Nansi Lake and Hongze Lake are both water storage lakes along the East Route of the South-to-North Water Transfer project(ESNT).Frequent changes in hydrologic properties are responsible factors for controlling the zoo...Nansi Lake and Hongze Lake are both water storage lakes along the East Route of the South-to-North Water Transfer project(ESNT).Frequent changes in hydrologic properties are responsible factors for controlling the zooplankton community assemblages in both lakes,so we studied the possible influence of water transfer and environmental factors on zooplankton community structure and abundance.Zooplankton assemblages were investigated seasonally for one year in both lakes;a total of 133 and 122 zooplankton taxa were identified in Nansi Lake and Hongze Lake,respectively.The most dominant rotifer species were littoral,e.g.,Keratella tecta,Keratella valga and Lecane lunaris in Nansi Lake and Brachionus angularis,Brachionus forficula and Polyarthra vulgaris in Hongze Lake.Comparatively,Nansi Lake had a higher Shannon-Wiener diversity index value(5.13),while Hongze Lake had a higher species richness index(4.21).The average number of zooplankton across seasons in Nansi Lake(protozoa:774±63 ind./L,rotifers:4817±212 ind./L,cladocerans:896±14 ind./L,copepod:435±42 ind./L)was comparatively lower than Hongze Lake(protozoa:1238±63 ind./L,rotifers:6576±112 ind./L,cladocerans:1013±20 ind./L,copepod:534±25 ind./L).Canonical correspondence analysis identified differing environmental gradients that were most responsible for influencing zooplankton communities in the two lakes(Hongze Lake:NH4-N,total nitrogen,transparency and pH;Nansi:pH,temperature and total phosphorus).Frequent changes related to water transfer in lakes favoured the diversity of rotifers and protozoa communities.Zooplankton habitat preference,changes in community structure and opportunistic peaks and extinction of certain taxa were also observed in the study lakes.展开更多
Objective To recognize and assess the impact of the South-to-north Water Transfer Project (SNWTP) on the ecological environment of Xiangfan, Hubei Province, situated in the water-out area, and develop sound scientific...Objective To recognize and assess the impact of the South-to-north Water Transfer Project (SNWTP) on the ecological environment of Xiangfan, Hubei Province, situated in the water-out area, and develop sound scientific countermeasures. Methods A three-layer BP network was built to simulate topology and process of the eco-economy system of Xiangfan. Historical data of ecological environmental factors and socio-economic factors as inputs, and corresponding historical data of ecosystem service value (ESV) and GDP as target outputs, were presented to train and test the network. When predicted input data after 2001 were presented to trained network as generalization sets, ESVs and GDPs of 2002, 2003, 2004... till 2050 were simulated as output in succession. Results Up to 2050, the area would have suffered an accumulative total ESV loss of RMB 104.9 billion, which accounted for 37.36% of the present ESV. The coinstantaneous GDP would change asynchronously with ESV, it would go through an up-to-down process and finally lose RMB89.3 billion, which accounted for 18.71% of 2001. Conclusions The simulation indicates that ESV loss means damage to the capability of socio-economic sustainable development, and suggests that artificial neural networks (ANNs) provide a feasible and effective method and have an important potential in ESV modeling.展开更多
Taking 13 water-receiving areas on the East Route of the South-to-North Water Diversion Project(ERSNWDP)in Shandong Province as the study area,and comparing it with Jiangsu Province on the ERSNWDP and the Middle Route...Taking 13 water-receiving areas on the East Route of the South-to-North Water Diversion Project(ERSNWDP)in Shandong Province as the study area,and comparing it with Jiangsu Province on the ERSNWDP and the Middle Route of the South-to-North(MRSNWDP),the current water-saving potential of the water-receiving areas within the municipalities of Shandong was analyzed.Different water-saving scenarios were constructed and analyzed with key water-saving indexes in various industries.These indexes include the effective utilization coefficient of farmland irrigation water,total water consumption of industrial sectors with an added value of over 10000 RMB,average leakage rate of the urban public water supply pipe network and the penetration rate of water-saving appliances.Based on the scenarios,comprehensive water-saving potential of the 13 water-receiving area cities was calculated.The results show that the water-saving potential of the study area is at a relative high level.However,some cities still have a certain amount of water-saving potential for agriculture and industry to be elevated.Under the recommended water-saving scenario,the water-saving potential is 1.134 billion m3,accounting for 5.33%of the current total water consumption,of which 460 million m3 is in agriculture,600 million m3 in industry,is and 74.20 million m3 in urban domestic sector.Comprehensive water-saving measures for the study area were proposed from the aspects of agricultural,industrial and domestic water uses.Agricultural and industrial water saving are more significant.The major cities for agricultural water saving include Jining City,Heze City,Weifang City and Jinan City;the focus cities of industrial water saving mainly include Weihai City,Jining City and Qingdao City and etc.;the key water-saving areas for urban use mainly include Zaozhuang City,Jining City and Heze City.展开更多
Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)ar...Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and compactness.Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs.Thus,optimization of their design may accelerate the promotion of PEMWEs.This paper reviews the advances in materials and flow-field design for bipolar plates.First,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and potential.Then,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are presented.Furthermore,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored.Finally,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science.展开更多
Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipat...Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipathic Ru(bda)-based catalysts(bda=2,2'-bipyrdine-6,6'-dicarbonoxyl acid)and aliphatic chain decorated electrode surfaces,forming lipid bilayer membrane(LBM)-like structures.The Ru(bda)catalysts on electrode-supported LBM films demonstrated remarkable water oxidation performance with different O-O formation mechanisms.However,compared to the slow charge transfer process,the O-O formation pathways did not determine the PEC water oxidation efficiency of the dyesensitized photoanodes,and the different reaction rates for similar catalysts with different catalytic paths did not determine the PEC performance of the DSPECs.Instead,charge transfer plays a decisive role in the PEC water oxidation rate.When an indolo[3,2-b]carbazole derivative was introduced between the Ru(bda)catalysts and aliphatic chain-modified photosensitizer in LBM films,serving as a charge transfer mediator for the tyrosine-histidine pair in PSⅡ,the PEC water oxidation performance of the corresponding photoanodes was dramatically enhanced.展开更多
Interbasin water-transfer schemes provide an engineering solution for reconciling the conflict between water demand and availability.In the context of climate change,which brings great uncertainties to water resource ...Interbasin water-transfer schemes provide an engineering solution for reconciling the conflict between water demand and availability.In the context of climate change,which brings great uncertainties to water resource distribution,interbasin water transfer plays an increasingly important role in the global water–food–energy nexus.However,the transfer of water resources simultaneously changes the hydrological regime and the characteristics of local water bodies,affecting biotic communities accordingly.Compared with high economic and technical inputs water-transfer projects require,the environmental and ecological implications of water-transfer schemes have been inadequately addressed.This work selects the largest water-transfer project in China,the South-to-North Water Diversion(SNWD)Project,to critically review its eco-environmental impacts on donor and recipient basins,as well as on regions along the diversion route.The two operated routes of the SNWD Project represent two typical water diversion approaches:The Middle Route uses an excavated canal,while the East Route connects existent river channels.An overview of the eco-environmental implications of these two routes is valuable for the design and optimization of future water-transfer megaprojects.展开更多
The Middle Route Project(MRP)of the Southto-North Water Transfer Scheme(SNWT)in China will require a very large financial expenditure to ensure the water supply and the associated water quality to northern China.An ec...The Middle Route Project(MRP)of the Southto-North Water Transfer Scheme(SNWT)in China will require a very large financial expenditure to ensure the water supply and the associated water quality to northern China.An eco-compensation mechanism between the water service source areas and its beneficiaries is essential.This paper establishes an analytic framework of ecocompensation standard for the protection of the water source area,including both the calculation of ecocompensation based on opportunity cost method(OCM)and calculation of the burden sharing of eco-compensation between the water source area and the external water reception area based on the deviation square method(DSM).Taking Shiyan City,Hubei Province in China as a case study,our results show that the eco-compensation in the first-phase of MRP for the water source area in Shiyan,Hubei Province should be 1.63×10^(10) CNY,about four times of planned eco-construction investment budget(4.33×10^(9) CNY).In addition,the burden sharing of eco-compensation varied greatly in terms of different methods.It would be better to integrate the results of different single-factor burden sharing methods by determining the corresponding weighting coefficient with DSM and form one unanimous consent result by the interested parties.展开更多
Baoying pumping station is a part of source pumping stations in East Route Project of South-to-North Water Transfer in China. Aiming at the characteristics of head varying, and making use of the function of pump adjus...Baoying pumping station is a part of source pumping stations in East Route Project of South-to-North Water Transfer in China. Aiming at the characteristics of head varying, and making use of the function of pump adjustable blade, mathematical models of pumping station optimal operation are established and solved with genetic algorithm. For different total pumping discharge and total pumping volume of water per day, in order to minimize pumping station operation cost, the number and operation duties of running pump units are respectively determined at different periods of time in a day. The results indicate that the saving of electrical cost is significantly effected by the schemes of adjusting blade angles and time-varying electrical price when pumping certain water volume of water per day, and compared with conventional operation schemes (namely, the schemes of pumping station operation at design blade angles based on certain pumping discharge), the electrical cost is saved by 4.73%-31.27%. Also, compared with the electrical cost of conventional operation schemes, the electrical cost is saved by 2.03%-5.79% by the schemes of adjusting blade angles when pumping certain discharge.展开更多
The main canal of the Middle Route Project of South-to-North Water Transfer totals more than 1 240 km in length. In Henan Province and Hebei Province, there will be a section of more than 120 km passing through an exp...The main canal of the Middle Route Project of South-to-North Water Transfer totals more than 1 240 km in length. In Henan Province and Hebei Province, there will be a section of more than 120 km passing through an expansive soils area. Expansive soils is a special kind of tenacious clay, which swells when meeting with water and shrinks when losing water. With complicated mechanical properties, it changes with the variation of water content. As a result, expansive soils become the key object of study on unsaturated soils mechanics for the project. From the status of study on unsaturated soils at home and abroad, this paper covers an analysis on stability analysis method of expansive soils slope, determination of expansive soils strength, rational design of canal slope ratio and support, and forecast of landslide for the Middle Route Project of South-to-North Water Transfer.展开更多
In terms of special geological conditions of the Western Route of South-to-North Water Transfer Project, the classification method for surrounding rocks is discussed by combining with the construction method of tunnel...In terms of special geological conditions of the Western Route of South-to-North Water Transfer Project, the classification method for surrounding rocks is discussed by combining with the construction method of tunnel boring machine (TBM). The classification standard of surrounding rocks is put forward on the basis of physical simulations and engineering practices. Damage, deformation and evolution of surrounding rocks induced by TBM excavation are discussed. Meanwhile, the long-term deformation mechanisms and stability of surrounding rocks are also studied. On this basis, a three-dimensional constitutive model for interbedded sandstone slate and a fiat shell-joint element-foundation system for calculating internal forces of segment lining are established. The deformation features of surrounding rocks of deep and steep interbedded sandstone slate and their influences on internal forces of segment lining are presented. Finally, the design methods of segment lining constructed in deep and steep flysch are proposed.展开更多
This study assess the effectiveness of groundwater pressure extraction in Beijing since the opening of the first phase of the South-to-North Water Diversion Project,using survey and evaluation methods.Firstly,an analy...This study assess the effectiveness of groundwater pressure extraction in Beijing since the opening of the first phase of the South-to-North Water Diversion Project,using survey and evaluation methods.Firstly,an analysis of water consumption structure and the usage of diverted river water in Beijing in recent years was conducted.Secondly,the volume of groundwater pressure extraction in Beijing after the 33 project's inauguration was examined,revealing a decrease from 1.96 billion m^(3) in 2014 to 1.35 billion m^(3) in 2020.The proportion of water supply reduced from 52.3%in 2014 to 33.3%in 2020,leading to an optimized water supply structure.By the end of 2020,groundwater pressure extraction in Beijing is estimated at 446 million m3,with a substantial reduction in over-exploitation of groundwater.Groundwater resources have been effectively replenished,and the strategic reserve capacity has been enhanced.Furthermore,this study evaluates the change in groundwater levels as an indicator of the effectiveness of pressure extraction.The declining trend of groundwater levels in Beijing has been effectively mitigated,and there has been a consistent rebound in groundwater levels over the past five years.展开更多
High spatiotemporal resolution radiances from the advanced imagers onboard the new generation of geostationary weather satellites provide a unique opportunity to evaluate the abilities of various reanalysis datasets t...High spatiotemporal resolution radiances from the advanced imagers onboard the new generation of geostationary weather satellites provide a unique opportunity to evaluate the abilities of various reanalysis datasets to depict multilayer tropospheric water vapor(WV),thereby enhancing our understanding of the deficiencies of WV in reanalysis datasets.Based on daily measurements from the Advanced Himawari Imager(AHI)onboard the Himawari-8 satellite in 2016,the bias features of multilayer WV from six reanalysis datasets over East Asia are thoroughly evaluated.The assessments show that wet biases exist in the upper troposphere in all six reanalysis datasets;in particular,these biases are much larger in summer.Overall,we find better depictions of WV in the middle troposphere than in the upper troposphere.The accuracy of WV in the ERA5 dataset is the highest,in terms of the bias magnitude,dispersion,and pattern similarity.The characteristics of the WV bias over the Tibetan Plateau are significantly different from those over other parts of East Asia.In addition,the reanalysis datasets all capture the shift of the subtropical high very well,with ERA5 performing better overall.展开更多
The factors influencing the water supply price of a hydraulic project include natural conditions and economic policies. This paper thoroughly demonstrates the water price of South-to-North Water Transfer Project from ...The factors influencing the water supply price of a hydraulic project include natural conditions and economic policies. This paper thoroughly demonstrates the water price of South-to-North Water Transfer Project from the viewpoint of economic policies. It is considered that if the project is assigned as a profitable one and built depending on commercial loan from bank completely or mostly, the water price will be too high to be undertaken by users,and if the project places the public good at first while considering the economic benefit, its investment mainly relies on the state (national or local governments) appropriation and self-raised funds and a little from the bank loan on favorable terms, the price determined according to the principle of satisfying the cost and reasonable profit will be relatively lower and can be undertaken by the users in the North China where water shortage is serious. The problem of higher water price of agricultural irrigation to the north of the Yellow River can be tackled by taking measures such as "compensating agriculture by industry" according to foreign practical experiences and relevant suggestions.展开更多
Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to t...Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.展开更多
This paper proposes a method on analyzing the asynchronism-synchronism of precipitation of different hydrological regions regarding the S-to-N water transfer areas of eastern China. The general process of the analysis...This paper proposes a method on analyzing the asynchronism-synchronism of precipitation of different hydrological regions regarding the S-to-N water transfer areas of eastern China. The general process of the analysis includes three steps. Firstly, we created the rainfall series of the region concerned by calculating the regional average rainfall of the stations in the area with the help of the classical Thiessen Polygon method. Secondly, the standards of assessment indices for wetness or dryness are set according to Gamma distribution function with a certain probability P 37.5% or 62.5% given respectively. Finally, the frequency of nine combinations are counted as the quantitative feature of asynchronism and synchronism in three time scales, that is the yearly, seasonal and monthly scales. The asynchronism-synchronism of two region pairs has been estimated. The results show that the frequency of precipitation asynchronism in 1957–1998 is larger than the synchronism frequency for both the North China-middle and lower Yangtze River pair and for the North China-upper Hanjiang River pair. As for the synchronism phenomena, the frequency of Nd?Sd is rather low. As the combinations that are suitable for water transfers are Nd?Sw, Nn?Sw, Nd?Sn and Nn?Sn, the total frequency of these combinations for North China-middle and lower Yangtze River is 40% on an annual basis, but only 28% in spring when water shortages are most likely to occur. The total frequency of these combinations for North China-upper Hanjiang River is about 24% on an annual basis, but 35% in spring and winter. It should be noted that if future precipitation patterns are similar to that of the period 1957–1998, it is very important to change the natural character of asynchronism-synchronism by enhancing the capability of hydro-projects regulation and improving management of the water transfer project.展开更多
The over-exploitation of water resources in the Haihe River Basin (HRB) has now become a serious problem. This is clearly evidenced by the fact that many local rivers and lakes are drying up and the total amount of ov...The over-exploitation of water resources in the Haihe River Basin (HRB) has now become a serious problem. This is clearly evidenced by the fact that many local rivers and lakes are drying up and the total amount of over-exploited groundwater has reached over 1000×108m3. It is important to note that the exploitation of water resources in HRB was reasonable before 1979. After 1980, however, over-exploitation happened with an annual average amount of 40×108m3. Both the dry season and rapid economic growth in HRB took place at the same time. Therefore, the over-exploitation of water in HRB was actually the negative result of the conjunction of a continuous dry season and rapid economic growth. So the over-exploitation would not be as serious as it is today if either of the above two stopped. After the first stage of south-to-north water transfer project, the water shortage problem in HRB could be eased for the following reasons: fi rstly, water transfer project will bring to the Basin 60×108m3 water resources; secondly, a wet season will come back eventually according to natural law of climate variability; finally, its agricultural and industrial use and total water consumption all have decreased from the peak value, so that the groundwater table will raise certainly and ecological water in rivers and lakes that were dried-up will be partly restored. In the future, the main problem of water resources security in HRB will include water pollution, operation risk of the south-to-north water transfer project, groundwater pollution and engineering geological hazards that may be brought by groundwater rise. The proposed countermeasures are as follows: keeping strengthening water demand management, raising water price as well as subsidies for the low-income family and improving other water related policies, preventing and dealing with water pollution seriously and getting fully prepared for the operation of south-to-north water transfer project.展开更多
Hydrophobic membrane can provide fast mass transfer for absorption-desorption of gasesform liquid to absorbent.The removal of ammonia from ammonia water and absorption with dilutesulphuric acid was studied in a pilot ...Hydrophobic membrane can provide fast mass transfer for absorption-desorption of gasesform liquid to absorbent.The removal of ammonia from ammonia water and absorption with dilutesulphuric acid was studied in a pilot plant with polypropylene hollow fiber column,The removalrate and influences of operation temperature,flow rate and concentration on mass transferperformances were discussed mathematically.Experimental results and computer calculation show thatthe ammonia removal rate is not affected by the feed concentration for a given system.Both partialand overall mass transfer coefficients vary along the axis of the fiber,and the mass transfer for themembrane process is controlled by membrane resistance.展开更多
A water model with a geometric similarity ratio of 1:5 was developed to investigate the gas-liquid mass transfer and flow charac- teristics in a Peirce-Smith converter. A gas mixture of CO2 and Ar was injected into a...A water model with a geometric similarity ratio of 1:5 was developed to investigate the gas-liquid mass transfer and flow charac- teristics in a Peirce-Smith converter. A gas mixture of CO2 and Ar was injected into a NaOH solution bath. The flow field, volumetric mass transfer coefficient per unit volume (Ak/V; where A is the contact area between phases, V is the volume, and k is the mass transfer coeffi- cient), and gas utilization ratio (t/) were then measured at different gas flow rates and blow angles. The results showed that the flow field could be divided into five regions, i.e., injection, strong loop, weak loop, splashing, and dead zone. Whereas the Ak/V of the bath increased and then decreased with increasing gas flow rate, and n steadily increased. When the converter was rotated clockwise, both Ak/F and t/increased. However, the flow condition deteriorated when the gas flow rate and blow angle were drastically increased. Therefore, these para- meters must be controlled to optimal conditions. In the proposed model, the optimal gas flow rate and blow angle were 7.5 m3.h-1 and 10°, respectively.展开更多
基金Supported by the Service Project of Special Institute of Chinese Academy of Sciences(No.Y55Z06)the Key Project in Frontier Science of Chinese Academy of Sciences(No.QYZDB-SSW-SMC041)+1 种基金the National Science Foundation of Jiangsu Province,China(No.BK20141268)the National Natural Science Foundation of China(No.31400486a)。
文摘Nansi Lake and Hongze Lake are both water storage lakes along the East Route of the South-to-North Water Transfer project(ESNT).Frequent changes in hydrologic properties are responsible factors for controlling the zooplankton community assemblages in both lakes,so we studied the possible influence of water transfer and environmental factors on zooplankton community structure and abundance.Zooplankton assemblages were investigated seasonally for one year in both lakes;a total of 133 and 122 zooplankton taxa were identified in Nansi Lake and Hongze Lake,respectively.The most dominant rotifer species were littoral,e.g.,Keratella tecta,Keratella valga and Lecane lunaris in Nansi Lake and Brachionus angularis,Brachionus forficula and Polyarthra vulgaris in Hongze Lake.Comparatively,Nansi Lake had a higher Shannon-Wiener diversity index value(5.13),while Hongze Lake had a higher species richness index(4.21).The average number of zooplankton across seasons in Nansi Lake(protozoa:774±63 ind./L,rotifers:4817±212 ind./L,cladocerans:896±14 ind./L,copepod:435±42 ind./L)was comparatively lower than Hongze Lake(protozoa:1238±63 ind./L,rotifers:6576±112 ind./L,cladocerans:1013±20 ind./L,copepod:534±25 ind./L).Canonical correspondence analysis identified differing environmental gradients that were most responsible for influencing zooplankton communities in the two lakes(Hongze Lake:NH4-N,total nitrogen,transparency and pH;Nansi:pH,temperature and total phosphorus).Frequent changes related to water transfer in lakes favoured the diversity of rotifers and protozoa communities.Zooplankton habitat preference,changes in community structure and opportunistic peaks and extinction of certain taxa were also observed in the study lakes.
文摘Objective To recognize and assess the impact of the South-to-north Water Transfer Project (SNWTP) on the ecological environment of Xiangfan, Hubei Province, situated in the water-out area, and develop sound scientific countermeasures. Methods A three-layer BP network was built to simulate topology and process of the eco-economy system of Xiangfan. Historical data of ecological environmental factors and socio-economic factors as inputs, and corresponding historical data of ecosystem service value (ESV) and GDP as target outputs, were presented to train and test the network. When predicted input data after 2001 were presented to trained network as generalization sets, ESVs and GDPs of 2002, 2003, 2004... till 2050 were simulated as output in succession. Results Up to 2050, the area would have suffered an accumulative total ESV loss of RMB 104.9 billion, which accounted for 37.36% of the present ESV. The coinstantaneous GDP would change asynchronously with ESV, it would go through an up-to-down process and finally lose RMB89.3 billion, which accounted for 18.71% of 2001. Conclusions The simulation indicates that ESV loss means damage to the capability of socio-economic sustainable development, and suggests that artificial neural networks (ANNs) provide a feasible and effective method and have an important potential in ESV modeling.
基金We would like to give our thanks to Water Resources Department of Shandong Province and Water Resources Research Institute of Shandong Province for their help.
文摘Taking 13 water-receiving areas on the East Route of the South-to-North Water Diversion Project(ERSNWDP)in Shandong Province as the study area,and comparing it with Jiangsu Province on the ERSNWDP and the Middle Route of the South-to-North(MRSNWDP),the current water-saving potential of the water-receiving areas within the municipalities of Shandong was analyzed.Different water-saving scenarios were constructed and analyzed with key water-saving indexes in various industries.These indexes include the effective utilization coefficient of farmland irrigation water,total water consumption of industrial sectors with an added value of over 10000 RMB,average leakage rate of the urban public water supply pipe network and the penetration rate of water-saving appliances.Based on the scenarios,comprehensive water-saving potential of the 13 water-receiving area cities was calculated.The results show that the water-saving potential of the study area is at a relative high level.However,some cities still have a certain amount of water-saving potential for agriculture and industry to be elevated.Under the recommended water-saving scenario,the water-saving potential is 1.134 billion m3,accounting for 5.33%of the current total water consumption,of which 460 million m3 is in agriculture,600 million m3 in industry,is and 74.20 million m3 in urban domestic sector.Comprehensive water-saving measures for the study area were proposed from the aspects of agricultural,industrial and domestic water uses.Agricultural and industrial water saving are more significant.The major cities for agricultural water saving include Jining City,Heze City,Weifang City and Jinan City;the focus cities of industrial water saving mainly include Weihai City,Jining City and Qingdao City and etc.;the key water-saving areas for urban use mainly include Zaozhuang City,Jining City and Heze City.
基金the National Natural Science Foundation of China(No.52125102)the National Key Research and Development Program of China(No.2021YFB4000101)Fundamental Research Funds for t he Central Universities(No.FRF-TP-2021-02C2)。
文摘Attaining a decarbonized and sustainable energy system,which is the core solution to global energy issues,is accessible through the development of hydrogen energy.Proton-exchange membrane water electrolyzers(PEMWEs)are promising devices for hydrogen production,given their high efficiency,rapid responsiveness,and compactness.Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs.Thus,optimization of their design may accelerate the promotion of PEMWEs.This paper reviews the advances in materials and flow-field design for bipolar plates.First,the working conditions of proton-exchange membrane fuel cells(PEMFCs)and PEMWEs are compared,including reaction direction,operating temperature,pressure,input/output,and potential.Then,the current research status of bipolar-plate substrates and surface coatings is summarized,and some typical channel-rib flow fields and porous flow fields are presented.Furthermore,the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored.Finally,this review discusses the potential directions of the development of bipolar-plate design,including material fabrication,flow-field geometry optimization using threedimensional printing,and surface-coating composition optimization based on computational materials science.
基金conducted by the Fundamental Research Center of Artificial Photosynthesis(FReCAP)financially supported by the National Natural Science Foundation of China(22172011 and 22088102)+1 种基金the National Key R&D Program of China(2022YFA0911904)the Fundamental Research Funds for the Central Universities(DUT22LK06,DUT22QN213 and DUT23LAB611)。
文摘Inspired by the function of crucial components in photosystemⅡ(PSⅡ),electrochemical and dyesensitized photoelectrochemical(DSPEC)water oxidation devices were constructed by the selfassembly of well-designed amphipathic Ru(bda)-based catalysts(bda=2,2'-bipyrdine-6,6'-dicarbonoxyl acid)and aliphatic chain decorated electrode surfaces,forming lipid bilayer membrane(LBM)-like structures.The Ru(bda)catalysts on electrode-supported LBM films demonstrated remarkable water oxidation performance with different O-O formation mechanisms.However,compared to the slow charge transfer process,the O-O formation pathways did not determine the PEC water oxidation efficiency of the dyesensitized photoanodes,and the different reaction rates for similar catalysts with different catalytic paths did not determine the PEC performance of the DSPECs.Instead,charge transfer plays a decisive role in the PEC water oxidation rate.When an indolo[3,2-b]carbazole derivative was introduced between the Ru(bda)catalysts and aliphatic chain-modified photosensitizer in LBM films,serving as a charge transfer mediator for the tyrosine-histidine pair in PSⅡ,the PEC water oxidation performance of the corresponding photoanodes was dramatically enhanced.
基金supported by National Key Science and Technology Program of China(2022YFC3203802)National Natural Science Foundation of China(52121006,92047303,and 51879165)+1 种基金supported by the Xplorer Prizesupported by the Young Elite Scientists Sponsorship Program by China Association for Science and Technology(2021QNRC001)。
文摘Interbasin water-transfer schemes provide an engineering solution for reconciling the conflict between water demand and availability.In the context of climate change,which brings great uncertainties to water resource distribution,interbasin water transfer plays an increasingly important role in the global water–food–energy nexus.However,the transfer of water resources simultaneously changes the hydrological regime and the characteristics of local water bodies,affecting biotic communities accordingly.Compared with high economic and technical inputs water-transfer projects require,the environmental and ecological implications of water-transfer schemes have been inadequately addressed.This work selects the largest water-transfer project in China,the South-to-North Water Diversion(SNWD)Project,to critically review its eco-environmental impacts on donor and recipient basins,as well as on regions along the diversion route.The two operated routes of the SNWD Project represent two typical water diversion approaches:The Middle Route uses an excavated canal,while the East Route connects existent river channels.An overview of the eco-environmental implications of these two routes is valuable for the design and optimization of future water-transfer megaprojects.
基金This research was supported by the National Water Pollution Control Technology Major Projects(No.2008ZX07033-03).
文摘The Middle Route Project(MRP)of the Southto-North Water Transfer Scheme(SNWT)in China will require a very large financial expenditure to ensure the water supply and the associated water quality to northern China.An eco-compensation mechanism between the water service source areas and its beneficiaries is essential.This paper establishes an analytic framework of ecocompensation standard for the protection of the water source area,including both the calculation of ecocompensation based on opportunity cost method(OCM)and calculation of the burden sharing of eco-compensation between the water source area and the external water reception area based on the deviation square method(DSM).Taking Shiyan City,Hubei Province in China as a case study,our results show that the eco-compensation in the first-phase of MRP for the water source area in Shiyan,Hubei Province should be 1.63×10^(10) CNY,about four times of planned eco-construction investment budget(4.33×10^(9) CNY).In addition,the burden sharing of eco-compensation varied greatly in terms of different methods.It would be better to integrate the results of different single-factor burden sharing methods by determining the corresponding weighting coefficient with DSM and form one unanimous consent result by the interested parties.
基金supported by Author Special Foundation of National Excellent Doctoral Dissertation of China (Grant No. 2007B41)Jiangsu Provincial Foundation of "333 Talents Engineering" of ChinaJiangsu Provincial Academic Header Foundation of Qinglan Engineering of China
文摘Baoying pumping station is a part of source pumping stations in East Route Project of South-to-North Water Transfer in China. Aiming at the characteristics of head varying, and making use of the function of pump adjustable blade, mathematical models of pumping station optimal operation are established and solved with genetic algorithm. For different total pumping discharge and total pumping volume of water per day, in order to minimize pumping station operation cost, the number and operation duties of running pump units are respectively determined at different periods of time in a day. The results indicate that the saving of electrical cost is significantly effected by the schemes of adjusting blade angles and time-varying electrical price when pumping certain water volume of water per day, and compared with conventional operation schemes (namely, the schemes of pumping station operation at design blade angles based on certain pumping discharge), the electrical cost is saved by 4.73%-31.27%. Also, compared with the electrical cost of conventional operation schemes, the electrical cost is saved by 2.03%-5.79% by the schemes of adjusting blade angles when pumping certain discharge.
文摘The main canal of the Middle Route Project of South-to-North Water Transfer totals more than 1 240 km in length. In Henan Province and Hebei Province, there will be a section of more than 120 km passing through an expansive soils area. Expansive soils is a special kind of tenacious clay, which swells when meeting with water and shrinks when losing water. With complicated mechanical properties, it changes with the variation of water content. As a result, expansive soils become the key object of study on unsaturated soils mechanics for the project. From the status of study on unsaturated soils at home and abroad, this paper covers an analysis on stability analysis method of expansive soils slope, determination of expansive soils strength, rational design of canal slope ratio and support, and forecast of landslide for the Middle Route Project of South-to-North Water Transfer.
基金Supported by the National Key Technology R&D Program in the 11th Five-year Plan of China (2006BAB04A06)
文摘In terms of special geological conditions of the Western Route of South-to-North Water Transfer Project, the classification method for surrounding rocks is discussed by combining with the construction method of tunnel boring machine (TBM). The classification standard of surrounding rocks is put forward on the basis of physical simulations and engineering practices. Damage, deformation and evolution of surrounding rocks induced by TBM excavation are discussed. Meanwhile, the long-term deformation mechanisms and stability of surrounding rocks are also studied. On this basis, a three-dimensional constitutive model for interbedded sandstone slate and a fiat shell-joint element-foundation system for calculating internal forces of segment lining are established. The deformation features of surrounding rocks of deep and steep interbedded sandstone slate and their influences on internal forces of segment lining are presented. Finally, the design methods of segment lining constructed in deep and steep flysch are proposed.
基金funded by the projects"Impacts of water transfer from the western route of the Southto-North Water Diversion Project on the ecological environment of the Yangtze and Yellow Rivers and coping strategies"(No.2022YFC3202400)"Ecological Compensation Mechanism and Biological Invasion Risk Analysis of Water Transfer from the Western Route Project"(No.2022YFC 3202404).
文摘This study assess the effectiveness of groundwater pressure extraction in Beijing since the opening of the first phase of the South-to-North Water Diversion Project,using survey and evaluation methods.Firstly,an analysis of water consumption structure and the usage of diverted river water in Beijing in recent years was conducted.Secondly,the volume of groundwater pressure extraction in Beijing after the 33 project's inauguration was examined,revealing a decrease from 1.96 billion m^(3) in 2014 to 1.35 billion m^(3) in 2020.The proportion of water supply reduced from 52.3%in 2014 to 33.3%in 2020,leading to an optimized water supply structure.By the end of 2020,groundwater pressure extraction in Beijing is estimated at 446 million m3,with a substantial reduction in over-exploitation of groundwater.Groundwater resources have been effectively replenished,and the strategic reserve capacity has been enhanced.Furthermore,this study evaluates the change in groundwater levels as an indicator of the effectiveness of pressure extraction.The declining trend of groundwater levels in Beijing has been effectively mitigated,and there has been a consistent rebound in groundwater levels over the past five years.
基金partly supported by the National Natural Science Foundation of China(Grant Nos.41975020 and 41975031)(Jun LI)。
文摘High spatiotemporal resolution radiances from the advanced imagers onboard the new generation of geostationary weather satellites provide a unique opportunity to evaluate the abilities of various reanalysis datasets to depict multilayer tropospheric water vapor(WV),thereby enhancing our understanding of the deficiencies of WV in reanalysis datasets.Based on daily measurements from the Advanced Himawari Imager(AHI)onboard the Himawari-8 satellite in 2016,the bias features of multilayer WV from six reanalysis datasets over East Asia are thoroughly evaluated.The assessments show that wet biases exist in the upper troposphere in all six reanalysis datasets;in particular,these biases are much larger in summer.Overall,we find better depictions of WV in the middle troposphere than in the upper troposphere.The accuracy of WV in the ERA5 dataset is the highest,in terms of the bias magnitude,dispersion,and pattern similarity.The characteristics of the WV bias over the Tibetan Plateau are significantly different from those over other parts of East Asia.In addition,the reanalysis datasets all capture the shift of the subtropical high very well,with ERA5 performing better overall.
文摘The factors influencing the water supply price of a hydraulic project include natural conditions and economic policies. This paper thoroughly demonstrates the water price of South-to-North Water Transfer Project from the viewpoint of economic policies. It is considered that if the project is assigned as a profitable one and built depending on commercial loan from bank completely or mostly, the water price will be too high to be undertaken by users,and if the project places the public good at first while considering the economic benefit, its investment mainly relies on the state (national or local governments) appropriation and self-raised funds and a little from the bank loan on favorable terms, the price determined according to the principle of satisfying the cost and reasonable profit will be relatively lower and can be undertaken by the users in the North China where water shortage is serious. The problem of higher water price of agricultural irrigation to the north of the Yellow River can be tackled by taking measures such as "compensating agriculture by industry" according to foreign practical experiences and relevant suggestions.
基金financially supported by the Industrial Technology Innovation Program of IMAST(No.2023JSYD 01003)the National Natural Science Foundation of China(Nos.52104292 and U2341209)。
文摘Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.
基金Key Project of Chinese Academy of Sciences, No. KZ951-A1-203-01
文摘This paper proposes a method on analyzing the asynchronism-synchronism of precipitation of different hydrological regions regarding the S-to-N water transfer areas of eastern China. The general process of the analysis includes three steps. Firstly, we created the rainfall series of the region concerned by calculating the regional average rainfall of the stations in the area with the help of the classical Thiessen Polygon method. Secondly, the standards of assessment indices for wetness or dryness are set according to Gamma distribution function with a certain probability P 37.5% or 62.5% given respectively. Finally, the frequency of nine combinations are counted as the quantitative feature of asynchronism and synchronism in three time scales, that is the yearly, seasonal and monthly scales. The asynchronism-synchronism of two region pairs has been estimated. The results show that the frequency of precipitation asynchronism in 1957–1998 is larger than the synchronism frequency for both the North China-middle and lower Yangtze River pair and for the North China-upper Hanjiang River pair. As for the synchronism phenomena, the frequency of Nd?Sd is rather low. As the combinations that are suitable for water transfers are Nd?Sw, Nn?Sw, Nd?Sn and Nn?Sn, the total frequency of these combinations for North China-middle and lower Yangtze River is 40% on an annual basis, but only 28% in spring when water shortages are most likely to occur. The total frequency of these combinations for North China-upper Hanjiang River is about 24% on an annual basis, but 35% in spring and winter. It should be noted that if future precipitation patterns are similar to that of the period 1957–1998, it is very important to change the natural character of asynchronism-synchronism by enhancing the capability of hydro-projects regulation and improving management of the water transfer project.
基金supported by the National Natural Sciences Fund of China (40971298)
文摘The over-exploitation of water resources in the Haihe River Basin (HRB) has now become a serious problem. This is clearly evidenced by the fact that many local rivers and lakes are drying up and the total amount of over-exploited groundwater has reached over 1000×108m3. It is important to note that the exploitation of water resources in HRB was reasonable before 1979. After 1980, however, over-exploitation happened with an annual average amount of 40×108m3. Both the dry season and rapid economic growth in HRB took place at the same time. Therefore, the over-exploitation of water in HRB was actually the negative result of the conjunction of a continuous dry season and rapid economic growth. So the over-exploitation would not be as serious as it is today if either of the above two stopped. After the first stage of south-to-north water transfer project, the water shortage problem in HRB could be eased for the following reasons: fi rstly, water transfer project will bring to the Basin 60×108m3 water resources; secondly, a wet season will come back eventually according to natural law of climate variability; finally, its agricultural and industrial use and total water consumption all have decreased from the peak value, so that the groundwater table will raise certainly and ecological water in rivers and lakes that were dried-up will be partly restored. In the future, the main problem of water resources security in HRB will include water pollution, operation risk of the south-to-north water transfer project, groundwater pollution and engineering geological hazards that may be brought by groundwater rise. The proposed countermeasures are as follows: keeping strengthening water demand management, raising water price as well as subsidies for the low-income family and improving other water related policies, preventing and dealing with water pollution seriously and getting fully prepared for the operation of south-to-north water transfer project.
文摘Hydrophobic membrane can provide fast mass transfer for absorption-desorption of gasesform liquid to absorbent.The removal of ammonia from ammonia water and absorption with dilutesulphuric acid was studied in a pilot plant with polypropylene hollow fiber column,The removalrate and influences of operation temperature,flow rate and concentration on mass transferperformances were discussed mathematically.Experimental results and computer calculation show thatthe ammonia removal rate is not affected by the feed concentration for a given system.Both partialand overall mass transfer coefficients vary along the axis of the fiber,and the mass transfer for themembrane process is controlled by membrane resistance.
基金financially supported by the National Natural Science Foundation of China(No.51504018)the China Postdoctoral Science Foundation(2015M580986)the Fundamental Research Funds for the Central Universities(FRF-TP-17-038A2)
文摘A water model with a geometric similarity ratio of 1:5 was developed to investigate the gas-liquid mass transfer and flow charac- teristics in a Peirce-Smith converter. A gas mixture of CO2 and Ar was injected into a NaOH solution bath. The flow field, volumetric mass transfer coefficient per unit volume (Ak/V; where A is the contact area between phases, V is the volume, and k is the mass transfer coeffi- cient), and gas utilization ratio (t/) were then measured at different gas flow rates and blow angles. The results showed that the flow field could be divided into five regions, i.e., injection, strong loop, weak loop, splashing, and dead zone. Whereas the Ak/V of the bath increased and then decreased with increasing gas flow rate, and n steadily increased. When the converter was rotated clockwise, both Ak/F and t/increased. However, the flow condition deteriorated when the gas flow rate and blow angle were drastically increased. Therefore, these para- meters must be controlled to optimal conditions. In the proposed model, the optimal gas flow rate and blow angle were 7.5 m3.h-1 and 10°, respectively.