Sulfonylcalix[4]arenes-based coordination containers,namely metal-organic supercontainers(MOSCs),are a new class of coordination containers constructed from the self-assembly of divalent metal ions,suitable carboxylat...Sulfonylcalix[4]arenes-based coordination containers,namely metal-organic supercontainers(MOSCs),are a new class of coordination containers constructed from the self-assembly of divalent metal ions,suitable carboxylate linkers,and sulfonylcalix[4]arenes container precursor.MOSCs feature both endo cavity surrounded by carboxylate linkers and exo cavities originated from the upper rim of sulfonylcalix[4]arenes.The molecular topologies and endo cavity of MOSCs are tuneable via judicious design of carboxylate linkers,while the modulation of endo cavity are accessible by chemical modification on the para substituent group of the sulfonylcalix[4]arenes.In this paper,recent advances and typical examples of design and functionalization of MOSCs are presented.展开更多
基金supported by the National Natural Science Foundation of China(21673239 and 21501179)。
文摘Sulfonylcalix[4]arenes-based coordination containers,namely metal-organic supercontainers(MOSCs),are a new class of coordination containers constructed from the self-assembly of divalent metal ions,suitable carboxylate linkers,and sulfonylcalix[4]arenes container precursor.MOSCs feature both endo cavity surrounded by carboxylate linkers and exo cavities originated from the upper rim of sulfonylcalix[4]arenes.The molecular topologies and endo cavity of MOSCs are tuneable via judicious design of carboxylate linkers,while the modulation of endo cavity are accessible by chemical modification on the para substituent group of the sulfonylcalix[4]arenes.In this paper,recent advances and typical examples of design and functionalization of MOSCs are presented.
