Plasma Modified Polyaramid Fiber Surface and Fiber/Epoxy Interface

Kevlar-49 fiber was surface-modified through cold air plasma treatment and plasma grafting of acrylic acid (AA).Fiber surface properties were studied with ESCA,while interface properties with a single fiber pull-out (SFPO) test.The stated surface modifications evidently improved the interfacial adhesion and increased the interfacial fracture energy of the aramid/epoxy composite system.

Spatial-temporal variation of the land surface temperature field and present-day tectonic activity

This study attempts to acquire information on tectonic activity in western China from land surface temperature （LST） field data. On the basis of the established relationship between heat and strain, we analyzed the LSTdistribution in western China using the satellite data product MODIS/Terra. Our results show that： 1. There are departures from annual changes of LSTin some areas, and that these changes are associated with the activity of some active tectonic zones. 2. When annual-change background values caused by climate factors are removed, the long-period component （LSTLow） of temperature residual （AT） of the LSTis able to serve as an indicator for tectonic activity. We have found that a major earthquake can produce different effects on the/ST fields of surrounding areas. These effects are characterized by both rises and drops in temperature. For example, there was a noteworthy temperature decline associated with the Sumatran M9 earthquake of 2004 in the Bayan Har-Songpan block of central Tibetan Plateau. 3. On the other hand, the LST field of a single area may respond differently to major shocks occurring in different areas in the regions surrounding China. For instance, the Kun- lun M 8.1 event made the LSTon the Longmen Mountains fault zone increase, whereas the Zaisan Lake M 7.9 quake of 2003, and the Sumatran M 9 event of 2004, caused decreases in the same area＇s LST. 4. The variations of land surface temperature （LST） over time are different in different tectonic areas. These phenomena may provide clues for the study of tectonic deformation processes. On the basis of these phenomena, we use a combi- nation of temperature data obtained at varied depths, regional seismicity and strain results obtained with GPS measurements, to test the information related to tectonic activity derived from variations of the LST field, and discuss its implications to the creation of models of regional tectonic deformation.

Analysis of H_2S Tolerance of Pd-Cu Alloy Hydrogen Separation Membranes

The presence of a limited amount of H2S in H2-rich feed adversely affects the Pd-Cu membrane permeation performance due to the sulphidization of the membrane surface. A theoretical model was proposed to predict the S-tolerant performance of the Pd-Cu membranes in presence of H2S under the industrial water-gas-shift(WGS) reaction conditions. The ideas of surface coverage and competitive adsorption thermodynamics of H2S and H2 on Pd-Cu surface were introduced in the model. The surface sulphidization of the Pd-Cu membranes mainly depended on the pressure ratio of H2S to H2, temperature and S-adsorbed surface coverage, i.e., the occurrence of sulphidization on the surface was not directly related with the bulk compositions and structures [body centered cubic and face centered cubic(bcc or fcc)] of Pd-Cu alloy membranes because of the surface segregation phenomena. The resulting equilibrium equations for the H2S adsorption/sulphidization reactions were solved to calculate the pressure ratio of H2S to H2 over a wide range of temperatures. A validation of the model was performed through a comparison between lots of literature data and the model calculations over a rather broad range of operating conditions. An extremely good agreement was obtained in the different cases, and thus, the model can serve to guide the development of S-resistant Pd alloy membrane materials for hydrogen separation.

A study on the reaction kinetics of mineral surface adsorption in mix system

The experimental results on adsorption of ions pb2+, Zn2+ and Ag+ onto mineral surfaces in a mix system show that the reaction kinetics of adions adsorbed onto mineral surfaces was mainly controlled by their diffusion rates in solution. The concentration variations can be fit for the second-order rate equation with good determined coefficients r = 0.800 5—0.979 7. In the near neutral solution, the concentration of exchanged ions K+ and Na+ related to reaction time can be described by the fint-order rate equation with r = 0.855 7–0.997 7. Meanwhile, the complex diffusionexchange rate equation is suitable for describing the ca2 + concentration variation, as ions Pb2 + and Zn2+ were adions. Experimental data show that the amount of ions K+, Na+and Ca2+ release is much more than that of adion decrement in solution. This fact may suggest that the complexstion reaction of adions Pb2+, Z2+ and Ag+ with the mineral surfaces was the major reaction process while adions were not entering the phyllosilicate interlayers or CaCO3 lattice to exchange the ions K+, Na+ and Ca2+ at room temperature.