The Ordos Basin(OB)in the western part of the North China Craton(NCC),was located at the jointed area of multi-plates and has recorded the Mesozoic tectonic characteristics.Its tectonic evolution in the Mesozoic is si...The Ordos Basin(OB)in the western part of the North China Craton(NCC),was located at the jointed area of multi-plates and has recorded the Mesozoic tectonic characteristics.Its tectonic evolution in the Mesozoic is significant to understand the tectonic transformation of the northern margin of the NCC.In this work,the detrital zircon and apatite(U-Th)/He chronological system were analyzed in the northern part of the OB,and have provided new evidence for the regional tectonic evolution.The(U-Th)/He chronological data states the weighted ages of 240‒235 Ma,141 Ma with the peak distribution of 244 Ma,219 Ma,173 Ma,147‒132 Ma.The thermal evolution,geochronological data,and regional unconformities have proved four stages of regional tectonic evolution for the OB and its surroundings in the Mesozoic:(1)The Late Permian-Early Triassic;(2)the Late Triassic-Early Jurassic;(3)the Late Jurassic-Early Cretaceous;(4)the Late Cretaceous-Early Paleogene.It is indicated that the multi-directional convergence from the surrounding tectonic units has controlled the Mesozoic tectonic evolution of the OB.Four-stage tectonic evolution reflected the activation or end of different plate movements and provided new time constraints for the regional tectonic evolution of the NCC in the Mesozoic.展开更多
The continental Asia is mainly composed of three major tectonic regimes,the Tethys,Paleo Asian Ocean,and West Pacific.It underwent multi-stage plate convergences,ocean-continent transformations,and subductions,collisi...The continental Asia is mainly composed of three major tectonic regimes,the Tethys,Paleo Asian Ocean,and West Pacific.It underwent multi-stage plate convergences,ocean-continent transformations,and subductions,collisions and/or collages,and post collisional(orogenic)extensions in Phanerozoic.Tectonic evolution of the Asia brings up a unique fault system and tectonic geomorphological features in the China's Mainland.Also,it provides a geodynamic background for the formation and evolution of metallogeneses and mineral systems,resulting in nonuniform distribution of tectono-metallogenic systems and metallogenic belts.The spatiotemporal distribution of mineral deposits in China and adjacent areas exhibits periodic variation under controlling of the full life Wilson cycle and tectonic evolution,forming the plate convergence-related mineral system in East Asia.Porphyry Cu deposits are mainly related to compressional systems in Paleozoic and early Mesozoic,and more closely related to post-collision extensional settings in late Mesozoic and Cenozoic.Orogenic Au deposits mainly formed in post-orogeny extensional setting.Alkaline rock related rare earth element deposits formed mainly at margins of the North China and Yangtze cratons.Granite-pegmatite Li and other rare metal deposits formed mainly in early Mesozoic,related to Indosinian post-orogeny extension.Tectono-metallogenic systems provide important basis for the prospecting of mineral resources.展开更多
The Bohai Bay Basin,as a super oil-rich basin in the world,is characterized by cyclic evolution and complex regional tectonic stress field,and its lifecycle tectonic evolution controls the formation of regional source...The Bohai Bay Basin,as a super oil-rich basin in the world,is characterized by cyclic evolution and complex regional tectonic stress field,and its lifecycle tectonic evolution controls the formation of regional source rocks.The main pre-Cenozoic stratigraphic system and lithological distribution are determined through geological mapping,and the dynamics of the pre-Cenozoic geotectonic evolution of the Bohai Bay Basin are investigated systematically using the newly acquired high-quality seismic data and the latest exploration results in the study area.The North China Craton where the Bohai Bay Basin is located in rests at the intersection of three tectonic domains:the Paleo-Asian Ocean,the Tethys Ocean,and the Pacific Ocean.It has experienced the alternation and superposition of tectonic cycles of different periods,directions and natures,and experienced five stages of the tectonic evolution and sedimentary building,i.e.Middle–Late Proterozoic continental rift trough,Early Paleozoic marginal-craton depression carbonate building,Late Paleozoic marine–continental transitional intracraton depression,Mesozoic intracontinental strike-slip–extensional tectonics,and Cenozoic intracontinental rifting.The cyclic evolution of the basin,especially the multi-stage compression,strike-slip and extensional tectonics processes in the Hercynian,Indosinian,Yanshan and Himalayan since the Late Paleozoic,controlled the development,reconstruction and preservation of several sets of high-quality source rocks,represented by the Late Paleozoic Carboniferous–Permian coal-measure source rocks and the Paleogene world-class extra-high-quality lacustrine source rocks,which provided an important guarantee for the hydrocarbon accumulation in the super oil-rich basin.展开更多
The Beishan orogen,located in the central segment of the Tianshan–Solonker suture within the southern Central Asian Orogenic Belt(CAOB),is crucial for understanding the accretionary processes and continental growth i...The Beishan orogen,located in the central segment of the Tianshan–Solonker suture within the southern Central Asian Orogenic Belt(CAOB),is crucial for understanding the accretionary processes and continental growth in Central Asia.This orogen developed through the episodic amalgamation and accretion of continental margin arcs,island arcs,ophiolites,and accretionary wedges,undergoing a complex process of accretion and evolution.Since the Phanerozoic,the Beishan orogen has experienced multiple phases of magmatic and collision events.The intricate distribution of magmatic arc rocks has obscured the complete basement traces,and the spatial superposition of multiple magmatic arc phases has complicated the study of its evolutionary history.展开更多
The rich accumulation of methane(CH_(4))in tectonic coal layers poses a significant obstacle to the safe and efficient extraction of coal seams and coalbed methane.Tectonic coal samples from three geologically complex...The rich accumulation of methane(CH_(4))in tectonic coal layers poses a significant obstacle to the safe and efficient extraction of coal seams and coalbed methane.Tectonic coal samples from three geologically complex regions were selected,and the main results obtained by using a variety of research tools,such as physical tests,theoretical analyses,and numerical simulations,are as follows:22.4–62.5 nm is the joint segment of pore volume,and 26.7–100.7 nm is the joint segment of pore specific surface area.In the dynamic gas production process of tectonic coal pore structure,the adsorption method of methane molecules is“solid–liquid adsorption is the mainstay,and solid–gas adsorption coexists”.Methane stored in micropores with a pore size smaller than the jointed range is defined as solid-state pores.Pores within the jointed range,which transition from micropore filling to surface adsorption,are defined as gaseous pores.Pores outside the jointed range,where solid–liquid adsorption occurs,are defined as liquid pores.The evolution of pore structure affects the methane adsorption mode,which provides basic theoretical guidance for the development of coal seam resources.展开更多
Pt-based nanocatalysts offer excellent prospects for various industries.However,the low loading of Pt with excellent performance for efficient and stable nanocatalysts still presents a considerable challenge.In this s...Pt-based nanocatalysts offer excellent prospects for various industries.However,the low loading of Pt with excellent performance for efficient and stable nanocatalysts still presents a considerable challenge.In this study,nanocatalysts with ultralow Pt content,excellent performance,and carbon black as support were prepared through in-situ synthesis.These~2-nm particles uniformly and stably dispersed on carbon black because of the strong s-p-d orbital hybridizations between carbon black and Pt,which suppressed the agglomeration of Pt ions.This unique structure is beneficial for the hydrogen evolution reaction.The catalysts exhibited remarkable catalytic activity for hydrogen evolution reaction,exhibiting a potential of 100 mV at 100 mA·cm^(-2),which is comparable to those of commercial Pt/C catalysts.Mass activity(1.61 A/mg)was four times that of a commercial Pt/C catalyst(0.37 A/mg).The ultralow Pt loading(6.84wt%)paves the way for the development of next-generation electrocatalysts.展开更多
The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the micro...The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was investigated.Furthermore,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric method.The findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and interconnect.This provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron coke.Accelerating the heating rate in non-isothermal gasification can enhance the reactivity of iron coke.The metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon atoms.The kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore structure.Moreover,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.展开更多
Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3...Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe oxide.It is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe oxide.Considering the excellent activity and stability,rechargeable Zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.展开更多
Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significan...Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.展开更多
The paper presents experimental investigation results of crack pattern change in cement pastes caused by external sulfate attack(ESA).To visualize the formation and development of cracks in cement pastes under ESA,an ...The paper presents experimental investigation results of crack pattern change in cement pastes caused by external sulfate attack(ESA).To visualize the formation and development of cracks in cement pastes under ESA,an X-ray computed tomography(X-ray CT)was used,i e,the tomography system of Zeiss Xradia 510 versa.The results indicate that X-CT can monitor the development process and distribution characteristics of the internal cracks of cement pastes under ESA with attack time.In addition,the C3A content in the cement significantly affects the damage mode of cement paste specimens during sulfate erosion.The damage of ordinary Portland cement(OPC)pastes subjected to sulfate attack with high C3A content are severe,while the damage of sulfate resistant Portland cement(SRPC)pastes is much smaller than that of OPC pastes.Furthermore,a quadratic function describes the correlation between the crack volume fraction and development depth for two cement pastes immermed in sulfate solution.展开更多
Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal int...Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in AEMWEs.Herein,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this work.Experimental and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER performance.More critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.展开更多
Binary composites(ZIF-67/rGO)were synthesized by one-step precipitation method using cobalt nitrate hexahydrate as metal source,2-methylimidazole as organic ligand,and reduced graphene oxide(rGO)as carbon carrier.Then...Binary composites(ZIF-67/rGO)were synthesized by one-step precipitation method using cobalt nitrate hexahydrate as metal source,2-methylimidazole as organic ligand,and reduced graphene oxide(rGO)as carbon carrier.Then Ru3+was introduced for ion exchange,and the porous Ru-doped Co_(3)O_(4)/rGO(Ru-Co_(3)O_(4)/rGO)composite electrocatalyst was prepared by annealing.The phase structure,morphology,and valence state of the catalyst were analyzed by X-ray powder diffraction(XRD),scanning electron microscope(SEM),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).In 1 mol·L^(-1)KOH,the oxygen evolution reaction(OER)performance of the catalyst was measured by linear sweep voltammetry,cyclic voltammetry,and chronoamperometry.The results show that the combination of Ru doping and rGO provides a fast channel for collaborative electron transfer.At the same time,rGO as a carbon carrier can improve the electrical conductivity of Ru-Co_(3)O_(4)particles,and the uniformly dispersed nanoparticles enable the reactants to diffuse freely on the catalyst.The results showed that the electrochemical performance of Ru-Co_(3)O_(4)/rGO was much better than that of Co_(3)O_(4)/rGO,and the overpotential of Ru-Co_(3)O_(4)/rGO was 363.5 mV at the current density of 50 mA·cm^(-2).展开更多
An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of t...An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of the internal variables were considered in this ISV model,and the parameters were optimized by genetic algorithm.After validation,the ISV model was used to simulate the evolution of grain size(GS)and dynamic recrystallization(DRX)fraction during hot spinning via Abaqus and its subroutine Vumat.By comparing the simulated results with the experimental results,the application of the ISV model was proven to be reliable.Meanwhile,the strength of the thin-walled spun ZK61 tube increased from 303 to 334 MPa due to grain refinement by DRX and texture strengthening.Besides,some ultrafine grains(0.5μm)that played an important role in mechanical properties were formed due to the proliferation,movement,and entanglement of dislocations during the spinning process.展开更多
Background The Bundelkhand Craton is significant for preserving the multiphase granitoids magmatism from Paleoarchean to Neoarchean periods.It consists of a variety of granite rocks,including TTGs,sanukitoids,and high...Background The Bundelkhand Craton is significant for preserving the multiphase granitoids magmatism from Paleoarchean to Neoarchean periods.It consists of a variety of granite rocks,including TTGs,sanukitoids,and high-K granitoids.This study presents geochemical characteristics of high-silica(68.97 wt.%–73.99 wt.%),low-silica(58.73wt.%–69.94 wt.%),and high K_(2)O(2.77 wt.%–6.16 wt.%)contents of granitoids.Objective The data on Bundelkhand Craton’s granitic magmatism and geodynamics is not sufficiently robust.Geochemical data from this study will be used to further understand the origin,source,and petrogenesis of granitoid rocks and their implications for the evolution of geodynamics.Methodology Twenty-one samples were collected and analyzed for major,trace,and REE elements.Major elements were measured using X-ray fluorescence spectrometry(XRF),and trace and REE elements were analyzed by ICP-MS.Standard procedures from the Geological Survey of India were followed.Results The geochemical analysis presents high-silica(68.97-73.99 wt.%),low-silica(58.73-69.94 wt.%),and high K2O(2.77-6.16 wt.%)contents in granitoids,classified as granite-granodiorite.The rocks are calcic to calcalkalic,magnesian,and range from peraluminous to metaluminous composition.REE patterns showed strong LREE enrichment relative to HREEs,with prominent negative Eu anomalies corresponding to earlier plagioclase fractionation.Multi-element patterns revealed negative anomalies in Nb,Sr,P,and Ti and positive anomalies in Pb.Conclusion The geochemical signatures attributed to the post-collisional magma generation and continental crustal contamination.The studied rocks show A-type and A2-type lineage,suggesting they originated from the melting of continental crust during transitional/post-collisional tectonic activity.The formation of hybrid granitoids in the Bundelkhand Craton is connected to the fractionation of hybrid magmas in shallow-seated magma chambers during these tectonic processes.展开更多
Detailed three-dimensional structural studies indicate that the Bixiling area, Dabie massif, central China shows the deepest exposed levels of the orogenic wedge formed during the Triassic Yangtze -Sino-Korean contine...Detailed three-dimensional structural studies indicate that the Bixiling area, Dabie massif, central China shows the deepest exposed levels of the orogenic wedge formed during the Triassic Yangtze -Sino-Korean continental collision. New 1 : 10 000 scale structural mapping, combined with detailed petrological analysis in this area, has enabled us to accurately distinguish structures related to the Triassic continental collision from those related to post-collisional deformation in the ultrahigh pressure (UHP) metamorphic unit. The collisional or compressional structures include the massive eclogite with a weak foliation, foliated eclogite or UHP ductile shear zones, as well as upper amphibolite facies shear zones, whereas the post-collisional deformation is characterized by a regionally, flat-lying foliation containing stretching lineations and common reclined folds. The former is present exclusively in the eclogite lenses and their margins, representing orogenic thickening or syn-collisional events, while the latter was best occurred on variable scales under amphibolite facies conditions, showing sub-vertical, extreme shortening and ductile thinning of the metamorphic rock stack. The eclogite facies tectonites that have a marked fabric discordance to the penetrative amphibolite facies extension flow fabric are common. It is emphasized that an extensional tectonic setting following the collision-orogenic thickening stage was, at least partly, responsible for exhumation of the UHP metamorphic rocks in the Dabie massif. A new tectonic evolution model is proposed for the UHP metamorphic belt on the scale of the Dabie massif. The Bixiling area thus provides a window, from which the dynamic processes concerning the formation and exhumation of the UHP rocks can be observed. Regional studies in the Dabie Mountains have confirmed this interpretation.展开更多
Okinawa Trough is a back-arc, initial marginal sea basin, located behind the Ryukyu Arc-Trench System. The formation and evolution of the Okinawa Trough is intimately related to the subduction process of the Philippin...Okinawa Trough is a back-arc, initial marginal sea basin, located behind the Ryukyu Arc-Trench System. The formation and evolution of the Okinawa Trough is intimately related to the subduction process of the Philippine Sea Plate beneath the Eurasian Plate since the late Miocene. The tectonic evolution of the trough is similar to other active back-arcs, such as the Mariana Trough and southern Lau Basin, all of which are experiencing the initial rifting and subsequent spreading process. This study reviews all petrologic and geochemical data of mafic volcanic lavas from the Okinawa Trough, Ryukyu Arc, and Philippine Sea Plate, combined with geophysical data to indicate the relationship between the subduction sources (input) and arc or back-arc magmas (output) in the Philippine Sea Plate-Ryukyu Arc-Okinawa Trough system (PROS). The results obtained showed that several components were variably involved in the petrogenesis of the Oki-nawa Trough lavas:sub-continental lithospheric mantle underlying the Eurasian Plate, Indian mid-oceanic ridge basalt (MORB)-type mantle, and Pacific MORB-type mantle. The addition of shallow aqueous fluids and deep hydrous melts from subducted components with the characteristics of Indian MORB-type mantle into the mantle source of lavas variably modifies the primitive mantle wedge beneath the Ryukyu and sub-continental lithospheric mantle (SCLM) beneath the Okinawa Trough. In the northeastern end of the trough and arc, instead of Indian MORB-type mantle, Pacific MORB-type mantle dominates the magma source. Along the strike of the Ryukyu Arc and Okinawa Trough, the systematic variations in trace element ratios and isotopic compositions reflect the first-order effect of variable subduction input on the magma source. In general, petrologic data, combined with geophysical data, imply that the Okinawa Trough is experiencing the"seafloor spreading"process in the southwest segment,"rift propagation"process in the middle seg-ment, and"crustal extension"process in the northeast segment, and a nascent ocean basin occurs in the southwest segment.展开更多
The Changning - Menglian belt , located between the Baoshan - Gengma massif and the Simao - Lincang massif in Western Yunnan , preserves the complete record of a suture zone and the most continuous record of deep wate...The Changning - Menglian belt , located between the Baoshan - Gengma massif and the Simao - Lincang massif in Western Yunnan , preserves the complete record of a suture zone and the most continuous record of deep water sedimentation , representing the main branch of the Palaeo - Tethys polyisland ocean in the Hercynian - Indo-sinian stage .This belt could be further subdivided into three tectono - lithofacies zones . In the east zone , terrigenous elastics , argillaceous ,marl-argillaceous and silicate sedi-ments lie on the metamorphosed Early Palaeozoic base ment in concealed unconformity , representing deep water sediments on a passive continental margin . The central zone , although the basement rocks are absent from outcropping here , includes a contemporary complex of various sedimentary types , among them one type is of deep ocean sediments represented by radiolarian bedded chert , appearing from at least early Early Devonian to the Middle Triassic . Another type includes pure carbonates of the Early Carboniferous to the Late Permian , a type of shallow water carbonate platform on seamount or oceanic plateau within an ocean basin . In the west zone , the Permo - Carboniferous terrigenous elastics , argillaceous and silicate sediments appear again -representing the passive continental slope sedimentation in the east of the Baoshan - Gengma massif .As the Permo-Carboniferous rock types,sedimentary environments and palaeontological characters of the east and west zones are quite similar , we hold that these two zones were originally formed all on the eastern continental slope of the Baoshan - Gengma massif , and were separated due to eastward thrust later in the Indosinian orogeny . Intense thrust compacting also resulted in tectonic melange in the central zone , which is displayed by shallow water carbonates overlapping on or embedded in deep water volcanics . In the Lancangjiang belt , the Permo - Carboniferous are very complicated in sedimentary types which include island arc volcanics , deep water turbidites, silicolites and shallow water carbonates , representing the active continental margin in the west of the Simao massif. Whether there existed by Early Permi an, a Lincang magma tic arc still awaits further evidence . From the Late Permian,both the Changning-Meng-lian belt and the Lancangjiang belt experienced important sedimentary and volanic events which took place contemporaneously or penecontemporaneously but with different characters . Evidence for the Lincang magmatic arc began to be apparent , and the turbidite deep water basin in the Lancangjiang belt closed . Nevertheless , the Palaeo - Tethys oceanic basin , represented by the Changning - Menglian suture zone , existed until the Mid-dle Triassic . In the Late Triassic . massifs of Baoshan -Gengma ,Simao - Lincang ,collided and aggregated ,resulting in the disappearance of the Palaeo - Tethys ocean .展开更多
The authors introduced two kinds of newly found soft-sediment deformation-synsedimentary extension structure and syn-sedimentary compression structure, and discuss their origins and constraints on basin tectonic evolu...The authors introduced two kinds of newly found soft-sediment deformation-synsedimentary extension structure and syn-sedimentary compression structure, and discuss their origins and constraints on basin tectonic evolution. One representative of the syn-sedimentary extension structure is syn-sedimentary boudinage structure, while the typical example of the syn-sedimentary compression structure is compression sand pillows or compression wrinkles. The former shows NW-SE-trendlng contemporaneous extension events related to earthquakes in the rift basin near a famous Fe-Nb-REE deposit in northern China during the Early Paleozoic (or Mesoproterozoic as proposed by some researches), while the latter indicates NE-SW-trending contemporaneous compression activities related to earthquakes in the Middle Triassic in the Nanpanjiang remnant basin covering south Guizhou, northwestern Guangxi and eastern Yunnan in southwestern China. The syn-sedimentary boudinage structure was found in an earthquake slump block in the lower part of the Early Paleozoic Sailinhudong Group, 20 km to the southeast of Bayan Obo, Inner Mongolia, north of China. The slump block is composed of two kinds of very thin layers-pale-gray micrite (microcrystalline limestone) of 1-2 cm thick interbedded with gray muddy micrite layers with the similar thickness. Almost every thin muddy micrite layer was cut into imbricate blocks or boudins by abundant tiny contemporaneous faults, while the interbedded micrite remain in continuity. Boudins form as a response to layer-parallel extension (and/or layer-perpendicular flattening) of stiff layers enveloped top and bottom by mechanically soft layers. In this case, the imbricate blocks cut by the tiny contemporaneous faults are the result of abrupt horizontal extension of the crust in the SE-NW direction accompanied with earthquakes. Thus, the rock block is, in fact, a kind of seismites. The syn-sedimentary boudins indicate that there was at least a strong earthquake belt on the southeast side of the basin during the early stage of the Sailinhudong Group. This may be a good constraint on the tectonic evolution of the Bayan Obo area during the Early Paleozoic time. The syn-sedimentary compression structure was found in the Middle Triassic flysch in the Nanpanjiang Basin. The typical structures are compression sand pillows and compression wrinkles. Both of them were found on the bottoms of sand units and the top surface of the underlying mud units. In other words, the structures were found only in the interfaces between the graded sand layer and the underlying mud layer of the flysch. A deformation experiment with dough was conducted, showing that the tectonic deformation must have been instantaneous one accompanied by earthquakes. The compression sand pillows or wrinkles showed uniform directions along the bottoms of the sand layer in the flysch, revealing contemporaneous horizontal compression during the time between deposition and diagenesis of the related beds. The Nanpanjiang Basin was affected, in general, with SSW-NNE compression during the Middle Triassic, according to the syn-sedimentary compression structure. The two kinds of syn-sedimentary tectonic deformation also indicate that the related basins belong to a rift basin and a remnant basin, respectively, in the model of Wilson Cycle.展开更多
The Ordos Basin is one of the most important oil and gas basins in China. Based on surface outcrop, key exploratory wells and seismic reflection data and by using the technology of "prototype basin recovery", seismi...The Ordos Basin is one of the most important oil and gas basins in China. Based on surface outcrop, key exploratory wells and seismic reflection data and by using the technology of "prototype basin recovery", seismic profile "layer flattening" and "restoration of balanced section", and other methods, the sedimentary boundary, structure and the evolution history of the Tianhuan depression on the western margin of the Ordos Basin are reestablished. The following results have been obtained. (1) The west boundary of the Late Triassic Ordos Basin was far beyond the scope of the current basin. The basin is connected with the Late Triassic Hexi Corridor Basin, and its western margin did not have tectonic characteristics of a foreland basin. (2) The Tianhuan depression was first formed in the Late Jurassic. At the late stage it was impacted by the late Yanshanian and Himalayan tectonic movement and the depression axis gradually moved eastwards to the present location with a cumulative migration distance of -30 km. (3) Eastward migration of the depression axis caused adjustment and even destruction of the originally formed oil and gas reservoirs, so that oil and gas remigrated and aggregated, resulting in secondary structural reservoirs formed at high positions on the western flank of the depression.展开更多
The South Yellow Sea Basin is the main body of the lower Yangtze area in which marine Mesozoic–Paleozoic strata are widely distributed.The latest geophysical data were used to overcome the limitation of previous poor...The South Yellow Sea Basin is the main body of the lower Yangtze area in which marine Mesozoic–Paleozoic strata are widely distributed.The latest geophysical data were used to overcome the limitation of previous poor-quality deep data.Meanwhile,the geological characteristics of hydrocarbon reservoirs in the marine Mesozoic–Paleozoic strata in the South Yellow Sea Basin were analyzed by comparing the source rocks and the reservoir and utilizing drilling and outcrop data.It is believed that the South Yellow Sea Basin roughly underwent six evolutionary stages:plate spreading,plate convergence,stable platform development,foreland basin development,faulted basin development,and depression basin development.The South Yellow Sea Basin has characteristics of a composite platform-fault depression geological structure,with a half-graben geological structure and with a ‘sandwich structure' in the vertical direction.Four sets of hydrocarbon source rocks developed – the upper Permian Longtan–Dalong formation,the lower Permian Qixia formation,the lower Silurian Gaojiabian formation,and the lower Cambrian Hetang formation/Mufushan formation,giving the South Yellow Sea Basin relatively good hydrocarbon potential.The carbonate is the main reservoir rock type in the South Yellow Sea area,and there are four carbonate reservoir types:porous dolomitic,reef-bank,weathered crust,and fractured.There are reservoir-forming horizons similar to the typical hydrocarbon reservoirs in the Yangtze land area developed in the South Yellow Sea,and there are three sets of complete source-reservoir-cap rock assemblages developed in the marine strata,with very good hydrocarbon potential.展开更多
基金This study was jointly supported by the Science&Technology Fundamental Resources Investigation Program(2022FY101800)National Science Foundation(92162212)+1 种基金the project from the Key Laboratory of Tectonics and Petroleum Resources(China University of Geosciences,Wuhan)(TPR-2022-22)the International Geoscience Programme(IGCP-675)。
文摘The Ordos Basin(OB)in the western part of the North China Craton(NCC),was located at the jointed area of multi-plates and has recorded the Mesozoic tectonic characteristics.Its tectonic evolution in the Mesozoic is significant to understand the tectonic transformation of the northern margin of the NCC.In this work,the detrital zircon and apatite(U-Th)/He chronological system were analyzed in the northern part of the OB,and have provided new evidence for the regional tectonic evolution.The(U-Th)/He chronological data states the weighted ages of 240‒235 Ma,141 Ma with the peak distribution of 244 Ma,219 Ma,173 Ma,147‒132 Ma.The thermal evolution,geochronological data,and regional unconformities have proved four stages of regional tectonic evolution for the OB and its surroundings in the Mesozoic:(1)The Late Permian-Early Triassic;(2)the Late Triassic-Early Jurassic;(3)the Late Jurassic-Early Cretaceous;(4)the Late Cretaceous-Early Paleogene.It is indicated that the multi-directional convergence from the surrounding tectonic units has controlled the Mesozoic tectonic evolution of the OB.Four-stage tectonic evolution reflected the activation or end of different plate movements and provided new time constraints for the regional tectonic evolution of the NCC in the Mesozoic.
基金funded by the Deep Geological Survey Project of the China Geological Survey(Grant Nos.DD20230229,DD20230008,DD20160083 and DD20190011)the DREAM―Deep Resource Exploration and Advanced Mining of the National Key Research and Development Program of China(Grant No.2018YFC0603701)。
文摘The continental Asia is mainly composed of three major tectonic regimes,the Tethys,Paleo Asian Ocean,and West Pacific.It underwent multi-stage plate convergences,ocean-continent transformations,and subductions,collisions and/or collages,and post collisional(orogenic)extensions in Phanerozoic.Tectonic evolution of the Asia brings up a unique fault system and tectonic geomorphological features in the China's Mainland.Also,it provides a geodynamic background for the formation and evolution of metallogeneses and mineral systems,resulting in nonuniform distribution of tectono-metallogenic systems and metallogenic belts.The spatiotemporal distribution of mineral deposits in China and adjacent areas exhibits periodic variation under controlling of the full life Wilson cycle and tectonic evolution,forming the plate convergence-related mineral system in East Asia.Porphyry Cu deposits are mainly related to compressional systems in Paleozoic and early Mesozoic,and more closely related to post-collision extensional settings in late Mesozoic and Cenozoic.Orogenic Au deposits mainly formed in post-orogeny extensional setting.Alkaline rock related rare earth element deposits formed mainly at margins of the North China and Yangtze cratons.Granite-pegmatite Li and other rare metal deposits formed mainly in early Mesozoic,related to Indosinian post-orogeny extension.Tectono-metallogenic systems provide important basis for the prospecting of mineral resources.
基金Supported by the Project from Department of Science and Information of CNOOC(2021-KT-YXKY-03)。
文摘The Bohai Bay Basin,as a super oil-rich basin in the world,is characterized by cyclic evolution and complex regional tectonic stress field,and its lifecycle tectonic evolution controls the formation of regional source rocks.The main pre-Cenozoic stratigraphic system and lithological distribution are determined through geological mapping,and the dynamics of the pre-Cenozoic geotectonic evolution of the Bohai Bay Basin are investigated systematically using the newly acquired high-quality seismic data and the latest exploration results in the study area.The North China Craton where the Bohai Bay Basin is located in rests at the intersection of three tectonic domains:the Paleo-Asian Ocean,the Tethys Ocean,and the Pacific Ocean.It has experienced the alternation and superposition of tectonic cycles of different periods,directions and natures,and experienced five stages of the tectonic evolution and sedimentary building,i.e.Middle–Late Proterozoic continental rift trough,Early Paleozoic marginal-craton depression carbonate building,Late Paleozoic marine–continental transitional intracraton depression,Mesozoic intracontinental strike-slip–extensional tectonics,and Cenozoic intracontinental rifting.The cyclic evolution of the basin,especially the multi-stage compression,strike-slip and extensional tectonics processes in the Hercynian,Indosinian,Yanshan and Himalayan since the Late Paleozoic,controlled the development,reconstruction and preservation of several sets of high-quality source rocks,represented by the Late Paleozoic Carboniferous–Permian coal-measure source rocks and the Paleogene world-class extra-high-quality lacustrine source rocks,which provided an important guarantee for the hydrocarbon accumulation in the super oil-rich basin.
基金supported by the China Geological Survey(Grant No.DD20230254)。
文摘The Beishan orogen,located in the central segment of the Tianshan–Solonker suture within the southern Central Asian Orogenic Belt(CAOB),is crucial for understanding the accretionary processes and continental growth in Central Asia.This orogen developed through the episodic amalgamation and accretion of continental margin arcs,island arcs,ophiolites,and accretionary wedges,undergoing a complex process of accretion and evolution.Since the Phanerozoic,the Beishan orogen has experienced multiple phases of magmatic and collision events.The intricate distribution of magmatic arc rocks has obscured the complete basement traces,and the spatial superposition of multiple magmatic arc phases has complicated the study of its evolutionary history.
基金supported by the National Natural Science Foundation of China(52164015)the Technology Funding Projects of Guizhou Province([2022]231).
文摘The rich accumulation of methane(CH_(4))in tectonic coal layers poses a significant obstacle to the safe and efficient extraction of coal seams and coalbed methane.Tectonic coal samples from three geologically complex regions were selected,and the main results obtained by using a variety of research tools,such as physical tests,theoretical analyses,and numerical simulations,are as follows:22.4–62.5 nm is the joint segment of pore volume,and 26.7–100.7 nm is the joint segment of pore specific surface area.In the dynamic gas production process of tectonic coal pore structure,the adsorption method of methane molecules is“solid–liquid adsorption is the mainstay,and solid–gas adsorption coexists”.Methane stored in micropores with a pore size smaller than the jointed range is defined as solid-state pores.Pores within the jointed range,which transition from micropore filling to surface adsorption,are defined as gaseous pores.Pores outside the jointed range,where solid–liquid adsorption occurs,are defined as liquid pores.The evolution of pore structure affects the methane adsorption mode,which provides basic theoretical guidance for the development of coal seam resources.
基金financially supported by the National Natural Science Foundation of China(No.5217042069)the Young Elite Scientist Sponsorship Program by China Association for Science and Technology(CAST)(No.YESS20200103)the Fundamental Research Funds for the Central Universities(No.265QZ2022004)。
文摘Pt-based nanocatalysts offer excellent prospects for various industries.However,the low loading of Pt with excellent performance for efficient and stable nanocatalysts still presents a considerable challenge.In this study,nanocatalysts with ultralow Pt content,excellent performance,and carbon black as support were prepared through in-situ synthesis.These~2-nm particles uniformly and stably dispersed on carbon black because of the strong s-p-d orbital hybridizations between carbon black and Pt,which suppressed the agglomeration of Pt ions.This unique structure is beneficial for the hydrogen evolution reaction.The catalysts exhibited remarkable catalytic activity for hydrogen evolution reaction,exhibiting a potential of 100 mV at 100 mA·cm^(-2),which is comparable to those of commercial Pt/C catalysts.Mass activity(1.61 A/mg)was four times that of a commercial Pt/C catalyst(0.37 A/mg).The ultralow Pt loading(6.84wt%)paves the way for the development of next-generation electrocatalysts.
基金financially supported by the National Science Foundation of China(Nos.51974212 and 52274316)the China Baowu Low Carbon Metallurgy Innovation Foundation(No.BWLCF202116)+1 种基金the Science and Technology Major Project of Wuhan(No.2023020302020572)the Foundation of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(No.FMRUlab23-04)。
文摘The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was investigated.Furthermore,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric method.The findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and interconnect.This provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron coke.Accelerating the heating rate in non-isothermal gasification can enhance the reactivity of iron coke.The metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon atoms.The kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore structure.Moreover,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.
基金Research Institute for Smart Energy(CDB2)the grant from the Research Institute for Advanced Manufacturing(CD8Z)+4 种基金the grant from the Carbon Neutrality Funding Scheme(WZ2R)at The Hong Kong Polytechnic Universitysupport from the Hong Kong Polytechnic University(CD9B,CDBZ and WZ4Q)the National Natural Science Foundation of China(22205187)Shenzhen Municipal Science and Technology Innovation Commission(JCYJ20230807140402006)Start-up Foundation for Introducing Talent of NUIST and Natural Science Foundation of Jiangsu Province of China(BK20230426).
文摘Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe oxide.It is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe oxide.Considering the excellent activity and stability,rechargeable Zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.
基金financially supported by the National Natural Science Foundation of China(52373271)Science,Technology and Innovation Commission of Shenzhen Municipality under Grant(KCXFZ20201221173004012)+1 种基金National Key Research and Development Program of Shaanxi Province(No.2023-YBNY-271)Open Testing Foundation of the Analytical&Testing Center of Northwestern Polytechnical University(2023T019).
文摘Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption.
基金Funded by Chinese National Natural Science Foundation of China(No.U2006224)。
文摘The paper presents experimental investigation results of crack pattern change in cement pastes caused by external sulfate attack(ESA).To visualize the formation and development of cracks in cement pastes under ESA,an X-ray computed tomography(X-ray CT)was used,i e,the tomography system of Zeiss Xradia 510 versa.The results indicate that X-CT can monitor the development process and distribution characteristics of the internal cracks of cement pastes under ESA with attack time.In addition,the C3A content in the cement significantly affects the damage mode of cement paste specimens during sulfate erosion.The damage of ordinary Portland cement(OPC)pastes subjected to sulfate attack with high C3A content are severe,while the damage of sulfate resistant Portland cement(SRPC)pastes is much smaller than that of OPC pastes.Furthermore,a quadratic function describes the correlation between the crack volume fraction and development depth for two cement pastes immermed in sulfate solution.
基金financially supported by the National Natural Science Foundation of China(22309137,22279095)Open subject project State Key Laboratory of New Textile Materials and Advanced Processing Technologies(FZ2023001).
文摘Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in AEMWEs.Herein,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this work.Experimental and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER performance.More critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.
文摘Binary composites(ZIF-67/rGO)were synthesized by one-step precipitation method using cobalt nitrate hexahydrate as metal source,2-methylimidazole as organic ligand,and reduced graphene oxide(rGO)as carbon carrier.Then Ru3+was introduced for ion exchange,and the porous Ru-doped Co_(3)O_(4)/rGO(Ru-Co_(3)O_(4)/rGO)composite electrocatalyst was prepared by annealing.The phase structure,morphology,and valence state of the catalyst were analyzed by X-ray powder diffraction(XRD),scanning electron microscope(SEM),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).In 1 mol·L^(-1)KOH,the oxygen evolution reaction(OER)performance of the catalyst was measured by linear sweep voltammetry,cyclic voltammetry,and chronoamperometry.The results show that the combination of Ru doping and rGO provides a fast channel for collaborative electron transfer.At the same time,rGO as a carbon carrier can improve the electrical conductivity of Ru-Co_(3)O_(4)particles,and the uniformly dispersed nanoparticles enable the reactants to diffuse freely on the catalyst.The results showed that the electrochemical performance of Ru-Co_(3)O_(4)/rGO was much better than that of Co_(3)O_(4)/rGO,and the overpotential of Ru-Co_(3)O_(4)/rGO was 363.5 mV at the current density of 50 mA·cm^(-2).
基金supported by the National Natural Science Foundation of China(No.51905123)Major Scientific and Technological Innovation Program of Shandong Province,China(Nos.2020CXGC010303,2022ZLGX04)Key R&D Programme of Shandong Province,China(No.2022JMRH0308).
文摘An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of the internal variables were considered in this ISV model,and the parameters were optimized by genetic algorithm.After validation,the ISV model was used to simulate the evolution of grain size(GS)and dynamic recrystallization(DRX)fraction during hot spinning via Abaqus and its subroutine Vumat.By comparing the simulated results with the experimental results,the application of the ISV model was proven to be reliable.Meanwhile,the strength of the thin-walled spun ZK61 tube increased from 303 to 334 MPa due to grain refinement by DRX and texture strengthening.Besides,some ultrafine grains(0.5μm)that played an important role in mechanical properties were formed due to the proliferation,movement,and entanglement of dislocations during the spinning process.
基金Geological Survey of India,Northern Region have provided the fi nancial funding for the study.
文摘Background The Bundelkhand Craton is significant for preserving the multiphase granitoids magmatism from Paleoarchean to Neoarchean periods.It consists of a variety of granite rocks,including TTGs,sanukitoids,and high-K granitoids.This study presents geochemical characteristics of high-silica(68.97 wt.%–73.99 wt.%),low-silica(58.73wt.%–69.94 wt.%),and high K_(2)O(2.77 wt.%–6.16 wt.%)contents of granitoids.Objective The data on Bundelkhand Craton’s granitic magmatism and geodynamics is not sufficiently robust.Geochemical data from this study will be used to further understand the origin,source,and petrogenesis of granitoid rocks and their implications for the evolution of geodynamics.Methodology Twenty-one samples were collected and analyzed for major,trace,and REE elements.Major elements were measured using X-ray fluorescence spectrometry(XRF),and trace and REE elements were analyzed by ICP-MS.Standard procedures from the Geological Survey of India were followed.Results The geochemical analysis presents high-silica(68.97-73.99 wt.%),low-silica(58.73-69.94 wt.%),and high K2O(2.77-6.16 wt.%)contents in granitoids,classified as granite-granodiorite.The rocks are calcic to calcalkalic,magnesian,and range from peraluminous to metaluminous composition.REE patterns showed strong LREE enrichment relative to HREEs,with prominent negative Eu anomalies corresponding to earlier plagioclase fractionation.Multi-element patterns revealed negative anomalies in Nb,Sr,P,and Ti and positive anomalies in Pb.Conclusion The geochemical signatures attributed to the post-collisional magma generation and continental crustal contamination.The studied rocks show A-type and A2-type lineage,suggesting they originated from the melting of continental crust during transitional/post-collisional tectonic activity.The formation of hybrid granitoids in the Bundelkhand Craton is connected to the fractionation of hybrid magmas in shallow-seated magma chambers during these tectonic processes.
基金This study is supported by the National Natural Science Foundation of China (No. 49972067) the Major State Basic Research Development Program (No. G1999075506).
文摘Detailed three-dimensional structural studies indicate that the Bixiling area, Dabie massif, central China shows the deepest exposed levels of the orogenic wedge formed during the Triassic Yangtze -Sino-Korean continental collision. New 1 : 10 000 scale structural mapping, combined with detailed petrological analysis in this area, has enabled us to accurately distinguish structures related to the Triassic continental collision from those related to post-collisional deformation in the ultrahigh pressure (UHP) metamorphic unit. The collisional or compressional structures include the massive eclogite with a weak foliation, foliated eclogite or UHP ductile shear zones, as well as upper amphibolite facies shear zones, whereas the post-collisional deformation is characterized by a regionally, flat-lying foliation containing stretching lineations and common reclined folds. The former is present exclusively in the eclogite lenses and their margins, representing orogenic thickening or syn-collisional events, while the latter was best occurred on variable scales under amphibolite facies conditions, showing sub-vertical, extreme shortening and ductile thinning of the metamorphic rock stack. The eclogite facies tectonites that have a marked fabric discordance to the penetrative amphibolite facies extension flow fabric are common. It is emphasized that an extensional tectonic setting following the collision-orogenic thickening stage was, at least partly, responsible for exhumation of the UHP metamorphic rocks in the Dabie massif. A new tectonic evolution model is proposed for the UHP metamorphic belt on the scale of the Dabie massif. The Bixiling area thus provides a window, from which the dynamic processes concerning the formation and exhumation of the UHP rocks can be observed. Regional studies in the Dabie Mountains have confirmed this interpretation.
基金The National Natural Science Foundation of China under contract Nos 41322036,41230960,40906034,41276003 and 41176058China Ocean Mineral Resources R&D Association(COMRA)under contract No.DY125-12-R-05
文摘Okinawa Trough is a back-arc, initial marginal sea basin, located behind the Ryukyu Arc-Trench System. The formation and evolution of the Okinawa Trough is intimately related to the subduction process of the Philippine Sea Plate beneath the Eurasian Plate since the late Miocene. The tectonic evolution of the trough is similar to other active back-arcs, such as the Mariana Trough and southern Lau Basin, all of which are experiencing the initial rifting and subsequent spreading process. This study reviews all petrologic and geochemical data of mafic volcanic lavas from the Okinawa Trough, Ryukyu Arc, and Philippine Sea Plate, combined with geophysical data to indicate the relationship between the subduction sources (input) and arc or back-arc magmas (output) in the Philippine Sea Plate-Ryukyu Arc-Okinawa Trough system (PROS). The results obtained showed that several components were variably involved in the petrogenesis of the Oki-nawa Trough lavas:sub-continental lithospheric mantle underlying the Eurasian Plate, Indian mid-oceanic ridge basalt (MORB)-type mantle, and Pacific MORB-type mantle. The addition of shallow aqueous fluids and deep hydrous melts from subducted components with the characteristics of Indian MORB-type mantle into the mantle source of lavas variably modifies the primitive mantle wedge beneath the Ryukyu and sub-continental lithospheric mantle (SCLM) beneath the Okinawa Trough. In the northeastern end of the trough and arc, instead of Indian MORB-type mantle, Pacific MORB-type mantle dominates the magma source. Along the strike of the Ryukyu Arc and Okinawa Trough, the systematic variations in trace element ratios and isotopic compositions reflect the first-order effect of variable subduction input on the magma source. In general, petrologic data, combined with geophysical data, imply that the Okinawa Trough is experiencing the"seafloor spreading"process in the southwest segment,"rift propagation"process in the middle seg-ment, and"crustal extension"process in the northeast segment, and a nascent ocean basin occurs in the southwest segment.
文摘The Changning - Menglian belt , located between the Baoshan - Gengma massif and the Simao - Lincang massif in Western Yunnan , preserves the complete record of a suture zone and the most continuous record of deep water sedimentation , representing the main branch of the Palaeo - Tethys polyisland ocean in the Hercynian - Indo-sinian stage .This belt could be further subdivided into three tectono - lithofacies zones . In the east zone , terrigenous elastics , argillaceous ,marl-argillaceous and silicate sedi-ments lie on the metamorphosed Early Palaeozoic base ment in concealed unconformity , representing deep water sediments on a passive continental margin . The central zone , although the basement rocks are absent from outcropping here , includes a contemporary complex of various sedimentary types , among them one type is of deep ocean sediments represented by radiolarian bedded chert , appearing from at least early Early Devonian to the Middle Triassic . Another type includes pure carbonates of the Early Carboniferous to the Late Permian , a type of shallow water carbonate platform on seamount or oceanic plateau within an ocean basin . In the west zone , the Permo - Carboniferous terrigenous elastics , argillaceous and silicate sediments appear again -representing the passive continental slope sedimentation in the east of the Baoshan - Gengma massif .As the Permo-Carboniferous rock types,sedimentary environments and palaeontological characters of the east and west zones are quite similar , we hold that these two zones were originally formed all on the eastern continental slope of the Baoshan - Gengma massif , and were separated due to eastward thrust later in the Indosinian orogeny . Intense thrust compacting also resulted in tectonic melange in the central zone , which is displayed by shallow water carbonates overlapping on or embedded in deep water volcanics . In the Lancangjiang belt , the Permo - Carboniferous are very complicated in sedimentary types which include island arc volcanics , deep water turbidites, silicolites and shallow water carbonates , representing the active continental margin in the west of the Simao massif. Whether there existed by Early Permi an, a Lincang magma tic arc still awaits further evidence . From the Late Permian,both the Changning-Meng-lian belt and the Lancangjiang belt experienced important sedimentary and volanic events which took place contemporaneously or penecontemporaneously but with different characters . Evidence for the Lincang magmatic arc began to be apparent , and the turbidite deep water basin in the Lancangjiang belt closed . Nevertheless , the Palaeo - Tethys oceanic basin , represented by the Changning - Menglian suture zone , existed until the Mid-dle Triassic . In the Late Triassic . massifs of Baoshan -Gengma ,Simao - Lincang ,collided and aggregated ,resulting in the disappearance of the Palaeo - Tethys ocean .
基金This paper was sponsored by the National Natural Science Foundation of China(grant No.40272049)Doctor Research Foundation of China University of Petroleum(Project No.Y020109).
文摘The authors introduced two kinds of newly found soft-sediment deformation-synsedimentary extension structure and syn-sedimentary compression structure, and discuss their origins and constraints on basin tectonic evolution. One representative of the syn-sedimentary extension structure is syn-sedimentary boudinage structure, while the typical example of the syn-sedimentary compression structure is compression sand pillows or compression wrinkles. The former shows NW-SE-trendlng contemporaneous extension events related to earthquakes in the rift basin near a famous Fe-Nb-REE deposit in northern China during the Early Paleozoic (or Mesoproterozoic as proposed by some researches), while the latter indicates NE-SW-trending contemporaneous compression activities related to earthquakes in the Middle Triassic in the Nanpanjiang remnant basin covering south Guizhou, northwestern Guangxi and eastern Yunnan in southwestern China. The syn-sedimentary boudinage structure was found in an earthquake slump block in the lower part of the Early Paleozoic Sailinhudong Group, 20 km to the southeast of Bayan Obo, Inner Mongolia, north of China. The slump block is composed of two kinds of very thin layers-pale-gray micrite (microcrystalline limestone) of 1-2 cm thick interbedded with gray muddy micrite layers with the similar thickness. Almost every thin muddy micrite layer was cut into imbricate blocks or boudins by abundant tiny contemporaneous faults, while the interbedded micrite remain in continuity. Boudins form as a response to layer-parallel extension (and/or layer-perpendicular flattening) of stiff layers enveloped top and bottom by mechanically soft layers. In this case, the imbricate blocks cut by the tiny contemporaneous faults are the result of abrupt horizontal extension of the crust in the SE-NW direction accompanied with earthquakes. Thus, the rock block is, in fact, a kind of seismites. The syn-sedimentary boudins indicate that there was at least a strong earthquake belt on the southeast side of the basin during the early stage of the Sailinhudong Group. This may be a good constraint on the tectonic evolution of the Bayan Obo area during the Early Paleozoic time. The syn-sedimentary compression structure was found in the Middle Triassic flysch in the Nanpanjiang Basin. The typical structures are compression sand pillows and compression wrinkles. Both of them were found on the bottoms of sand units and the top surface of the underlying mud units. In other words, the structures were found only in the interfaces between the graded sand layer and the underlying mud layer of the flysch. A deformation experiment with dough was conducted, showing that the tectonic deformation must have been instantaneous one accompanied by earthquakes. The compression sand pillows or wrinkles showed uniform directions along the bottoms of the sand layer in the flysch, revealing contemporaneous horizontal compression during the time between deposition and diagenesis of the related beds. The Nanpanjiang Basin was affected, in general, with SSW-NNE compression during the Middle Triassic, according to the syn-sedimentary compression structure. The two kinds of syn-sedimentary tectonic deformation also indicate that the related basins belong to a rift basin and a remnant basin, respectively, in the model of Wilson Cycle.
文摘The Ordos Basin is one of the most important oil and gas basins in China. Based on surface outcrop, key exploratory wells and seismic reflection data and by using the technology of "prototype basin recovery", seismic profile "layer flattening" and "restoration of balanced section", and other methods, the sedimentary boundary, structure and the evolution history of the Tianhuan depression on the western margin of the Ordos Basin are reestablished. The following results have been obtained. (1) The west boundary of the Late Triassic Ordos Basin was far beyond the scope of the current basin. The basin is connected with the Late Triassic Hexi Corridor Basin, and its western margin did not have tectonic characteristics of a foreland basin. (2) The Tianhuan depression was first formed in the Late Jurassic. At the late stage it was impacted by the late Yanshanian and Himalayan tectonic movement and the depression axis gradually moved eastwards to the present location with a cumulative migration distance of -30 km. (3) Eastward migration of the depression axis caused adjustment and even destruction of the originally formed oil and gas reservoirs, so that oil and gas remigrated and aggregated, resulting in secondary structural reservoirs formed at high positions on the western flank of the depression.
基金supported by the National Natural Science Foundation of China(No.41506080)the Project of China Geological Survey(Nos.DD20160152,DD20160147,and GZH200800503)+1 种基金the Project of China Ministry of Land and Resources(Nos.XQ-2005-01,and 2009GYXQ10)the Postdoctoral Innovation Fund Project of Shandong Province(No.201602004)
文摘The South Yellow Sea Basin is the main body of the lower Yangtze area in which marine Mesozoic–Paleozoic strata are widely distributed.The latest geophysical data were used to overcome the limitation of previous poor-quality deep data.Meanwhile,the geological characteristics of hydrocarbon reservoirs in the marine Mesozoic–Paleozoic strata in the South Yellow Sea Basin were analyzed by comparing the source rocks and the reservoir and utilizing drilling and outcrop data.It is believed that the South Yellow Sea Basin roughly underwent six evolutionary stages:plate spreading,plate convergence,stable platform development,foreland basin development,faulted basin development,and depression basin development.The South Yellow Sea Basin has characteristics of a composite platform-fault depression geological structure,with a half-graben geological structure and with a ‘sandwich structure' in the vertical direction.Four sets of hydrocarbon source rocks developed – the upper Permian Longtan–Dalong formation,the lower Permian Qixia formation,the lower Silurian Gaojiabian formation,and the lower Cambrian Hetang formation/Mufushan formation,giving the South Yellow Sea Basin relatively good hydrocarbon potential.The carbonate is the main reservoir rock type in the South Yellow Sea area,and there are four carbonate reservoir types:porous dolomitic,reef-bank,weathered crust,and fractured.There are reservoir-forming horizons similar to the typical hydrocarbon reservoirs in the Yangtze land area developed in the South Yellow Sea,and there are three sets of complete source-reservoir-cap rock assemblages developed in the marine strata,with very good hydrocarbon potential.