Characteristics of Temperature Change in China over the Last 2000 years and Spatial Patterns of Dryness/Wetness during Cold and Warm Periods

This paper presents new high-resolution proxies and paleoclimatic reconstructions for studying climate changes in China for the past 2000 years. Multi-proxy synthesized reconstructions show that temperature variation in China has exhibited significant 50–70-yr, 100–120-yr, and 200–250-yr cycles. Results also show that the amplitudes of decadal and centennial temperature variation were 1.3℃ and 0.7℃, respectively, with the latter significantly correlated with long-term changes in solar radiation, especially cold periods, which correspond approximately to sunspot minima. The most rapid warming in China occurred over AD 1870–2000, at a rate of 0.56°± 0.42℃（100 yr）^（-1）; however, temperatures recorded in the 20 th century may not be unprecedented for the last 2000 years, as data show records for the periods AD 981–1100 and AD1201–70 are comparable to the present. The ensemble means of dryness/wetness spatial patterns in eastern China across all centennial warm periods illustrate a tripole pattern： dry south of 25°N, wet from 25°–30°N, and dry to the north of 30°N. However, for all centennial cold periods, this spatial pattern also exhibits a meridional distribution. The increase in precipitation over the monsoonal regions of China associated with the 20 th century warming can primarily be attributed to a mega El Nino–Southern Oscillation and the Atlantic Multidecadal Oscillation. In addition, a significant association between increasing numbers of locusts and dry/cold conditions is found in eastern China. Plague intensity also generally increases in concert with wetness in northern China, while more precipitation is likely to have a negative effect in southern China.

Zonally Asymmetric Temperature Trends near the Northern Middle and High Latitude Stratopause during Winter

The temperature trend near the stratopause is rarely evaluated owing to the limited long-term observations of global temperature. In this study, the spatial patterns of the temperature trends near the northern stratopause are investigated by using satellite and reanalysis datasets. Our analysis reveals a zonally asymmetric temperature trend pattern near the northern mid-to-high latitude stratopause during January, and this pattern underwent an evident transition around the 2000s. From 1980 to 2003, there was a cooling trend in the Western Hemisphere and a warming trend in the Eastern Hemisphere. In contrast, a reversed zonally asymmetric temperature trend pattern existed in the east–west direction from 2003 to 2020. Although the warming trends are statistically insignificant, they contrasted with the overall cooling trend in the upper stratosphere due to ozone depletion and an increase in well-mixed greenhouse gases in recent decades. The zonally asymmetric temperature trends were induced by the transition in the intensity of quasi-stationary planetary wavenumber 1(wave 1) near the stratopause. The increasing(decreasing) trend of the intensity of wave 1 enhanced(weakened) its meridional temperature advection near the stratopause before(after) the 2000s;consequently, a zonally asymmetric temperature trend pattern exists in the east–west direction near the stratopause. The transition in the intensity of the stratospheric wave 1 around the 2000s is most likely caused by the transition in the intensity of wave 1 activity in the troposphere.

Distinctive South and East Asian monsoon circulation responses to global warming

The Asian summer monsoon(ASM)is the most energetic circulation system.Projecting its future change is critical for the mitigation and adaptation of billions of people living in the region.There are two important components within the ASM:South Asian summer monsoon(SASM)and East Asian summer monsoon(EASM).Although current state-of-the-art climate models projected increased precipitation in both SASM and EASM due to the increase of atmospheric moisture,their circulation changes differ markedlyÐA robust strengthening(weakening)of EASM(SASM)circulation was projected.By separating fast and slow processes in response to increased CO_(2) radiative forcing,we demonstrate that EASM circulation strengthening is attributed to the fast land warming and associated Tibetan Plateau thermal forcing.In contrast,SASM circulation weakening is primarily attributed to an El Niño-like oceanic warming pattern in the tropical Pacific and associated suppressed precipitation over the Maritime Continent.

The gelation rule of the polyol acetal derivatives in binary solvent mixtures

The gelation properties of polyol acetal derivatives including 2,4-（3,4-dichlorobenzylidene）-D-sorbitol（DCBS）, 1,3：2,4-di（3,4-dichlorobenzylidene）-D-sorbitol（DDCBS） and 1,3：2,5：4,6-tris（3,4-dichlorobenzylidene）-D-mannitol（TDCBM） in 35 single solvents and 39 binary solvent mixtures have been studied. FTIR and XRD results suggest that the self-assembly patterns of the gelator will not change in either the single solvent component or the corresponding solvent mixtures, but the critical gelation concentration（CGC）will be influenced. The results of SEM and rheology showed that the formation of true gels at saturated concentrations. Improving the heating temperature may promote the dissolving of gelators which are even insoluble at the temperature of the solvent boiling point and change the gelation behaviors. FloryHuggins parameter（x） was used to predict the gelation behavior of DCBS in the mixed solvents, and it is shown that the x values for the mixed solvents that can be gelled by DCBS are either greater or smaller than those for the selected good solvents.