Surface Loess Susceptibility Anomalies Directly Indicating Oil and Gas Reservoirs

It is a fact that the near surface loess has magnetic susceptibility anomalies in oil and gas areas. Why these anomalies occur and whether they have any significant value for the exploration of oil and gas reservoirs are questions that geophysicists are mostly concerned about and study. We analyze the cause of the formation of surface loess susceptibility anomalies in oil and gas areas, process the observations of the susceptibility of loess samples taken from an oil and gas area in western China with proper mathematical methods, and determine the background value of loess susceptibility. These results are used to determine oil and gas prospect areas with a numeric evaluation factor based on the susceptibility anomalies. Actual oil wells have verified that using the susceptibility anomalies to indicate the location of oil and gas reservoirs is valid.

Approach to increasing the quality of pressure-relieved gas drained from protected coal seam using surface borehole and its industrial application

During mining of lower protective coal seam, a surface borehole can efficiently extract not only the pressure-relieved gas from the protected layer, but also the gas from the mining layer gob. If the distance between the borehole and gob is too large, the quantity of gas drained from the protected layer decreases substantially. To solve this problem, a mathematical model for extracting pressure-relieved gas from a protected coal seam using a surface borehole was established, based on the radial gas flow theory and law of conservation of energy. The key factors influencing the quantity of gas and the drainage flow network using a surface borehole were presented. The results show that the quantity of pressure-relieved gas drained from the protected layer can be significantly increased by increasing the flow resistance of the borehole bottom. Application of this method in the Wulan Coal Mine of the Shenhua Group significantly increased the flow of pure gas and the gas concentration （by factors of 1.8 and 2.0, respectively）, thus demonstrating the remarkable effects of this method.

Study of the Surface Morphology of Gas Hydrate

Study of the surface morphology of gas hydrate is of great importance in understanding its physical properties and occurrence.In order to investigate the surface morphology of different types(sI and sII)and occurrences(pore-filling and fracture-filling)of gas hydrate,both lab-synthesized and drilled-gas hydrate samples were measured using cryo-scanning electron microscopy(cryo-SEM).Results showed that the surface of s I hydrate was relatively smooth,and spongy nano-pores(200–400 nm)gradually occurred at the surface during continuous observation.The surface of sII hydrate was more compact,showing a tier-like structure.Hydrate occurred in quartz sand and usually filled the pores of the sediments and both hydrate and sediments were cemented with each other.SEM observation of the gas hydrates collected from the South China Sea showed that the surface morphology and contact relation with sediments varied with hydrate occurrence.For instance,hydrates dispersed in sediments mainly filled the pores of the sediments.The existence of microorganism shells,such as foraminifera,was beneficial to the formation of gas hydrate.When hydrate occurred as a massive or vein structure,it was easily distinguished from the surrounding sediments.The surface of hydrate with massive or vein structure showed two distinct characters:one was dense and smooth,the other is porous(several to tens of micrometers in diameter).The occurrence of different hydrate morphologies was probably caused by the supplement rates of methane gas.

Research on forced gas draining from coal seams by surface well drilling

Surface drilling was performed at the Luling Coal Mine,in Huaibei,to shorten the period required for gas draining.The experimental study was designed to reduce the cost of gas control by efficiently draining gas from the upper protected layer.The structural arraignment and technical principles of pressure relief via surface drilling are discussed.Results from the trial showed that gas drained from the surface system over a period of 10 months.The total amount of collected gas was 248.4 million m^3.The gas draining occurred in three stages：a growth period;a period of maximum gas production;and an attenuation period.The period of maximum gas production lasted for 4 months.During this time the methane concentration ranged from 60%to 90%and the average draining rate was 10.6 m^3/min.Combined with other methods of draining it was possible to drain 70.6%of the gas from middle coal seam groups.The amount of residual gas dropped to 5.2 m^3/ton,and the pressure of the residual gas fell to 0.53 MPa, thereby eliminating the outburst danger in the middle coal seam groups.The factors affecting pressure relief gas draining by surface drilling were analysed.

The simulation of gas production from oceanic gas hydrate reservoir by the combination of ocean surface warm water flooding with depressurization

A new method is proposed to produce gas from oceanic gas hydrate reservoir by combining the ocean surface warm water flooding with depressurization which can efficiently utilize the synthetic effects of thermal, salt and depressurization on gas hydrate dissociation. The method has the advantage of high efficiency, low cost and enhanced safety. Based on the proposed conceptual method, the physical and mathematical models are established, in which the effects of the flow of multiphase fluid, the kinetic process of hydrate dissociation, the endothermic process of hydrate dissociation, ice-water phase equilibrium, salt inhibition, dispersion, convection and conduction on the hydrate disso- ciation and gas and water production are considered. The gas and water rates, formation pressure for the combination method are compared with that of the single depressurization, which is referred to the method in which only depres- surization is used. The results show that the combination method can remedy the deficiency of individual producing methods. It has the advantage of longer stable period of high gas rate than the single depressurization. It can also reduce the geologic hazard caused by the formation defor- mation due to the maintaining of the formation pressure by injected ocean warm water.

Viscoelastic Analysis of a Surface Acoustic Wave Gas Sensor Coated by a New Deposition Technique

An analysis of the response of surface acoustic wave sensors coated with polymer film based on new coating deposition （self-assemble and molecularly imprinted technology） is described and the response formulas are hence deduced. Using the real part of shear modulus, the polymer can be classified into three types： glassy film, glassy-rubbery film and rubbery film, Experimental results show that the attenuation response is in better consistence with the simulation than in Martin＇s theory, but the velocity response does not accord with the calculation exactly. Maybe it is influenced by the experimental methods and environment. In addition, simulations of gas sorption for polymer films are performed. As for glassy film, the SAW sensor response increases with increasing fihn thickness, and the relationship between the sensor response and the concentration of gas is pretty linear, while as for glassy-rubbery flint and rubbery film, the relationship between the sensor sensitivity anti concentration of gas is very complicated. The ultimately calculated results indicate that the relationship between the sensor response and frequency is not always linear due to the viscoelastic prooerties of the polymer.

Influence of the Moho surface distribution on the oil and gas basins in China seas and adjacent areas

Owing to the strategic significance of national oil and gas resources,their exploration and production must be prioritized in China.Oil and gas resources are closely related to deep crustal structures,and Moho characteristics influence oil and gas distribution.Therefore,it is important to study the relationship between the variation of the Moho surface depth undulation and hydrocarbon basins for the future prediction of their locations.The Moho depth in the study area can be inverted using the Moho depth control information,the Moho gravity anomaly,and the variable density distribution calculated by the infinite plate.Based on these results,the influences of Moho characteristics on petroleum basins were studied.We found that the Moho surface depth undulation deviation and crustal thickness undulation deviation in the hydrocarbon-rich basins are large,and the horizontal gradient deviation of the Moho surface shows a positive linear relationship with oil and gas resources in the basin.The oil-bearing mechanism of the Moho basin is further discussed herein.The Moho uplift area and the slope zone correspond to the distribution of oil and gas fields.The tensile stress produced by the Moho uplift can form tensile fractures or cause tensile fractures on the surface,further developing into a fault or depression basin that receives deposits.The organic matter can become oil and natural gas under suitable chemical and structural conditions.Under the action of groundwater or other dynamic forces,oil and natural gas are gradually transported to the uplift or the buried hill in the depression zone,and oil and gas fields are formed under the condition of good caprock.The research results can provide new insights into the relationship between deep structures and oil and gas basins as well as assist in the strategic planning of oil and gas exploration activities.

Fractal characteristics of surface crack evolution in the process of gas-containing coal extrusion

In this paper, simulated experiment device of coal and gas outburst was employed to perform the experiment on gas-containing coal extrusion. In the experiment, coal surface cracks were observed with a high-speed camera and then the images were processed by sketch. Based on the above description, the paper studied the fractal dimension values from different positions of coal surface as well as their changing laws with time. The results show that there is a growing parabola trend of crack dimension value in the process of coal extrusion. Accordingly, we drew the conclusion that extruded coal crack evolution is a process of fractal dimension value increase. On the basis of fractal dimension values taken from different parts of coal masses, a fractal dimension of the contour map was drawn. Thus, it is clear that the contour map involves different crack fractal dimension values from different positions. To be specific, where there are complicated force and violent movement in coal mass, there are higher fractal dimension values, i.e., the further the middle of observation surface is from the exit of coal mass, and the lower the fractal dimension value is. In line with fractal geometry and energy theory of coal and gas outburst, this study presents the relation between fractal dimension and energy in the process of extruding. In conclusion, the evolution of crack fractal dimension value can signify that of energy, which has laid a solid foundation for the quantification research on the mechanism of gas-containing coal extrusion.

Different Responses of Sea Surface Temperature in the North Pacific to Greenhouse Gas and Aerosol Forcing

The responses of Sea Surface Temperature(SST) to greenhouse gas(GHG) and anthropogenic aerosol in the North Pa- cific are compared based on the historical single and all-forcing simulations with Geophysical Fluid Dynamics Laboratory Climate Model version 3(GFDL CM3). During 1860–2005, the effect of GHG forcing on the North Pacific SST is opposite to that of the aerosol forcing. Specifically, the aerosol cooling effect exceeds the GHG warming effect in the Kuroshio Extension(KE) region dur- ing 1950–2004 in the CM3 single forcing. The mid-latitude response of ocean circulation to the GHG(aerosol) forcing is to enhance(weaken) the Subtropical Gyre. Then the SST warming(cooling) lies on the zonal band of 40?N because of the increased(reduced) KE warm advection effect in the GHG(aerosol) forcing simulations, and the cooling effect to SST will surpass the warming effect in the KE region in the historical all-forcing simulations. Besides, the positive feedback between cold SST and cloud can also strengthen the aerosol cooling effect in the KE region during boreal summer, when the mixed layer depth is shallow. In the GHG(aerosol) forcing simulations, corresponding to warming(cooling) SST in the KE region, the weakened(enhanced) Aleutian Low appears in the Northeast Pacific. Consequently, the SST responses to all-forcing in the historical simulations are similar to the re- sponses to aerosol forcing in sign and spatial pattern, hence the aerosol effect is quite important to the SST cooling in the mid-latitude North Pacific during the past 55 years.

Support surface pore structures matter: Effects of support surface pore structures on the TFC gas separation membrane performance over a wide pressure range

In this work, the effects of support surface pore structures(including surface pore size, surface pore density and surface porosity) on the performance of thin film composite(TFC) gas separation membrane over a wide pressure range(from 0.3 to 2.0 MPa) were studied. To fulfill it, the polysulfone(PSf) supports with different surface pore structures were prepared. Two kinds of wide-accepted polymeric membrane materials, i.e., polyvinylamine(PVAm) and Pebax 1657 copolymer, were used as skin layer materials. We pointed out for the first time that the support surface average pore size and pore density could affect the chain mobility of polymer of skin layer at the support surface pore entrance, then, can affect the TFC membrane performance. Besides, we also discussed the effects of support on the TFC membrane performance when the feed pressure changes for the first time. This work can provide guidance for choosing a suitable support for TFC gas separation membrane.

A new hypothesis for cavitation nucleation in gas saturated solutions:Clustering of gas molecules lowers significantly the surface tension

Cavitation in water generally takes place at much lower negative pressure than predicted from theories.In this work,we try to stress the discrepancy from the influence of the dissolved gas on cavitation nucleation.By combining molecular dynamics simulation and thermodynamic analysis,we evaluated the lowering of surface tension as a function of density of gas molecules in gas clusters formed in aqueous solution.We found that the obtained surface tension of small gas clusters is much more substantially reduced than expected.The surface tension lowering and the non-ideality of gas molecules in the clusters are then taken into account in determining the nucleation of cavitation,and as a consequence,the required negative pressure for cavitation becomes comparable to experimental values.Thus,we give an alternative explanation for the discrepancy of cavitation pressure between experiment and theory,i.e.,it is the substantially reduced surface tension for small gas nuclei,which have not been taken into account in theory,along with the ideal gas approxiamtion that induce its deviation from the experimental values.

Investigation on the electrode surface roughness effects on a repetitive self-breakdown gas switch

In this work,the influence of the electrode surface roughness on the self-breakdown gas switch is investigated by physical analysis,computer simulation and experiment.Cu-W electrodes of different surface roughness were tested under the conditions of a pulse repetitive frequency of50 Hz,self-breakdown voltage of~30 kV,and peak current of~2 k A for~93000 shots(the total charge transferred was~15 C).The coefficients of variation of the self-breakdown voltage of Cu-W 0.8,Cu-W 3.2 and Cu-W 12.5 electrodes were~2.95%,~1.62%and~1.16%,respectively.With the increase of electrode roughness,the erosion area decreased continuously,indicating that the breakdown positions were more stable and the coefficient of variation of breakdown voltage decreased.The method showed that decreasing the coefficient of variation of the self-breakdown voltage by increasing the surface roughness of electrode greatly improves the stability of the self-breakdown switch,which is significant for their application in compact highpower pulse power devices over a long time with stable operation.

The effect of surface roughness on rarefied gas flows by lattice Boltzmann method

This paper studies the roughness effect combining with effects of rarefaction and compressibility by a lattice Boltzmann model for rarefied gas flows at high Knudsen numbers. By discussing the effect of the tangential momentum accommodation coefficient on the rough boundary condition, the lattice Boltzmann simulations of nitrogen and helium flows are performed in a two-dimensional microchannel with rough boundaries. The surface roughness effects in the microchannel on the velocity field, the mass flow rate and the friction coefficient are studied and analysed. Numerical results for the two gases in micro scale show different characteristics from macroscopic flows and demonstrate the feasibility of the lattice Boltzmann model in rarefied gas dynamics.

Impinging Cooling with a Crescent Surface Inspired by Barchan Dunes in a Simplified Gas Turbine Transition Section

For the enhancement of heat transfer efficiency,a novel turbulator inspired by the morphology of barchan dunes,called the mimetic barchan dune(MBD)turbulator,is designed and evaluated in the simplified gas turbine transition section.By using computational fluid dynamics(CFD),the numerical simulations for comparison have been carried out,concluding the smooth thermal surface,a thermal surface with riblet-shaped turbulator and a thermal surface with MBD turbulator.Then,two indicators are investigated for evaluating the coolant performance which are the heat transfer efficiency(η)on the outlet and the pressure loss(ΔP)in the coolant chamber.The numerical results show that the coolant has the best heat transfer efficiency with less pressure loss in the coolant chamber with the MBD turbulator.Then,the effect of the MBD turbulator sizes on heat transfer efficiency is investigated.When the height of the MBD turbulator(h)is set at 8 mm,the maximum amount of heat that could be transfered by the coolant is up to566.2 K and the corresponding heat transfer efficiency is 26.62%.The detail flows have been shown to elucidate the function of the MBD surface which may greatly arouse more design for solving harsh circumstance.

Surface performance of workpieces processed by electrical discharge machining in gas

The surface performance of workpieces processed by electrical discharge machining in gas(dry EDM)was studied in this paper.Firstly,the composition,micro hardness and recast layer of electrical discharge machined(EDMed)surface of 45 carbon steels in air were investigated through different test analysis methods.The results show that the workpiece surface EDMed in air contains a certain quantity of oxide,and oxidation occurs on the workpiece surface.Compared with the surface of workpieces processed in kerosene,fewer cracks exist on the dry EDMed workpiece surface,and the surface recast layer is thinner than that obtained by conventional EDM.The micro hardness of workpieces machined by dry EDM method is lower than that machined in kerosene,and higher than that of the matrix.In addition,experiments were conducted on the surface wear resistance of workpieces processed in air and kerosene using copper electrode and titanium alloy electrode.The results indicate that the surface wear resistance of workpieces processed in air can be improved,and it is related with tool material and dielectric.

Application of response surface methodology for optimization of purge gas recycling to an industrial reactor for conversion of CO_2 to methanol

Nowadays, by the increasing attention to environment and high rate of fuel production, recycling of purge gas as reactant to a reactor is highly considered. In this study, it is proposed that the purge gases of methanol production unit, which are approximately15.018 t·h^(-1) in the largest methanol production complexes in the world, can be recycled to the reactor and utilized for increasing the production rate. Purge gas streams contain 63% hydrogen,20% carbon monoxide and carbon dioxide as reactants and 17% nitrogen and methane as inert. The recycling effect of beneficial components on methanol production rate has been investigated in this study. Simulation results show that methanol production enhances by recycling just hydrogen, carbon dioxide and carbon monoxide which is an effective configuration among the others. It is named as Desired Recycle Configuration(DRC) in this study. The optimum fraction of returning purge gas is calculated via one dimensional modeling of process and Response Surface Methodology(RSM) is applied to maximize the methanol flow rate and minimize the carbon dioxide flow rate. Simulation results illustrate that methanol flow rate increases by 0.106% in DRC compared to Conventional Recycle Configuration(CRC) which therefore shows the superiority of applying DRC to CRC.

Forming characteristics of triple-wire gas indirect arc surfacing

Based on the advantages of triple-wire gas indirect arc welding(TW-GIA),such as small heat input,low dilution rate,and high deposition rate,the surfacing test on Q345 steel was carried out,and the surfacing forming characteristics of TW-GIA were studied.Results showed that due to excessive wetting angle of the weld and the limitation of the heat source mode,there was unfused defect between the weld toes of the adjacent welds.To improve the morphology of the surfacing layer,the inclined substrate surfacing process was used.As the inclination angle increases,the size of unfused defect between adjacent welds gradually decreases.When the angle of inclination is in-creased to 30°-40°,the single-layer multi-pass surfacing layer with uniform forming and available fusion between welds can be achieved.Compared with tandem double-wire arc(T-DW)surfacing,the deposition rate of TW-GIA increased by 61.49%,while the dilution rate of the base metal decreased by 71.91%.The surfacing method has the advantages of a high deposition rate and low heat input,which is benefi-cial to improve the microstructure of the surfacing layer,making the coarse columnar crystals smaller,and improving the microhardness.The average microhardness level is 233.1 HV,which is higher than the average microhardness of the T-DW surfacing layer 220.4 HV.

The effects of gas flow pattern on the generation of ozone in surface dielectric barrier discharge

Ozone production utilizing surface dielectric barrier discharge（SDBD） was experimental studied for different flow patterns considering the influences of transversal flow, lateral flow and different lateral flow positions. Results show that the flow patterns have a remarkable impact on the ozone yield by affecting the uniformity and turbulence of gas flow. Meanwhile, distributing the O2 flow rate according to the intensity of the plasma reaction would also increase the generation efficiency of SDBD for ozone production. By improving the uniformity and introducing the lateral flow to the transversal flow, the highest ozone yield was obtained in flow pattern ‘F’. In this case, the ozone yield increased by 28.4% to 131 g kWh-1 from 102.8 g k Wh-1 in flow pattern ‘A’.

Surface Geochemical Patterns over Oil and Gas Traps

Surface geochemical exploration for oil and gas is still in the empirical stage , despite 50 years has passed since the method was first proposed by Laubmeyer and Sokolov . A boom of its application is emerging in China followed the depression during 60 - 70 's . However , before the method can be accepted by the industry as a routine technique , a relatively sound basis should be established . This paper presents several cases over known oil and gas fields and discusses the factors that effect the surface geochemical expression of underground oil pools .

Surface Characterization of Glass Fiber by Inverse Gas Chromatography

The surface properties of glass fiber were quantificationally analyzed by inverse gas chromatography （IGC）. Five n-alkanes （C6, C7, C8, C9, and C10） were chosen as apolar probes to characterize the dispersive component of surface free energy. Trichloromethane （CHCl3）, acetone, and tetrahydrofuran （THF） were chosen as polar probes to detect the Lewis acid-base parameters. It is found that the dispersive components of free energy are 32.3, 30.5, 27.5, and 26.9 mJ/m^2 at 70, 80, 90, and 100 ℃. respectively. The Lewis acidic number Ka of the glass fiber is 0.512 4, and the basic number Kb is 2.862. The results mean the glass fiber is a Lewis basic material.