This paper reports a new route for the preparation of layered alpha-zirconium phosphate （α-ZrP）-supported metalloporphyrin MnTMPyP. MnTMPyP was intercalated into α-ZrP using α-ZrP.BA （i.e. pre-intercalated bulty...This paper reports a new route for the preparation of layered alpha-zirconium phosphate （α-ZrP）-supported metalloporphyrin MnTMPyP. MnTMPyP was intercalated into α-ZrP using α-ZrP.BA （i.e. pre-intercalated bultylamine was arranged by a monolayer mode in α-ZrP） as a starting material. The catalytic activity of the supported material for homovanillic acid （HVA） oxidation was investigated. The results showed a promising layered material-supported catalyst in catalytic system.展开更多
The support layer is an important component of twin-block ballastless track. The modulus of the support layer is an important design parameter and must be carefully solved. We studied the bending stress and deformatio...The support layer is an important component of twin-block ballastless track. The modulus of the support layer is an important design parameter and must be carefully solved. We studied the bending stress and deformation of track slab and support layer due to train load using the beam-plate finite element model on elastic foundation. The results show that support layer type has great impact on both support layer deformation and the stress on subgrade, but has little impact on the bending stress of either track slab or support layer. The continuous support layer type, and articulated support layer type with shear transfer device at their ends, are recommended. In order to keep the stress in the support layer less than that in track slab, the modulus of the continuous, unit, and articulated types of support layer （ in unit twin-block ballastless track）, and the support layer in continuous twin-block ballastless track, should not be larger than 15, 22, 20.5 and 5 GPa, respectively. In addition, the modulus of the unit-type support layer should not be more than 20 GPa, to ensure the step in support layer remains less than 1 mm.展开更多
Metal–organic-framework(MOF)has been an increasingly hot organic-inorganic hybrid compounds. Here we develop an innovative concept by engineering a supporting layer made of MOF derived carbon materials. The supportin...Metal–organic-framework(MOF)has been an increasingly hot organic-inorganic hybrid compounds. Here we develop an innovative concept by engineering a supporting layer made of MOF derived carbon materials. The supporting thin layer is prepared by carbonizing zeolitic-imidazole framework(ZIF-67). CdSe quantum dot sensitized TiO_2 nanocrystalline thin film deposited by the method of chemical bath deposition(CBD). The MOF unique microstructure in the support layer builds the electronic highway, which greatly improves the efficiency of the CdSe quantum dot-sensitized solar cells(QDSSCs), and the power conversion efficiency(PCE)of the device was significantly improved from 2.98% to 5.79% via ZIF-67 derived carbon supporting thin layer.展开更多
This paper focuses on some application issues in m.multi-layered perceptrons researches. The following problem areas are discussed: (1) the classification capability of multi-layered perceptrons; (2) theself-configura...This paper focuses on some application issues in m.multi-layered perceptrons researches. The following problem areas are discussed: (1) the classification capability of multi-layered perceptrons; (2) theself-configuration algorithm for facilitating the design of the neural nets' structure;and,finally (3) the application of the fast BP algorithm to speed up the learning procedure. Some experimental results with respect to the application of multi-layered perceptrons as classifier systems in the comprehensive evaluation of Chinese large cities are presented.展开更多
基金supported by The Basic Research Foundation of China (No.HAISANKE,2008010)The National Natural Science Foundation of China (No.40706043)+2 种基金The Natural Science Foundation of Fujian Province (No.2006J0184)The Open Research of Key laboratory of Coastal Ecosystem and Environment (No.200610)The Youth Foundation of SOA of China (No.2007606).
文摘This paper reports a new route for the preparation of layered alpha-zirconium phosphate （α-ZrP）-supported metalloporphyrin MnTMPyP. MnTMPyP was intercalated into α-ZrP using α-ZrP.BA （i.e. pre-intercalated bultylamine was arranged by a monolayer mode in α-ZrP） as a starting material. The catalytic activity of the supported material for homovanillic acid （HVA） oxidation was investigated. The results showed a promising layered material-supported catalyst in catalytic system.
基金The National Natural Science Foundation of China(Director Program)(No.50848015)the Innovative Research Team Incubation Financing Projects of Southwest Jiaotong University(No.2007IRT06)
文摘The support layer is an important component of twin-block ballastless track. The modulus of the support layer is an important design parameter and must be carefully solved. We studied the bending stress and deformation of track slab and support layer due to train load using the beam-plate finite element model on elastic foundation. The results show that support layer type has great impact on both support layer deformation and the stress on subgrade, but has little impact on the bending stress of either track slab or support layer. The continuous support layer type, and articulated support layer type with shear transfer device at their ends, are recommended. In order to keep the stress in the support layer less than that in track slab, the modulus of the continuous, unit, and articulated types of support layer （ in unit twin-block ballastless track）, and the support layer in continuous twin-block ballastless track, should not be larger than 15, 22, 20.5 and 5 GPa, respectively. In addition, the modulus of the unit-type support layer should not be more than 20 GPa, to ensure the step in support layer remains less than 1 mm.
文摘Metal–organic-framework(MOF)has been an increasingly hot organic-inorganic hybrid compounds. Here we develop an innovative concept by engineering a supporting layer made of MOF derived carbon materials. The supporting thin layer is prepared by carbonizing zeolitic-imidazole framework(ZIF-67). CdSe quantum dot sensitized TiO_2 nanocrystalline thin film deposited by the method of chemical bath deposition(CBD). The MOF unique microstructure in the support layer builds the electronic highway, which greatly improves the efficiency of the CdSe quantum dot-sensitized solar cells(QDSSCs), and the power conversion efficiency(PCE)of the device was significantly improved from 2.98% to 5.79% via ZIF-67 derived carbon supporting thin layer.
文摘This paper focuses on some application issues in m.multi-layered perceptrons researches. The following problem areas are discussed: (1) the classification capability of multi-layered perceptrons; (2) theself-configuration algorithm for facilitating the design of the neural nets' structure;and,finally (3) the application of the fast BP algorithm to speed up the learning procedure. Some experimental results with respect to the application of multi-layered perceptrons as classifier systems in the comprehensive evaluation of Chinese large cities are presented.
