Response of Terrigenous Sediment Input to Sea Level Change and East Asian Monsoon Evolution Since 30kyr in the Southwestern Taiwan Basin

The compositions of grain size,clay minerals,and geochemical elements in core sediments(TS4)from the southwestern Taiwan Basin(South China Sea)were investigated to assess the response of terrigenous sediment input to sea level change and the East Asian monsoon evolution since 30 kyr.The chronology was discussed based on foraminiferal AMS14C dates.Our results indi-cated that rivers in Taiwan have been the major sediment contributors since 30 kyr,followed by the Pearl River;and Luzon Island contribute little sediments to the southwestern Taiwan Basin.In this study,we reconstructed the variations in terrigenous sediment input by using the proxies such as Al2O_(3)(%),F1 score,and TiO_(2)/CaO.The F1 score can be used to indicate the flux of terrigenous sediments.The contribution of Taiwan Residents rivers and the Pearl River were evaluated by using the value of(illite+chlorite)/kaolinite.The variations of Al2O_(3)(%),F1 score,and TiO_(2)/CaO values along the core were clearly correlated to the evolution of the East Asian summer monsoon since 30 kyr.Based on these records,we recognized three evolutionary stages of terrigenous sediment input in the southwestern Taiwan Basin.During stage Ⅰ(29-24kyr),the input of terrigenous sediments continued to increase.During stage Ⅱ(24-11.5 kyr),the sediment input decreased at first and then increased,with the lowest value during the last glacial period(21-17kyr).Terrigenous sediment input during stage Ⅲ(11.5 kyr-)showed the decreasing first and then increasing trends,generally higher than those in the first and second stages.The variations of terrigenous sediment input in the study area corresponded well with the evolu-tion of the East Asian summer monsoon since 30 kyr.Increased terrigenous sediment input during 4-1.8 kyr was suggested to be caused by the enhanced ENSO activity.Sea level change does not alter the overall trend of terrigenous sediment input,but does change the relative contributions of rivers in Taiwan and the Pearl River.

Source of silica and its implications for organic matter enrichment in the Upper Ordovician-Lower Silurian black shale in western Hubei Province,China:Insights from geochemical and petrological analysis

To improve the understanding of the relationship between silica source and organic matter accumulation,the origin of silica and its implications for organic matter enrichment in the Upper OrdovicianLower Silurian(O_(3)w-S_(1)l)black shale in western Hubei Province in the middle Yangtze area,were investigated through geochemical and petrological analyses.The results show that the O_(3)w-S_(1)l black shale is mainly composed of five lithofacies with varying graptolite abundance,total organic carbon(TOC),and silica contents.Biogenic silica and terrigenous siliciclastic input constitute the main silica sources in O_(3)w-S_(1)l black shale and they exhibit an upward inverse variation trend interpreted to be related to sea-level changes.Moreover,with the increase in biogenic silica content or decrease in terrigenous siliciclastic input,TOC values in black shale initially rise and then fall,which is different from originally expected simple linear relationship.We infer that organic matter enrichment and the distribution of silica from different origins are controlled by sea-level changes and variations in terrigenous input in a continental shelf with little hydrothermal influence.An environment with appropriate sea level and terrigenous input should be most favorable for organic matter accumulation,rather than one with excessive high sea level and less terrigenous input.

Molecular biomarker record of paleooceanographic environment in the East China Sea during the last 35000 years

By reference of the δ18O and δ13C isotopic compositions of G.sacculifer and accelerator mass spectrometry (AMS)14C dates, the U K 37 , ∑C – 21 /∑C +- 22 and Pr/Pn in core DGKS9603 have been used to characterize the changes of paleooceanographic environment occurring in the East China Sea (ECS) during the last 35000 years. The stratigraphic records of these proxies have shown that during the last 35 ka the Okinawa Trough has gone through 7 stronger cold-climate events (C1–C7) and 9 terrigenous matter-decreasing events (e2–e9), of which, the C1 corresponds to the cold episode occurring in the middle late Holocene, C2–C4 and C7 correspond to the H1–H4 events, respectively. e1 and e3–e8 correspond to the decrease of sea surface temperature (SST), respectively. The terrigenous inputs increased when Heinrich events occurred. Climate colding resulted in the decrease of terrigenous matter transported by rivers, and the increase of that transported by winter monsoon. Heinrich events are closely related to East Asia monsoon. During the Last Glacial Maximum (LGM, 15.5–25.8 Cal ka BP), reduction environment fluctuated strongly, bringing forth three stronger reduction events (R1–R3) and one weaker reduction event (O), of which, R1–R3 correspond to the decrease of SST and increase of terrigenous nutrient and O corresponds to the decrease of terrigenous nutrient. The fluctuation of reduction condition must be related to the change of sea surface productivity.

Novel Tetracyclic Terpanes in Crude Oils and Source Rock Extracts in Pearl River Mouth Basin and Their Geological Significance

Novel tetracyclic terpanes X and Y namely C24-des-A-oleanane and C27 tetracyclic terpane were detected in crude oils and source rock extracts in Zhu 1 depression in Pearl River Mouth Basin by GC-MS analysis technology. These compounds are similar to oleanane in the structure, and their relative abundance in m/z 191 partial mass cbromatogram has a good correlation with oleanane. Here compounds X and Y are considered to be derived from the des-A degradation of oleanoid precursor. The ratio of X/（X-I-C24） and Y/（Y-I-C24） increase with the increasing inputs of terrigenous organic matter in crude oils. Wenchang Formation middle-deep lacustrine source rocks with planktonic algae organic matter inputs and oil generating from it contain low abundance of compounds X and Y, while Enping Formation coal measures source rocks with terrigenous higher plants organic matter inputs and oil generating from it usually have higher compounds X and Y. In general when two terrigenous compounds C19 tricyclic terpane and bicadinane-T are high in crude oils, there are also a corresponding high abundant compounds X and Y. Relative abundance of compounds X and Y is closely related to the source of organic matter and it can indicate the input of terrigenous organic matter.

Detection and indication of 1,3,4-C27-29 triol in the sediment of northern South China Sea

After the detection of the 1,20,21-C29 long-chain triol in some sediments and freshwater pteridophytes, in this study a new homologous long-chain triol, 1,3,4-C27-29, is detected for the first time in the Site4B core sediment in the northern South China Sea. The hydroxyl location and length of the carbon chain of this newly discovered triol differ from those of 1,20,21-C29 triol. The test results of its molecular distribution and individual carbon isotope reveal that 1,3,4-C29triol has a good correlation with n-C26-30 even carbon-numbered long-chain fatty alcohols, with R2 （n=68） values of 0.905, 0.929 and 0.903, respectively, and its carbon isotope composition, at -32.3%o_1.9%o, is similar to that of rt-C26.30, at -29.13%o^0.87%o, -32.98%o^1.28%o, and -32.98%o^1.28%o. 1,3,4-C29 triol from the Site4B core sediment and terrigenous long-chain fatty alcohol （n-C26.34） show highly consistent distribution trends in the entire section; thus, the former could serve as a proxy indicator of the terrigenous input. Considering that the 1,20,21-C29 triol in previous research belongs to Azolla, which are fresh water pteridophytes, the 1,3,4-C27-29 triol identified in this study might have similar biogenetic derivation. Thus, determination of its biogenic area and growing environment could provide potential organic geochemical evidence supporting the terrigenous input and source in the northern South China Sea.

Spatiotemporal Distribution of Microbial Tetraether Lipids in a Lake and Its Inflowing River:Implications for the Identification of Flooding Events

Microbial glycerol dialkyl glycerol tetraethers(GDGTs)in lacustrine sediments are widely used to reconstruct terrestrial paleoenvironments.However,lipids of diverse origin in lakes make it difficult to decipher environmental information,appealing for the necessity to evaluate the impact of terrigenous input on the distribution of GDGTs through long-term monitoring.In this study,we conducted two-year monitoring of GDGTs along the river,estuary,near shore,to the center of Lake Liangzi in central China.By comparing the spatiotemporal changes of GDGT distribution in suspended particulate matter(SPM)and surface sediments,we found that the archaeal isoprenoid GDGTs(isoGDGTs)were mainly produced in situ in the river-lake systems,and not affected by the soil input.In contrast,the bacterial branched GDGTs(brGDGTs)were affected,to some extent,by soil input,depending on the distance to the lakeshore.The soil input of brGDGTs was enhanced during an episode of abnormal rainfall(flood).Moreover,the large variation of isoGDGTs indicates the in situ production under the anoxic condition in lake water.The paired increase in the GDGT-0/Cren ratio and GDGT concentration might be diagnostic of flooding events in ancient times.