To clarify the formation and distribution of feldspar dissolution pores and predict the distribution of high-quality reservoir in gravity flow sandstone of the 7^(th) member of Triassic Yanchang Formation(Chang 7 Memb...To clarify the formation and distribution of feldspar dissolution pores and predict the distribution of high-quality reservoir in gravity flow sandstone of the 7^(th) member of Triassic Yanchang Formation(Chang 7 Member)in the Ordos Basin,thin sections,scanning electron microscopy,energy spectrum analysis,X-ray diffraction whole rock analysis,and dissolution experiments are employed in this study to investigate the characteristics and control factors of feldspar dissolution pores.The results show that:(1)Three types of diagenetic processes are observed in the feldspar of Chang 7 sandstone in the study area:secondary overgrowth of feldspar,replacement by clay and calcite,and dissolution of detrital feldspar.(2)The feldspar dissolution of Chang 7 tight sandstone is caused by organic acid,and is further affected by the type of feldspar,the degree of early feldspar alteration,and the buffering effect of mica debris on organic acid.(3)Feldspars have varying degrees of dissolution.Potassium feldspar is more susceptible to dissolution than plagioclase.Among potassium feldspar,orthoclase is more soluble than microcline,and unaltered feldspar is more soluble than early kaolinized or sericitized feldspar.(4)The dissolution experiment demonstrated that the presence of mica can hinder the dissolution of feldspar.Mica of the same mass has a significantly stronger capacity to consume organic acids than feldspar.(5)Dissolution pores in feldspar of Chang 7 Member are more abundant in areas with low mica content,and they improve the reservoir physical properties,while in areas with high mica content,the number of feldspar dissolution pores decreases significantly.展开更多
The mineralogical development and diagenetic sequence of lacustrine shales in the Chang 7 Member of the Yanchang Formation in the Ordos Basin are detailed studied.A model of their depositional system and a diagenetic ...The mineralogical development and diagenetic sequence of lacustrine shales in the Chang 7 Member of the Yanchang Formation in the Ordos Basin are detailed studied.A model of their depositional system and a diagenetic diagram are proposed in this study.Through detailed petrographic,mineralogical,and elemental analyses,four distinct shale types are identified:argillaceous shale,siliceous shale,calcareous shale,and carbonate,clay,and silt-bearing shale.The main diagenetic process in argillaceous shale is the transformation of illite to smectite,negatively impacting shale porosity.Siliceous shale undergoes carbonate cementation and quartz dissolution,contributing to increased porosity,particularly in mesopores.Calcareous shale experiences diagenesis characterised by carbonate formation and dissolution,with a prevalence of siderite.In carbonate,clay,and silt-bearing shale,the dissolution of K-feldspar contributes to illitization of kaolinite.Argillaceous shale,characterised by more clay minerals and lower mesopore volume,is identified as a potential hydrocarbon seal.Siliceous shale,with the highest pore volume and abundant inter-mineral pores,emerges as a promising shale oil reservoir.These findings contribute to a comprehensive understanding of shale properties,aiding in the prediction of shale oil exploration potential in the studied area.展开更多
1 Introduction Shale formations bear abundant mineral resource and*unconventional petroleum resource,and the unconventional petroleum resource that contain in the shale formation should be integrated and researched.
Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral c...Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral constitution affected by provenance. There are such apparent signatures as lithology, sedimentary structure, sedimentary sequence and well logs, to recognize turbidite. During the paleogeographic evolution of Chang-7 Member, lake basin and deep lake are both at their maximum extent during Chang-73 stage, resulting in the deposition of Zhangjiatan shale with widespread extent and of turbidite with fragmental-like. Deep lake line is gradually moving toward lake center and turbidite sand bodies are gradually turning better with better lateral continuity, connectivity and more thickness, from stages of Chang-73, Chang-72 and Chang-7t, which can be favorable reservoir in deep-water.展开更多
A set of shale-dominated source rocks series were deposited during the heyday of lake basin development in the Member 7 of Triassic Yanchang Formation,Ordos Basin,and the thickness is about 110 m.Aimed at whether this...A set of shale-dominated source rocks series were deposited during the heyday of lake basin development in the Member 7 of Triassic Yanchang Formation,Ordos Basin,and the thickness is about 110 m.Aimed at whether this layer can form large-scale oil enrichment of industrial value,comprehensive geological research and exploration practice have been carried out for years and obtained the following important geologic findings.Firstly,widely distributed black shale and dark mudstone with an average organic matter abundance of 13.81%and 3.74%,respectively,lay solid material foundation for the formation of shale oil.Secondly,sandy rocks sandwiched in thick organic-rich shale formations constitute an oil-rich"sweet spot",the average thickness of thin sandstone is 3.5 m.Thirdly,fine-grained sandstone and siltstone reservoirs have mainly small pores of 2–8μm and throats of 20–150 nm in radius,but with a large number of micro-pores and nano-throats,through fracturing,the reservoirs can provide good conductivity for the fluid in it.Fourthly,continued high-intensity hydrocarbon generation led to a pressure difference between the source rock and thin-layer reservoir of up to 8–16 MPa during geological history,driven by the high pressure,the oil charged into the reservoirs in large area,with oil saturation reaching more than 70%.Under the guidance of the above theory,in 2019,the Qingcheng Oilfield with geologic oil reserves of billion ton order was proved in the classⅠmulti-stage superimposed sandstone shale reservoir of Chang 7 Member by the Changqing Oilfield Branch through implementation of overall exploration and horizontal well volume fracturing.Two risk exploration horizontal wells were deployed for the classⅡthick layer mud shale interbedded with thin layers of silt-and fine-sandstones reservoir in the Chang 73 submember,and they were tested high yield oil flows of more than 100 tons per day,marking major breakthroughs in petroleum exploration in classⅠshale reservoirs.The new discoveries have expanded the domain of unconventional petroleum exploration.展开更多
综合利用地球化学、扫描电镜、岩心薄片、测井等资料以及油井生产数据等,对鄂尔多斯盆地陕北地区三叠系延长组7段储层特征、烃源岩特征和致密油分布特征进行了分析,从烃源岩展布、输导体系和源-储组合关系3个方面对致密油差异富集控制...综合利用地球化学、扫描电镜、岩心薄片、测井等资料以及油井生产数据等,对鄂尔多斯盆地陕北地区三叠系延长组7段储层特征、烃源岩特征和致密油分布特征进行了分析,从烃源岩展布、输导体系和源-储组合关系3个方面对致密油差异富集控制因素进行了探讨,并总结了成藏模式。研究结果表明:(1)陕北地区长7段致密砂岩储层主要分布在一亚段(长71)和二亚段(长72),以灰色—灰白色长石砂岩和岩屑长石砂岩为主,长71和长72平均孔隙度分别为5.56%和7.32%,平均渗透率分别为0.097 m D和0.110 m D,长72储层物性更好;孔隙空间以溶孔为主,发育少量粒间孔。(2)研究区烃类主要来源于本地长72顶部和长73这2套烃源岩,平均厚度大于20 m,有机质丰度高,平均TOC值为3.02%,干酪根类型以Ⅰ型和Ⅱ1型为主,处于生烃高峰期,平均生烃量为270.2×10^(4)t/km^(2),长73烃源岩生烃潜力更大,供烃至长72储层,长71致密油来源于长72烃源岩;新安边地区三角洲前缘亚相末端的长72储层中致密油由湖盆烃源岩侧向供烃。(3)研究区致密油富集受烃源岩展布、砂体连通性以及源-储组合共同控制,在长72更富集,在新安边地区分布面积最大,安塞地区无大规模致密油聚集;纵向上和平面上致密油的聚集差异受控于烃源岩厚度和源-储组合关系,下生上储、上下生油而中间储集和砂泥互层时含油性更好;新安边地区三角洲前缘亚相末端的长72致密油聚集规模大于三角洲前缘主体,是由于三角洲前缘末端发育的局部连通砂体阻碍了湖盆烃类物质的侧向运移。(4)研究区致密油为“源控-砂控”成藏模式,远源河道优势砂体尖灭处和近源局部连通的砂体是有利勘探区。展开更多
The kinetic parameters of hydrocarbon generation are determined through experimental simulation and mathematical calculation using four typical samples selected from the Cretaceous Nenjiang Formation in the northwest ...The kinetic parameters of hydrocarbon generation are determined through experimental simulation and mathematical calculation using four typical samples selected from the Cretaceous Nenjiang Formation in the northwest of Songliao Basin,Chang 7 Member of Triassic Yanchang Formation in the southwest of Ordos Basin,Paleogene in the southwest of Qaidam Basin,and Lucaogou Formation of Jimusar Sag in the east of Junggar Basin.The results show that activation energy of hydrocarbon generation of organic matter is closely related to maturity and mainly ranges between 197 kJ/mol and 227 kJ/mol.On this basis,the temperature required for organic matter in shale to convert into oil was calculated.The ideal heating temperature is between 270℃and 300℃,and the conversation rate can reach 90%after 50-300 days of heating at constant temperature.When the temperature rises at a constant rate,the temperature corresponding to the major hydrocarbon generation period ranges from 225 to 350℃at the temperature rise rate of 1-150℃/month.In order to obtain higher economic benefits,it is suggested to adopt higher temperature rise rate(60-150℃/month).The more reliable kinetic parameters obtained can provide a basis for designing more reasonable scheme of in-situ heating conversion.展开更多
基金Supported by the National Natural Science Foundation of China(42202176)CNPC-Southwest University of Petroleum Innovation Consortium Cooperation Project(2020CX050103).
文摘To clarify the formation and distribution of feldspar dissolution pores and predict the distribution of high-quality reservoir in gravity flow sandstone of the 7^(th) member of Triassic Yanchang Formation(Chang 7 Member)in the Ordos Basin,thin sections,scanning electron microscopy,energy spectrum analysis,X-ray diffraction whole rock analysis,and dissolution experiments are employed in this study to investigate the characteristics and control factors of feldspar dissolution pores.The results show that:(1)Three types of diagenetic processes are observed in the feldspar of Chang 7 sandstone in the study area:secondary overgrowth of feldspar,replacement by clay and calcite,and dissolution of detrital feldspar.(2)The feldspar dissolution of Chang 7 tight sandstone is caused by organic acid,and is further affected by the type of feldspar,the degree of early feldspar alteration,and the buffering effect of mica debris on organic acid.(3)Feldspars have varying degrees of dissolution.Potassium feldspar is more susceptible to dissolution than plagioclase.Among potassium feldspar,orthoclase is more soluble than microcline,and unaltered feldspar is more soluble than early kaolinized or sericitized feldspar.(4)The dissolution experiment demonstrated that the presence of mica can hinder the dissolution of feldspar.Mica of the same mass has a significantly stronger capacity to consume organic acids than feldspar.(5)Dissolution pores in feldspar of Chang 7 Member are more abundant in areas with low mica content,and they improve the reservoir physical properties,while in areas with high mica content,the number of feldspar dissolution pores decreases significantly.
基金founded by National Natural Science Foundation of China(grant Nos.:42072186 and 42090025)National Science and Technology Major Project,China(grant No.:2016ZX05046001)+3 种基金Science and Technology Research Project of Petro China Company Limited,China(grant No.:2021DJ1806)the fund support from China Scholarship Council(No.201806440002)the International Postdoctoral Exchange Fellowship Program,China(Talent-Introduction Program,No.270152)Lin Ma wishes to acknowledge the fund support from Natural Environment Research Council,United Kingdom(NE/R013527/1)。
文摘The mineralogical development and diagenetic sequence of lacustrine shales in the Chang 7 Member of the Yanchang Formation in the Ordos Basin are detailed studied.A model of their depositional system and a diagenetic diagram are proposed in this study.Through detailed petrographic,mineralogical,and elemental analyses,four distinct shale types are identified:argillaceous shale,siliceous shale,calcareous shale,and carbonate,clay,and silt-bearing shale.The main diagenetic process in argillaceous shale is the transformation of illite to smectite,negatively impacting shale porosity.Siliceous shale undergoes carbonate cementation and quartz dissolution,contributing to increased porosity,particularly in mesopores.Calcareous shale experiences diagenesis characterised by carbonate formation and dissolution,with a prevalence of siderite.In carbonate,clay,and silt-bearing shale,the dissolution of K-feldspar contributes to illitization of kaolinite.Argillaceous shale,characterised by more clay minerals and lower mesopore volume,is identified as a potential hydrocarbon seal.Siliceous shale,with the highest pore volume and abundant inter-mineral pores,emerges as a promising shale oil reservoir.These findings contribute to a comprehensive understanding of shale properties,aiding in the prediction of shale oil exploration potential in the studied area.
基金supported by funding the National Basic Research Program of China (973 Program) and the grant number is 2014CB239000
文摘1 Introduction Shale formations bear abundant mineral resource and*unconventional petroleum resource,and the unconventional petroleum resource that contain in the shale formation should be integrated and researched.
文摘Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral constitution affected by provenance. There are such apparent signatures as lithology, sedimentary structure, sedimentary sequence and well logs, to recognize turbidite. During the paleogeographic evolution of Chang-7 Member, lake basin and deep lake are both at their maximum extent during Chang-73 stage, resulting in the deposition of Zhangjiatan shale with widespread extent and of turbidite with fragmental-like. Deep lake line is gradually moving toward lake center and turbidite sand bodies are gradually turning better with better lateral continuity, connectivity and more thickness, from stages of Chang-73, Chang-72 and Chang-7t, which can be favorable reservoir in deep-water.
基金Supported by the China National Science and Technology Major Project(2016ZX05050)the National Key Basic Research and Development Program(973 Program),China(2014CB239003)
文摘A set of shale-dominated source rocks series were deposited during the heyday of lake basin development in the Member 7 of Triassic Yanchang Formation,Ordos Basin,and the thickness is about 110 m.Aimed at whether this layer can form large-scale oil enrichment of industrial value,comprehensive geological research and exploration practice have been carried out for years and obtained the following important geologic findings.Firstly,widely distributed black shale and dark mudstone with an average organic matter abundance of 13.81%and 3.74%,respectively,lay solid material foundation for the formation of shale oil.Secondly,sandy rocks sandwiched in thick organic-rich shale formations constitute an oil-rich"sweet spot",the average thickness of thin sandstone is 3.5 m.Thirdly,fine-grained sandstone and siltstone reservoirs have mainly small pores of 2–8μm and throats of 20–150 nm in radius,but with a large number of micro-pores and nano-throats,through fracturing,the reservoirs can provide good conductivity for the fluid in it.Fourthly,continued high-intensity hydrocarbon generation led to a pressure difference between the source rock and thin-layer reservoir of up to 8–16 MPa during geological history,driven by the high pressure,the oil charged into the reservoirs in large area,with oil saturation reaching more than 70%.Under the guidance of the above theory,in 2019,the Qingcheng Oilfield with geologic oil reserves of billion ton order was proved in the classⅠmulti-stage superimposed sandstone shale reservoir of Chang 7 Member by the Changqing Oilfield Branch through implementation of overall exploration and horizontal well volume fracturing.Two risk exploration horizontal wells were deployed for the classⅡthick layer mud shale interbedded with thin layers of silt-and fine-sandstones reservoir in the Chang 73 submember,and they were tested high yield oil flows of more than 100 tons per day,marking major breakthroughs in petroleum exploration in classⅠshale reservoirs.The new discoveries have expanded the domain of unconventional petroleum exploration.
文摘综合利用地球化学、扫描电镜、岩心薄片、测井等资料以及油井生产数据等,对鄂尔多斯盆地陕北地区三叠系延长组7段储层特征、烃源岩特征和致密油分布特征进行了分析,从烃源岩展布、输导体系和源-储组合关系3个方面对致密油差异富集控制因素进行了探讨,并总结了成藏模式。研究结果表明:(1)陕北地区长7段致密砂岩储层主要分布在一亚段(长71)和二亚段(长72),以灰色—灰白色长石砂岩和岩屑长石砂岩为主,长71和长72平均孔隙度分别为5.56%和7.32%,平均渗透率分别为0.097 m D和0.110 m D,长72储层物性更好;孔隙空间以溶孔为主,发育少量粒间孔。(2)研究区烃类主要来源于本地长72顶部和长73这2套烃源岩,平均厚度大于20 m,有机质丰度高,平均TOC值为3.02%,干酪根类型以Ⅰ型和Ⅱ1型为主,处于生烃高峰期,平均生烃量为270.2×10^(4)t/km^(2),长73烃源岩生烃潜力更大,供烃至长72储层,长71致密油来源于长72烃源岩;新安边地区三角洲前缘亚相末端的长72储层中致密油由湖盆烃源岩侧向供烃。(3)研究区致密油富集受烃源岩展布、砂体连通性以及源-储组合共同控制,在长72更富集,在新安边地区分布面积最大,安塞地区无大规模致密油聚集;纵向上和平面上致密油的聚集差异受控于烃源岩厚度和源-储组合关系,下生上储、上下生油而中间储集和砂泥互层时含油性更好;新安边地区三角洲前缘亚相末端的长72致密油聚集规模大于三角洲前缘主体,是由于三角洲前缘末端发育的局部连通砂体阻碍了湖盆烃类物质的侧向运移。(4)研究区致密油为“源控-砂控”成藏模式,远源河道优势砂体尖灭处和近源局部连通的砂体是有利勘探区。
基金Supported by the PetroChina Science and Technology Major Project(2016E-0101).
文摘The kinetic parameters of hydrocarbon generation are determined through experimental simulation and mathematical calculation using four typical samples selected from the Cretaceous Nenjiang Formation in the northwest of Songliao Basin,Chang 7 Member of Triassic Yanchang Formation in the southwest of Ordos Basin,Paleogene in the southwest of Qaidam Basin,and Lucaogou Formation of Jimusar Sag in the east of Junggar Basin.The results show that activation energy of hydrocarbon generation of organic matter is closely related to maturity and mainly ranges between 197 kJ/mol and 227 kJ/mol.On this basis,the temperature required for organic matter in shale to convert into oil was calculated.The ideal heating temperature is between 270℃and 300℃,and the conversation rate can reach 90%after 50-300 days of heating at constant temperature.When the temperature rises at a constant rate,the temperature corresponding to the major hydrocarbon generation period ranges from 225 to 350℃at the temperature rise rate of 1-150℃/month.In order to obtain higher economic benefits,it is suggested to adopt higher temperature rise rate(60-150℃/month).The more reliable kinetic parameters obtained can provide a basis for designing more reasonable scheme of in-situ heating conversion.
