Spatial and temporal variations of water quality in Cao-E River of eastern China

Evaluation and analysis of water quality variations were performed with integrated consideration of water quality parameters, hydrological-meteorologic and anthropogenic factors in Cao-E River, Zhejiang Province of China. Cao-E River system has been polluted and the water quality of some reaches are inferior to Grade V according to National Surface Water Quality Standard of China （GB2002）. However, mainly polluted indices of each tributary and mainstream are different. Total nitrogen （TN） and total phosphorus （TP） in the water are the main polluted indices for mainstream that varies from 1.52 to 45.85 mg/L and 0.02 to 4.02 mg/L, respectively. TN is the main polluted indices for Sub-watershed Ⅰ, Ⅱ, Ⅳ and Ⅴ（0.76 to 18.27 mg/L）. BOD5 （0.36 to 289.5 mg/L）, CODMn （0.47 to 78.86 mg/L）, TN （0.74 to 31.09 mg/L） and TP （0 to 3.75 mg/L） are the main polluted indices for Sub-watershed Ⅲ. There are tow pollution types along the river including nonpoint source pollution and point source pollution types. Remarkably temporal variations with a few spatial variations occur in nonpoint pollution type reaches （including mainstream, Sub-watershed Ⅰ and Ⅱ） that mainly drained by arable field and/or dispersive rural dwelling district, and the maximum pollutant concentration appears in flooding seasons. It implied that the runoff increases the pollutant concentration of the water in the nonpoint pollution type reaches. On the other hand, remarkably spatial variations occur in the point pollution type reaches （include Sub-watershed Ⅲ, Ⅳ and Ⅴ） and the maximum pollutant concentration appears in urban reaches. The runoff always decreases the pollutant concentration of the river water in the seriously polluted reaches that drained by industrial point sewage. But for the point pollution reaches resulted from centralized town domestic sewage pipeline and from frequent shipping and digging sands, rainfall always increased the concentration of pollutant （TN） in the river water too. Pollution controls were respectively suggested for these tow types according to different pollution causes.

Spatial and temporal variations in pH and total alkalinity at the beginning of the rainy season in the Changjiang Estuary, China

The results of field observation carried out in May 2003 were used to examine pH and total alkalinity behaviors in the Changjiang Estuary. It was showed that pH and total alkalinity took on clear spatial variations in values with the minima in the low salinity region. Like salinity, transect distributions of pH and total alkalinity （TA） in a downriver direction had a sharp gradient each. These gradients appeared in such a sequence that the TA gradient was earlier than salinity and pH gradients, and the salinity gradient was earlier than the pH gradient. These distribution characteristics seemed to be strongly influenced by the mixing process of freshwater and seawater, for both pH and total alkalinity had significant linear relationships with salinity and temperature. For pH, phytoplankton activities also had a significant impact upon its spatial distribution. During a period of 48 h, pH and total alkalinity changed within wide ranges for every layer of the two anchor stations, namely, Stas 13 and 20, which were located at the mixed water mass and seawater mass, respectively. For both Stas 13 and 20, pH and TA fluctuation of every layer could be very wide during a 4 h period. As a whole, the data of the two anchor stations showed that neither variations in salinity and temperature nor phytoplankton activities were the main factors strongly influencing the total alkalinity temporal variability on a small time scale. The data of Sta. 20 implied that both salinity variation and phytoplankton activities had a significant influence on pH temporal variability, but the same conclusion could not be drawn from the data of Sta. 13.

Geographic and temporal variations of sulfate aerosols over the Pacific Ocean

To investigate the life cycle of marine sulfate aerosols, chemicophysical characteristics of marine aerosolswere measured during five cruises in the Pacific Ocean. Dimethyl sulfide concentrations in seawater and in the air were also measured. The geographic variation of sulfate-aerosol concentrations was studied in relation to biogenic and anthropogenic sources,transport with air trajectories, and chemical transformations in the atmosphere. The highest concentrations were found near Asian and American ports, indicating anthropogenic pollution is the major sulfate aerosols source. Higher concentrations were observed in the upwelling regions than in the oligotrophic areas. Along the coastal regions, both mass and number concentrations of sulfate aerosols depended on wind direction and wind speed, and land-breeze and sea-breeze oscillations; no clear diurnal variation was detected. In pelagic areas, along the equator, the concentrations of small sulfate particles showed a maximum in the afternoon and the minimum at night , indicating photo-oxidation as an important process for gas-to-particle conversion. Higher sulfate-aerosol concentrations were observed in spring than in autumn and higher concentrations were found during the La Nina anomaly than during the El Nino anomaly. Biogenic source of sulfate aerosols has an important role in the remote ocean. Case studies of sulfate-aerosol distributions are discussed.

Spatial and Temporal Variations of Blocking and Cyclogenesis in the 1978 / 79 Winter

Complex empirical orthogonal function (CEOF) and Fourier analyses are applied to 500 hPa geopotential height anomaly for two selected latitude belts in the Northern Hemisphere from Dec 1978 through Feb 1979 based on the ECMWF FGGE Hl-b data. The positive anomalies in the three leading CEOFs for the high-latitude belt mainly show the preferred locations for blocking activity in the North Atlantic, the North Pacific and to the west of the Ural Mountains. The negative anomalies in the three leading CEOFs for the mid-latitude belt mainly show the preferred locations for cyclogenesis in the east coasts of Asia and North America, and the Mediterranean; weak cyclogenesis is also seen in the western United States and off the coasts of Spain and Morocco. The travelling components of the positive anomalies in the high-latitude belt mainly propagate westward, weakening as approaching the east side of some mountain chains while intensifying to the west side. On the contrary, the travelling components of the negative anomalies in the mid-latitude belt mainly propagate eastward, intensifying over the lee side of mountain and/or approaching the east coasts of the two continents. These preferred locations for blocking and cyclogenesis are basically consistent with the climatological results, and related to some teleconnection patterns found earlier.The temporal variation of blocking highs seems to relate with the vacillation of the potential vorticity (PV) index defined by Weng (1992). There are two build-up stages of the PV index during the winter. Each build-up stage corresponds to a westward propagation of a large-scale positive anomaly in the high-latitude belt, resulting in the occurrence of a series of blocking highs over the western Eurasia, Scandinavia, Greenland and the Pacific. In general, the temporal variation of cyclogenesis is less reflected by the PV index than blocking highs. The duration of a PV index cycle of build-up and break-down is about 30-50 days. Within this low-frequency envelope, there is a global quasi-two-week vacillation of the PV index, reflecting one of the preferred time scales of mid-latitude cyclone and anticyclone activity in some preferred locations during the 1978 / 79 winter.

Temporal Variations of the Chemical Composition of Three Seaweeds in Two Tropical Coastal Environments

The seaweeds Chaetomorpha antennina, Gymnogongrus griffithsiae and Ulva fasciata were studied regarding tissue concentrations of total nitrogen, total phosphorus, total protein, hydrosoluble protein, total carbohydrate, chlorophyll a and total carotenoid throughout a 39-month survey in two coastal environments of Rio de Janeiro State, Brazil. One of the sites (Itapuca Stone) has high concentrations of dissolved nutrients and an intense long-term process of cultural eutrophication;the second site (Bananal Inlet) is thought to have lower concentrations of dissolved nutrients and no relevant anthropic impact. Seaweeds experienced changes in the concentrations of the substances in the thalli;however they did not show any cyclic seasonal pattern, except for pigments, with lower values in summer in both sites. The differences found for each species in each sampling at the sites were small (e.g. U. fasciata, more total nitrogen at Itapuca Stone) or absent (e.g. C. antennina, no significant differences for hydrosoluble protein in the sites). Differences in the concentrations of dissolved nutrients in the sites did not generate contrasting chemical profiles in the seaweeds. There is no evidence of nitrogen- or phosphorus-limitation in any season. It is presumable that the concentrations of dissolved nutrients at the nutrient-poorer site are sufficient to generate high concentrations of the substances in the thalli of the species tested, similar to the concentrations measured in the eutrophic site. Experimental data are needed to elucidate the factors that promote the success of the species tested under contrasting nutrient availability and environmental disturbance.

Geographical Patterns and Temporal Variations of Regional Dry and Wet Heatwave Events in China during 1960–2008

Daily maximum/minimum temperatures and relative humidity records from 510 stations in China for the period 1960–2008 were used to investigate geographical patterns and temporal variations of heatwave （HW） events. Dry and wet HW events were compared by different definitions. Regionally, both dry and wet HW events are commonly located in southeastern China in the monsoon area, with neither type occurring in the northeast part of Northeast China and Southwest China, while the north-northwest region of the country experiences dry HW events and a few wet HW events. In the southeast of the country, site dry HW events occurred from April to September and mostly in June, while site wet HW events occurred from April to October and mostly in September. In total, 163 regional wet HW events were identified. The ten longest regional wet HW events lasted for more than 20 days, while the mean duration for 163 events was about 11 days. For the top ten events, six occurred after the 1990s, compared with four before this time. Global surface warming was clear since 1979, but the frequency and severity of regional wet HW events were relatively low in the 1980s, increasing remarkably since the 1990s. Possible reasons for this might be the strong interdecadal and interannual variations in regional atmospheric circulations, as well as water transport related directly to temperature contrasts in different regions, rather than global-mean temperature changes.

Temporal variations in free core nutation period

Based on the nearly diurnal resonance in the tidal gravity observations, the temporal variations in period of the Earth＇s free core nutation （FCN） are investigated by using the tidal gravity observations of 18-year duration recorded continu- ously with a superconducting gravimeter （SG） at Brussels. The effects of the global oceanic tide loading and local barometric pressure on the SG observations have been removed by using eleven high-precision global digital models of oceanic tides and barometric pressure measurements recorded simultaneously at the same site. The results indicate that there exist decade-scale variations in the FCN period. The results should be further confirmed by the measurements using other space-based geodetic techniques （such as the very long baseline interferometry） and the SG observations from globally distributed stations.

Reliability Analysis of Slope Stability Considering Temporal Variations of Rock Mass Properties

Temporal variation of rock mass properties,especially the strength degradation due to drying-wetting cycles as well as the acidic wetting fluid(rainfall or reservoir water)is crucial to stability of reservoir rock slopes.Based on a series of drying-wetting cycling and experiments considering the influences of pH values,the degradation degree models of the reduced cohesion𝑐𝑐′,friction angle𝜑𝜑′are developed.2D stability analysis of the slope is subsequently carried out to calculate the factor of safety(Fs)via limit equilibrium method(LEM)and a predictive model of Fs is built using multivariate adaptive regression splines(MARS),revealing the effect of the drying-wetting cycles and pH value.The reliability analysis by Monte Carlo simulation is performed to rationally consider the uncertainty and the temporal variation of the shear strength parameters of rock mass.Results indicate that the MARS-based model can estimate the Fs accurately.The Fs and the reliability indexβdecrease with increase of drying-wetting cycles,and the temporal variation of rock mass properties has significant influence on the slope reliability.Overlooking the temporal variation of rock properties may overestimate the Fs and reliability indexβin the longer term.

Temporal Variations in Physico-Chemical Parameters of Ground Water in Kibujjo Village, Namayumba Sub-County, Wakiso District, Uganda

Water is one of the essential life’s basic needs. However, the purity and quality of water from groundwater sources in developing countries are still in doubt due to contamination by different anthropogenic activities. This study assessed the temporal variations in physico-chemical parameters of water sources in Kibujjo Village, Wakiso District, Uganda. Water samples were collected from four water sources: two (2) wells and two (2) boreholes. The levels of both physical and chemical parameters were assessed using APHA standard analytical methods. The results indicated that most of the measured water quality variables did not exceed the UNBS and WHO standards for drinking water, and the majority of the water parameters positively correlated. Borehole waters had a better quality than well waters. The highest levels of most of the variables were recorded during the wet season. There was a significant statistical difference (p SO2-4 showed a significant difference in the dry season amongst the water sources but no significant difference during the wet season (p > 0.05). Therefore, water from wells is not recommended for drinking before treatment, most especially during the wet season.

Eff ects of environmental factors on the temporal and spatial variations in branch and leaf CO_(2)effl ux of Larix gmelinii var.principis-rupprechtii Mayr

The CO_(2)effl ux of branches and leaves plays an important role in ecosystem carbon balance.Using a carbon fl ux system,the effl ux of Larix gmelinii var.principisrupprechtii(Dahurian larch)was investigated in 27 years(immature),31 years(near-mature),and 47 years(mature)stands at diurnal,seasonal,and spatial scales(direction and height)as well as its connection with environmental factors from May to October 2020.Diurnal variation in effl ux was a single peak,and the maximum occurring between 14:00 and 16:00.Seasonal variation also exhibited a single peak,with the maximum in late July and the minimum in early October.From May to September,effl ux on the south side was the largest among the three stands,and mean values on the south side of 27 year-old,31 year-old,and 47 year-old trees were 0.50,0.97 and 1.05μmol·m^(–2)·s^(–1),respectively.The minimum occurred on the north side.Except for the maximum in July and September in the 27 year-old stand in the middle of the canopy,the maximum effl ux in the upper canopy,and the means in the 27 year-old,31 year-old,and 47 year-old stands were 0.49,0.96 and 1.04μmol·m^(-2)·s^(-1),respectively;the minimum occurred in the lower canopy.Temperatures and relative humidity infl uenced seasonal variations in effl ux.Seasonal variation in temperature sensitivity coeffi cient(Q 10)was opposite that of temperature,increasing with decreasing temperature.At the spatial scale,maximum Q 10 occurred in the mid canopy.With the effl ux and temperature data in diff erent locations,it is possible to better estimate effl ux variations in each stand.

Spatial and Temporal Variations of Atmospheric Angular Momentum and Its Relation to the Earth Length of Day

The characteristics of atmospheric-angular-momentum （AAM） and length-of-day （LOD） on different timescales are investigated in this paper, on the basis of the NECP/NCAR reanalysis data and an LOD dataset for 1962-2010. The variation and overall trend of the AAM anomaly （AAMA） at different latitudes are presented, and the relationship between AAMA and LOD is discussed. The AAMAs in different latitude regions exhibit different patterns of variation, and the AAMA in the tropics makes a dominant contribution to the global AAMA. In the tropics, the AAMA propagates poleward to the extratropical regions. It is confirmed that a downward propagation of the AAMA occurs in the lower stratosphere. Correlation analysis shows that the relationship between AAMA and LOD varies significantly on different timescales. Specifically, the tropical AAMA is positively correlated with LOD on short timescales, but they are not obviously correlated on long timescales. This indicates that the interaction between AAM and the earth＇s angular momentum follows the conservative restriction on short timescales, but the influence of the earth angular momentum on that of the atmosphere depends on the interaction process on long timescales.

Spatial–temporal variations of NDVI and its response to climate in China from 2001 to 2020

Vegetation plays an important role in global or regional environmental change.In this study,the spatial–temporal variations of NDVI and its response to climate in China and its seven sub-regions were investigated based on MODIS NDVI data,ERA5-land precipitation(PRE)and temperature(TEM)data from 2001 to 2020.The inter-annual growth rate of NDVI in China was 0.0021/yr in the past 20 years.The inter-annual growth rates of NDVI in seven sub-regions had significant differences at regional or seasonal scales.The ratio of improved vegetation area to the total studied area reached about 70%.In summer,vegetation degradation was concentrated in East China and Southwest China.The vegetation in Central China and South China improved more obviously in autumn than in the other seasons.The vegetation of Northeast China had a remarkable degradation in autumn and winter,especially in winter.The influence degree of PRE(q=0.54,P<0.01)was greater than that of TEM(q=0.27,P<0.01)in the control of the spatial distribution of NDVI.The interaction influence degree q of PRE∩TEM was about 0.71 in the last 20 years.However,the PRE and TEM played different roles in vegetation growth in seven sub-regions.

Spatiotemporal variations of ambient air pollutants and meteorological influences over typical urban agglomerations in China during the COVID-19 lockdown

To investigate the air quality change during the COVID-19 pandemic,we analyzed spatiotemporal variations of six criteria pollutants in nine typical urban agglomerations in China using ground-based data and examined meteorological influences through correlation analysis and backward trajectory analysis under different responses.Concentrations of PM2.5,PM10,NO2,SO2 and CO in urban agglomerations respectively decreased by 18%–45%(30%–62%),17%–53%(22%–39%),47%-64%(14%–41%),9%–34%(0%–53%)and 16%-52%(23%–56%)during Lockdown(Post-lockdown)period relative to Pre-lockdown period.PM2.5 pollution events occurred during Lockdown in Beijing-Tianjin-Hebe(BTH)and Middle and South Liaoning(MSL),and daily O3 concentration rose to gradeⅡstandard in Post-lockdown period.Distinct from the nationwide slump of NO2 during Lockdown period,a rebound(~40%)in Post-lockdown period was observed in Cheng-Yu(CY),Yangtze River Middle-Reach(YRMR),Yangtze River Delta(YRD)and Pearl River Delta(PRD).With slightly higher wind speed compared with 2019,the reduction of PM2.5(51%–62%)in Post-lockdown period is more than2019(15%–46%)in HC(Harbin-Changchun),MSL,BTH,CP(Central Plain)and SP(ShandongPeninsula),suggesting lockdown measures are effective to PM2.5 alleviation.Although O3 concentrations generally increased during the lockdown,its increment rate declined compared with 2019 under similar sunlight duration and temperature.Additionally,unlike HC,MSL and BTH,which suffered from additional(>30%)air masses from surrounding areas after the lockdown,the polluted air masses reaching YRD and PRD mostly originated from the long-distance transport,highlighting the importance of joint regional governance.

SPATIAL AND TEMPORAL VARIATIONS OF THE KINEMATIC CHARACTERISTICS IN THE PROPAGATION OF ATMOSPHERIC STATIONARY WAVES

Time-mean global general circulation data are employed to analyze the temporal and spatial variations of the meridional gradient of zonal mean potential vorticity,the critical wavenumber n_s for horizontal wave- propagation,and the critical wavenumber K_c for vertical wave-propagation.Thereby the kinematic charac- teristics in the propagation of atmospheric stationary waves and their annual variations are studied.Results show that in the troposphere n_s and K_c usually decrease with the increase of either latitude or altitude. Synoptic and near-resonant Rossby waves could be trapped during their upward and meridional propagations. These characteristics possess prominent annual variations,especially in the Northern Hemisphere.It is found that the spatial and temporal variations of these kinematic characteristics are in good agreement with those of the atmospheric wave patterns.

Temporal and spatial variations of δ^18O in precipitation of the Yarlung Zangbo River Basin

This paper reveals the temporal and spatial variations of stable isotope in precipitation of the Yarlung Zangbo River Basin based on the variations of δ^18O in precipitation at four stations （Lhaze, Nugesha, Yangcun and Nuxia） in 2005. The results show that δ^18O of precipitation has distinct seasonal changes in the Yarlung Zangbo River Basin. The higher value of δ^18O occurs in spring prior to monsoon precipitation, and the lower value occurs during monsoon precipitation. From the spatial variations, with the altitude-effect and rainout process during moisture transport along the Yarlung Zangbo River Valley, δ^18O of precipitation is gradually depleted. Thus, δ^18O of precipitation decreases gradually from the downstream to the upstream, and the lapse rate of δ^18O in precipitation is approximately 0.34‰/100m and 0.7%J‰/100km for the two reasons. During monsoon precipitation, spatial variation of δ^18O in precipitation is dominated by the amount effect in the large scale synoptic condition.

Spatial and Temporal Variations of Tropical Cyclones at Different Intensity Scales over the Western North Pacific from 1945 to 2005

The tropical cyclone （TC） track data provided by the Joint Typhoon Warning Center （JTWC） of the U.S. Navy over the western North Pacific （including the South China Sea） from 1945 to 2005 are employed to analyze the temporal and spatial variations of TCs of different intensity scales. Most of the TCs occurred between 15° and 25°N, from the northern part of the South China Sea to the eastern part of the Bashi Channel until near 140°E. Most of the severe and super typhoons occurred over waters from the eastern part of the Bashi Channel to about 140°E. The TCs in a weakening or steady state take up a weak majority in the area west of 123°E and north of 20°N; those in an intensifying or steady state are mostly found in the area east of 123°E and south of 20°N. For severe tropical storms, typhoons, severe typhoons, and super typhoons, their average decaying rates are all greater than the respective average growing rates; for tropical storms, however, the average decaying rate is smaller than the average growing rate. Generally speaking, the stronger the TC, the faster the intensification （weakening） is. The percentage of weak TCs is higher in June to August while that of strong TCs is higher in September to November. There are annual, interannual, and interdecadal variations in the observed number （every 6 h） and frequency of TCs at different intensity scales. As far as the long-term trend is concerned, the frequency and observed number of tropical storms have a significant linear increase, but the averaged intensity and number of TCs of other intensity categories do not exhibit such a significant linear trend. In E1 Nifio years, the number and percentage of super typhoons are significantly higher, while the total number of tropical storms, severe tropical storms, typhoons, and severe typhoons is significantly lower, and the mean intensity of TCs is prominently stronger; in La Nifia years, however, the opposite comes true.

Temporal and spatial variations of the Huanghe River mouth bars

On the basis of the bathymetric records of 371 survey sections in the present Huanghe mouth area from 1996 to 2001, the temporal and spatial variations of the Huanghe mouth bars were studied by using GIS technology. The variation of the mouth bars is closely related to the water and sediment discharges from the Huanghe River to the sea that has been decreasing drastically in recent years, and to coastal hydrodynamic regimes. The characteristics of the mouth bars are unique in contrast with those of other estuaries in the world. (1) The mouth bars of the Huanghe River consist of many small sandbars. Usually the sandbars are of ellipse-shape with the long axis of about 1~6 km, and short axis of about 1~4 km. The long axis is parallel to the principal direction of tidal current, and the short axis is variable, depending on the local dynamics. The crest of the sandbars is only about 0.4 m below the water surface at low tide. They are distributed within an area of 20 km2, not far from the river mouth area. The present mouth bars are in small-medium size, quite different from the large one formed during the 1970s and 1980s, when the river sediment discharge was several times larger than that after 1996. (2) The scale of a river mouth bar is related to the river discharge of that year. In 1997 sediment discharge from the Huanghe River was 42 Mt, and the mouth bar consisted of several small scattered sandbars. In 1998 the size of mouth bars was much larger than that in 1997, as the sediment discharge from the Huanghe River increased to 363 Mt. Variation of the mouth bars largely depends on the sediment discharge with a correlation coefficient of 0.78. The calculation of the volume of the mouth bar area shows that about 30%~40% of the river's into-sea sediment is deposited in the mouth bar area. (3) Compared with other large estuaries in the world, the Huanghe mouth bars have three unique features in responding to its high sediment concentration: small size, steep slope gradient and shallow crest depth.

The temporal and spatial variations in the Pacific wind and wave fields for the period 2002–2011

The temporal and spatial variations in the wind and wave fields in the Pacific Ocean between 2002 and 2011 are analyzed using a third-generation wave model（WAVEWATCH III）. The model performance for a significant wave height is validated using in situ buoy data. The results show that the wave model effectively hindcasts the significant wave height in the Pacific Ocean, but the errors are relatively large in the mid- and low-latitude regions. The spatial distributions and temporal variations in a wind speed and the significant wave height in the Pacific Ocean are then considered after dividing the Pacific Ocean into five regions, which show meridional differences and seasonal cycles. Regional mean values are used to give yearly average time series for each separate zone. The high latitude region in the Southern Hemisphere had a stronger significant wave height trend in the model results than regions at other latitudes. The sources and sinks of wave energy are then investigated. Their regional mean values are used to quantify variations in surface waves. Finally, the spectral analyses of the daily mean wind speeds and the significant wave heights are obtained. The significant wave height and the wind speed spectra are found to be connected in some ways but also show certain differences.

Analysis on temporal and spatial variations of groundwater hydrochemical characteristics in the past decade in southern plain of Beijing, China

Groundwater utilization and protection are crucial for sustainable urban development. This is especially true for Beijing, where groundwater is an important source for urban water supply. In this study, statistical methods, including descriptive statistics, correlation analysis, principal component analysis, and Piper-Tri-linear diagram, were used in analyzing the temporal and spatial variations of the hydrochemical characteristics of groundwater based on monitored data from the southern plain of Beijing, China. Results indicated consistent changes of groundwater's hydrochemical characteristics in different aquifers in the study area. The percentage of HCO_3^-in total anion increased significantly in the groundwater, and hydrochemical water type evolved gradually from Ca-Mg-Cl-SO_4 based to Ca-Mg-HCO_3 based from period 2005-2007 to period 2013-2015. In shallow groundwater, the concentration of Na^+, Ca^(2+), SO_4^(2-), HCO_3^-, and total dissolved solids(TDS) increased from period 2005-2007 to period 2013-2015, and the greatest change came from HCO_3^-, rising from 428.93 to 528.96 mgL^(-1). The changes of main ionic concentrations in the deep groundwater were consistent with those in the shallow groundwater for both periods. However, the variations in deep groundwater were less than those in shallow groundwater. The temporal and spatial variations of hydrochemical characteristics reflect the groundwater quality in the study area. This study could facilitate decision-making process on the protection of groundwater resources to ensure its sustainable utilization.

Precise Positioning Method for Seafloor Geodetic Stations Based on the Temporal Variation of Sound Speed Structure

At present,GNSS-Acoustic(GNSS-A)combined technology is widely used in positioning for seafloor geodetic stations.Based on Sound Velocity Profiles(SVPs)data,the equal gradient acoustic ray-tracing method is applied in high-precision position inversion.However,because of the discreteness of the SVPs used in the forementioned method,it ignores the continuous variation of sound velocity structure in time domain,which worsens the positioning accuracy.In this study,the time-domain variation of Sound Speed Structure(SSS)has been considered,and the cubic B-spline function is applied to characterize the perturbed sound velocity.Based on the ray-tracing theory,an inversion model of“stepwise iteration&progressive corrections”for both positioning and sound speed information is proposed,which conducts the gradual correction of seafloor geodetic station coordinates and disturbed sound velocity.The practical data was used to test the effectiveness of our method.The results show that the Root Mean Square(RMS)errors of the residual values of the traditional methods without sound velocity correction,based on quadratic polynomial correction and based on cubic B-spline function correction are 1.43 ms,0.44 ms and 0.21 ms,respectively.The inversion model with sound velocity correction can effectively eliminate the systematic error caused by the change of SSS,and significantly improve the positioning accuracy of the seafloor geodetic stations.