A simple and reliable method has been developed for separation and preconcentration of trace amounts of copper ions in cereals food for subsequent measurement by flame atomic absorption spectrometry （FAAS）. The Cu^2...A simple and reliable method has been developed for separation and preconcentration of trace amounts of copper ions in cereals food for subsequent measurement by flame atomic absorption spectrometry （FAAS）. The Cu^2＋ ions are adsorbed selectively and quantitatively during the passage. The retained copper ions were desorbed from the potassium tetratitanate whisker with 10.0mL of 2mol/L sulphuric acid solutions as eluent and were determined by FAAS. The linear range was 0.05μg/mL-0.20μg/mL in the original solution with a correlation coefficient of 0.9998. The detection limit of the proposed method is 2. lng/mL in the original solution （3σ, n=9）. Determination of copper in standard ions showed that the proposed method has good accuracy （recovery was more than 95%）. The method was successfully applied for recovery and determination of copper in cereals food samples展开更多
The synthesis of pillared clays have led to the development of new materialswith suitable pore size and sufficient stability to be used as shape-selective catalystsand molecular sieves. There are numerous layered inor...The synthesis of pillared clays have led to the development of new materialswith suitable pore size and sufficient stability to be used as shape-selective catalystsand molecular sieves. There are numerous layered inorganic oxides which havethe potential to undergo ion-exchange reactions analogous to those observed withclays, but the nonswelling nature of most ionic layered oxides generally prevents展开更多
The first chromia-pillared layered tetratitanate was prepared by the reaction of layered tetramethylammonium tetratitanate with chromium (III) acetate [Cr(OAc)3] aqueous solution and subsequent calcination of the resu...The first chromia-pillared layered tetratitanate was prepared by the reaction of layered tetramethylammonium tetratitanate with chromium (III) acetate [Cr(OAc)3] aqueous solution and subsequent calcination of the resultant solid product in air at 400°C. The obtained chromia-pillared layered tetratitanate has an interlayer distance of 1.06 nm and a high thermal stability up to 600°C. It was also found that calcination in N2 led to the chromia-pillared layered tetratitanate with relatively higher Brunauer-Emmett-Teller (BET) specific surface area (93.9 m2·g?1) and smaller average pore diameter (4.44 nm) than that in air (82.0 m2·g?1, 7.61 nm). Both Br?nsted and Lewis acid sites (mainly Lewis type) are present on the chromia-Pillared layered tetratitanate (500°C, N2, 8 h) and strong enough to still remain a small proportion of pyridine upon outgassing at 250°C. Moreover, ammonia temperature-programmed desorption (NH3-TPD) result showed that there were three NH3 desorption peaks at 160, 200 and 315°C, respectively. The corresponding acid amount is 41.3, 73.9 and 290.7 μmol·g?1. The total acid amount is 405.9 μmol·g?1.展开更多
A new kind of inorganic composite adsorbent based on chitin whiskers（CHW） and potassium tetratitanate whiskers（PTW） was synthesized via the thermal deposition to remove Cu2＋ and Pb2＋ from wastewater. CHW could b...A new kind of inorganic composite adsorbent based on chitin whiskers（CHW） and potassium tetratitanate whiskers（PTW） was synthesized via the thermal deposition to remove Cu2＋ and Pb2＋ from wastewater. CHW could be successfully coated on the surface of PTW when thermal treated 8 times. The adsorption process was better fitted with the Langmuir and Freundlich models. The adsorption process was more conformed to the Pseudo-second-order model. The results from XPS（X-ray photoelectron spectrum） further show that the adsorption mechanism between CHW-PTW and Cu2＋, Pb2＋ are both ion exchange and chemical adsorption. Thermodynamic parameters suggest that the adsorption processes are nonspontaneous. The adsorption of Cu2＋ and Pb2＋ is endothermic and exothermic, respectively.展开更多
基金Imburse Fund of Science and Technology Office (05C26213100474)
文摘A simple and reliable method has been developed for separation and preconcentration of trace amounts of copper ions in cereals food for subsequent measurement by flame atomic absorption spectrometry （FAAS）. The Cu^2＋ ions are adsorbed selectively and quantitatively during the passage. The retained copper ions were desorbed from the potassium tetratitanate whisker with 10.0mL of 2mol/L sulphuric acid solutions as eluent and were determined by FAAS. The linear range was 0.05μg/mL-0.20μg/mL in the original solution with a correlation coefficient of 0.9998. The detection limit of the proposed method is 2. lng/mL in the original solution （3σ, n=9）. Determination of copper in standard ions showed that the proposed method has good accuracy （recovery was more than 95%）. The method was successfully applied for recovery and determination of copper in cereals food samples
文摘The synthesis of pillared clays have led to the development of new materialswith suitable pore size and sufficient stability to be used as shape-selective catalystsand molecular sieves. There are numerous layered inorganic oxides which havethe potential to undergo ion-exchange reactions analogous to those observed withclays, but the nonswelling nature of most ionic layered oxides generally prevents
基金Project (No. 29573108) supported by the National Natural Science Foundation of China
文摘The first chromia-pillared layered tetratitanate was prepared by the reaction of layered tetramethylammonium tetratitanate with chromium (III) acetate [Cr(OAc)3] aqueous solution and subsequent calcination of the resultant solid product in air at 400°C. The obtained chromia-pillared layered tetratitanate has an interlayer distance of 1.06 nm and a high thermal stability up to 600°C. It was also found that calcination in N2 led to the chromia-pillared layered tetratitanate with relatively higher Brunauer-Emmett-Teller (BET) specific surface area (93.9 m2·g?1) and smaller average pore diameter (4.44 nm) than that in air (82.0 m2·g?1, 7.61 nm). Both Br?nsted and Lewis acid sites (mainly Lewis type) are present on the chromia-Pillared layered tetratitanate (500°C, N2, 8 h) and strong enough to still remain a small proportion of pyridine upon outgassing at 250°C. Moreover, ammonia temperature-programmed desorption (NH3-TPD) result showed that there were three NH3 desorption peaks at 160, 200 and 315°C, respectively. The corresponding acid amount is 41.3, 73.9 and 290.7 μmol·g?1. The total acid amount is 405.9 μmol·g?1.
基金Supported by the National Natural Science Foundation of China（No.51308314）.
文摘A new kind of inorganic composite adsorbent based on chitin whiskers（CHW） and potassium tetratitanate whiskers（PTW） was synthesized via the thermal deposition to remove Cu2＋ and Pb2＋ from wastewater. CHW could be successfully coated on the surface of PTW when thermal treated 8 times. The adsorption process was better fitted with the Langmuir and Freundlich models. The adsorption process was more conformed to the Pseudo-second-order model. The results from XPS（X-ray photoelectron spectrum） further show that the adsorption mechanism between CHW-PTW and Cu2＋, Pb2＋ are both ion exchange and chemical adsorption. Thermodynamic parameters suggest that the adsorption processes are nonspontaneous. The adsorption of Cu2＋ and Pb2＋ is endothermic and exothermic, respectively.
