Two coordination polymers with 1,4-benzenedicarboxylic acid(H2BDC) ligand, namely, [Tb3(BDC)(4.5)(H2O)(DMF)2]n (1) and [Tb2(BDC)3(H2O)2(DMF)2]n(2), have been synthesized and characterized. Both com...Two coordination polymers with 1,4-benzenedicarboxylic acid(H2BDC) ligand, namely, [Tb3(BDC)(4.5)(H2O)(DMF)2]n (1) and [Tb2(BDC)3(H2O)2(DMF)2]n(2), have been synthesized and characterized. Both compounds crystallize in the triclinic system, space group P1. For compound 1, a = 10.8528(5), b = 12.2516(5), c = 16.9031(7) A, α = 104.462(1), β = 93.659(1), γ = 101.404(1)°, V = 2118.1(2) A^3, Z = 2, C(42)H(34)N2O(21)Tb3, Mr = 1379.47, Dc = 2.163 g/cm^3, μ = 5.045 mm^-1, F(000) = 1326, the final R = 0.0212 and wR = 0.0570 for 8592 observed reflections with I 〉 2σ(I). For compound 2, a = 8.547(1), b = 10.170(1), c = 11.192(1)A?, α = 65.531(1), β = 71.886(1), γ = 78.796(1)°, V = 839.2(2) A^3, Z = 1, C(30)H(30)N2O(16)Tb2, Mr = 992.40, Dc = 1.964 g/cm^3, μ = 4.257 mm^-1, F(000) = 482, the final R = 0.0220 and wR = 0.0649 for 3626 observed reflections with I 〉 2σ(I). The compounds exhibit different structural topologies depending on the nature of templating agents in the reactions though the templating agents are not incorporated in the final solids. Compound 1 exhibits a three-dimensional(3D) framework based on the rod-shaped terbium-carboxylate building blocks constructed from linear trinuclear Tb3 units. Compound 2 has a 3D framework containing two interpenetrating pcu topological networks based on the 6-connected dinuclear Tb2 secondary building units. Photoluminescence studies show both compounds exhibit typical Tb(Ⅲ) luminescence emissions. An efficient ligand-to-Tb(Ⅲ) energy transfer is observed in the emission spectra for both compounds.展开更多
基金Supported by the NNSFC(21361011)the Provincial Natural Science Foundation of Jiangxi(20151BAB203002)+1 种基金the Project of Education Department of Jiangxi Province(GJJ14235)the Open Project Program of Key Laboratory of Functional Small Organic Molecule,Ministry of Education,Jiangxi Normal University(KLFS-KF-201412)
文摘Two coordination polymers with 1,4-benzenedicarboxylic acid(H2BDC) ligand, namely, [Tb3(BDC)(4.5)(H2O)(DMF)2]n (1) and [Tb2(BDC)3(H2O)2(DMF)2]n(2), have been synthesized and characterized. Both compounds crystallize in the triclinic system, space group P1. For compound 1, a = 10.8528(5), b = 12.2516(5), c = 16.9031(7) A, α = 104.462(1), β = 93.659(1), γ = 101.404(1)°, V = 2118.1(2) A^3, Z = 2, C(42)H(34)N2O(21)Tb3, Mr = 1379.47, Dc = 2.163 g/cm^3, μ = 5.045 mm^-1, F(000) = 1326, the final R = 0.0212 and wR = 0.0570 for 8592 observed reflections with I 〉 2σ(I). For compound 2, a = 8.547(1), b = 10.170(1), c = 11.192(1)A?, α = 65.531(1), β = 71.886(1), γ = 78.796(1)°, V = 839.2(2) A^3, Z = 1, C(30)H(30)N2O(16)Tb2, Mr = 992.40, Dc = 1.964 g/cm^3, μ = 4.257 mm^-1, F(000) = 482, the final R = 0.0220 and wR = 0.0649 for 3626 observed reflections with I 〉 2σ(I). The compounds exhibit different structural topologies depending on the nature of templating agents in the reactions though the templating agents are not incorporated in the final solids. Compound 1 exhibits a three-dimensional(3D) framework based on the rod-shaped terbium-carboxylate building blocks constructed from linear trinuclear Tb3 units. Compound 2 has a 3D framework containing two interpenetrating pcu topological networks based on the 6-connected dinuclear Tb2 secondary building units. Photoluminescence studies show both compounds exhibit typical Tb(Ⅲ) luminescence emissions. An efficient ligand-to-Tb(Ⅲ) energy transfer is observed in the emission spectra for both compounds.