used－silical capillary columns containing heptakis（2、3、6－tri－o－pentyl）-β-cyclodextrinand dibenzo-18-crown-6 were prepared．By studying the selectivity of mixed stationary phases forsome solute pairs.as well a...used－silical capillary columns containing heptakis（2、3、6－tri－o－pentyl）-β-cyclodextrinand dibenzo-18-crown-6 were prepared．By studying the selectivity of mixed stationary phases forsome solute pairs.as well as comparing with the heptakis（2．3、6-tri-O-pentyl）-β-cyclodextrin and thedibenzo-18-crown-6 used as individual stationary phase、the synergistic effects were observed.These effects were affected by the column temperature．mixed ratio and linear velocity of carrier gas．展开更多
Electrocatalytic nitrate reduction reaction(e-NO_(3)RR)offers a promising alternative method for nitrogen cycling and ammonia(NH3)production under ambient conditions.However,the method is still in the dilemma of lower...Electrocatalytic nitrate reduction reaction(e-NO_(3)RR)offers a promising alternative method for nitrogen cycling and ammonia(NH3)production under ambient conditions.However,the method is still in the dilemma of lowering the reaction overpotential and increasing the reaction activity.We successfully developed the composition-adjustable Co_(6)Mo_(6)C/Co/N-doped carbon(NC)catalysts by in situ carbonization of Co-based metal-organic framework(MOF)with the constrained phosphomolybdic acid.After adjusting the ratio of Co0 and Co_(6)Mo_(6)C,Co_(6)Mo_(6)C/Co/NC-3 could satisfy both NO_(3)−conversion at low potential and NH_(x)hydrogenation,and synthesize ammonia efficiently through the synergistic effect of Co0 and Co_(6)Mo_(6)C.It achieved an ammonia yield rate as 1233.2μg·h^(−1)·mgcat^(−1)and Faradaic efficiency of NH4+93.6%at−0.33 V vs.reversible hydrogen electrode(RHE).Importantly,density functional theory(DFT)calculations and experimental results have demonstrated for the first time the excellent adsorption of nitrite(NO_(2)^(−))by the Mo sites of Co_(6)Mo_(6)C during e-NO_(3)RR,avoiding the undesirable accumulation of NO_(2)^(−).展开更多
The corrosion and tribocorrosion behaviors of AISI 316 stainless steel and Ti6Al4V alloys sliding against Al2O3 in artificial seawater using a pin-on-disk test rig were investigated. And the synergistic effect between...The corrosion and tribocorrosion behaviors of AISI 316 stainless steel and Ti6Al4V alloys sliding against Al2O3 in artificial seawater using a pin-on-disk test rig were investigated. And the synergistic effect between corrosion and wear was emphatically evaluated. The results show that the open circuit potentials of both alloys drop down to more negative value due to friction. The corrosion current densities obtained under tribocorrosion condition are much higher than those under corrosion-only condition. Friction obviously accelerates the corrosion of the alloys. The wear loss for both alloys is larger in seawater than that in pure water. Wear loss is obviously accelerated by corrosion. And AISI 316 stainless steel is less resistant to sliding damage than Ti6Al4V alloy. The synergistic effect between wear and corrosion is a significant factor for the materials loss in tribocorrosion. In this surface-on-surface contact geometry friction system, the material loss is large but the ratio of wear-accelerated-corrosion to the total wear loss is very low.展开更多
The synergistic effect is investigated in mixed gas chromatographic stationary phase containing dibenzo-18-crown-6 and resorcarene derivative, with benzene/cyclohexane, halogenated hydrocarbon, aromatics, ketone, phen...The synergistic effect is investigated in mixed gas chromatographic stationary phase containing dibenzo-18-crown-6 and resorcarene derivative, with benzene/cyclohexane, halogenated hydrocarbon, aromatics, ketone, phenol, alcohol and aniline derivatives as the sample compound pairs. This separation effect is affected by temperature, mixing ratio of stationary phases and linear velocity of carrier gas.展开更多
文摘used－silical capillary columns containing heptakis（2、3、6－tri－o－pentyl）-β-cyclodextrinand dibenzo-18-crown-6 were prepared．By studying the selectivity of mixed stationary phases forsome solute pairs.as well as comparing with the heptakis（2．3、6-tri-O-pentyl）-β-cyclodextrin and thedibenzo-18-crown-6 used as individual stationary phase、the synergistic effects were observed.These effects were affected by the column temperature．mixed ratio and linear velocity of carrier gas．
基金supported by the National Natural Science Foundation of China(Nos.22065030 and U22A20391)the Natural Science Foundation of Ningxia Province(No.2022AAC03109)X.M.L.expresses gratitude for the support received from the Ningxia Youth Talent Support Project of Science and Technology,as well as Professor Guidong Yang.
文摘Electrocatalytic nitrate reduction reaction(e-NO_(3)RR)offers a promising alternative method for nitrogen cycling and ammonia(NH3)production under ambient conditions.However,the method is still in the dilemma of lowering the reaction overpotential and increasing the reaction activity.We successfully developed the composition-adjustable Co_(6)Mo_(6)C/Co/N-doped carbon(NC)catalysts by in situ carbonization of Co-based metal-organic framework(MOF)with the constrained phosphomolybdic acid.After adjusting the ratio of Co0 and Co_(6)Mo_(6)C,Co_(6)Mo_(6)C/Co/NC-3 could satisfy both NO_(3)−conversion at low potential and NH_(x)hydrogenation,and synthesize ammonia efficiently through the synergistic effect of Co0 and Co_(6)Mo_(6)C.It achieved an ammonia yield rate as 1233.2μg·h^(−1)·mgcat^(−1)and Faradaic efficiency of NH4+93.6%at−0.33 V vs.reversible hydrogen electrode(RHE).Importantly,density functional theory(DFT)calculations and experimental results have demonstrated for the first time the excellent adsorption of nitrite(NO_(2)^(−))by the Mo sites of Co_(6)Mo_(6)C during e-NO_(3)RR,avoiding the undesirable accumulation of NO_(2)^(−).
基金Project (LSL-1310) supported by the Open Project of State Key Laboratory of Solid Lubrication,Collaborative Innovation Center of Nonferrous Metals of Henan Province,ChinaProject (51171059) supported by the National Natural Science Foundation of China
文摘The corrosion and tribocorrosion behaviors of AISI 316 stainless steel and Ti6Al4V alloys sliding against Al2O3 in artificial seawater using a pin-on-disk test rig were investigated. And the synergistic effect between corrosion and wear was emphatically evaluated. The results show that the open circuit potentials of both alloys drop down to more negative value due to friction. The corrosion current densities obtained under tribocorrosion condition are much higher than those under corrosion-only condition. Friction obviously accelerates the corrosion of the alloys. The wear loss for both alloys is larger in seawater than that in pure water. Wear loss is obviously accelerated by corrosion. And AISI 316 stainless steel is less resistant to sliding damage than Ti6Al4V alloy. The synergistic effect between wear and corrosion is a significant factor for the materials loss in tribocorrosion. In this surface-on-surface contact geometry friction system, the material loss is large but the ratio of wear-accelerated-corrosion to the total wear loss is very low.
文摘The synergistic effect is investigated in mixed gas chromatographic stationary phase containing dibenzo-18-crown-6 and resorcarene derivative, with benzene/cyclohexane, halogenated hydrocarbon, aromatics, ketone, phenol, alcohol and aniline derivatives as the sample compound pairs. This separation effect is affected by temperature, mixing ratio of stationary phases and linear velocity of carrier gas.
