Carbon Storage Dynamics in Lower Shimentan Formation of the Qiantang Sag, East China Sea Shelf Basin: Stratigraphy, Reservoir ‒ Cap Analysis, and Source ‒ Sink Compatibility

Excessive carbon emissions have resulted in the greenhouse effect, causing considerable global climate change. Marine carbon storage has emerged as a crucial approach to addressing climate change. The Qiantang Sag(QTS) in the East China Sea Shelf Basin, characterized by its extensive area, thick sedimentary strata, and optimal depth, presents distinct geological advantages for carbon dioxide(CO_(2)) storage. Focusing on the lower section of the Shimentan Formation in the Upper Cretaceous of the QTS, this study integrates seismic interpretation and drilling data with core and thin-section analysis. We reveal the vertical variation characteristics of the strata by providing a detailed stratigraphic description. We use petrophysical data to reveal the development characteristics of high-quality carbon-storage layers and favorable reservoircaprock combinations, thereby evaluating the geological conditions for CO_(2) storage in various stratigraphic sections. We identify Layer B of the lower Shimentan Formation as the most advantageous stratum for marine CO_(2) storage. Furthermore, we analyze the carbon emission trends in the adjacent Yangtze River Delta region. Considering the characteristics of the source and sink areas, we suggest a strong correlation between the carbon emission sources of the Yangtze River Delta and the CO_(2) storage area of the QTS, making the latter a priority area for conducting experiments on marine CO_(2) storage.

Sedimentary systems of the Oligocene Huagang Formation in the central anticline zone of the Xihu Depression,East China Sea Shelf Basin

The Xihu Depression is the largest hydrocarbon-bearing depression of the East China Sea Shelf Basin(also referred to as the ECSSB).However,the depositional systems and reservoir distribution of the Oligocene Huagang Formation in the Xihu Depression are still controversial.Under the guidance of sedimentology and stratigraphy,this study documented a marine-terrestrial transitional environment in the restricted bay setting of the Oligocene Huagang Formation through core description,well logging,and seismic data analysis.This study also revealed that the Oligocene Huagang Formation is dominated by tidal delta,estuary,and gravity flow deposits in the central anticline zone of the Xihu Depression.The new understanding of the sedimentary systems and the discovery of the transgressive gap in the eastern Diaoyu Islands uplift explain the origin of fine-grained sediments and the EW-trending sand bodies in the central depression and the sand bodies parallel to shoreline in the west slope belt,which cannot be explained by previous study results,such as southern transgression or fluvial deltas and even lacustrine deposition.Moreover,the tidal channels,tidal sand flats,and gravity flow sand bodies formed by the transgressive tides are high-quality reservoirs.The study will provide a basis for well placement and serve as guidance for the selection of favorable hydrocarbon exploration areas in the Xihu Depression.

New interpretation on the provenance changes of the upper Pinghu–lower Huagang Formation within Xihu Depression,East China Sea Shelf Basin

Both Pinghu and Huagang formations are important hydrocarbon reservoirs of the Xihu Depression in the East China Sea Shelf Basin.Clarifying the source suppliers and restoring source-to-sink transport routes are of great significance to the future petroleum and gas undertakings.Previous researchers were largely confined by either limitation of geological records,highly dependence on a singular method or low-precision dating techniques.Our study integrated heavy mineral assemblages,geochemical analyses and detrital zircon U-Pb dating to reconstruct multiple source-to-sink pathways,and to provide a better understanding on the provenance evolution for the upper Pinghu–lower Huagang depositions of the Xihu Depression.At least three major provenances have been confirmed and systematically investigated for their separate compositional features.The Hupijiao Uplift(or even farther northern area)was dominated by a major Paleoproterozoic population peaked at ca.1830 Ma along with minor Mesozoic clusters.The Haijiao Uplift to the west and the Yushan Low Uplift to the southwest,on the other hand,generate opposite U-Pb age spectra with apparently larger peaks of Indosinian and Yanshanian-aged zircons.To be noted,both Indosinian and Paleoproterozoic peaks are almost identical in proportion for the Haijiao Uplift.The overall sedimentary pattern of late Eocene-early Oligocene was featured by both spatial and temporal distinction.The Hupijiao Uplift was likely to cast limited impact during the late Eocene,whereas the broad southern Xihu Depression was transported by a large abundance of materials from the nearby Haijiao and Yushan Low Uplifts.The northern source substantially extended its influence to the farther south during the early Oligocene by delivering plentiful sediments of higher-degree metamorphic parent rocks.Combined with the proximal western and southwestern suppliers,the overall Xihu Depression was under control from both distant and local provenances.

Origin of hydrocarbon fluids and discussion of abnormal carbon isotopic compositions in the Lishui-Jiaojiang Sag,East China Sea Shelf Basin

The hydrocarbon gases in the L1 gas field of the Lishui-Jiaojiang Sag have been commonly interpreted to be an accumulation of pure sapropelic-type thermogenic gas.In this study,chemical components,stable isotopic compositions,and light hydrocarbons were utilized to shed light on the origins of the hydrocarbon fluids in the L1gas pool.The hydrocarbon fluids in the L1 gas pool are proposed to be a mixture of three unique components:mid-maturity oil from the middle Paleocene coastal marine Lingfeng source rock,oil-associated(late oil window)gas generated from the lower Paleocene lacustrine Yueguifeng source rock,and primary microbial gas from the paralic deposits of the upper Paleocene Mingyuefeng source rock.Here,for the first time,the hydrocarbon gases in the L1 gas pool are diagnosed as mixed oil-associated sapropelic-type gas and microbial gas via four pieces of principal evidence:(1)The abnormal carbon isotopic distributions of all methane homologues from C_(1)(CH_(4)or methane)to C_(5)(C_(5)H_(12)or pentane)shown in the Chung plot;(2)the diagnostic~(13)C-depleted C_(1)compared with the thermogenic sapropelic-type gas model,whileδ^(13)C_(2)(C_(2)H_(6)or ethane)andδ^(13)C_(3)(C_(3)H_(8)or propane)both fit perfectly;(3)the excellent agreement of the calculated carbon isotopic compositions of the pure thermogenic gas with the results of the thermal simulated gas from the type-II1 kerogen-rich Yueguifeng source rock;and(4)the oil-associated gas inferred from various binary genetic diagrams with an abnormally elevated gas oil ratio.Overall,the natural gases of the L1 gas pool were quantified in this study to comprise approximately 13%microbial gas,nearly 48%oil-associated sapropelic-type gas,and 39%of nonhydrocarbon gas.The microbial gas is interpreted to have been codeposited and entrained in the humic-kerogen-rich Mingyuefeng Formation under favorable lowtemperature conditions during the late Paleocene-middle Eocene.The microbial gas subsequently leaked into the structurally and stratigraphically complex L1 trap with oil-associated sapropelic-type gas from the Yueguifeng source rock during the late Eocene-Oligocene uplifting event.A small amount of humic-kerogen-generated oil in the L1 gas pool is most likely to be derived from the underlying Lingfeng source rock.The detailed geological and geochemical considerations of source rocks are discussed to explain the accumulation history of hydrocarbon fluids in the L1 gas pool.This paper,therefore,represents an effort to increase the awareness of the pitfalls of various genetic diagrams,and an integrated geochemical and geological approach is required for hydrocarbonsource correlation.

Application of seismic sedimentology in characterization of fluvial-deltaic reservoirs in Xihu sag, East China Sea shelf basin

The fluvial-deltaic reservoirs of the Oligocene Huagang Formation in the Xihu sag of the East China Sea shelf basin reflect rapid lateral change in sedimentary facies and poor morphology of conventional slice attributes,which bring difficulties to the reservoir prediction for subsequent exploration and development of lithologic reservoirs.The traditional seismic sedimentology technology is optimized by applying the characteristic technologies such as frequency-boosting interpretation,inversion-conventional–90°phase shift joint construction of seismic lithologic bodies,nonlinear slices,paleogeomorphology restoration,and multi-attribute fusion,to obtain typical slice attributes,which are conducive to geological form description and sedimentary interpretation.The Huagang Formation developed three types of sedimentary bodies:braided river,meandering river and shallow water delta,and the vertical sedimentary evolution was controlled by the mid-term base-level cycle and paleogeomorphology.In the early–middle stage of the mid-term base-level ascending cycle,braided channel deposits were dominant,and vertical superimposed sand bodies were developed.In the late stage of the ascending half-cycle and the early stage of the descending half-cycle,meandering river deposits were dominant,and isolated sand bodies were developed.In the middle–late stage of the descending half-cycle,shallow-water delta deposits were dominant,and migratory medium–thick sand bodies were developed.Restricted paleogeomorphology controlled the sand body distribution,while non-restricted paleogeomorphology had little effect on the sand body distribution.Based on reservoir characterization,the fault sealing type and reservoir updip pinch-out type structural lithological traps are proposed as the main directions for future exploration and development in the Xihu sag.

Clay minerals and elemental composition of sediments on different sedimentary units in the northern East China Sea shelf:provenance tracing and genetic mechanism analysis

The composition,provenance,and genetic mechanism of sediment on different sedimentary units of the East China Sea(ECS)shelf are essential for understanding the depositional dynamics environment in the ECS.The sediments in the northern ECS shelf are distributed in a ring-shaped distribution centered on the southwestern Cheju Island Mud.From the inside to the outside,the grain size goes from fine to coarse.Aside from the“grain size effect”,hydrodynamic sorting and mineral composition are important restrictions on the content of rare earth elements(REEs).Based on the grain size,REEs,and clay mineral composition of 300 surface sediments,as well as the sedimentary genesis,the northern ECS shelf is divided into three geochemical zones:southwestern Cheju Island Mud Area(ZoneⅠ),Changjiang Shoal Sand Ridges(ZoneⅡ-1),Sand Ridges of the East China Sea shelf(ZoneⅡ-2).The northern ECS shelf is mostly impacted by Chinese mainland rivers(the Changjiang River and Huanghe River),and the provenance and transport mechanism of sediments of different grain sizes is diverse.The bulk sediments come primarily from the Changjiang River,with some material from the Huanghe River carried by the Yellow Sea Coastal Current and the North Jiangsu Coastal Current,and less from Korean rivers.Among them,surface sediments in the southwestern Cheju Island Mud Area(ZoneⅠ)come mostly from the Changjiang River and partly from the Huanghe River.It was formed by the counterclockwise rotating cold eddies in the northern ECS shelf,which caused the sedimentation and accumulation of the fine-grained sediments of the Changjiang River and the Huanghe River.The Changjiang Shoal Sand Ridges(ZoneⅡ-1)were developed during the early-middle Holocene sea-level highstand.It is the modern tidal sand ridge sediment formed by intense hydrodynamic action under the influence of the Yellow Sea Coastal Current,North Jiangsu Coastal Current,and Changjiang Diluted Water.The surface sediments mainly originate from the Changjiang River and Huanghe River,with the Changjiang River dominating,and the Korean River(Hanjiang River)influencing just a few stations.Sand Ridges of the East China Sea shelf(ZoneⅡ-2)are the relict sediments of the paleo-Changjiang River created by sea invasion at the end of the Last Deglaciation in the Epipleistocene.The clay mineral composition of the surface sediments in the study area is just dominated by the Changjiang River,with the North Jiangsu Coastal Current and the Changjiang Diluted Water as the main transporting currents.

Tectonics and Petroleum Potential of the East China Sea Shelf Rift Basin

There are two Cenozoic sedimentary basins in the East China Sea. They are the East China Sea shelf basin and the Okinawa Trough basin. The former can be divided into a western and an eastern rift region. The development of the shelf basin underwent continental-margin fault depression, post-rift and then tectonic inversion stages. Available exploration results show that the distribution of source rocks is controlled by the basin architecture and its tectonic evolution. In the Xihu depression, mudstones and coals are the main source rocks. The eastern rift region has good geological conditions for the formation of large oil and gas fields.

Diagenesis and Diagenetic Evolution of Deltaic and Neritic Gas-Bearing Sandstones in the Lower Mingyuefeng Formation of Paleogene, Lishui Sag, East China Sea Shelf Basin: Implications for Depositional Environments and Sequence Stratigraphy Controls

Gas-bearing deposits in the Lower Mingyuefeng Formation of Paleogene, Lishui Sag, East China Sea Shelf Basin consist of shoreface sandstones of the highstand systems tract（HST） and transgressive systems tract（TST）, and deltaic sandstones of the lowstand systems tract（LST） and falling stage systems tract（FSST）.Detailed petrographic observations suggest that the diagenetic features and related evolution of these deposits cannot be simply characterized and demonstrated in the depth domain.However, the occurrence of diagenetic minerals systematically depends on the studied interval within the HST, TST, LST, and FSST; therefore, diagenesis in this region can be better constrained when studied in the context of the depositional environments and sequence stratigraphic framework.The eogenetic processes in such settings include：（1） microcrystalline siderite precipitated as concretions in almost all environments and systems tracts, which inhibited further mechanical compaction;（2） grain dissolution and kaolinitization occurred in shoreface HST sandstones and deltaic LST and FSST sandstones;（3） glaucony was locally observed, which did not clearly reflect the controls of facies or sequence stratigraphy; and（4） cementation by pyrite aggregates occurred in the shoreface HST sandstones and deltaic LST sandstones.The mesogenetic diagenesis includes：（1） partial conversion of kaolinite into dickite in deltaic LST sandstones, and minor chlorite cementation in deltaic FSST sandstones;（2） transformation of kaolinite into illite and quartz cementation in deltaic LST and FSST sandstones;（3） frequent precipitation of ankerite and ferroan calcite in shoreface TST sandstones and early HST sandstones, forming baffles and barriers for fluid flow, with common calcite in shoreface HST sandstones as a late diagenetic cement; and（4） formation of dawsonite in the deltaic LST and FSST sandstones, which is interpreted to be a product of the invasion of a CO2-rich fluid, and acts as a good indicator of CO2-bearing reservoirs.This study has thus constructed a reliable conceptual model to describe the spatial and temporal distribution of diagenetic alterations.The results may provide an entirely new conceptual framework and methodology for successful gas exploration in the continental margins of offshore China, thus allowing us to predict and unravel the distribution and quality evolution of clastic reservoirs at a more detailed and reliable scale.

The Mesozoic Basin-Mountain Coupling Process of the Southern East China Sea Shelf Basin and its Adjacent Land Area

Basin-mountain coupling is a key issue for basin formation and evolution. The analysis of basin-mountain coupling process, as well as quantitative or semiquantitative restoration of prototype basin and the evolution of continental margin, can be used to interpret the geological process of basin-range conversion and reconstruct early prototype basins, which is a difficult and leadin~ scientific oroblem of basin research.

Discovery of Late Cretaceous-Paleocene faulted basins developed on the Yandang Low Uplift, East China Sea Shelf Basin

1.Objective The East China Sea Shelf Basin (ECSSB) is a typical Meso-Cenozoic superimposed basin which consists several tectonic units including the Changjiang Sag, Oujiang Sag, Hupijiao Uplift, Haijiao Uplift, Yandang Low Uplift (YDLU), Minjiang Sag, Taipei Low Uplift, Xihu Sag, Jilong Sag and so on.

Study on interaction between the coastal water, shelf water and Kuroshio water in the Huanghai Sea and East China Sea

The main processes of interaction between the coastal water, shelf water and Kuroshio water in the Huanghai Sea (HS) and East China Sea (ECS) are analyzed based on the observation and study results in recent years. These processes include the intrusion of the Kuroshio water into the shelf area of the ECS, the entrainment of the shelf water into the Kuroshio, the seasonal process in the southern shelf area of the ECS controlled alternatively by the Taiwan Strait water and the Kuroshio water intruding into the shelf area, the interaction between the Kuroshio branch water, shelf mixed water and modified coastal water in the northeastern ECS, the water-exchange between the HS and ECS and the spread of the Changjiang diluted water.

Geochemical and isotopic characteristics of volcanic rocks from the northern East China Sea shelf margin and the Okinawa Trough

Volcanic rocks both from the northern East China Sea （NECS） shelf margin and the northern Okinawa Trough are subalkaline less aluminous,and lower in High Field Strength Elements （HFSE）.These rocks are higher in Large Ion Lithophile Elements （LILE）,thorium and uranium contents,positive lead anomalies,negative Nb-Ta anomalies,and enrichment in Light Rare Earth Elements （LREE）.Basalts from the NECS shelf margin are akin to Indian Ocean Mid-Ocean Ridge Basalt （MORB）,and rhyolites from the northern Okinawa Trough have the highest 207 Pb/ 204 Pb and 208 Pb/ 204 Pb ratios.The NECS shelf margin basalts have lower 87 Sr/ 86 Sr ratios,ε N d and σ 18 O than the northern Okinawa Trough silicic rocks.According to 40 K– 40 Ar isotopic ages of basalts from the NECS shelf margin,rifting of the Okinawa Trough may have been active since at least 3.65–3.86 Ma.The origin of the NECS shelf margin basalt can be explained by the interaction of melt derived from Indian Ocean MORB-like mantle with enriched subcontinental lithosphere.The basalts from both sides of the Okinawa Trough may have a similar origin during the initial rifting of the Okinawa Trough,and the formation of basaltic magmas closely relates to the thinning of continental crust.The source of the formation of the northern Okinawa Trough silicic rocks was different from that of the middle Okinawa Trough,which could have been generated by the interaction of basaltic melt with an enriched crustal component.From the Ryukyu island arc to East China,the Cenozoic basalts have apparently increasing trends of MgO contents and ratios of LREE to Heavy Rare Earth Elements （HREE）,suggesting that the trace element variabilities of basalts may have been influenced by the subduction of the Philippine Sea plate,and that the effects of subduction of the Philippine Sea plate on the chemical composition of basaltic melts have had a decreasing effect from the Ryukyu island arc to East China.

Recent sedimentary records in the East China Sea inner shelf and their response to environmental change and human activities

The East China Sea continental shelf is a unique area for the study of land-sea interactions and paleoenvironmental change because it receives a large amount of terrestrial material inputs. In recent decades, human activities and global climate change have greatly aff ected river discharges into the sea. However, changes in the deposition process caused by these factors in the East China Sea continental shelf are unclear. We collected eight short sediment cores from the East China Sea inner shelf(ECSIS) using a box core sampler in 2012 and 2015. The grainsize, 2 10 Pb, and 1 37 Cs of these cores were analyzed in order to reconstruct the deposition history since the 1950 s, and to reveal human activity and climate change influences on sediment deposition in the ECSIS. Results indicated that sediment grain size became finer after 1969, turned coarser after 1987, and then further coarser since 2003, corresponding well to the three steps of sediment load drop in the Changjiang(Yangtze) River, which are mainly caused by human activities(particularly the closure of the Three Gorges Dam). Simultaneously, the East Asian Monsoon influenced the deposition process in the ECSIS by changing the intensity of coastal currents. Mean grain size variations in the fine-grained population(divided by grain size vs. standard deviation method) coincided with that of the East Asian Winter Monsoon strength and reflected its weakness in 1987. Abrupt changes in sediment grain size over a short time scale in these sediment cores were generally caused by floods and typhoons. Spectral analyses of the sediment cores showed periodicities of 10–11 and 20–22 years, corresponding to the periodicity of solar activity(Schwabe cycle and Hale cycle). Mean grain size time series also displayed a 3–8 year periodicity corresponding to El Ni?o Southern Oscillation periodic change.

Tertiary Sea Level Changes and Sequence Stratigraphic Framework in East China Sea Shelf Basin

The East China Sea shelf basin is a key area for setting up the sea level changes of Cenozoic in the West Pacific. Based upon the characteristics of seismic reflection, the analysis of sequence stratigraphy and depositional system, the high resolution chronostratigraphic framework has been set up by using the data of micropaleontologic biozone fossils. The relative sea level change curve has been set up by combining analysis of paleoecology, genetic facies, specific sedimentary structures and on lap recognized from the seismic profiles with study of geochemical characteristics. There are 4 2nd order basin cycles showing the long term sea level changes, and 22 3rd order cycles showing short term ones with relative changing ranges of 0-150 m. Transgression and regression showing long term sea level changes bear asymmetric feature, which indicates that the speed of transgression is faster than that of regression. There are a lot of differences when compared with Haq ’s curve. The sequence stratigraphic framework has also been set up and 3 tectonic sequences, 7 supersequences and 19 sequences have been subdivided for Tertiary in the East China Sea shelf basin. On the basis of detailed analysis of genetic facies and log facies, 9 sedimentary systems, 20 depositional assemblages and many genetic facies have also been recognized and investigated. Based on the studies mentioned above, the favorable source and reservoir facies of gas and petroleum are indicated.

Measurement of the current and spectral analysis on the continental shelf in the East China Sea

Direct measurements of current velocity and water temperature were undertaken at the mooring Sta. M (125°29.38' N, 31°49.70' E) on the continental shelf area in the East China Sea in June 1999 by R/V Xiangyanghong 14. The relationship between various time series of oceanic fluctuations is calculated by spectral analysis. The major results are as follows: (1) an average (u,v) of (6.9,-3.0 cm/s) at the 30 m depth is obtained during the 9-day observation, and that at the 45 m depth is (3.7,-1.1 cm/s), i. e., the mean flows are southeastward at both the 30 and 45 m depths;the currents become stronger gradually during the observation period; this may be mainly attributed to the transition of the tidal currents from neap to spring; (2)semidiurnal fluctuation is the most dominant in the current fluctuations, and rotates mainly clockwise; in the next place, there is also diurnal fluctuation;the local inertial period is close to the period of diurnal fluctuation, and an inertial motion is clockwise; thus, local inertial motion combines with diurnal fluctuation, and makes the spectral peaks in clockwise components much higher than those in counterclockwise ones; except for the fluctuations of above main periods, there is also the peak at 3 d period for counterclockwise compo-nents in the upper and lower layers; (3) the calculation of cross spectra between two time series of current velocities at the 30 and 45 m depths shows that both the current fluctuations at the 30 and 45 m depths are much alike, i. e., they are synchro; this shows that the flow field here is rather vertically homogeneous; (4)power spectra of tempera-ture time series at both the 30 and 45 m depths show that the semidiurnal peak is the most predominant, and the second highest peak is the diurnal period; besides spectral peaks at above periods, there are also obvious spectral peaks at 6.8 h and 2 d; (5)plots of temperature time series at 16 , 30 , 35 , 45 and 50 m depths show that the temporal variations of temperature at these depths are synchro, which are like those in the velocity field; temperature records also show a gradual rise in temperature, which are also like those in the velocity field.

TRANSPORT OF SUSPENDED MATTER FROM THE CHANGJIANG RIVER TO THE EAST CHINA SEA SHELF

Suspended matter (SM) in the East China Sea (ECS) shelf seawater was investigated during Oct. 1993, Apr. and Oct. 1994. Results showed that the high total suspended matter(TSM) region (>7200)mg/L) was limted to near the estuary and reduced rapidly to <10 mg/L at 122 °30’E. The high TSM contour extended mainly NE in surface water but SE in near bottom Water,i. e., SM transport from the Changjiang River was characterized by "stratification and different transport directions in different layers’. TSM distribution on sections showed that the up-climbing Kuroshio water prevents Changjiang River SM in middle and bottom water from transporting to the Okinawa Trough. Vertical distributions of the TSM showed a suspended-cline that appeared in the inner and middle shelf TSM below it was dense and formed a turbid water laper, TSM above it was less dense, so the water was reatively clear. Formation of the suspended-cline correlated with high density current and resuspension of bottom sediment.

Temporal-Spatial Variation of Surface Suspended Matter and Controlling Factors in the Inner Shelf of the East China Sea in Winter

Based on the observed surface suspended matter in the East China Sea in February 2007 and June 2015, an empirical model was established using L1 b's band 4 data to retrieve surface suspended matter from the Moderate Resolution Imagine Spectroradiometer Terra imagery. The squared correlation coefficient is 0.8358, and the root mean square error is 0.4285 mg L-1. The model reflects the distribution characteristics of surface suspended matter in the inner shelf of the East China Sea. In this paper, the satellite images of the study area were retrieved in January from 2001 to 2015, and the monthly distribution of surface suspended matter were obtained. The inter-annual distribution of the study area is similar, and the concentration of surface suspended matter is higher near the shore than offshore. A large amount of surface suspended matter is transported southeast under the influence of Zhejiang and Fujian coastal current and Taiwan warm current. Only a small amount of surface suspension can reach the Kuroshio area. The surface suspended matter concentration changes obviously near the estuary because of the effect of differences in the flux of the Yangtze River. Meanwhile, winter monsoon, temperature front, El Ni?o events, and other factors affect the distribution of surface suspended matter in 100 m isobath to coastal water but minimally influence the distribution in 100 m isobath to deep sea.

Facies Architecture Model of the Shimentan Formation Pyroclastic Rocks in the Block-T Units, Xihu Sag, East China Sea Basin, and its Exploration Significance

A gas field consisting of volcanic reservoir rocks was discovered in the block-T units of the Xihu Sag,East China Sea Basin.The lithology of the volcanic rocks is dominated by tuff and reworked tuff.The lithofacies are dominated by base surge deposits of explosive facies.As the architecture model of volcanic facies is still uncertain,it has restricted the exploration and development of mineral resources in this area.Using core and cuttings data,the lithology,lithofacies,geochemistry as well as grain size characteristics of volcanic rocks were analyzed.Based on these analyses,the volcanic rocks in the well section are divided into three eruptive stages.The transport direction of each volcanic eruption is analyzed using crystal fragment size analysis.The facies architecture of the block-T units was established based on the reconstruction results of paleo-geomorphology.The results show that the drilling reveals proximal facies(PF)and distal facies(DF)of the volcanic edifices.However,the crater-near crater facies(CNCF)are not revealed.Compared with the reservoirs of the Songliao Basin,it is shown that the volcanic rocks in the Xihu Sag have good exploration potential;a favorable target area is the CNCF near the contemporaneous fault.

Factors controlling the development of tight sandstone reservoirs in the Huagang Formation of the central inverted structural belt in Xihu sag, East China Sea Basin

By means of thin section analysis, zircon U-Pb dating, scanning electron microscopy, electron probe, laser micro carbon and oxygen isotope analysis, the lithologic features, diagenetic environment evolution and controlling factors of the tight sandstone reservoirs in the Huagang Formation of Xihu sag, East China Sea Basin were comprehensively studied. The results show that: the sandstones of the Huagang Formation in the central inverted structural belt are poor in physical properties, dominated by feldspathic lithic quartz sandstone, high in quartz content, low in matrix, kaolinite and cement contents, and coarse in clastic grains;the acidic diagenetic environment formed by organic acids and meteoric water is vital for the formation of secondary pores in the reservoirs;and the development and distribution of the higher quality reservoirs in the tight sandstones of the Huagang Formation are controlled by sediment source, sedimentary facies belt, abnormal overpressure and diagenetic environment evolution. Sediment provenance and dominant sedimentary facies led to favorable initial physical properties of the sandstones in the Huagang Formation, which is the prerequisite for development of reservoirs with better quality later. Abnormal high pressure protected the primary pores, thus improving physical properties of the reservoirs in the Huagang Formation. Longitudinally, due to the difference in diagenetic environment evolution, the high-quality reservoirs in the Huagang Formation are concentrated in the sections formed in acidic diagenetic environment. Laterally, the high-quality reservoirs are concentrated in the lower section of the Huagang Formation with abnormal high pressure in the middle-northern part;but concentrated in the upper section of Huagang Formation shallower in burial depth in the middle-southern part.

pCO_2 distribution and CO_2 flux on the inner continental shelf of the East China Sea during summer 2011

Measurements ofpH, total alkalinity （TA）, partial pressure of CO2 （pCO2） and air-sea CO2 flux （FCO2） were conducted for the inner continental shelf of the East China Sea （ECS） during August 2011. Variations in pCO2 distribution and FCO2 magnitude during the construction of the Three Gorges Dam （TGD） （2003-2009）, and the potential effects of the TGD on the air-sea CO2 exchange were examined. Results showed that the ECS acts as an overall CO2 sink during summer, with pCO2 ranging from 107 to 585 p.atm and an average FCO2 of -6.39 mmol/（m2·d）. Low pCO2 （〈350 μatm） levels were observed at the central shelf （28°-32°N, 123°-125.5°E） where most CO2-absorption occurred. HighpCO2 （〉420 μatm） levels were found in the Changjiang estuary and Hangzhou Bay which acted as the main CO2 source. A negative relationship between pCO2 and salinity （R2=0.722 0） in the estuary zone indicated the predominant effect of the Changjiang Diluted Water （CDW） on the seawater CO2 system, whereas a positive relationship （R2=0.744 8） in the offshore zone revealed the influence of the Taiwan Current Warm Water （TCWW）. Together with the historical data, our results indicated that the CO2 sink has shown a shift southwest while FC02 exhibited dramatic fluctuation during the construction of the TGD, which is located in the middle reaches of the Changjiang. These variations probably reflect fluctuation in the Changjiang runoff, nutrient import, phytoplankton productivity, and sediment input, which are likely to have been caused by the operations of the TGD. Nevertheless, the potential influence of the TGD on the CO2 flux in the ECS is worthy of further study.