Thermal behavior of bulk amorphous sulfur is investigated by in situ temperature measurements at high pressures of 0.9, 1.4 and 2.1 GPa, and under different heating rates of 8, 10 and 12K/min at 0.9 GPa. The results s...Thermal behavior of bulk amorphous sulfur is investigated by in situ temperature measurements at high pressures of 0.9, 1.4 and 2.1 GPa, and under different heating rates of 8, 10 and 12K/min at 0.9 GPa. The results show that the onset temperature of the transition from the supercooled Hquid to the liquid state for sulfur increases with the pressure and the heating rate. It is deduced that the transition does not follow the Clapeyron equation, indicating considerable coupling of the molecular structure change in the transition. Along with the data at ambient pressure and high pressure, we present a dynamic diagram to demonstrate the relationship between the amorphous solid, supercooled liquid, liquid, and crystal phases of sulfur, and suggest an experimental approach to establish pressure-temperature-time transition diagrams for supercooled liquid and liquid.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 11004163the Fundamental Research Funds for the Central Universities under Grant No 2682014ZT31
文摘Thermal behavior of bulk amorphous sulfur is investigated by in situ temperature measurements at high pressures of 0.9, 1.4 and 2.1 GPa, and under different heating rates of 8, 10 and 12K/min at 0.9 GPa. The results show that the onset temperature of the transition from the supercooled Hquid to the liquid state for sulfur increases with the pressure and the heating rate. It is deduced that the transition does not follow the Clapeyron equation, indicating considerable coupling of the molecular structure change in the transition. Along with the data at ambient pressure and high pressure, we present a dynamic diagram to demonstrate the relationship between the amorphous solid, supercooled liquid, liquid, and crystal phases of sulfur, and suggest an experimental approach to establish pressure-temperature-time transition diagrams for supercooled liquid and liquid.
