Vanadium films were prepared on zinc surfaces by using a solution containing vanadate. Corrosion protection properties of vanadium-treated （V-treated）, chromium-treated （Cr-treated）, and untreated zinc surfaces in...Vanadium films were prepared on zinc surfaces by using a solution containing vanadate. Corrosion protection properties of vanadium-treated （V-treated）, chromium-treated （Cr-treated）, and untreated zinc surfaces in contact with a 3.5 wt.% NaC1 solution were studied using potentiodynamic polarization, electrochemical impedance spectroscopy （EIS）, and neutral salt spray （NSS） tests. According to these results, the V-treated layer significantly improved the corrosion resistance of zinc surfaces. In comparison with the Cr-treated layer, the V-treated layer exhibited a better corrosion resistance. The composition of the V-treated layer was studied using X-ray photoelectron spectroscopy （XPS）. XPS measurements indicated that the vanadium layer formed on zinc surfaces and the vanadium-rich coating was a hydrated oxide with a composition of V2O5, VO2, and its hydrates such as V2O5.nH2O and VO（OH）2.展开更多
Sulphur dioxide （SO 2 ） mixed with carrier gases was used as an alternative to SF 6 to protect molten magnesium alloys. The protection behavior of AZ91D alloy in a sealed melting furnace was investigated under the a...Sulphur dioxide （SO 2 ） mixed with carrier gases was used as an alternative to SF 6 to protect molten magnesium alloys. The protection behavior of AZ91D alloy in a sealed melting furnace was investigated under the atmosphere containing SO 2 with different mixed gases. The morphology and composition of the surface film were studied. The melt was well protected in an atmosphere of SO 2 and a proper amount of air, and was not protected properly in the other atmospheres. Based on the understanding of the protective effects of SO 2 in the sealed furnace, the protection mechanism of SO 2 -containing cover gases on molten AZ91D alloy was studied in an open melting furnace. The cover gas protected the melt by reacting with the melt to form a coherent protective film with a network structure on the melt surface. The film contains MgO and MgS. MgS increases the Pilling and Bedworth ratio of the surface film and enhances the protective capability of the films.展开更多
The sulphur hexa-fluoride gas（SF6）, which is commonly used as the cover gas of molten magnesium alloys in the magnesium industry today, has an extremely high global warming potential（GWP）. The protection mechanism...The sulphur hexa-fluoride gas（SF6）, which is commonly used as the cover gas of molten magnesium alloys in the magnesium industry today, has an extremely high global warming potential（GWP）. The protection mechanism of SF6 containing cover gases on molten magnesium alloys was presented. The cover gas protects the melt by reacting with the melt to form a coherent protective film on the melt surface. The film contains MgO and MgF2. Particles containing MgF2 form on the interface between the oxide film and the bulk magnesium alloy, which correspond to the concave areas from the surface observation. These particles increase the Pilling and Bedworth ratio of surface film and enhance the protective capability of the films. Based on the understanding of the mechanism of SF6, a melting technology in a sealed furnace was proposed, and the protection behavior of magnesium alloys in the sealed melting furnace was investigated under the protective atmosphere containing HFC-134a. The morphology and composition of the surface film were also studied. Experiments to evaluate the protective effect of two other fluorine containing gases with low GWPs on AZglD alloy in the sealed furnace were also carried out, and the results show that the new gases are potential substitutes for SF6.展开更多
Phenolic formaldehyde(PF)and epoxy(EP)resins are commonly used in electronic packaging. In this paper, high-ohmic resistors(2.2 M?, ±0.5%,)with Cr-Si film were coated by PF/EP paint, and the resulting coated resi...Phenolic formaldehyde(PF)and epoxy(EP)resins are commonly used in electronic packaging. In this paper, high-ohmic resistors(2.2 M?, ±0.5%,)with Cr-Si film were coated by PF/EP paint, and the resulting coated resistors were used for heat and humid(HH)experiments. The experimental results show that the corrosion of bandlike resistive films is selective and isotropic, and that the corrosion spots in resistive films all form along grooves and extend in the same direction. It is revealed that OH^- ions are generated due to the electrochemical reactions of resistive film in HH experiments, so a NaOH aqueous solution with pH about 10 was used to study the effects of absorbed water and OH^- ions on PF/EP polymer film. The results indicates that the color of some part on PF/EP polymer film changes due to corrosion, and that the corrosion part of the polymer film is easy to be peeled off. It can be inferred that OH^- ions generated in HH experiments may play a catalytic role in the chemical reactions between polymer film and the absorbed water, which accelerates the degradation of PF/EP protection film for a resistor.展开更多
文摘Vanadium films were prepared on zinc surfaces by using a solution containing vanadate. Corrosion protection properties of vanadium-treated （V-treated）, chromium-treated （Cr-treated）, and untreated zinc surfaces in contact with a 3.5 wt.% NaC1 solution were studied using potentiodynamic polarization, electrochemical impedance spectroscopy （EIS）, and neutral salt spray （NSS） tests. According to these results, the V-treated layer significantly improved the corrosion resistance of zinc surfaces. In comparison with the Cr-treated layer, the V-treated layer exhibited a better corrosion resistance. The composition of the V-treated layer was studied using X-ray photoelectron spectroscopy （XPS）. XPS measurements indicated that the vanadium layer formed on zinc surfaces and the vanadium-rich coating was a hydrated oxide with a composition of V2O5, VO2, and its hydrates such as V2O5.nH2O and VO（OH）2.
基金Project(2009AA03Z114)supported by the National High-tech Research and Development Program of ChinaProject(20090002110029)supported by the Specialized Research Fund for the Doctoral Program of Higher Education,China
文摘Sulphur dioxide （SO 2 ） mixed with carrier gases was used as an alternative to SF 6 to protect molten magnesium alloys. The protection behavior of AZ91D alloy in a sealed melting furnace was investigated under the atmosphere containing SO 2 with different mixed gases. The morphology and composition of the surface film were studied. The melt was well protected in an atmosphere of SO 2 and a proper amount of air, and was not protected properly in the other atmospheres. Based on the understanding of the protective effects of SO 2 in the sealed furnace, the protection mechanism of SO 2 -containing cover gases on molten AZ91D alloy was studied in an open melting furnace. The cover gas protected the melt by reacting with the melt to form a coherent protective film with a network structure on the melt surface. The film contains MgO and MgS. MgS increases the Pilling and Bedworth ratio of the surface film and enhances the protective capability of the films.
基金Project(2009AA03Z114)supported by the National High-Tech Research and Development Program of ChinaProject supported by Tsinghua-Toyo R&D Center of Magnesium and Aluminum Alloys Processing Technology,China
文摘The sulphur hexa-fluoride gas（SF6）, which is commonly used as the cover gas of molten magnesium alloys in the magnesium industry today, has an extremely high global warming potential（GWP）. The protection mechanism of SF6 containing cover gases on molten magnesium alloys was presented. The cover gas protects the melt by reacting with the melt to form a coherent protective film on the melt surface. The film contains MgO and MgF2. Particles containing MgF2 form on the interface between the oxide film and the bulk magnesium alloy, which correspond to the concave areas from the surface observation. These particles increase the Pilling and Bedworth ratio of surface film and enhance the protective capability of the films. Based on the understanding of the mechanism of SF6, a melting technology in a sealed furnace was proposed, and the protection behavior of magnesium alloys in the sealed melting furnace was investigated under the protective atmosphere containing HFC-134a. The morphology and composition of the surface film were also studied. Experiments to evaluate the protective effect of two other fluorine containing gases with low GWPs on AZglD alloy in the sealed furnace were also carried out, and the results show that the new gases are potential substitutes for SF6.
基金Supported by the National Natural Science Foundation of China(No.61201038)
文摘Phenolic formaldehyde(PF)and epoxy(EP)resins are commonly used in electronic packaging. In this paper, high-ohmic resistors(2.2 M?, ±0.5%,)with Cr-Si film were coated by PF/EP paint, and the resulting coated resistors were used for heat and humid(HH)experiments. The experimental results show that the corrosion of bandlike resistive films is selective and isotropic, and that the corrosion spots in resistive films all form along grooves and extend in the same direction. It is revealed that OH^- ions are generated due to the electrochemical reactions of resistive film in HH experiments, so a NaOH aqueous solution with pH about 10 was used to study the effects of absorbed water and OH^- ions on PF/EP polymer film. The results indicates that the color of some part on PF/EP polymer film changes due to corrosion, and that the corrosion part of the polymer film is easy to be peeled off. It can be inferred that OH^- ions generated in HH experiments may play a catalytic role in the chemical reactions between polymer film and the absorbed water, which accelerates the degradation of PF/EP protection film for a resistor.
