The role of water in CO oxidation was investigated on Pd/CeO2 with different morphologies(rods(R),cubes(C)and octahedrons(O)).Compared with the absence of water,CO oxidation activity increases 2 times in the presence ...The role of water in CO oxidation was investigated on Pd/CeO2 with different morphologies(rods(R),cubes(C)and octahedrons(O)).Compared with the absence of water,CO oxidation activity increases 2 times in the presence of water on Pd/CeO2-C;but a decrease is found on Pd/CeO2-R.Catalyst characterization reveals that Pd is mainly in the form of solid solution(PdxCe1-xO2-σ)on Pd/CeO2-R and a mixture of metal and PdxCe1-xO2-σsolid solution on Pd/CeO2-C.The strong interaction between Pd and CeO2-R results in the form of stable bidentate carbonates species;while the relatively weak interaction between Pd and CeO2-C leads to the produce of unstable monodentate carbonates species.The effects of water on CO oxidation activity closely relate with the Pd chemical state and the types of carbonates species.Water restrains CO adsorption on PdxCe1-xO2-σsolid solution,but it has negligent effects on metallic Pd species.In the presence of water,bidentate carbonates species remains stable but the decrease in the amount of monodentate carbonates species is observed.展开更多
Pidan or century egg, also known as preserved egg, is one of the most traditional and popular egg products in China. The crack detection of preserved eggshell is very important to guarantee its quality. In this study,...Pidan or century egg, also known as preserved egg, is one of the most traditional and popular egg products in China. The crack detection of preserved eggshell is very important to guarantee its quality. In this study, we develop an image algorithm for preserved eggshell＇s crack detection by using natural light and polarized image. Four features including crack length, crack state coefficient, maximum projection and angular point are extracted from the natural light image by morphology calculus algorithms. The support vector machines（SVM） model with radial basis kernel function is established using the four features with an accuracy of about 92%. The detection accuracy is improved to 94% by using a new characteristic parameter of crack length on polarization image. The Multi-information fusion analysis indicates the potential for cracks detection by a real-time synthesis imaging system.展开更多
基金Project supported financially by the National Key Research and Development Program of China(2016YFC0204300)the National Natural Science Foundation of China(21976057,21922602)the Shanghai“Pujiang”Program(18PJD011)。
文摘The role of water in CO oxidation was investigated on Pd/CeO2 with different morphologies(rods(R),cubes(C)and octahedrons(O)).Compared with the absence of water,CO oxidation activity increases 2 times in the presence of water on Pd/CeO2-C;but a decrease is found on Pd/CeO2-R.Catalyst characterization reveals that Pd is mainly in the form of solid solution(PdxCe1-xO2-σ)on Pd/CeO2-R and a mixture of metal and PdxCe1-xO2-σsolid solution on Pd/CeO2-C.The strong interaction between Pd and CeO2-R results in the form of stable bidentate carbonates species;while the relatively weak interaction between Pd and CeO2-C leads to the produce of unstable monodentate carbonates species.The effects of water on CO oxidation activity closely relate with the Pd chemical state and the types of carbonates species.Water restrains CO adsorption on PdxCe1-xO2-σsolid solution,but it has negligent effects on metallic Pd species.In the presence of water,bidentate carbonates species remains stable but the decrease in the amount of monodentate carbonates species is observed.
基金Supported by the Fundamental Funds for Central University(2662014BQ062)
文摘Pidan or century egg, also known as preserved egg, is one of the most traditional and popular egg products in China. The crack detection of preserved eggshell is very important to guarantee its quality. In this study, we develop an image algorithm for preserved eggshell＇s crack detection by using natural light and polarized image. Four features including crack length, crack state coefficient, maximum projection and angular point are extracted from the natural light image by morphology calculus algorithms. The support vector machines（SVM） model with radial basis kernel function is established using the four features with an accuracy of about 92%. The detection accuracy is improved to 94% by using a new characteristic parameter of crack length on polarization image. The Multi-information fusion analysis indicates the potential for cracks detection by a real-time synthesis imaging system.
