A New Approach of Studying Correlation between Outdoor Exposure and Indoor Accelerated Corrosion Test for High Polymer Materials

The correlation between outdoor exposure and indoor accelerated corrosion test for high polymer materials was investigated according to the variation of the functional group of exposure models aged. Environment aging intensities at different zones （ Wuhan and Lasa with the same latitude ） and the influences of indoor accelerating factors including water and ultraviolet on weathering performant.e of high polymer materials were also studied by comparing different indoor accelerated corrosion testing results. The experimental results show that ： by testing variations of carbonyl exponent of polythene （ which represented the degradation behavior of high polymer materials due to ultraviolet oxidation of douIole bond） and ultraviolet absorbance of polycarbonate （which represented the degradation behavior of high polymer materials due to abevacuation of branched chain ）, the degradation behavior of high polymer materials could be studied. Carbonyl exponent of polythene exposed in Wuhan and Lasa for 1 year was equal to that exposed in indoor cycle ultraviolet for 128 h anti 170 It, respectively, the ultraviolet absorbance of polycarbonate exposed in Wuhan for 1 year was equal to that exposed in indoor cycle ultraviolet for 240 h. The ratio of environment aging intensity of Lasa to Wuhan was around 1.2. With the prolongation of cycle accelerated ultraviolet exposure time, the variations of carbonyl exponent of polythene and the ultraviolet absorbance of polycarbonate were in the same shape of first order exponential decay curiae. Accompanied with ultraviolet, the effect of water condensated on the sample on weathering performance of polythene was more .significant than that of polycarbonate.

Law of Water Content Change in Subgrade Soil Under Action of Dry-Wet Cycle

Due to the influence of the groundwater level,the internal humidity of the subgrade changes and the stability of the subgrade is affected. The main purpose of this paper is to obtain a reliable model of subgrade soil water content variation under the action of dry-wet cycle through sensor readings. Thus,an indoor soil column model test system is designed,and the readings of the sensors are used to determine the changing law of moisture field in the subgrade soil. The sensor readings indicate that the water content gradually decreases along the height of the soil column,and the water in the upper part of the soil column continuously loses,while the water in the lower part migrates upward to supplement. With the increase of dry-wet cycle index,the water holding capacity of soil decreases,and the soil surface gradually cracks and tends to rupture.

Creep damage constitutive model of rock based on the mechanisms of crack-initiated damage and extended damage

Since the classical element model cannot describe the nonlinear characteristics of rock during the entire compressive creep process,nonlinear elements and creep damage are generally introduced in the model to resolve this issue.However,several previous studies have reckoned that creep damage in rock only occurs in the accelerated creep stage and is only described by the Weibull distribution.Nevertheless,the creep damage mechanism of rocks is still not clearly understood.In this study,a reasonable representation of the damage variables of solid materials is presented.Specifically,based on the Gurson damage model,the damage state functions reflecting the constant creep stage and accelerated creep stage of rock are established.Further,the one-dimensional and three-dimensional creep damage constitutive equations of rock are derived by modifying the Nishihara model.Finally,the creep-acoustic emission tests of phyllite under different confining pressures are conducted to examine the creep damage characteristics of phyllite.And the proposed constitutive model is verified by analyzing the results of creep tests performed on saturated phyllite.Overall,this study reveals the relationship between the creep characteristics of rocks and the corresponding damage evolution pattern,which bridges the gap between the traditional theory and the quantitative analysis of rock creep and its damage pattern.

Correlation between indoor and outdoor corrosion tests for coal train body steel in a coal medium environment

Q345B carbon steel as well as Q450NQR1 and S500AW weathering steels were subjected to outdoor exposure corrosion tests in coal environments and indoor periodic immersion accelerated corrosion tests with a simulated coal leaching solution.The corrosion kinetics were studied by the weight loss method,and the corrosion morphology and corrosion product composition were observed and analyzed by scanning electron microscopy,energy-dispersive spectroscopy and X-ray diffraction.Afterward,correlation analysis of the indoor and outdoor tests was carried out by the gray correlation analysis method.The results show that the relationship between the corrosion weight loss and corrosion time of the three steels conforms to follow the exponent power law.In particular,Q450NQR1 steel has the best corrosion resistance.The types of corrosion products and the distribution of elements in the rust layer of the three steels are similar in the indoor and outdoor tests.The gray correlation degrees of the three steels in the indoor and outdoor tests are all greater than 0.6;thus,the two corrosion tests have a good correlation.Based on this,the accelerated simulation test method of the coal leaching solution is determined,and life prediction models of three steels in coal leaching solution are established to simulate the corrosion of the bottom board and side board.