Optimization of Rolling Parameters for Enhancing Surface Integrity of Aluminum Alloy

In this current work,aluminum alloy grade 2024 is adopted as a plate material that is used in the rolling process with three different parameters including thickness reduction,forming temperature,and density of lubrication type.The experimental procedure of the rolling process is performed using the design of the experiment based on the Taguchi technique(L27),then surface roughness,surface hardness,and surface residual stresses are measured.The results showed that the lubrication density has a significant impact on the surface roughness which depends on the lubrication properties(mineral oil type,natural fat,and kinematic viscosity)while surface hardness and surface residual stresses were strongly affected by thickness reduction.On the other side,the augment in forming temperature can decrease the quality of the final surface finish and the surface hardness but reduce the induced residual stresses.The best surface finish is obtained based on the optimum condition of the rolling factors are(R%_(3),T_(1),andρ_(3))while the optimum condition of rolling parameters that generate higher hardness and compressive residual stresses are(R%_(3)T_(1)ρ_(1)).

Effect of surface stress and surface-induced stress on behavior of piezoelectric nanobeam

A new continuum model is developed to study the influence of surface stress on the behaviors of piezoelectric nanobeams. Different from existing piezoelectric surface models which only consider the surface properties, the proposed model takes surfaceinduced initial fields into consideration. Due to the fact that the surface-induced initial fields are totally different under various boundary conditions, two kinds of beams, the doubly-clamped beam and the cantilever beam, are analyzed. Furthermore, boundary conditions can affect not only the initial state of the piezoelectric nanobeam but also the forms of the governing equations. Based on the Euler-Bernoulli beam theory, the nonlin- ear Green-Lagrangian strain-displacement relationship is applied. In addition, the surface area change is also considered in the proposed model. The governing equations of the doubly-clamped and cantilever beams are derived by the energy variation principle. Com- pared with existing Young-Laplace models, the proposed model for the doubly-clamped beam is similar to the Young-Laplace models. However~ the governing equation of the cantilever beam derived by the proposed model is very different from that derived by the Young-Laplace models. The behaviors of piezoelectric nanobeams predicted by these two models Mso have significant discrepancies, which is owing to the surface-induced initial fields in the bulk beam.

An Objective Analysis Method for Surface Residual Current Field in the East China Seas

Since the volume transport across the pycnocline is much smaller than that in the mixed layer, the current in the mixed layer can be regarded as non-divergent. An objective analysis method is deduced based on this hypothesis. The linear combination method is used to solve the non-divergent component of the current field of an ocean basin containing islands,which is equivalent to a mathematical problem of solving a Poisson equation in a multi-connected domain. The method is applied to the Bohai Sea, the Yellow Sea and the East China Sea (ECS). The modeled result is consistent with the current maps constructed by other oceanographers.

Analytical Solutions for an Isotropic Elastic Half-Plane with Complete Surface Effects Subjected to a Concentrated/Uniform Surface Load

Within the context of Gurtin-Murdoch surface elasticity theory,closed-form analytical solutions are derived for an isotropic elastic half-plane subjected to a concentrated/uniform surface load.Both the effects of residual surface stress and surface elasticity are included.Airy stress function method and Fourier integral transform technique are used.The solutions are provided in a compact manner that can easily reduce to special situations that take into account either one surface effect or none at all.Numerical results indicate that surface effects generally lower the stress levels and smooth the deformation profiles in the half-plane.Surface elasticity plays a dominant role in the in-plane elastic fields for a tangentially loaded half-plane,while the effect of residual surface stress is fundamentally crucial for the out-of-plane stress and displacement when the half-plane is normally loaded.In the remaining situations,combined effects of surface elasticity and residual surface stress should be considered.The results for a concentrated surface force serve essentially as fundamental solutions of the Flamant and the half-plane Cerruti problems with surface effects.The solutions presented in this work may be helpful for understanding the contact behaviors between solids at the nanoscale.

Enhanced chemoselectivity of a plant cytochrome P450 through protein engineering of surface and catalytic residues

Cytochrome P450s(P450s)are the most versatile catalysts utilized by plants to produce structurally and functionally diverse metabolites.Given the high degree of gene redundancy and challenge to functionally characterize plant P450s,protein engineering is used as a complementarystrategy to study the mechanisms of P450-mediated reactions,or to alter their functions.We previously proposed an approach of engineering plant P450s based on combining high accuracy homology models generated by Rosetta combined with data-driven design using evoluti onary information of these enzymes.With this strategy,we repurposed a multi-functional P450(CYP87D20)into a monooxygenase after red esigning its active site.Since most plant P450s are membrane-anchored proteins that are adapted to the micro-environments of plant cells,expressing them in heterologous hosts usually results in problems of expression or activity.Here,we applied compu-tational design to tackle these issues by simultaneous optimization of the protein surface and active site.After screening 17 variants,effective su bstitutions of surface residues were observed to improve both expression and activity of CYP87D20.In addition,the identified substitutions were additive and by com-bining them a highly eficient C11 hydroxylase of cucurbitadienol was created to participate in the mogrol biosynthesis.This study shows the importance of considering the interplay between surface and active site residues for P450 engineering.Our integrated strategy also opens an avenue to create more tai loring enzymes with desired functions for the metabolic engineering of high-valued compounds like mogrol,the precursor of natural sweetener mogrosides.

Investigation on the cleaning of KDP ultra-precision surface polished with micro water dissolution machining principle

A potassium dihydrogen phosphate(KDP) optical crystal was machined to an ultra-precision surface with water-in-oil(W/O) micro emulsion polishing fluid. The micro water dissolution principle utilized in the machining process is discussed, its planarization mechanism is illustrated, and an ultra-precision polished surface with 2.205 nm RMS roughness is obtained. However, a substantial quantity of residual contamination remained on the polished surface after machining. This can seriously impact the optical performance of the crystal, and so it must be removed. Fourier transform infrared(FTIR) spectroscopy was used to conduct an investigation into the composition of the surface residue, and the results showed that the residue was comprised of organic chemicals with hydrocarbon chains and aromatic ether, i.e., mostly the polishing fluid. The cleaning method and the principle on which the KDP ultra precision surface investigation is based are discussed in detail, and the cleaning experiments with selected KDP-compatible organic solvents were then performed. FTIR transmittance spectra measurement and microscopic observations were employed to assess the effects of the cleaning process on the surface of the KDP crystal. The results showed that toluene cleaning achieved the most desirable results. This cleaning method produced a surface roughness of 1.826 nm RMS, which allows the KDP crystal to be applied to subsequent engineering applications.

Removal of residual CuO particles on the post CMP wafer surface of multi-layered copper

This article introduces the removal technology of CuO particles on the post CMP wafer surface of multi-layered copper. According to the Cu film corrosion curve with different concentrations of HEO2 and the effect curve of time on the growth rate of CuO film, CuO film with the thickness of 220 nm grown on Cu a surface was successfully prepared without the interference of CuC12.2H20. Using the static corrosion experiment the type of chelating agent （FA/O II type chelating agent） and the concentration range （10-100 ppm） for CuO removal was determined, and the Cu removal rate was close to zero. The effect of surfactant on the cleaning solution properties was studied, and results indicated that the surfactant has the effect of reducing the surface tension and viscosity of the cleaning solution, and making the cleaning agent more stable. The influence of different concentrations of FA/O I type surfactant and the mixing of FA/O II type chelating agent and FA/O I type surfactant on the CuO removal effect and the film surface state was analyzed. The experimental results indicated that when the concentration of FA/O I type surfactant was 50 ppm, CuO particles were quickly removed, and the surface state was obviously improved. The best removal effect of CuO on the copper wiring film surface was achieved with the cleaning agent ratio of FA/O II type chelating agent 75 ppm and FA/O I type surfactant 50 ppm. Finally, the organic residue on the copper pattern film after cleaning with that cleaning agent was detected, and the results showed that the cleaning used agent did not generate organic residues on the film surface, and effectively removes the organic residue on the water.

Environmental behaviors of phoxim with two formulations in bamboo forest under soil surface mulching

Phoxim（emulsifiable concentrate（EC） and granules（G）） has been widely used in bamboo forests. The persistence and magnitude of phoxim residues in the crop and soil must be investigated to ensure human and environmental safety. The environmental behaviors of the two formulations were investigated in a bamboo forest under soil surface mulching conditions（CP） and non-covered cultivation conditions（NCP）. The half-lives of phoxim in soil under the two conditions in soil were 4.1–6.2 days（EC） and 31.5–49.5 days（G）,respectively. Phoxim in EC could be leached from the topsoil into the subsoil. A minimized leaching effect was observed for G under NCP. Inversely, an enhanced leaching effect was observed for G under CP. The G formulation resulted in more parent compound（in bamboo shoots） and metabolite（in soil） residues of phoxim than in the case of EC, especially under CP conditions. In addition, the intensity and duration of the formulation effect on soil p H adjustment from G were more obvious than that from EC. Results showed that the environmental behaviors（distribution, degradation, residue） of phoxim in the bamboo forest were significantly influenced by the type of formulation. The prolongation effect from phoxim G might cause persistence and long-term environmental risk. However,bamboo shoot consumption could be considered relatively safe after applying the recommended dose of the two phoxim formulations.

Effect of Surface Polishing Treatment on the Fatigue Performance of Shot-Peened Ti–6Al–4V Alloy

In this study, shot peening is applied to the titanium alloy Ti–6Al–4V, and the surface treatment effect on fatigue life of shot-peened specimens under high cycle loading is investigated. The induced residual stress is measured by using the orbital hole-drilling method. Surface profilometer and optical microscopy are employed to characterize the surface roughness and morphology. The deformed microstructure layers of the shot-peened specimens are investigated by using scanning electron microscopy. Experiments reveal that the fatigue life of Ti–6Al–4V is improved by the shot peening process, and the surface pre-peening polishing. The combination of pre-and post-peening polishing treatments further improves fatigue life of Ti–6Al–4V specimens. The present work provides useful guidelines for developing more efficient shot peening strategies.

Serrated plastic flow behavior and microstructure in a Zr-based bulk metallic glass processed by surface mechanical attrition treatment

The serrated plastic flow,microstructure and residual stress of a Zr_（55）Cu_（30）Ni_5Al_（10） bulk metallic glass（BMG）undergone surface mechanical attrition treatment（SMAT）have been investigated by a combination of compression tests with scanning electron microscopy（SEM）,high resolution transmission electron microscopy（HRTEM）and the incremental hole-drilling strain-gage method.It is found that SMAT leads to various microstructural modifications and residual stress distribution in the surface layers of the Zrbased BMG due to the mechanically-induced nanocrystallization and generation of shear bands.As a result,the BMG alloy exhibits a remarkable work-hardening like behavior and significant increase of plastic strain from less than 1%to 15%,and its plastic deformation dynamics yields a power-law distribution of shear avalanches.Based upon the analysis of the experimental results,it is indicated that this can be connected to the SMAT-induced microstructural modifications and the resulting residual compressive stress in the Zr-based BMG.

Influence of residual surface stress on the fracture of nanoscale piezoelectric materials with conducting cracks

In this paper,we analyze the stress and electric field intensity factors affected by residual surface stress for conducting cracks in piezoelectric nanomaterials.The problem is reduced to a system of non-linear singular integral equations,whose solution is determined by iteration technique.Numerical results indicate that the residual surface stress can significantly alter the crack tip fields at nanometer length scales.Due to the residual surface stress,281he electric field can produce stress around crack tip.This suggests a strong electromechanical coupling crack tip field for nanoscale piezoelectric materials.Such a finding is considerably different from the classical fracture mechanics results.A transit electric field to stress load ratio is identified,for which influences of residual surface stresses vanish.The research is useful for the applications of nanoscale piezoelectric devices.

Towards Understanding Why the Thin Membrane Transducer Deforms:Surface Stress-Induced Buckling

This study is directed towards a comprehensive exploration on the deformation mechanism of the thin membrane transducer（TMT） caused by surface stress variation.We stress that the biomolecular interaction has changed the magnitude of the surface stress;and when the surface stress exceeds a critical value the TMT will buckle and deform.Based upon Gurtin＇s theory of surface elasticity and principle of finite deformation,we abstract the TMT as a nanobeam with two clamped ends,and the close-formed governing equation set is derived accordingly.A computer code via the shooting method is developed to solve the presented two-point boundary value problem.In succession,the nanobeam deflection and critical parameters for buckling are quantitatively discussed.This investigation lays the theoretical foundation of TMTs;and it is also beneficial to gain deep insight into characterizing mechanical properties of nanomaterials and engineering nano-devices.

Three-dimensional modeling and reconstructive change of residual stress during machining process of milling, polishing, heat treatment, vibratory finishing, and shot peening of fan blade

Residual stress during the machining process has always been a research hotspot,especially for aero-engine blades.The three-dimensional modeling and reconstructive laws of residual stress among various processes in the machining process of the fan blade is studied in this paper.The fan blades of Ti-6Al-4V are targeted for milling,polishing,heat treatment,vibratory finishing,and shot peening.The surface and subsurface residual stress after each process is measured by the X-ray diffraction method.The distribution of the surface and subsurface residual stress is analyzed.The Rational Taylor surface function and cosine decay function are used to fit the characteristic function of the residual stress distribution,and the empirical formula with high fitting accuracy is obtained.The value and distribution of surface and subsurface residual stress vary greatly due to different processing techniques.The reconstructive change of the surface and subsurface residual stress of the blade in each process intuitively shows the change of the residual stress between the processes,which has a high reference significance for the research on the residual stress of the blade processing and the optimization of the entire blade process.