Acrylonitrile (AN)-chlorinated polyethylene (CPE)-styrene (St) (ACS) terpolymer was synthesized by suspension-swelling graft copolymerization method, in which two key factors such as dispersing system and time were st...Acrylonitrile (AN)-chlorinated polyethylene (CPE)-styrene (St) (ACS) terpolymer was synthesized by suspension-swelling graft copolymerization method, in which two key factors such as dispersing system and time were studied. Highly effective comples dispersing system was chosen and determined, and two-layer protection model was put forward to clarify the stable effect mechanism Varying the swelling time of CPE in AN and St monomer mixture, some results such as grafting effect, particle characteristics, rubber particle morphology and its size distribution, and properties of ACS resins were investigated , thus the optimum swelling time was proposed.展开更多
基金This work is supported by National Natural Science Foundation of China
文摘Acrylonitrile (AN)-chlorinated polyethylene (CPE)-styrene (St) (ACS) terpolymer was synthesized by suspension-swelling graft copolymerization method, in which two key factors such as dispersing system and time were studied. Highly effective comples dispersing system was chosen and determined, and two-layer protection model was put forward to clarify the stable effect mechanism Varying the swelling time of CPE in AN and St monomer mixture, some results such as grafting effect, particle characteristics, rubber particle morphology and its size distribution, and properties of ACS resins were investigated , thus the optimum swelling time was proposed.