The in-situ growing approach was utilized in this article to construct the magnesium–aluminum layered double hydroxide(MgAl-LDH)film on the surface of a 1060 aluminum anodized film.To improve the corrosion resistance...The in-situ growing approach was utilized in this article to construct the magnesium–aluminum layered double hydroxide(MgAl-LDH)film on the surface of a 1060 aluminum anodized film.To improve the corrosion resistance and friction qualities of aluminum alloy,the MgAl-LDH coating was treated using stearic acid(SA)and thiourea(TU).The aluminum substrate and anodized aluminum film layer corroded to varying degrees after 24 h of immersion in 3.5%(mass)NaCl solution,while the modified hydrotalcite film layer continued to exhibit the same microscopic morphology even after being immersed for 7 d.The results show that the synergistic action of thiourea and stearic acid can effectively improve the corrosion resistance of the MgAl-LDH substrate.The tribological testing reveals that the hydrotalcite film layer and the modified film layer lowered the friction coefficient of the anodized aluminum surface substantially.The results of the simulations and experiments demonstrate that SA forms the dense LDH-TU interlayer film layer by exchanging NO_(3)^(-)ions between TU layers on the one hand and the LDH-SA film layer by adsorption on the surface of LDH on the other.Together,these two processes create LDH-TUSA,which can significantly increase the substrate’s corrosion resistance.This synergistically modified superhydrophobic and retardant hydrotalcite film layer offers a novel approach to the investigation of wear reduction and corrosion protection on the surface of aluminum and its alloys.展开更多
Excellent mechanical properties are the prerequisite for the application of superhydrophobic polymer coatings.However,significantly improving the mechanical properties without affecting other properties such as hydrop...Excellent mechanical properties are the prerequisite for the application of superhydrophobic polymer coatings.However,significantly improving the mechanical properties without affecting other properties such as hydrophobicity is a huge challenge.In this study,a superhydrophobic coating with excellent mechanical properties was prepared by spraying a mixture of polysiloxane resins based on three siloxane monomers,hexadecyltrimethoxysilane(HDTMS) modified nano-SiO_(2)particles(SiO_(2)-HDTMS) and polystyrene-grafted halloysite nanotubes(HNTs-PS).SiO_(2)-HDTMS dispersed homogeneously in polysiloxane coatings and the water contact angle of corresponding coating exceeding 150°,achieving superhydrophobicity.The SiO_(2)-HDTMS/HNTs-PS/polysiloxane composite coatings showed excellent abrasion resistance with the water coating contact angle remaining above 150°after 90 abrasion cycles,indicating that HNTs-PS can significantly improve the mechanical properties of the coating without affecting the hydrophobic properties of the coating.The achieved coating also exhibited excellent antifouling and acid and alkali corrosion resistance.This work provides a convenient and ecologically friendly method to prepare superhydrophobic polysiloxane composite coating with excellent mechanical properties,which is promising in the application of anti-fouling,anti-corrosion,and oil-water separation etc.展开更多
Bio-inspired superhydrophobic magnesium(Mg)alloy surfaces are of increasing interest in corrosion protection due to superior barrier and shielding effects.However,superhydrophobic(SHB)anti-corrosion surfaces are susce...Bio-inspired superhydrophobic magnesium(Mg)alloy surfaces are of increasing interest in corrosion protection due to superior barrier and shielding effects.However,superhydrophobic(SHB)anti-corrosion surfaces are susceptible to damage,which limit their extensive applications.To this end,a micro/nano structure-functional molecule SHB composite coating with self-healing and active anti-corrosion dual-function properties was designed on Mg alloys substrate.The dual-function SHB composite anti-corrosion coating based on lauric acid(La)intercalated and modified hydrotalcite(La-LDH)consisted of three-layer structure,namely La-LDH powder/polydimethylsiloxane(PDMS)/La-LDH film.The anti-corrosion performance of as-prepared coatings was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy(EIS).The results indicate that the SHB coating shows excellent active corrosion resistance.Moreover,we also examined the self-healing and anti-corrosion properties of SHB coating upon physical damage and explained the healing mechanism.After heat treatment,the damaged SHB coating regain its surface microstructure and corrosion protection property.This work expands new insights for the wide application of Mg alloys and the research in the field of metal protection.展开更多
Torrefaction operation is an essential pathway for solid biofuel upgrading,and good hydrophobicity of torrefied biochar is conducive to its storage.Herein,a two-stage treatment of torrefaction followed by modification...Torrefaction operation is an essential pathway for solid biofuel upgrading,and good hydrophobicity of torrefied biochar is conducive to its storage.Herein,a two-stage treatment of torrefaction followed by modification by hexadecyltrimethoxysilane was adopted to improve the moisture resistance performance of biochar.This two-stage treatment process led to a longer torrefied microalgal biochar preservation time(60-200%improved)and great superhydrophobicity and superlipophilicity.Therefore,the modified microalgal biochar could significantly adsorb leaking oil for environmental remediation and further improve the calorific value of the biochar.The obtained results indicated that the oil adsorption capacity of modified microalgal biochar was correlated to torrefaction temperature and oil species.Specifically,the oil adsorption capacity was enhanced up to 70-80%from the modification process when comparing to raw microalga.Increasing the torrefaction temperature enhanced the adsorption quantity of the modified microalgal biochar.By adsorbing the oil,the calorific value of oilchar,namely,biochar with adsorbed oil,could be higher than 40 MJ kg^(−1).Furthermore,the pyrolysis and combustion characteristics suggested that biochar stability gradually rose as the torrefaction temperature increased.By comprehensively analyzing and comparing the fuel performance of the modified microalgal biochar with previous literature,the obtained modified microalgal biochar possessed better fuel properties and environmental sustainability.展开更多
ZnO film with claviform structure was synthesized on quartz substrates through a hydrothermal method at 90℃. The microstructure of the film is composed of clusters of submicrometer rods, which therefore endues the fi...ZnO film with claviform structure was synthesized on quartz substrates through a hydrothermal method at 90℃. The microstructure of the film is composed of clusters of submicrometer rods, which therefore endues the film with good superhydrophobicity. Meanwhile, the film with such tanglesome structure also shows highly crystalline quality testified by a strong ultra-violet (UV) emission and very low deep-level emission observed on the photoluminescence (PL) spectrum as well as high transparence of about 89% transmittance in visible light range.展开更多
基金financially supported by the National Natural Science Foundation of China(51971071 and 52075112)Fundamental Research Projects of Science&Technology Innovation and development Plan in Yantai City(2022JCYJ023)。
文摘The in-situ growing approach was utilized in this article to construct the magnesium–aluminum layered double hydroxide(MgAl-LDH)film on the surface of a 1060 aluminum anodized film.To improve the corrosion resistance and friction qualities of aluminum alloy,the MgAl-LDH coating was treated using stearic acid(SA)and thiourea(TU).The aluminum substrate and anodized aluminum film layer corroded to varying degrees after 24 h of immersion in 3.5%(mass)NaCl solution,while the modified hydrotalcite film layer continued to exhibit the same microscopic morphology even after being immersed for 7 d.The results show that the synergistic action of thiourea and stearic acid can effectively improve the corrosion resistance of the MgAl-LDH substrate.The tribological testing reveals that the hydrotalcite film layer and the modified film layer lowered the friction coefficient of the anodized aluminum surface substantially.The results of the simulations and experiments demonstrate that SA forms the dense LDH-TU interlayer film layer by exchanging NO_(3)^(-)ions between TU layers on the one hand and the LDH-SA film layer by adsorption on the surface of LDH on the other.Together,these two processes create LDH-TUSA,which can significantly increase the substrate’s corrosion resistance.This synergistically modified superhydrophobic and retardant hydrotalcite film layer offers a novel approach to the investigation of wear reduction and corrosion protection on the surface of aluminum and its alloys.
基金supported by the National Natural Science Foundation of China(21878092,21838003,91834301 and 51621002)the Shanghai Scientific and Technological Innovation Project(19JC1410400)+2 种基金Program of Shanghai Academic Research Leader(19XD1401400)the Innovation Program of Shanghai Municipal Education Commissionthe Fundamental Research Funds for the Central Universities(222201718002)。
文摘Excellent mechanical properties are the prerequisite for the application of superhydrophobic polymer coatings.However,significantly improving the mechanical properties without affecting other properties such as hydrophobicity is a huge challenge.In this study,a superhydrophobic coating with excellent mechanical properties was prepared by spraying a mixture of polysiloxane resins based on three siloxane monomers,hexadecyltrimethoxysilane(HDTMS) modified nano-SiO_(2)particles(SiO_(2)-HDTMS) and polystyrene-grafted halloysite nanotubes(HNTs-PS).SiO_(2)-HDTMS dispersed homogeneously in polysiloxane coatings and the water contact angle of corresponding coating exceeding 150°,achieving superhydrophobicity.The SiO_(2)-HDTMS/HNTs-PS/polysiloxane composite coatings showed excellent abrasion resistance with the water coating contact angle remaining above 150°after 90 abrasion cycles,indicating that HNTs-PS can significantly improve the mechanical properties of the coating without affecting the hydrophobic properties of the coating.The achieved coating also exhibited excellent antifouling and acid and alkali corrosion resistance.This work provides a convenient and ecologically friendly method to prepare superhydrophobic polysiloxane composite coating with excellent mechanical properties,which is promising in the application of anti-fouling,anti-corrosion,and oil-water separation etc.
基金supported by the Fundamental Research Fund(No.2020-JCJQ-JJ-008)the National Natural Science Foundation of China(No.21871020)the Postdoctoral Research Foundation of China(Nos.2021TQ0023,2020M680296,2022T150035 and 2022TQ0022).
文摘Bio-inspired superhydrophobic magnesium(Mg)alloy surfaces are of increasing interest in corrosion protection due to superior barrier and shielding effects.However,superhydrophobic(SHB)anti-corrosion surfaces are susceptible to damage,which limit their extensive applications.To this end,a micro/nano structure-functional molecule SHB composite coating with self-healing and active anti-corrosion dual-function properties was designed on Mg alloys substrate.The dual-function SHB composite anti-corrosion coating based on lauric acid(La)intercalated and modified hydrotalcite(La-LDH)consisted of three-layer structure,namely La-LDH powder/polydimethylsiloxane(PDMS)/La-LDH film.The anti-corrosion performance of as-prepared coatings was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy(EIS).The results indicate that the SHB coating shows excellent active corrosion resistance.Moreover,we also examined the self-healing and anti-corrosion properties of SHB coating upon physical damage and explained the healing mechanism.After heat treatment,the damaged SHB coating regain its surface microstructure and corrosion protection property.This work expands new insights for the wide application of Mg alloys and the research in the field of metal protection.
文摘Fluoroalkyl end-capped vinyltrimethoxysilane-<i><span style="font-family:Verdana;">N</span></i><span><span style="font-family:Verdana;">,</span><i><span style="font-family:Verdana;">N</span></i></span><span style="font-family:Verdana;">-dimethylacrylamide cooli</span><span style="font-family:;" "=""><span style="font-family:Verdana;">gomer [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(CH</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">-CHSi(OMe)</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(CH</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">-CHC(=O)NMe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">;R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;"> = CF(CF</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">)OC</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">F</span><sub><span style="font-family:Verdana;">7</span></sub><span style="font-family:Verdana;">:</span></span><span style="font-family:;" "=""><span style="font-family:Verdana;"> R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] was synthesized by reaction of fluoroalkanoyl peroxide [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-C(=O)O-O(O=)C-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] with vinyltrimethoxysilane (VM) and </span><i><span style="font-family:Verdana;">N</span></i><span><span style="font-family:Verdana;">,</span><i><span style="font-family:Verdana;">N</span></i></span><span style="font-family:Verdana;">-</span></span><span style="font-family:Verdana;">dimethylacrylamide (DMAA). The modified glass surface treated with the</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> cooligomeric nanoparticles [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] prepared under the sol-gel reaction of the cooligomer under alkaline conditions was found to exhibit an oleophobic/superhydrophilic property, although the corresponding fluorinated homooligomeric nanoparticles [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] afforded an </span><span style="font-family:Verdana;">oleophobic/hydrophobic property on the modified surface under similar </span><span style="font-family:Verdana;">con</span><span><span style="font-family:Verdana;">ditions. R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/</span><b><i><span style="font-family:Verdana;">PSt</span></i></b><span style="font-family:Verdana;"> (micro-sized</span></span> <span style="font-family:Verdana;">polystyrene particles) composites, which were prepared by the sol-gel reac</span><span style="font-family:Verdana;">tions of the corresponding homooligomer and cooligomer in the presence of </span><b><i><span style="font-family:Verdana;">PSt </span></i></b><span style="font-family:Verdana;">particle under alkaline conditions, provided an oleophobic/superhydrophilic </span><span style="font-family:Verdana;">property on the modified surface. However, it was demonstrated that the</span><span><span style="font-family:Verdana;"> surface wettability on the modified surface treated with the R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-</span></span><span><span style="font-family:Verdana;">SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/</span><b><i><span style="font-family:Verdana;">PSt</span></i></b><span style="font-family:Verdana;"> composites changes dramatically from oleophobic/superhydrophilic to superoleophilic/superhydrophilic </span><span style="font-family:Verdana;">and superoleophilic/superhydrophobic characteristics, increasing with </span><span style="font-family:Verdana;">greater </span><span><span style="font-family:Verdana;">feed ratios (mg/mg) of the R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;"> homooligomer in homooligo</span></span><span style="font-family:Verdana;">mer/cooligo</span></span><span style="font-family:Verdana;">mer from 0 to 100 in the preparation of the composites. Such controlled surfac</span>
基金National Science and Technology Council,Taiwan region,under the grant numbers MOST 109-2221-E-006-040-MY3,MOST 110-2622-E-006-001-CC1,and MOST 110-3116-F-006-003-.
文摘Torrefaction operation is an essential pathway for solid biofuel upgrading,and good hydrophobicity of torrefied biochar is conducive to its storage.Herein,a two-stage treatment of torrefaction followed by modification by hexadecyltrimethoxysilane was adopted to improve the moisture resistance performance of biochar.This two-stage treatment process led to a longer torrefied microalgal biochar preservation time(60-200%improved)and great superhydrophobicity and superlipophilicity.Therefore,the modified microalgal biochar could significantly adsorb leaking oil for environmental remediation and further improve the calorific value of the biochar.The obtained results indicated that the oil adsorption capacity of modified microalgal biochar was correlated to torrefaction temperature and oil species.Specifically,the oil adsorption capacity was enhanced up to 70-80%from the modification process when comparing to raw microalga.Increasing the torrefaction temperature enhanced the adsorption quantity of the modified microalgal biochar.By adsorbing the oil,the calorific value of oilchar,namely,biochar with adsorbed oil,could be higher than 40 MJ kg^(−1).Furthermore,the pyrolysis and combustion characteristics suggested that biochar stability gradually rose as the torrefaction temperature increased.By comprehensively analyzing and comparing the fuel performance of the modified microalgal biochar with previous literature,the obtained modified microalgal biochar possessed better fuel properties and environmental sustainability.
基金supported by the National Natural Science Foundation of China(Grant No.50871046)the Foundation of National Key Basic Research and Development Program(No.2010CB631001)the Program for Changjiang Scholars and Innovative Research Team inUniversity
文摘ZnO film with claviform structure was synthesized on quartz substrates through a hydrothermal method at 90℃. The microstructure of the film is composed of clusters of submicrometer rods, which therefore endues the film with good superhydrophobicity. Meanwhile, the film with such tanglesome structure also shows highly crystalline quality testified by a strong ultra-violet (UV) emission and very low deep-level emission observed on the photoluminescence (PL) spectrum as well as high transparence of about 89% transmittance in visible light range.