Evolution of the porous structure for phosphoric acid etching carbon as cathodes in Li–O_(2) batteries:Pyrolysis temperature-induced characteristics changes

Although biomass-derived carbon(biochar)has been widely used in the energy field,the relation between the carbonization condition and the physical/chemical property of the product remains elusive.Here,we revealed the carbonization condition's effect on the morphology,surface property,and electrochemical performance of the obtained carbon.An open slit pore structure with shower-puff-like nanoparticles can be obtained by finely tuning the carbonization temperature,and its unique pore structure and surface properties enable the Li–O_(2) battery with cycling longevity(221 cycles with 99.8%Coulombic efficiency at 0.2 mA cm^(−2) and controlled discharge–charge depths of 500 mAh g^(−1))and high capacity(16,334 mAh g^(−1) at 0.02 mA cm^(−2)).This work provides a greater understanding of the mechanism of the biochar carbonization procedure under various pyrolysis conditions,paving the way for future study of energy storage devices.

Interval finite difference method for steady-state temperature field prediction with interval parameters

A new numerical technique named interval finite difference method is proposed for the steady-state temperature field prediction with uncertainties in both physical parameters and boundary conditions. Interval variables are used to quantitatively describe the uncertain parameters with limited information. Based on different Taylor and Neumann series, two kinds of parameter perturbation methods are presented to approximately yield the ranges of the uncertain temperature field. By comparing the results with traditional Monte Carlo simulation, a numerical example is given to demonstrate the feasibility and effectiveness of the proposed method for solving steady-state heat conduction problem with uncertain-but-bounded parameters.

Effect of temperature on the efficiency of organometallic perovskite solar cells

In recent years perovskite solar cells have attracted an increasing scientific and technological interest in the scientific community. It is important to know that the temperature is one of the factors which have a strong effect on the efficiency of perovskite solar cell. This study communicates a temperature analysis on the pho- tovoltaic parameters of CH3NH3Pbl3-based perovskite solar cell in a broad interval from 80 to 360 K. Strong temperature-dependent photovoltaic effects have been observed in the type of solar cell, which could be mainly attributed to CH3NH3PbI3, showing a ferroelectric-paraelectric phase transition at low temperature （T 〈 160 K）. An increase in temperature over the room temperature decreased the perovskite solar cell performance and reduced its efficiency from 16Z to 9%. The investigation with electronic impedance spectroscopy reveals that at low temperature （T 〈 120 K） the charge transport layer limits the device performance, while at high temperature （T 〉 200 K）, the interfacial charge recombination becomes the dominant factor.

A LOWER BOUND LIMIT ANALYSIS OF DUCTILE COMPOSITE MATERIALS

The plastic load-bearing capacity of ductile composites such as metal matrix composites is studied with an insight into the microstructures. The macroscopic strength of a composite is obtained by combining the homogenization theory with static limit analysis, where the temperature parameter method is used to construct the self-equilibrium stress field. An interface failure model is proposed to account for the effects of the interface on the failure of composites. The static limit analysis with the finite-element method is then formulated as a constrained nonlinear programming problem, which is solved by the Sequential Quadratic Programming （SQP） method. Finally, the macroscopic transverse strength of perforated materials, the macroscopic transverse and off-axis strength of fiber-reinforced composites are obtained through numerical calculation. The computational results are in good agreement with the experimental data.

A STUDY ON THE ESTIMATION OF TEMPERATURE STRUCTURE PARAMETER IN ABL WITH ELEVATED INVERSION

Temperature structure parameter in the vertical is estimated once by using the turbulence outer scale approximation and another by using the Obukhov similarity relationship during the formation of an elevated inversion.A comparison of the profiles drawn using both the methods is done for the pur- pose of assessing the accuracy of the similarity method when applied to levels above the surface-based layer.The profiles obtained by both the methods are also compared with a similar profile obtained af- ter considering a bulk shear between the ground and top of the elevated layer.

Nano inhomogeneity effects on small Ag/n-Si Schottky diode parameters at high temperature

Schottky diodes with an Ag/n-Si/W/Cu structure and 100μm in diameter were studied.Analyzing the silver metal surface coating on the n-Si substrate using a scanning probe microscopy（SPM） device showed a large number of nano patches in the surface with dimensions of 0 to 100 nm.The potential distribution of the patches revealed that the potential of each patch with the neighboring patches was different.The electrical characteristics of the devices were studied between temperature ranges of 300 and 380 K.When the temperature ideality factor approximately increases,the potential barrier height decreases.The potential barrier height was calculated separately from theⅠ-Ⅴand C-V characteristics.The main reasons for the significant difference between room temperature and higher temperatures were the differences in patch distribution,the different potentials of each patch,and the interactions between them.The effective potential barrier height depended on the degree of inhomogeneity,and thus the operating potential barrier height in the contact surface was smaller than the average value,and the ideality factor was more than unitary.With the increase in the potential value,the ideality factor becomes close to unitary, and with increasing temperatures,the ideality factor is increased.In this case,the maximum potential barrier height accrues at a greater distance from the metal contact.For this reason,at high temperatures the average value of the potential barrier height is smaller.Moreover,with increasing temperature,the ideality factor is increased.

Maximum mass of a hot neutron star with a quark core

We have considered a hot neutron star with a quark core, a mixed phase of quark-hadron matter, and a hadronic matter crust and have determined the equation of state of the hadronic phase and the quark phase. We have then found the equation of state of the mixed phase under the Gibbs conditions. Finally, we have computed the structure of a hot neutron star with a quark core and compared our results with those of the neutron star without a quark core. For the quark matter calculations, we have used the MIT bag model in which the total energy of the system is considered as the kinetic energy of the particles plus a bag constant. For the hadronic matter calculations, we have used the lowest order constrained variational formalism. Our calculations show that the results for the maximum gravitational mass of a hot neutron star with a quark core are substantially different from those of a neutron star without the quark core.

The effects of strong magnetic fields on neutron star structure:lowest order constrained variational calculations

We investigate the effects of strong magnetic fields upon the large-scale properties of neutron and protoneutron stars. In our calculations, the neutron star mat- ter was approximated by pure neutron matter. Using the lowest order constrained vari- ational approach at zero and finite temperatures, and employing AV18 potential, we present the effects of strong magnetic fields on the gravitational mass, radius, and gravitational redshift of neutron and protoneutron stars. It is found that the equation of state for a neutron star becomes stiffer with an increase of magnetic field and tem- perature. This leads to larger values of the maximum mass and radius for the neutron stars.

Temperature-variable high-frequency dynamic modeling of PIN diode

The PIN diode model for high frequency dynamic transient characteristic simulation is important in conducted EMI analysis. The model should take junction temperature into consideration since equipment usually works at a wide range of temperature. In this paper, a temperature-variable high frequency dynamic model for the PIN diode is built, which is based on the Laplace-transform analytical model at constant temperature. The relationship between model parameters and temperature is expressed as temperature functions by analyzing the physical principle of these parameters. A fast recovery power diode MUR1560 is chosen as the test sample and its dynamic performance is tested under inductive load by a temperature chamber experiment, which is used for model parameter extraction and model verification. Results show that the model proposed in this paper is accurate for reverse recovery simulation with relatively small errors at the temperature range from 25 to 120 ℃.

In-situ Health Monitoring of IGBT Modules of an On-line Medium-voltage Inverter System Using Industrial Internet of Things

Requirements of the Internet of things for the network includes the ability to monitor the equipment and devices.Nowadays,the reliability of a power electronics converter has raised concerns of both academia and industry.In particular,power semiconductor devices are continuously exposed to excessive stress while being designed with high power handling capability and are considered as the most fragile component in power converters suffering from a high failure rate.Aiming to find an effective monitoring method which is also helpful for the Internet of Things and improve the reliability of a three-level neutral-point-clamped power inverter,an in-situ health monitoring method is proposed by harnessing the inverter operational characteristics and degradation sensitive electrical parameters to address the IGBT wire bonding faults.The zero voltage state provides an inherent redundant feature that allows for a power switch to be diagnosed during its normal operation in a neutralpoint-clamped power inverter.The proposed prognostic approach obtains both the wire bonding failure features and junction temperature from the terminals of an IGBT module,which is regarded as non-invasive on-line health monitoring.The system performance can be affected by the designated testing point and testing window,which is discussed and experimentally validated.The proposed technique allows unhealthy wire bonding in IGBT modules online monitoring during the operational period of the inverter.And the proposed in-situ health monitoring of IGBT modules can be used for the industrial Internet of things.