A silica gel supported cobalt(lI) Schiff base complex was synthesized and used for the oxidation of alkyl aromatics using molecular oxygen as an oxidant under atmosphere pressure. The catalyst shows a high conversio...A silica gel supported cobalt(lI) Schiff base complex was synthesized and used for the oxidation of alkyl aromatics using molecular oxygen as an oxidant under atmosphere pressure. The catalyst shows a high conversion of alkyl aromatics and selectivity to benzylic ketones, and could be reused at least 5 times without significant loss of catalytic activity.展开更多
基金the financial support from the National Natural Science Foundation of China–Academy of Engineering Physics(No.10976014)Natural Science Foundation of Jiangsu Province(No.BK2011697)
文摘A silica gel supported cobalt(lI) Schiff base complex was synthesized and used for the oxidation of alkyl aromatics using molecular oxygen as an oxidant under atmosphere pressure. The catalyst shows a high conversion of alkyl aromatics and selectivity to benzylic ketones, and could be reused at least 5 times without significant loss of catalytic activity.