Yiquan Yang 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2009年第2期161-166,共6页
Co-Mo-based catalysts supported on mixed oxide supports MgO-Al2O3 with different Mg/Al atom ratios for water gas shift reaction were studied by means of TPR, Raman, XPS and ESR. It was found that the octahedral Mo spe... Co-Mo-based catalysts supported on mixed oxide supports MgO-Al2O3 with different Mg/Al atom ratios for water gas shift reaction were studied by means of TPR, Raman, XPS and ESR. It was found that the octahedral Mo species in oxidized Co-Mo/MgO(x)-Al2O3 catalyst and the contents of Mo^5+, Mo^4+, S^2- and S^2-2 species in the functioning catalysts increased with increasing the Mg/Al atom ratio of the support under the studied experimental conditions. This is favorable for the formation of the active Co-Mo-S phase of the catalysts. Catalytic performance testing results showed that the catalysts Co-Mo/MgO-Al2O3 with the Mg/Al atom ratio of the support in the range of 0.475-0.525 exhibited optimal catalytic activity for the reaction. 展开更多
关键词 Co-Mo catalyst reduction SULFIDATION mixed support water gas shift
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Catalytic Reduction of CO2 to CO via Reverse Water Gas Shift Reaction:Recent Advances in the Design of Active and Selective Supported Metal Catalysts 被引量:14
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作者 Min Zhu Qingfeng Ge Xinli Zhu 《Transactions of Tianjin University》 EI CAS 2020年第3期172-187,共16页
The catalytic conversion of CO2 to CO via a reverse water gas shift(RWGS)reaction followed by well-established synthesis gas conversion technologies may provide a potential approach to convert CO2 to valuable chemical... The catalytic conversion of CO2 to CO via a reverse water gas shift(RWGS)reaction followed by well-established synthesis gas conversion technologies may provide a potential approach to convert CO2 to valuable chemicals and fuels.However,this reaction is mildly endothermic and competed by a strongly exothermic CO2 methanation reaction at low temperatures.Therefore,the improvement in the low-temperature activities and selectivity of the RWGS reaction is a key challenge for catalyst designs.We reviewed recent advances in the design strategies of supported metal catalysts for enhancing the activity of CO2 conversion and its selectivity to CO.These strategies include varying support,tuning metal–support interactions,adding reducible transition metal oxide promoters,forming bimetallic alloys,adding alkali metals,and enveloping metal particles.These advances suggest that enhancing CO2 adsorption and facilitating CO desorption are key factors to enhance CO2 conversion and CO selectivity.This short review may provide insights into future RWGS catalyst designs and optimization. 展开更多
关键词 Carbon dioxide REVERSE water gas shift reaction METHANATION SUPPORTED metal catalyst Mechanism
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Water gas shift activity of Co-Mo/MgO-Al_2O_3 catalysts presulfided with ammonium sulfide 被引量:4
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作者 Yixin Lian, Huifang Wang, Weiping Fang, Yiquan Yang Department of Chemistry, College of Chemistry and Chemical Engineering, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Xiamen University, Xiamen 361005, Fujian, China 《Journal of Natural Gas Chemistry》 CSCD 2010年第1期61-66,共6页
Co-Mo/MgO-Al2O3 catalyst was presulfided with ammonium sulfide in aqueous solution and activated with synthesis gas for water gas shift reaction. The assay results indicate that the presulfided Co-Mo/MgO-Al2O3 catalys... Co-Mo/MgO-Al2O3 catalyst was presulfided with ammonium sulfide in aqueous solution and activated with synthesis gas for water gas shift reaction. The assay results indicate that the presulfided Co-Mo/MgO-Al2O3 catalyst exhibits an excellent catalytic activity and stability. XRD and EPR characterization results show that the O-S exchange might occur during the impregnation, leading to the formation of (NH4)2MoS4 (or (NH4)zMoxSy) precursor, which was then thermally decomposed and reduced to MoS2. The higher catalytic performance is attributed to an optimization formation of active Co-Mo sulfides, consisting of well dispersed MoS2 and Co-Mo-S phase due to the redispersion of Co sulfide particles over the edges of newly formed MoS2 crystallites. 展开更多
关键词 Co-Mo-based catalyst ammonium sulfide presulfidation water-gas shift
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A Novel γ-Alumina Supported Fe-Mo Bimetallic Catalyst for Reverse Water Gas Shift Reaction 被引量:10
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作者 Abolfazl Gharibi Kharaji Ahmad Shariati Mohammad Ali Takassi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第9期1007-1014,共8页
In reverse water gas shift (RWGS) reaction COa is converted to CO which in turn can be used to pro- duce beneficial chemicals such as methanol. In the present study, Mo/AlaO3, Fe/AlaO3 and Fe-Mo/Al2O3 catalysts were... In reverse water gas shift (RWGS) reaction COa is converted to CO which in turn can be used to pro- duce beneficial chemicals such as methanol. In the present study, Mo/AlaO3, Fe/AlaO3 and Fe-Mo/Al2O3 catalysts were synthesised using impregnation method. The structures of catalysts were studied using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) method, inductively coupled plasma atomic emission spectrometer (ICP-AES), temperature programmed reduction (H2-TPR), CO chemisorption, energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) techniques. Kinetic properties of all catalysts were investigated in a batch re- actor for RWGS reaction. The results indicated that Mo existence in structure of Fe-Mo/AlzO3 catalyst enhances its activity as compared to Fe/AlaO3. This enhancement is probably due to better Fe dispersion and smaller particle size of Fe species. Stability test of Fe-Mo/AlzO3 catalyst was carried out in a fixed bed reactor and a high CO yield for 60 h of time on stream was demonstrated. Fez(MoO4)3 phase was found in the structures of fresh and used catalysts. TPR results also indicate that Fez(MoO4)3 phase has low reducibility, therefore the Fe2(MoO4)3 phase significantly inhibits the reduction of the remaining Fe oxides in the catalyst, resulted in high stability of Fe-Mo/Al2O3 catalyst. Overall, this study introduces Fe-Mo/Al2O3 as a novel catalyst with high CO yield, almost no by-products and fairly stable for RWGS reaction. 展开更多
关键词 reverse water gas shift reaction Fe-Mo/Al2O3 catalyst SELECTIVITY stability REDUCIBILITY
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Effects of Cerium on Reduction of Non-Chromium Iron Based CO Shift Catalyst 被引量:2
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作者 苏运来 胡捷 +2 位作者 马卓娜 杜宝石 郭益群 《Journal of Rare Earths》 SCIE EI CAS CSCD 2001年第4期304-307,共4页
The effects of Ce on reduction of non-chromium iron based CO shift catalyst were studied by XRD, TPR, SEM and XPS. The results show that Ce refines Fe2O3 grains and riches on the surface of catalyst in the process of ... The effects of Ce on reduction of non-chromium iron based CO shift catalyst were studied by XRD, TPR, SEM and XPS. The results show that Ce refines Fe2O3 grains and riches on the surface of catalyst in the process of reduction, which leads to decrease of the initial reductive temperature and increase of the final reductive temperature. 展开更多
关键词 rare earths CERIUM ABSORPTION activity CO shift catalyst
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Effect of Addition Sequence during Neutralization and Precipitation on Iron-based Catalysts for High Temperature Shift Reaction 被引量:1
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作者 Li Wei Zhu Jianhua Mou Zhanjun 《Petroleum Science》 SCIE CAS CSCD 2007年第1期75-80,共6页
The preparation of the iron-based catalysts promoted by cobalt with a small amount of copper and aluminum for the high temperature shift reaction (HTS) with different sequences of adding catalyst raw materials durin... The preparation of the iron-based catalysts promoted by cobalt with a small amount of copper and aluminum for the high temperature shift reaction (HTS) with different sequences of adding catalyst raw materials during neutralization and precipitation was investigated. XRD, BET and particle size distribution (PSD) were used to characterize the prepared catalysts. It was found that the catalyst crystals were all γ-Fe2O3, and the intermediate of the catalyst after aging was Fe3O4. The crystallographic form of the catalyst and its intermediate was not affected by the addition sequence in the neutralization and precipitation process. The results showed that the specific surface area and the particle size of the catalysts depended on the addition sequence to the mother liquor. Cobalt with a small amount of copper and aluminum could increase the specific surface area and decrease the particle size of catalysts. 展开更多
关键词 Water gas shift reaction Γ-FE2O3 cobalt-promoted catalyst iron-based catalyst
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Boosting the water gas shift reaction on Pt/CeO_(2)-based nanocatalysts by compositional modification: Support doping versus bimetallic alloying 被引量:3
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作者 Kun Yuan Xiao-Chen Sun +4 位作者 Hai-Jing Yin Liang Zhou Hai-Chao Liu Chun-Hua Yan Ya-Wen Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第4期241-249,共9页
The water gas shift reaction is of vital significance for the generation and transition of energy due to the application in hydrogen production and industries such as ammonia synthesis and fuel cells.The influence of ... The water gas shift reaction is of vital significance for the generation and transition of energy due to the application in hydrogen production and industries such as ammonia synthesis and fuel cells.The influence of support doping and bimetallic alloying on the catalytic performance of Pt/Ce O_(2)-based nanocatalysts in water gas shift reaction was reported in this work.Various lanthanide ions and 3d transition metals were respectively introduced into the Ce O_(2)support or Pt to form Pt/Ce O_(2):Ln(Ln=La,Nd,Gd,Tb,Yb)and Pt M/Ce O_(2)(M=Fe,Co,Ni)nanocatalysts.The sample of Pt/Ce O_(2):Tb showed the highest activity(TOF at 200℃=0.051 s^(-1))among the Pt/Ce O_(2):Ln and the undoped Pt/Ce O_(2)catalysts.Besides,the sample of Pt Fe/Ce O_(2)exhibited the highest activity(TOF at 200℃=0.12 s^(-1))among Pt M/Ce O_(2)catalysts.The results of the multiple characterizations indicated that the catalytic activity of Pt/Ce O_(2):Ln catalysts was closely correlated with the amount of oxygen vacancies in doped ceria support.However,the different activity of Pt M/Ce O_(2)bimetallic catalysts was owing to the various Pt oxidation states of the bimetals dispersed on ceria.The study of the reaction pathway indicated that both the samples of Pt/Ce O_(2)and Pt/Ce O_(2):Tb catalyzed the reaction through the formate pathway,and the enhanced activity of the latter derived from the increased concentration of oxygen vacancies along with promoted water dissociation.As for the sample of Pt Fe/Ce O_(2),its catalytic mechanism was the carboxyl route with a higher reaction rate due to the moderate valence of Pt along with improved CO activation. 展开更多
关键词 Pt/CeO_(2)catalysts Water–gas shift reaction Support doping Bimetallic alloying
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Effects of ZrO_2 Content on Structure and Performance of Cu/CeO_2-ZrO_2 Catalysts for Water-Gas Shift Reaction 被引量:1
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作者 郑云弟 林性贻 +3 位作者 郑起 詹瑛瑛 李达林 魏可镁 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第6期685-689,共5页
Cu/CeO2-ZrO2 catalysts for water-gas shift (WGS) reaction were prepared with co-precipitation method, and the influence of ZrO2 content on the catalytic structure and properties was investigated by the techniques of... Cu/CeO2-ZrO2 catalysts for water-gas shift (WGS) reaction were prepared with co-precipitation method, and the influence of ZrO2 content on the catalytic structure and properties was investigated by the techniques of N2 physical adsorption analysis, XRD and H2-TPR. The results indicate that the BET surface areas of the catalysts are increased in varying degrees due to the presence of ZrO2. With increasing ZrO2 content, the pore size distribution is centered on 1.9 nm. ZrO2 can efficiently restrain the growth of Cu crystal particles. The appropriate amount of ZrO2 in the Cu/CeO2 catalysts can help the catalyst keep better copper dispersion in the WGS reaction, which can lead to both higher catalytic activity and better thermal stability. When ZrO2 content is 10% (atom fraction), Cu/CeO2-Zr02 catalyst reaches a CO conversion rate of 73.7% at the reaction temperature of 200℃. 展开更多
关键词 water-gas shift Cu/CeO2-ZrO2 catalyst rare earths
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Promotion effect of Re additive on the bifunctional Ni catalysts for methanation coupling with water gas shift of biogas: Insights from activation energy 被引量:1
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作者 Xinxin Dong Baosheng Jin +1 位作者 Zhiwei Kong Yiqing Sun 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2020年第6期1628-1636,共9页
The cheap manganese sand was first modified by H2O2 and was further creatively utilized as Ni-based catalyst support.In order to enhance the catalytic performance,Re was added into the Ni-based catalyst and the promot... The cheap manganese sand was first modified by H2O2 and was further creatively utilized as Ni-based catalyst support.In order to enhance the catalytic performance,Re was added into the Ni-based catalyst and the promotion effect of Re on the methanation coupling with water gas shift of biogas was investigated from the perspective of activation energy.It was found that CH4 and CO2 formation rates,which separately represented the reaction rate of methanation and water gas shift,were both enhanced after Re addition compared to non-added catalyst.Two kinetics models including empirical model and K-model were employed and from the results of calculation,it showed that Re selectively decreased the activation energy of methanation reaction and had little impact on the activation energy of water gas shift.The increased CO2 formation rate was owing to the assistance of accelerated H2O production from methanation rather than the activation energy change in water gas shift. 展开更多
关键词 PROMOTER catalyst Nickel METHANATION Water gas shift Kinetics
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Kinetics of the water-gas shift reaction in Fischer-Tropsch synthesis over a nano-structured iron catalyst 被引量:2
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作者 Ali Nakhaei Pour Mohammad Reza Housaindokht +1 位作者 Sayyed Faramarz Tayyari Jamshid Zarkesh 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2010年第4期362-368,共7页
Based on formate and direct oxidation mechanisms,three Langmuir-Hinshelwood-Hougen-Watson (LHHW) kinetic models of the water-gasshift (WGS) reaction over a nano-structured iron catalyst under Fischer-Tropsch synth... Based on formate and direct oxidation mechanisms,three Langmuir-Hinshelwood-Hougen-Watson (LHHW) kinetic models of the water-gasshift (WGS) reaction over a nano-structured iron catalyst under Fischer-Tropsch synthesis (FTS) reaction conditions were derived and compared with those over the conventional catalyst.The conventional and nanostructured Fe/Cu/La/Si catalysts were prepared by co-precipitation of Fe and Cu nitrates in aqueous media and water-oil micro-emulsion,respectively.The WGS kinetic data were measured by experiments over a wide range of reaction conditions and comparisons were also made for various rate equations.WGS rate expressions based on the formate mechanism with the assumption that the formation of formate is rate determining step were found to be the best. 展开更多
关键词 KINETICS water-gas-shift reaction iron catalyst Fischer-Tropsch synthesis
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For more and purer hydrogen-the progress and challenges in water gas shift reaction 被引量:2
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作者 Limin Zhou Yanyan Liu +8 位作者 Shuling Liu Huanhuan Zhang Xianli Wu Ruofan Shen Tao Liu Jie Gao Kang Sun Baojun Li Jianchun Jiang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第8期363-396,I0010,共35页
The water gas shift(WGS) reaction is a standard reaction that is widely used in industrial hydrogen production and removal of carbon monoxide. The improved catalytic performance of WGS reaction also contributes to amm... The water gas shift(WGS) reaction is a standard reaction that is widely used in industrial hydrogen production and removal of carbon monoxide. The improved catalytic performance of WGS reaction also contributes to ammonia synthesis and other reactions. Advanced catalysts have been developed for both high and low-temperature reactions and are widely used in industry. In recent years, supported metal nanoparticle catalysts have been researched due to their high metal utilization. Low-temperature catalysts have shown promising results, including high selectivity, high shift rates, and higher activity potential. Additionally, significant progress has been made in removing trace CO through the redox reaction in electrolytic cell. This paper reviews the development of WGS reaction catalysts, including the reaction mechanism, catalyst design, and innovative research methods. The catalyst plays a crucial role in the WGS reaction, and this paper provides an instant of catalyst design under different conditions. The progress of catalysts is closely related to the development of advanced characterization techniques.Furthermore, modifying the catalyst surface to enhance activity and significantly increase reaction kinetics is a current research direction. This review goals to stimulate a better understanding of catalyst design, performance optimization, and driving mechanisms, leading to further progress in this field. 展开更多
关键词 Water gas shift reaction Hydrogen production Heterogeneous catalysis Reaction Mechanism Single atomic catalysts
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Effect of yttrium addition on water-gas shift reaction over CuO/CeO_2 catalysts
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作者 佘育生 李雷 +3 位作者 詹瑛瑛 林性贻 郑起 魏可镁 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第3期412-418,共7页
This paper presented a study on the role of yttrium addition to CuO/CeO2 catalyst for water-gas shift reaction. A single-step co-precipitation method was used for preparation of a series of yttrium doped CuO/CeO2 cata... This paper presented a study on the role of yttrium addition to CuO/CeO2 catalyst for water-gas shift reaction. A single-step co-precipitation method was used for preparation of a series of yttrium doped CuO/CeO2 catalysts with yttrium content in the range of 0-5wt.%. Properties of the obtained samples were characterized and analyzed by X-ray diffraction (XRD), Raman spectroscopy, H2-TPR, cyclic voltammetry (CV) and the BET method. The results revealed that catalytic activity was increased with the yttrium content at first, but then decreased with the further increase of yttrium content. Herein, CuO/CeO2 catalyst doped with 2wt.% of yttrium showed the highest catalytic activity (CO conversion reaches 93.4% at 250 ℃) and thermal stability for WGS reaction. The catalytic activity was correlated with the surface area, the area of peak γ of H2-TPR profile (i.e., the reduction of surface copper oxide (crystalline forms) interacted with surface oxygen vacancies on ceria), and the area of peak C2 and A1 (Cu^0→←Cu^2+ in cyclic voltammetry process), respectively. Besides, Raman spectra provided evidences for a synergistic Cu-Ovacancy interaction, and it was indicated that doping yttrium may facilitate the formation of oxygen vacancies on ceria. 展开更多
关键词 CuO/CeO2 catalyst water-gas shift YTTRIUM cyclic voltammetry rare earths
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Potassium-decorated active carbon supported Co-Mo-based catalyst for water-gas shift reaction
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作者 Yixin Lian RuiFen Xiao +1 位作者 Weiping Fang Yiquan Yang 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2011年第1期77-83,共7页
The effect of potassium-decoration was studied on the activity of water-gas shift (WGS) reaction over the Co-Mo-based catalysts supported on active carbon (AC), which was prepared by incipient wetness co-impregnat... The effect of potassium-decoration was studied on the activity of water-gas shift (WGS) reaction over the Co-Mo-based catalysts supported on active carbon (AC), which was prepared by incipient wetness co-impregnation method. The decoration of potassium on active carbon in advance enhances the activities of the CoMo-K/AC catalysts for WGS reaction. Highest activity (about 92% conversion) was obtained at 250 ? C for the catalyst with an optimum K 2 O/AC weight ratio in the range from 0.12 to 0.15. The catalysts were characterized by TPR and EPR, and the results show that activated carbon decorated with potassium makes Co-Mo species highly dispersed, and thus easily reduced and sulfurized. XRD results show that an appropriate content of potassium-decoration on active carbon supports may favors the formation of highly dispersed Co 9 S 8 -type structures which are situated on the edge or a site in contact with MoS 2 , K-Mo-O-S, Mo-S-K phase. Those active species are responsible for the high activity of CoMo-K/AC catalysts. 展开更多
关键词 active carbon potassium-decorated active phase Co-Mo-based catalyst water-gas shift
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Influence of Gas Components on the Formation of Carbonyl Sulfide over Water-Gas Shift Catalyst B303Q
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作者 Ju Shangguan Litong Liang Huiling Fan Fang Shen 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第1期53-59,共7页
Water-gas shift reaction catalyst at lower temperature (200-400 ℃) may improve the conversion of carbon monoxide. But carbonyl sulfide was found to be present over the sulfided cobaltmolybdenum/alumina catalyst for... Water-gas shift reaction catalyst at lower temperature (200-400 ℃) may improve the conversion of carbon monoxide. But carbonyl sulfide was found to be present over the sulfided cobaltmolybdenum/alumina catalyst for water-gas shift reaction. The influences of temperature, space velocity, and gas components on the formation of carbonyl sulfide over sulfided cobalt-molybdenum/alumina catalyst B303Q at 200-400 ℃ were studied in a tubular fixed-bed quartz-glass reactor under simulated water-gas shift conditions. The experimental results showed that the yield of carbonyl sulfide over B303Q catalyst reached a maximum at 220 ℃ with the increase in temperature, sharply decreased with the increase in space velocity and the content of water vapor, increased with the increase in the content of carbon monoxide and carbon dioxide, and its yield increased and then reached a stable value with the increase in the content of hydrogen and hydrogen sulfide. The formation mechanism of carbonyl sulfide over B303Q catalyst at 200-400 ℃ was discussed on the basis of how these factors influence the formation of COS. The yield of carbonyl sulfide over B303Q catalyst at 200-400 ℃ was the combined result of two reactions, that is, COS was first produced by the reaction of carbon monoxide with hydrogen sulfide, and then the as-produced COS was converted to hydrogen sulfide and carbon dioxide by hydrolysis. The mechanism of COS formation is assumed as follows: sulfur atoms in the Co9Ss-MoS2/Al2O3 crystal lattice were easily removed and formed carbonyl sulfide with CO, and then hydrogen sulfide in the water-gas shift gas reacted with the crystal lattice oxygen atoms in CoO-MoOa/Al2O3 to form Co9S8-MoS2/Al2O3. This mechanism for the formation of COS over water-gas shift catalyst B303Q is in accordance with the Mars-Van Krevelen's redox mechanism over metal sulfide. 展开更多
关键词 FORMATION carbonyl sulfide sulfided cobalt-molybdenum/alumina catalyst water-gas shift
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Performance and Industrial Application of New-Type Sulfur Tolerant CO Shift Catalyst QDB-04
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作者 Bonan Liu Tiancun Xiao +3 位作者 Peter P. Edwards Jiefei Xiao Gao Hui Qiuyun Zong 《Open Journal of Inorganic Chemistry》 2016年第1期15-22,共8页
This paper presents the performance and characteristics of new-type sulfur tolerant shift catalyst QDB-04 and its industrial side-line test as well as the first-time industrial application in Lunan Chemical Fertilizer... This paper presents the performance and characteristics of new-type sulfur tolerant shift catalyst QDB-04 and its industrial side-line test as well as the first-time industrial application in Lunan Chemical Fertilizer Plant of Shandong in China. The results show that the catalyst has high strength and strength stability, good low temperature activity and stability as well as low potassium bleeding ratio which well meet for the requirements of the methanol plant on catalyst performance in Lunan Chemical Fertilizer Plant. 展开更多
关键词 Sulfur Tolerant shift catalyst PERFORMANCE Industrial Side-Line Test Application
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Computational Screening of Pt1@Ti_(3)C_(2)T_(2)(T=O,S)MXene Catalysts for Water-Gas Shift Reaction 被引量:1
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作者 Yang Meng Haiyan Wang +2 位作者 Jin-Xia Liang Chun Zhu Jun Li 《Precision Chemistry》 2024年第2期70-80,共11页
Single-atom catalysts(SACs)provide an oppor-tunity to elucidate the catalytic mechanism of complex reactions in heterogeneous catalysis.The low-temperature water-gas shift(WGS)reaction is an important industrial techn... Single-atom catalysts(SACs)provide an oppor-tunity to elucidate the catalytic mechanism of complex reactions in heterogeneous catalysis.The low-temperature water-gas shift(WGS)reaction is an important industrial technology to obtain high purity hydrogen.Herein,we study the catalytic activity of Pt1@Ti_(3)C_(2)T_(2)(T=O,S)SACs,where one subsurface Ti atom with three T vacancies in the functionalized Ti_(3)C_(2)T_(2)(T=O,S)MXene is substituted by one Pt atom,for the low-temperature show that Pt1@Ti_(3)C_(2)T_(2)provides an excellent platform for the WGS reaction by its bowl-shaped vacancy derived from the Pt1 single atom and three T defects surrounding it.Especially,Pt1@Ti_(3)C_(2)S_(2)SAC has higher catalytic performance for the WGS reaction,due to the weaker electronegativity of the S atom than the O atom,which significantly reduces the energy barrier of H*migration in the WGS reaction,which is often the rate-determining step.In the most favorable redox mechanism of the WGS reaction on Pt1@Ti_(3)C_(2)S_(2),the rate-determining step is the dissociation of OH*into O*and H*with the energy barrier as low as 1.12 eV.These results demonstrate that Pt1@Ti_(3)C_(2)S_(2)is promising in the application of MXenes for low-temperature WGS reactions. 展开更多
关键词 single-atom catalyst(SAC) density functional theory(DFT) water gas shift(WGS)reaction defective MXene thermocatalysis
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吸附强化水气变换制氢复合催化剂研究进展
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作者 张金鹏 屈婷 +1 位作者 荆洁颖 李文英 《化工进展》 EI CAS CSCD 北大核心 2024年第5期2629-2644,共16页
吸附强化水气变换反应(SEWGS)是实现高纯氢制备及二氧化碳(CO_(2))减排的关键反应之一。SEWGS借助复合催化剂将水气变换反应(制氢)和原位移除CO_(2)反应(脱碳)耦合,打破热力学限制使反应平衡向制氢侧移动。SEWGS具有一步制取高纯氢气的... 吸附强化水气变换反应(SEWGS)是实现高纯氢制备及二氧化碳(CO_(2))减排的关键反应之一。SEWGS借助复合催化剂将水气变换反应(制氢)和原位移除CO_(2)反应(脱碳)耦合,打破热力学限制使反应平衡向制氢侧移动。SEWGS具有一步制取高纯氢气的特点,但复合催化剂在连续操作过程中由于烧结和CO_(2)扩散受阻存在循环稳定性下降的问题,进而影响制氢效率。本文阐述了高温Ni/CaO基复合催化剂吸附强化制氢的研究现状,简述了Fe/CaO基复合催化剂SEWGS制氢面临的主要问题,回顾了中温Cu/MgO基和Cu/类水滑石基复合催化剂的SEWGS制氢现状及现阶段的核心问题。从复合催化剂的催化组分和吸附组分角度,分析了SEWGS制氢过程中复合催化剂循环稳定性降低的原因,简述了现阶段最有效的改性手段。进一步从增强CO_(2)扩散和改善烧结角度入手,围绕复合催化剂设计、操作条件和床层装填方式等方面探讨提高复合催化剂循环稳定性的策略。指出设计开发组成简单、易制备、兼具高活性和高稳定性的复合催化剂实现制氢和脱碳耦合是今后SEWGS制氢的研究方向。 展开更多
关键词 制氢 复合催化剂 水气变换反应 吸附强化 CO_(2)扩散 烧结 稳定性
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QDB-06型耐硫变换催化剂在等温变换装置上的工业应用
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作者 葛超伟 沈忠全 +3 位作者 刘天亮 张峰 侯玉婷 高辉 《肥料与健康》 CAS 2024年第3期51-55,共5页
合成氨变换装置由四段绝热耐硫变换改造为等温变换后,催化剂改用QDB-06型耐硫变换催化剂。介绍了等温变换装置的工艺流程、催化剂的装填及升温硫化。6个多月的实际运行情况表明,QDB-06型耐硫变换催化剂具有良好的低温活性、颗粒强度和... 合成氨变换装置由四段绝热耐硫变换改造为等温变换后,催化剂改用QDB-06型耐硫变换催化剂。介绍了等温变换装置的工艺流程、催化剂的装填及升温硫化。6个多月的实际运行情况表明,QDB-06型耐硫变换催化剂具有良好的低温活性、颗粒强度和强度稳定性,完全可以满足变换深度和等温变换工况的要求。 展开更多
关键词 耐硫变换催化剂 QDB-06型 等温变换 变换深度 工业应用
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