Surface-induced Microstructure and Performance Changes in P3HT Ultrathin Films

In this work,poly(3-hexylthiophene)(P3HT)ultrathin films(P3HT-T)were prepared by spin-coating a dilute P3HT solution(in a toluene:o-dichlorobenzene(Tol:ODCB)blend with a volume ratio of 80:20)with ultrasonication and the addition of the nucleating agent bicycle[2.2.1]heptane-2,3-dicarboxylic acid disodium salt(HPN-68L)on glass,Si wafers and indium tin oxide(ITO)substrates.The electrical and mechanical properties of the P3HT-T ultrathin films were investigated,and it was found that the conductivity and crack onset strain(COS)were simultaneously improved in comparison with those of the corresponding pristine P3HT film(P3HT-0,without ultrasonication and nucleating agent)on the same substrate,regardless of what substrate was used.Moreover,the conductivity of P3HT-T ultrathin films on different substrates was similar(varying from 3.7 S·cm^(-1)to 4.4 S·cm^(-1)),yet the COS increased from 97%to 138%by varying the substrate from a Si wafer to ITO.Combining grazing-incidence wide-angle X-ray diffraction(GIXRD),UV-visible(UV-Vis)spectroscopy and atomic force microscopy(AFM),we found that the solid order and crystallinity of the P3HT-T ultrathin film on the Si wafer are highest,followed by those on glass,and much lower on ITO.Finally,the surface energy and roughness of three substrates were investigated,and it was found that the polar component of the surface energyγp plays a critical role in determining the crystalline microstructures of P3HT ultrathin films on different substrates.Our work indicates that the P3HT ultrathin film can obviously improve the stretchability and simultaneously retain similar electrical performance when a suitable substrate is chosen.These findings offer a new direction for research on stretchable CP ultrathin films to facilitate future practical applications.

Spatial distribution of surface energy fluxes over the Loess Plateau in China and its relationship with climate and the environment

China's Loess Plateau is located at the edge of the Asian summer monsoon in a transition zone of climate and ecology. In the Loess Plateau, climate and environments change along with space, which has an obvious impact on the spatial distribution of surface energy fluxes. Because of scarce land-surface observation sites and short observation time in this area, previous studies have failed to fully understand the land-surface energy balance characteristics over the entire the Loess Plateau and their effect mechanisms. In this paper, we first test the simulation ability of the Community Land Model(CLM) model by comparing its simulated data with observed data. Based on the simulation data for the Loess Plateau over the past thirty years, we then analyze the spatial distribution of surface energy fluxes and compare the pattern differences between the area averages for the driest year and wettest year. Furthermore, we analyze the relationship between the spatial distribution of the components of the surface energy balance with longitude, latitude, altitude, precipitation and temperature. The main results are as follows: the spatial distribution of surface energy fluxes are significantly different, with the surface net radiation and sensible heat flux increasing from south to north and latent heat flux and soil heat flux decreasing from southeast to northwest. The sensible heat flux at the driest point is nearly twice as high as that at the wettest point, whereas the latent heat flux and soil heat flux at the driest point are half as much as that at the wettest point. The impact of variations of annual precipitation on the components of the surface energy balance is also obvious, and the maximum magnitude of the changes to the sensible heat flux and latent heat flux is nearly 30%. To a certain extent, geographical factors(including longitude, latitude, and altitude) and climate factors(including temperature and precipitation) affect the surface energy fluxes. However, the surface net radiation is more closely related to latitude and altitude, sensible heat flux is more closely related to the monsoon rainfall and latitude, and latent heat flux and soil heat flux are more closely related to the monsoon rainfall.