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DSN-BR-Based Online Inspection Method and Application for Surface Defects of Pharmaceutical Products in Aluminum-Plastic Blister Packages
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作者 Mingzhou Liu Yu Gong +2 位作者 Xiaoqiao Wang Conghu Liu Jing Hu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第4期194-214,共21页
Ensuring high product quality is of paramount importance in pharmaceutical drug manufacturing,as it is subject to rigorous regulatory practices.This study presents a research focused on the development of an on-line d... Ensuring high product quality is of paramount importance in pharmaceutical drug manufacturing,as it is subject to rigorous regulatory practices.This study presents a research focused on the development of an on-line detection method and system for identifying surface defects in pharmaceutical products packaged in aluminum-plastic blisters.Firstly,the aluminum-plastic blister packages exhibit multi-scale features and inter-class indistinction.To address this,the deep semantic network with boundary refinement(DSN-BR)model is proposed,which leverages semantic segmentation domain knowledge,to accurately segment the defects in pixel level.Additionally,a specialized image acquisition module that minimizes the impact of ambient light is established,ensuring high-quality image capture.Finally,the image acquisition module,image detection module,and data management module are designed to construct a comprehensive online surface defect detection system.To validate the effectiveness of our approach,we employ a real dataset for instance verification on the implemented system.The experimental results substantiate the outstanding performance of the DSN-BR,achieving the mean intersection over union(MIoU)of 90.5%.Furthermore,the proposed system achieves an inference speed of up to 14.12 f/s,while attaining an F1-Score of 98.25%.These results demonstrate that the system meets the actual needs of the enterprise and provides theoretical and methodological support for intelligent inspection of product surface quality.By standardizing the control process of pharmaceutical manufacturing and improving the management capability of the manufacturing process,our approach holds significant market application prospects. 展开更多
关键词 surface defect detection system Deep learning Semantic segmentation Aluminum-plastic blister packages identification
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SAM Era:Can It Segment Any Industrial Surface Defects?
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作者 Kechen Song Wenqi Cui +2 位作者 Han Yu Xingjie Li Yunhui Yan 《Computers, Materials & Continua》 SCIE EI 2024年第3期3953-3969,共17页
Segment Anything Model(SAM)is a cutting-edge model that has shown impressive performance in general object segmentation.The birth of the segment anything is a groundbreaking step towards creating a universal intellige... Segment Anything Model(SAM)is a cutting-edge model that has shown impressive performance in general object segmentation.The birth of the segment anything is a groundbreaking step towards creating a universal intelligent model.Due to its superior performance in general object segmentation,it quickly gained attention and interest.This makes SAM particularly attractive in industrial surface defect segmentation,especially for complex industrial scenes with limited training data.However,its segmentation ability for specific industrial scenes remains unknown.Therefore,in this work,we select three representative and complex industrial surface defect detection scenarios,namely strip steel surface defects,tile surface defects,and rail surface defects,to evaluate the segmentation performance of SAM.Our results show that although SAM has great potential in general object segmentation,it cannot achieve satisfactory performance in complex industrial scenes.Our test results are available at:https://github.com/VDT-2048/SAM-IS. 展开更多
关键词 Segment anything SAM surface defect detection salient object detection
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Surface Defect Detection and Evaluation Method of Large Wind Turbine Blades Based on an Improved Deeplabv3+Deep Learning Model
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作者 Wanrun Li Wenhai Zhao +1 位作者 Tongtong Wang Yongfeng Du 《Structural Durability & Health Monitoring》 EI 2024年第5期553-575,共23页
The accumulation of defects on wind turbine blade surfaces can lead to irreversible damage,impacting the aero-dynamic performance of the blades.To address the challenge of detecting and quantifying surface defects on ... The accumulation of defects on wind turbine blade surfaces can lead to irreversible damage,impacting the aero-dynamic performance of the blades.To address the challenge of detecting and quantifying surface defects on wind turbine blades,a blade surface defect detection and quantification method based on an improved Deeplabv3+deep learning model is proposed.Firstly,an improved method for wind turbine blade surface defect detection,utilizing Mobilenetv2 as the backbone feature extraction network,is proposed based on an original Deeplabv3+deep learning model to address the issue of limited robustness.Secondly,through integrating the concept of pre-trained weights from transfer learning and implementing a freeze training strategy,significant improvements have been made to enhance both the training speed and model training accuracy of this deep learning model.Finally,based on segmented blade surface defect images,a method for quantifying blade defects is proposed.This method combines image stitching algorithms to achieve overall quantification and risk assessment of the entire blade.Test results show that the improved Deeplabv3+deep learning model reduces training time by approximately 43.03%compared to the original model,while achieving mAP and MIoU values of 96.87%and 96.93%,respectively.Moreover,it demonstrates robustness in detecting different surface defects on blades across different back-grounds.The application of a blade surface defect quantification method enables the precise quantification of dif-ferent defects and facilitates the assessment of risk levels associated with defect measurements across the entire blade.This method enables non-contact,long-distance,high-precision detection and quantification of surface defects on the blades,providing a reference for assessing surface defects on wind turbine blades. 展开更多
关键词 Structural health monitoring computer vision blade surface defects detection Deeplabv3+ deep learning model
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Formation and control of the surface defect in hypo-peritectic steel during continuous casting:A review 被引量:1
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作者 Quanhui Li Peng Lan +3 位作者 Haijie Wang Hongzhou Ai Deli Chen Haida Wang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第12期2281-2296,共16页
Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur ... Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur during continuous casting,which includes depression,longitudinal cracks,deep oscillation marks,and severe level fluctuation with slag entrapment.The high-efficiency production of hypo-peritectic steels by continuous casting is still a great challenge due to the limited understanding of the mechanism of peritectic solidification.This work reviews the definition and classification of hypo-peritectic steels and introduces the formation tendency of common surface defects related to peritectic solidification.New achievements in the mechanism of peritectic reaction and transformation have been listed.Finally,countermeasures to avoiding surface defects of hypo-peritectic steels duiring continuous casting are summarized.Enlightening certain points in the continuous casting of hypo-peritectic steels and the development of new techniques to overcome the present problems will be a great aid to researchers. 展开更多
关键词 hypo-peritectic steel continuous casting surface defect massive transformation grain coarsening DEPRESSION longitudinal crack level fluctuation oscillation mark
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Rail Surface Defect Detection Based on Improved UPerNet and Connected Component Analysis 被引量:1
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作者 Yongzhi Min Jiafeng Li Yaxing Li 《Computers, Materials & Continua》 SCIE EI 2023年第10期941-962,共22页
To guarantee the safety of railway operations,the swift detection of rail surface defects becomes imperative.Traditional methods of manual inspection and conventional nondestructive testing prove inefficient,especiall... To guarantee the safety of railway operations,the swift detection of rail surface defects becomes imperative.Traditional methods of manual inspection and conventional nondestructive testing prove inefficient,especially when scaling to extensive railway networks.Moreover,the unpredictable and intricate nature of defect edge shapes further complicates detection efforts.Addressing these challenges,this paper introduces an enhanced Unified Perceptual Parsing for Scene Understanding Network(UPerNet)tailored for rail surface defect detection.Notably,the Swin Transformer Tiny version(Swin-T)network,underpinned by the Transformer architecture,is employed for adept feature extraction.This approach capitalizes on the global information present in the image and sidesteps the issue of inductive preference.The model’s efficiency is further amplified by the windowbased self-attention,which minimizes the model’s parameter count.We implement the cross-GPU synchronized batch normalization(SyncBN)for gradient optimization and integrate the Lovász-hinge loss function to leverage pixel dependency relationships.Experimental evaluations underscore the efficacy of our improved UPerNet,with results demonstrating Pixel Accuracy(PA)scores of 91.39%and 93.35%,Intersection over Union(IoU)values of 83.69%and 87.58%,Dice Coefficients of 91.12%and 93.38%,and Precision metrics of 90.85%and 93.41%across two distinct datasets.An increment in detection accuracy was discernible.For further practical applicability,we deploy semantic segmentation of rail surface defects,leveraging connected component processing techniques to distinguish varied defects within the same frame.By computing the actual defect length and area,our deep learning methodology presents results that offer intuitive insights for railway maintenance professionals. 展开更多
关键词 Rail surface defects connected component analysis TRANSFORMER UPerNet
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Analytical Modeling and Mechanism Analysis of Time-Varying Excitation for Surface Defects in Rolling Element Bearings 被引量:1
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作者 Laihao Yang Yu Sun +2 位作者 Ruobin Sun Lixia Gao Xuefeng Chen 《Journal of Dynamics, Monitoring and Diagnostics》 2023年第2期89-101,共13页
Surface defects,including dents,spalls,and cracks,for rolling element bearings are the most common faults in rotating machinery.The accurate model for the time-varying excitation is the basis for the vibration mechani... Surface defects,including dents,spalls,and cracks,for rolling element bearings are the most common faults in rotating machinery.The accurate model for the time-varying excitation is the basis for the vibration mechanism analysis and fault feature extraction.However,in conventional investigations,this issue is not well and fully addressed from the perspective of theoretical analysis and physical derivation.In this study,an improved analytical model for time-varying displacement excitations(TVDEs)caused by surface defects is theoretically formulated.First and foremost,the physical mechanism for the effect of defect sizes on the physical process of rolling element-defect interaction is revealed.According to the physical interaction mechanism between the rolling element and different types of defects,the relationship between time-varying displacement pulse and defect sizes is further analytically derived.With the obtained time-varying displacement pulse,the dynamic model for the deep groove bearings considering the internal excitation caused by the surface defect is established.The nonlinear vibration responses and fault features induced by surface defects are analyzed using the proposed TVDE model.The results suggest that the presence of surface defects may result in the occurrence of the dual-impulse phenomenon,which can serve as indexes for surface-defect fault diagnosis. 展开更多
关键词 analytical model rolling bearings surface defects time-varying excitation vibration mechanism
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Application of multi-scale feature extraction to surface defect classification of hot-rolled steels 被引量:7
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作者 Ke Xu Yong-hao Ai Xiu-yong Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2013年第1期37-41,共5页
Feature extraction is essential to the classification of surface defect images. The defects of hot-rolled steels distribute in different directions. Therefore, the methods of multi-scale geometric analysis (MGA) wer... Feature extraction is essential to the classification of surface defect images. The defects of hot-rolled steels distribute in different directions. Therefore, the methods of multi-scale geometric analysis (MGA) were employed to decompose the image into several directional subba^ds at several scales. Then, the statistical features of each subband were calculated to produce a high-dimensional feature vector, which was reduced to a lower-dimensional vector by graph embedding algorithms. Finally, support vector machine (SVM) was used for defect classification. The multi-scale feature extraction method was implemented via curvelet transform and kernel locality preserving projections (KLPP). Experiment results show that the proposed method is effective for classifying the surface defects of hot-rolled steels and the total classification rate is up to 97.33%. 展开更多
关键词 hot rolling strip metal surface defects CLASSIFICATION feature extraction
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Building surface defects by doping with transition metal on ultrafine TiO_2 to enhance the photocatalytic H_2 production activity 被引量:6
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作者 Qi‐Feng Liu Qian Zhang +2 位作者 Bing‐Rui Liu Shiyou Li Jing‐Jun Ma 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第3期542-548,共7页
Inefficient charge separation and limited light absorption are two critical issues associated with high‐efficiency photocatalytic H2production using TiO2.Surface defects within a certain concentration range in photoc... Inefficient charge separation and limited light absorption are two critical issues associated with high‐efficiency photocatalytic H2production using TiO2.Surface defects within a certain concentration range in photocatalyst materials are beneficial for photocatalytic activity.In this study,surface defects(oxygen vacancies and metal cation replacement defects)were induced with a facile and effective approach by surface doping with low‐cost transition metals(Co,Ni,Cu,and Mn)on ultrafine TiO2.The obtained surface‐defective TiO2exhibited a3–4‐fold improved activity compared to that of the original ultrafine TiO2.In addition,a H2production rate of3.4μmol/h was obtained using visible light(λ>420nm)irradiation.The apparent quantum yield(AQY)at365nm reached36.9%over TiO2‐Cu,significantly more than the commercial P25TiO2.The enhancement of photocatalytic H2production activity can be attributed to improved rapid charge separation efficiency andexpanded light absorption window.This hydrothermal treatment with transition metal was proven to be a very facile and effective method for obtaining surface defects. 展开更多
关键词 Construction of surface defects Ultrafine TiO2 Low‐cost transition metal surface doping Photocatalytic H2 production
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Application of a new feature extraction and optimization method to surface defect recognition of cold rolled strips 被引量:6
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作者 Guifang Wu Ke Xu Jinwu Xu 《Journal of University of Science and Technology Beijing》 CSCD 2007年第5期437-442,共6页
Considering that the surface defects of cold rolled strips are hard to be recognized by human eyes under high-speed circumstances, an automatic recognition technique was discussed. Spectrum images of defects can be go... Considering that the surface defects of cold rolled strips are hard to be recognized by human eyes under high-speed circumstances, an automatic recognition technique was discussed. Spectrum images of defects can be got by fast Fourier transform (FFF) and sum of valid pixels (SVP), and its optimized center region, which concentrates nearly all energies, are extracted as an original feature set. Using genetic algorithm to optimize the feature set, an optimized feature set with 51 features can be achieved. Using the optimized feature set as an input vector of neural networks, the recognition effects of LVQ neural networks have been studied. Experiment results show that the new method can get a higher classification rate and can settle the automatic recognition problem of surface defects on cold rolled strips ideally. 展开更多
关键词 cold rolled strip surface defect neural networks fast Fourier transform (FFT) feature extraction and optimization genetic algorithm feature set
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Surface defects in 4H-SiC homoepitaxial layers 被引量:3
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作者 Lixia Zhao 《Nanotechnology and Precision Engineering》 CAS CSCD 2020年第4期229-234,共6页
Although a high-quality homoepitaxial layer of 4H‑silicon carbide(4H-SiC)can be obtained on a 4°off-axis substrate using chemical vapor deposition,the reduction of defects is still a focus of research.In this stu... Although a high-quality homoepitaxial layer of 4H‑silicon carbide(4H-SiC)can be obtained on a 4°off-axis substrate using chemical vapor deposition,the reduction of defects is still a focus of research.In this study,several kinds of surface defects in the 4H-SiC homoepitaxial layer are systemically investigated,including triangles,carrots,surface pits,basal plane dislocations,and step bunching.Themorphologies and structures of surface defects are further discussed via optical microscopy and potassium hydroxide-based defect selective etching analysis.Through research and analysis,we found that the origin of surface defects in the 4H-SiC homoepitaxial layer can be attributed to two aspects:the propagation of substrate defects,such as scratches,dislocation,and inclusion,and improper process parameters during epitaxial growth,such as in-situ etch,C/Si ratio,and growth temperature.It is believed that the surface defects in the 4H-SiC homoepitaxial layer can be significantly decreased by precisely controlling the chemistry on the deposition surface during the growth process. 展开更多
关键词 4H silicon carbide surface defect Chemical vapor deposition REDUCTION
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Tuning the crystallite size of monoclinic ZrO_(2) to reveal critical roles of surface defects on m–ZrO_(2) catalyst for direct synthesis of isobutene from syngas 被引量:2
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作者 Xuemei Wu Minghui Tan +7 位作者 Bing Xu Shengying Zhao Qingxiang Ma Yingluo He Chunyang Zeng Guohui Yang Noritatsu Tsubaki Yisheng Tan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第7期211-219,共9页
The effects of crystallite size on the physicochemical properties and surface defects of pure monoclinic ZrO_(2) catalysts for isobutene synthesis were studied.We prepared a series of monoclinic ZrO_(2) catalysts with... The effects of crystallite size on the physicochemical properties and surface defects of pure monoclinic ZrO_(2) catalysts for isobutene synthesis were studied.We prepared a series of monoclinic ZrO_(2) catalysts with different crystallite size by changing calcination temperature and evaluated their catalytic performance for isobutene synthesis from syngas.ZrO_(2) with small crystalline size showed higher CO conversion and isobutene selectivity,while samples with large crystalline size preferred to form dimethyl ether(DME)instead of hydrocarbons,much less to isobutene.Oxygen defects(ODefects)analyzed by X-ray photoelectron spectroscopy(XPS)provided evidence that more ODefectsoccupied on the surface of ZrO_(2) catalysts with smaller crystalline size.Electron paramagnetic resonance(EPR)and ultraviolet–visible diffuse reflectance(UV–vis DRS)confirmed the presence of high concentration of surface defects and Zr3+on mZrO_(2)-5.9 sample,respectively.In situ diffuse reflectance infrared Fourier transform spectroscopy(in situ DRIFTS)analysis indicated that the adsorption strength of formed formate species on catalyst reduced as the crystalline size decreased.These results suggested that surface defects were responsible for CO activation and further influenced the adsorption strength of surface species,and thus the products distribution changed.This study provides an in-depth insight for active sites regulation of ZrO_(2) catalyst in CO hydrogenation reaction. 展开更多
关键词 SYNGAS ISOBUTENE ZrO_(2)catalyst Crystallite size surface defects
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Surface defect-rich ceria quantum dots anchored on sulfur-doped carbon nitride nanotubes with enhanced charge separation for solar hydrogen production 被引量:2
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作者 Mengru Li Changfeng Chen +3 位作者 Liping Xu Yushuai Jia Yan Liu Xin Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第1期51-59,I0003,共10页
Designing defect-engineered semiconductor heterojunctions can effectively promote the charge carrier separation.Herein,novel ceria(CeO2) quantum dots(QDs) decorated sulfur-doped carbon nitride nanotubes(SCN NTs) were ... Designing defect-engineered semiconductor heterojunctions can effectively promote the charge carrier separation.Herein,novel ceria(CeO2) quantum dots(QDs) decorated sulfur-doped carbon nitride nanotubes(SCN NTs) were synthesized via a thermal polycondensation coupled in situ depositionprecipitation method without use of template or surfactant.The structure and morphology studies indicate that ultrafine CeO2 QDs are well distributed inside and outside of SCN NTs offering highly dispersed active sites and a large contact interface between two components.This leads to the promoted formation of rich Ce^(3+) ion and oxygen vacancies as confirmed by XPS.The photocatalytic performance can be facilely modulated by the content of CeO2 QDs introduced in SCN matrix while bare CeO2 does not show activity of hydrogen production.The optimal catalyst with 10% of CeO2 loading yields a hydrogen evolution rate of 2923.8 μmol h-1 g-1 under visible light,remarkably higher than that of bare SCN and their physical mixtures.Further studies reveal that the abundant surface defects and the created 0 D/1 D junctions play a critical role in improving the separation and transfer of charge carriers,leading to superior solar hydrogen production and good stability. 展开更多
关键词 Photocatalytic hydrogen evolution Ceria quantum dots Sulfur-doped carbon nitride nanotubes surface defects Charge separation
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Laser ultrasonic technique for surface defects detection of 6061 aluminum alloy 被引量:2
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作者 LI Hai-yang WEI Zhuang-zhuang PAN Qiang-Hua 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2019年第3期293-298,共6页
In order to estimate and detect the surface defect depth of metals, the transmission method of laser ultrasonic surface waves is used in this work. The laser ultrasonic detection platform taking use of thermoelastic m... In order to estimate and detect the surface defect depth of metals, the transmission method of laser ultrasonic surface waves is used in this work. The laser ultrasonic detection platform taking use of thermoelastic mechanism as acoustic signal excitation method and interference receiver as acoustic signal receiver method was built, by which B-scan images of detected specimens with surface defects were collected to establish the relationship between the transmission coefficient and depth of the surface defect. Experimental results show that the amplitude of transmitted acoustic signal is related to the depth of surface defect. At last, a fitted curve of transmission coefficient using measured experimental data is obtained to estimate depth of surface defect on the 6061 aluminum alloy. Furthermore, a surface defect depth of 0.3 mm is estimated by the fitting curve with an estimated error of 16%. Therefore, a experimental method using the transmission method by laser ultrasonic is presented in this paper. 展开更多
关键词 laser ultrasonics transmission method surface defect depth detection
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A fast detection algorithm for ceramic ball surface defects based on fringe reflection 被引量:2
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作者 SUN Ying FU Lu-hua WANG Zhong 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2020年第1期28-37,共10页
A ceramic ball is a basic part widely used in precision bearings.There is no perfect testing equipment for ceramic ball surface defects at present.A fast visual detection algorithm for ceramic ball surface defects bas... A ceramic ball is a basic part widely used in precision bearings.There is no perfect testing equipment for ceramic ball surface defects at present.A fast visual detection algorithm for ceramic ball surface defects based on fringe reflection is designed.By means of image preprocessing,grayscale value accumulative differential positioning,edge detection,pixel-value row difference and template matching,the algorithm can locate feature points and judge whether the spherical surface has defects by the number of points.Taking black silicon nitride ceramic balls with a diameter of 6.35 mm as an example,the defect detection time for a single gray scale image is 0.78 s,and the detection limit is 16.5μm. 展开更多
关键词 ceramic ball surface defect fringe reflection visual detection algorithm
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Creation of surface defects on carbon nanofibers by steam treatment 被引量:1
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作者 Zhengfeng Shao Min Pang +2 位作者 Wei Xia Martin Muhler Changhai Liang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2013年第5期804-810,共7页
A direct strategy for the creation of defects on carbon nanofibers (CNFs) has been developed by steam treatment.Nitrogen physisorption,XRD,Raman spectra,SEM and TEM analyses proved the existence of the new defects on ... A direct strategy for the creation of defects on carbon nanofibers (CNFs) has been developed by steam treatment.Nitrogen physisorption,XRD,Raman spectra,SEM and TEM analyses proved the existence of the new defects on CNFs.BET surface area of CNFs after steam treatment was enhanced from 20 to 378 m2/g.Pd catalysts supported on CNFs were also prepared by colloidal deposition method.The different activity of Pd/CNFs catalysts in the partial hydrogenation of phenylacetylene further demonstrated the diverse surfaces of CNFs could be formed by steam treatment. 展开更多
关键词 carbon nanofibers surface defects steam treatment PALLADIUM
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Research on Surface Defect Detection Method of E-TPU Midsole Based on Machine Vision 被引量:2
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作者 Ruizhi Li Fang Tian Shiqiang Chen 《Journal of Computer and Communications》 2020年第11期145-160,共16页
In the industrial production of expanded thermoplastic polyurethane (E-TPU) midsoles, the surface defects still rely on manual inspection at present, and the eligibility criteria are uneven. Therefore, this paper prop... In the industrial production of expanded thermoplastic polyurethane (E-TPU) midsoles, the surface defects still rely on manual inspection at present, and the eligibility criteria are uneven. Therefore, this paper proposes an E-TPU midsole surface defect detection method based on machine vision to achieve automatic detection and defect classification. The proposed method is divided into three parts: image preprocessing, block defect detection, and linear defect detection. Image preprocessing uses RGB three channel self-inspection to identify scorch and color pollution. Block defect detection uses superpixel segmentation and background prior mining to determine holes, impurities, and dirt. Linear defect detection uses Gabor filter and Hough transform to detect indentation and convex marks. After image preprocessing, block defect detection and linear defect detection are simultaneously performed by parallel computing. The false positive rate (FPR) of the proposed method in this paper is 8.3%, the false negatives rate (FNR) of the hole is 4.7%, the FNR of indentation is 2.1%, and the running time does not exceed 1.6 s. The test results show that this method can quickly and accurately detect various defects in the E-TPU midsole. 展开更多
关键词 Midsole surface defect Detection Image Processing Linear defect Detection Block defect Detection
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Impact of Methanol Photomediated Surface Defects on Photocatalytic H2 Production Over Pt/TiO2 被引量:1
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作者 Zhi Jiang Rongjie Qi +3 位作者 Zhengwen Huang Wenfeng Shanggguan Roong Jien Wong Adam Lee 《Energy & Environmental Materials》 2020年第2期202-208,共7页
Co-catalysts play a critical role in enhancing the efficiency of inorganic semiconductor photocatalysts;however,synthetic approaches to tailoring cocatalyst properties are rarely the focus of research efforts.A photom... Co-catalysts play a critical role in enhancing the efficiency of inorganic semiconductor photocatalysts;however,synthetic approaches to tailoring cocatalyst properties are rarely the focus of research efforts.A photomediated route to control the dispersion and oxidation state of a platinum(Pt)cocatalyst through defect generation in the P25 titania photocatalyst substrate is reported.Titania photoirradiation in the presence of methanol induces longlived surface defects which subsequently promote the photodeposition of highly dispersed(2.2±0.8 nm)and heavily reduced Pt nanoparticles on exposure to H2 PtCl6.The optimal methanol concentration of 20 vol%produces the highest density of metallic Pt nanoparticles.Photocatalytic activity for water splitting and associated hydrogen(H2)production under UV irradiation mirrors the methanol concentration employed during the P25 photoirradiation pretreatment and resulting Pt loading resulting in a common mass-normalized H2 productivity of 3800±130 mmol gpt-1 h-1.Photomediated surface defects(arising in the presence of a methanol hole scavenger)provide electron traps that regulate subsequent photodeposition of a Pt co-catalyst over P25,offering a facile route to tune photocatalytic efficiency. 展开更多
关键词 METHANOL PLATINUM surface defects TITANIUM
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Contribution of Surface Defects to the Interface Conductivity of SrTiO_3/LaAlO_3
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作者 关丽 谈凤雪 +3 位作者 贾国奇 申光明 刘保亭 李旭 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第8期105-108,共4页
Based on the first-principles method, the structural stability and the contribution of point defects such as O, Sr or Ti vacancies on two-dimensional electron gas of n- and p-type LaAlO3/SrTiO3 interfaces are investig... Based on the first-principles method, the structural stability and the contribution of point defects such as O, Sr or Ti vacancies on two-dimensional electron gas of n- and p-type LaAlO3/SrTiO3 interfaces are investigated. The results show that O vacancies at p-type interfaces have much lower formation energies, and Sr or Ti vacancies at n-type interfaces are more stable than the ones at p-type interfaces under O-rich conditions. The calculated densities of states indicate that O vacancies act as donors and give a significant compensation to hole carriers, resulting in insulating behavior at p-type interfaces. In contrast, Sr or Ti vacancies tend to trap electrons and behave as acceptors. Sr vacancies are the most stable defects at high oxygen partial pressures, and the Sr vacancies rather than Ti vacancies are responsible for the insulator-metal transition of n-type interface. The calculated results can be helpful to understand the tuned electronic properties of LaAlO3 /SrTiO3 heterointerfaces. 展开更多
关键词 of LAO in on STO Contribution of surface defects to the Interface Conductivity of SrTiO3/LaAlO3 for
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AN EFFICIENT LABELLING ALGORITHM FOR WOODPANELS SURFACE DEFECTS
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作者 王克奇 《Journal of Northeast Forestry University》 SCIE CAS CSCD 1995年第4期54-57,共4页
This paper describes an efficient approach for labeling images using a combination of pipeline (Datacube) and (general purpose computer) processing. The output of the algorithm is coordinate list of labeled object pix... This paper describes an efficient approach for labeling images using a combination of pipeline (Datacube) and (general purpose computer) processing. The output of the algorithm is coordinate list of labeled object pixels that facilitates further high level operations. It is an efficient labeling algorithm for a automatic classification of surface defects on wood boards. 展开更多
关键词 Image modeling Patter recognition WOOD surface defects
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Effects of Surface Defects on Adsorption of CO and Methyl Groups on Rutile TiO_(2)(110)
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作者 Deng-fang Tang Xiao Chen +1 位作者 Qing Guo Wen-shao Yang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2021年第3期249-255,I0013,I0014,I0047,共10页
The interaction of reactants with catalysts has always been an important subject for catalytic reactions.As a promising catalyst with versatile applications,titania has been intensively studied for decades.In this wor... The interaction of reactants with catalysts has always been an important subject for catalytic reactions.As a promising catalyst with versatile applications,titania has been intensively studied for decades.In this work we have investigated the role of bridge bonded oxygen vacancy(O_(v))in methyl groups and carbon monoxide(CO)adsorption on rutile TiO_(2)(110)(R-TiO_(2)(110))with the temperature programmed desorption technique.The results show a clear different tendency of the desorption of methyl groups adsorbed on bridge bonded oxygen(O_(b)),and CO molecules on the five coordinate Ti^(4+)sites(Ti_(5c))as the Ovconcentration changes,suggesting that the surface defects may have crucial influence on the absorption of species on different sites of R-TiO_(2)(110). 展开更多
关键词 Temperature programmed desorption TiO_(2)(110) Bridge bonded oxygen vacancy Adsorption sites surface defects
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