Two new tetranortriterpenoids 3-oxo-24, 25, 26, 27-tetranortirucall-7-ene-23(21)- lactone, 3á-hydroxy-24, 25, 26, 27-tetranortirucall-7-ene-23(21)-lactone were isolated from Amoora dasyclada. Their structures wer...Two new tetranortriterpenoids 3-oxo-24, 25, 26, 27-tetranortirucall-7-ene-23(21)- lactone, 3á-hydroxy-24, 25, 26, 27-tetranortirucall-7-ene-23(21)-lactone were isolated from Amoora dasyclada. Their structures were elucidated by spectroscopic evidences.展开更多
A tetranortriterpenoid, named munronin G, was isolated from Munronia delavayi (Meliaceae) by chromatography. Its structure was determined on the basis of 1D-, 2D-NMR and mass spectral analyses.
Five new toosendanin limonoids with highly oxidative furan ring walsurobustones A-D(1-4),and one new furan ring degraded limonoid walsurobustone E(5)together with one known compound toonapubesic acid B(6)were isolated...Five new toosendanin limonoids with highly oxidative furan ring walsurobustones A-D(1-4),and one new furan ring degraded limonoid walsurobustone E(5)together with one known compound toonapubesic acid B(6)were isolated from the leaves of Walsura robusta.Their structures were elucidated by NMR and MS data.Especially,the absolute configuration of toonapubesic acid B(6)was confirmed by X-ray diffraction study.Compounds 1-6 exhibited good cytotoxicity against the cancer cell lines HL-60,SMMC-7721,A-549,MCF-7,and SW480.展开更多
文摘Two new tetranortriterpenoids 3-oxo-24, 25, 26, 27-tetranortirucall-7-ene-23(21)- lactone, 3á-hydroxy-24, 25, 26, 27-tetranortirucall-7-ene-23(21)-lactone were isolated from Amoora dasyclada. Their structures were elucidated by spectroscopic evidences.
基金Project supported by the National Natural Science Foundation of China (No. 30370160).Acknowledgements The authors are grateful to Mr. Xie Li-Shan (Kunming Institute of Botany, the Chinese Academy of Sciences) for collection and identification of the specimens, and members of the analytical group of the State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, for the spectral measurements.
文摘A tetranortriterpenoid, named munronin G, was isolated from Munronia delavayi (Meliaceae) by chromatography. Its structure was determined on the basis of 1D-, 2D-NMR and mass spectral analyses.
基金the National Natural Science Foundation of China(U1812403 to X.-J.Hao and 22177050 to M.Cao)Project of Yunnan Characteristic Plant Screening and R&D Service CXO Platform(2022YKZY001)+1 种基金Foundation of Central Asian Drug Discovery and Development Center of Chinese Academy of Sciences(CAM202103,China)Youth Innovation Promotion Association CAS to M.Cao(2022-2026).
文摘Five new toosendanin limonoids with highly oxidative furan ring walsurobustones A-D(1-4),and one new furan ring degraded limonoid walsurobustone E(5)together with one known compound toonapubesic acid B(6)were isolated from the leaves of Walsura robusta.Their structures were elucidated by NMR and MS data.Especially,the absolute configuration of toonapubesic acid B(6)was confirmed by X-ray diffraction study.Compounds 1-6 exhibited good cytotoxicity against the cancer cell lines HL-60,SMMC-7721,A-549,MCF-7,and SW480.