Geochemical identification of a source rock affected by migrated hydrocarbons and its geological significance:Fengcheng Formation,southern Mahu Sag,Junggar Basin,NW China

The Fengcheng Formation is a crucial source rock and the primary reservoir for oil accumulation in the Mahu Sag.Crude oils are distributed throughout the Fengcheng Formation,ranging from the edge to the interior of the sag in the southern Mahu Sag.These crude oils originate from in-situ source rocks in shallowly buried areas and the inner deep sag.During migration,the crude oil from the inner deep sag affects the source rocks close to carrier beds,leading to changes in the organic geochemical characteristics of the source rocks.These changes might alter source rock evaluations and oil-source correlation.Based on data such as total organic carbon(TOC),Rock-Eval pyrolysis of source rocks,and gas chromatography-mass spectrometry(GC-MS)of the saturated fraction,and considering the geological characteristics of the study area,we define the identification characteristics of source rock affected by migrated hydrocarbons and establish the various patterns of influence that migrated hydrocarbons have on the source rock of the Fengcheng Formation in the southern Mahu Sag.The source rocks of the Fengcheng Formation are mostly fair to good,containing mainly Type II organic matter and being thermally mature enough to generate oil.Source rocks affected by migrated hydrocarbons exhibit relatively high hydrocarbon contents(S1/TOC>110 mg HC/g TOC,Extract/TOC>30%,HC:hydrocarbon),relatively low Rock-Eval Tmax values,and relatively high tricyclic terpane contents with a descending and mountain-shaped distribution.Furthermore,biomarker composition parameters indicate a higher thermal maturity than in-situ source rocks.Through a comparison of the extract biomarker fingerprints of adjacent reservoirs and mudstones in different boreholes,three types of influence patterns of migrated hydrocarbons are identified:the edge-influence of thin sandstone-thick mudstone,the mixed-influence of sandstone-mudstone interbedded,and the full-influence of thick sandstone-thin mudstone.This finding reminds us that the influence of migrated hydrocarbons must be considered when evaluating source rocks and conducting oil-source correlation.

Differences in spring precipitation over southern China associated with multiyear La Ni?a events

Composite analyses were performed in this study to reveal the difference in spring precipitation over southern China during multiyear La Ni?a events during 1901 to 2015. It was found that there is significantly below-normal precipitation during the first boreal spring, but above-normal precipitation during the second year. The difference in spring precipitation over southern China is correlative to the variation in western North Pacific anomalous cyclone(WNPC), which can in turn be attributed to the different sea surface temperature anomaly(SSTA) over the Tropical Pacific. The remote forcing of negative SSTA in the equatorial central and eastern Pacific and the local air-sea interaction in the western North Pacific are the usual causes of WNPC formation and maintenance.SSTA in the first spring is stronger than those in the second spring. As a result, the intensity of WNPC in the first year is stronger, which is more likely to reduce the moisture in southern China by changing the moisture transport, leading to prolonged precipitation deficits over southern China. However, the tropical SSTA signals in the second year are too weak to induce the formation and maintenance of WNPC and the below-normal precipitation over southern China. Thus, the variation in tropical SSTA signals between two consecutive springs during multiyear La Ni?a events leads to obvious differences in the spatial pattern of precipitation anomaly in southern China by causing the different WNPC response.

Late Neoarchean volcanic rocks in the southern Liaoning Terrane and their tectonic implications for the formation of the eastern North China Craton

The late Neoarchean metamorphosed volcanic rocks in the southern Liaoning Terrane(SLT) of the eastern North China Craton(NCC) are mainly composed of amphibolites and felsic gneisses and can be chemically classified as basalt(Group#1),basaltic andesite(Group#2),dacite(Group#3) and rhyodacite(Group#4).LA-ICP-MS zircon U-Th-Pb dating reveals that they formed at ~2.53-2.51 Ga.Group#1 samples are characterized by approximately flat chondrite-normalized rare earth element(REE) patterns with low(La/Yb)_N ratios and a narrow range of(Hf/Sm)N ratios,and their magmatic precursors were generated by partial melting of a depleted mantle wedge weakly metasomatized by subducted slab fluids.Compared to Group#1 samples,Group#2 samples display strongly fractionated REE patterns with higher(La/Yb)_N ratios and more scattered(Hf/Sm)N ratios,indicative of a depleted mantle wedge that had been intensely metasomatized by slab-derived melts and fluids.Group#3 samples are characterized by high MgO and transition trace element concentrations and fractionated REE patterns,which resemble typical high-Si adakites,and the magmatic precursors were derived from partial melting of a subducted oceanic slab.Group#4 samples have the highest SiO_2 and the lowest MgO and transition trace element contents,and were derived from partial melting of basaltic rocks at lower crust levels.Integrating these tholeiitic to calcalkaline volcanic rocks with the mass of contemporaneous dioritic-tonalitic-trondhjemitic-granodioritic gneisses,the late Neoarchean volcanic rocks in the SLT were most likely produced in an active continental margin.Furthermore,the affinities in lithological assemblages,metamorphism and tectonic regime among SLT,eastern Hebei to western Liaoning Terrane(EH-WLT),northern Liaoning to southern Jilin Terrane(NL-SJT),AnshanBenxi continental nucleus(ABN) and Yishui complex(YSC) collectively indicate that an integral and much larger continental block had been formed in the late Neoarchean and the craton-scale lateral accretion was a dominantly geodynamic mechanism in the eastern NCC.

Cretaceous-Cenozoic regional stress field evolution from borehole imaging in the southern Jinzhou area, western Liaoning, North China Craton

The Mesozoic Yanshanian Movement affected the tectonic evolution of the North China Craton(NCC).It is proposed that Mesozoic cratonic destruction peaked~125 Ma,possibly influenced by subduction of the western Pacific Plate beneath the Euro-Asian Plate in the Early Cretaceous.The southern Jinzhou area in the eastern block of the NCC preserves clues about the tectonic events and related geological resources.Studies of the regional stress field evolution from the Cretaceous to the Cenozoic can enhance our understanding of the tectonics and dynamics of the NCC.Borehole image logging technology was used to identify and collect attitudes of tensile fractures from 11 boreholes;these were subdivided into four groups according to dip direction,i.e.,NNW-SSE,NWW-SEE,W-E and NE-SW.The development of these fractures was controlled primarily by the regional tectonic stress field;temperature,lithology,and depth contributed to some extent.In 136-125 Ma in the Early Cretaceous,the area was characterized by extension that was oriented NNW-SSE and NWW-SEE;from 125-101 Ma the extension was oriented W-E;after 101 Ma it was NE-SW.This counterclockwise trend has persisted to the present,probably related to oblique subduction of the Pacific Plate,and is characterized by ongoing extension that is nearly N-S-oriented and NEE-SWW-oriented compression.

Diel vertical migration of mesozooplankton in the northern Yellow Sea

The Yellow Sea Cold Water Mass(YSCWM),one of the most vital hydrological features of the Yellow Sea,causes a seasonal thermocline from spring to autumn.The diel vertical migration(DVM)of zooplankton is crucial to structural pelagic communities and food webs,and its patterns can be aff ected by thermocline depth and strength.Hence,we investigated zooplankton community succession and seasonal changes in zooplankton DVM at a fixed station in the YSCWM.Annual zooplankton community succession was aff ected by the forming and fading of the YSCWM.A total of 37 mesozooplankton taxa were recorded.The highest and lowest species numbers in autumn and spring were detected.The highest and lowest total densities were observed in autumn(14464.1 inds./m^(3))and winter(3115.4 inds./m^(3)),respectively.The DVM of the dominant species showed obvious seasonal variations.When the YSCWM was weak in spring and autumn,most species(e.g.Paracalanus parvus,Oithona similis,and Acartia bifilosa)stayed above the thermocline and vertically migrated into the upper layer.Calanus sinicus and Aidanosagitta crassa crossed the thermocline and vertically migrated.No species migrated through the stratification in summer,and all of the species were limited above(P.parvus and A.crassa)or below(C.sinicus and Centropages abdominalis)the thermocline.The YSCWM disappeared in winter,and zooplankton species were found throughout the water column.Thus,the existence of thermocline influenced the migration patterns of zooplankton.Cluster analyses showed that the existence of YSCWM resulted in significant differences between zooplankton communities above and below the thermocline.

LA-ICP-MS Zircon U-Pb Age of Longtou Syenite body in South Songxian County, Southern Margin of the North China Craton

Objective Indosinian magmatic rocks mainly locate in west Qinling Orogen, which are, however, extremely rare in east Qingling Orogen （Lu Xinxiang, 2000; Zhang Guowei et al., 2001; Guo Xianqing et al., 2017）. The Zhifang Huangzhuang （ZH） area in south Songxian County is located in the southern margin of the North China Craton （Fig. l a）, which is an important lndosinian alkaline magmatic occurrence including 32 syenite bodies and syenitic dykes in east Qinling Orogen. There are five syenite bodes in the ZH area, i.e., the Lang＇aogou, Mogou, Longtou, Jiaogou and Wusanggou from west to east （Fig. l b）.

Petrogenesis of the Early Cretaceous Laojunshan monzogranite at the southern margin of the North China Craton: Constrains on the transition of the tectonic regime

1 Introduction Voluminous Mesozoic magmatic rocks containing abundant Au-Mo polymetallic mineralization resources are developed in the Xiaoqinling-Xiong’ershan district of the southern margin of the North China Craton(NCC).

An Unique Glomerophyric Diorite Porphyry from the Southern Margin of North China Craton:Geochronology,Geochemical and Quantitative Textural Analysis Constraints

1 Introduction The Wulong glomerophyric diorite porphyry has an extremely peculiar texture with plagioclase phenocrysts clustered as flower-like glomerocrysts(Figs.1a&b),which is never discovered elsewhere of the world.The

Distribution of the low velocity bulk in the middle-to-lower crust of southern Tibet: implications for formation of the north–south trending rift zones

We conducted the ambient noise tomography to image the shallow crustal structure of southern Tibet. The2D maps of phase velocity anomalies at the periods of10–16 s show that the low velocities are mainly confined along or near some of the rift zones. While the maps at the periods of 18–25 s show that the coherent patterns that the low velocities expand outside of the rift zones. It means that the low velocities are prevailing in the middle crust of southern Tibet. According to the previous study of surface wave tomography with teleseismic data,we find that the low velocities from the lower crust to the lithospheric mantle are also restricted to the same rift zones. Thus,the integrated knowledge of the distribution of the low velocities in southern Tibet provides some new insight on the formation of the north–south trending rift zones. Compiling the multidiscipline evidences,we conclude that the rifting was an integrated process of the entire lithosphere in the early stage（＊26–10 Ma）,but mainly occurred within the upper crust due to the weakening a decoupling in the low velocity middle crust in the late stage（later than ＊8 Ma）.

Magnetic Fabric Studies of Xiong'er Volcanic Rocks in Southern Margin of the North China Craton and its Implications

The Paleoproterozoic Xiong’er Group is composed of mafic to felsic volcanic rocks and minor sedimentary rocks,distributed along the southern margin of the North China craton(NCC).It is a key marker for regional

Gold Distribution in Tellurium-Rich Pyrite and Tellurides from the Xiaoqinling Gold District,Southern Margin of the North China Craton

Gold is commonly associated with arsenic in As-rich pyrite or arsenopyrite in a variety types of gold deposit,such as sediment-hosted gold deposits,epithermal Au-Ag deposits,Au-rich VMS deposits,and mesothermal lode gold deposits(Ciobanu and Cook,2002;Pals et al.

Role of the Subtropical Westerly Jet Waveguide in a Southern China Heavy Rainstorm in December 2013

An extreme rainstorm hit southern China during 13–17 December 2013, with a record-breaking daily rainfall rate, large spatial extent, and unusually long persistence. We examined what induced this heavy rainfall process, based on observed rainfall data and NCEP–NCAR reanalysis data through composite and diagnostic methods. The results showed that a Rossby waveguide within the subtropical westerly jet caused the event. The Rossby wave originated from strong cold air intrusion into the subtropical westerly jet over the eastern Mediterranean. With the enhancement and northward shift of the Middle East westerly jet, the Rossby wave propagated slowly eastward and deepened the India–Burma trough, which transported a large amount of moisture from the Bay of Bengal and South China Sea to southern China. Strong divergence in the upper troposphere, caused by the enhancement of the East Asian westerly jet, also favored the heavy rainfall process over Southeast China. In addition, the Rossby wave was associated with a negative-to-positive phase shift and enhancement of the North Atlantic Oscillation, but convergence in the eastern Mediterranean played the key role in the eastward propagation of the Rossby wave within the subtropical westerly jet.

Teleconnections of Inter-Annual Streamflow Fluctuation in Slovakia with Arctic Oscillation,North Atlantic Oscillation,Southern Oscillation,and Quasi-Biennial Oscillation Phenomena

The aim of the paper is to analyze a possible teleconnection of Quasi-Biennial Oscillation （QBO）, Southern Oscillation （SO）, North Atlantic Oscillation （NAO）, and Arctic Oscillation （AO） phenomena with longterm streamflow fluctuation of the Bela River （1895-2004） and Cierny Hron River （1931-2004） （central Slovakia）. Homogeneity, long-term trends, as well as inter-annual dry and wet cycles were analyzed for the entire 1895-2004 time series of the Bela River and for the 1931-2004 time series of the Cierny Hron River. Inter-annual fluctuation of the wet and dry periods was identified using spectral analysis. The most significant period is that of 3.6 years. Other significant periods are those of 2.35 years, 13.5 years, and 21 years. Since these periods were found in other rivers of the world, as well as in SO, NAO, and AO phenomena, they can be considered as relating to the general regularity of the Earth.

The Springtime North Asia Cyclone Activity Index and the Southern Annular Mode

The relationship between the North Asia cyclone （NAC） activity and the Southern Annular Mode （SAM） is documented in this research. The definition of the NAC index （NACI） is based on the atmospheric relative vorticity in North Asia. The analysis yields a significant positive correlation between previous winter Southern Annular Mode index （SAMI） and spring NACI in the interannual variability, with a correlation coefficient of 0.51 during 1948-2000. Analysis of the NAC-related and SAM-related atmospheric general circulation variability demonstrates such a relationship. The study further reveals that when the winter SAM becomes strong, the springtime atmospheric convection in tropical western Pacific will intensify and the local Hadley circulation will be strengthened. As a result, the abnormal subsiding motion over South China makes the temperature gradient intensified in the low level and strengthens the jet in the high level, both of which are beneficial to the development of NAC activity.

Late Cenozoic Geomorphology, Geochronology and Physiography of Yuntaishan in Southern Taihang Mountain, North China

The late Cenozoic geomorphic features and geochronologic data of the Zhingfang River catchment in the Yuntaishan World Geopark are studied. Several quarternary geochronologic methods, including electron spin resonance （ESR）, optically stimulated luminescence （OSL）, thermo-luminescence （TL） and U-series are presented in this paper. The results suggest that there are two planation surfaces, named as the Taihang surface which is a peneplain of Taihang stage formed during Oligocene or Oligocene to early-middle Miocene period, and Tang-hien surface which is a mature wide valley of Tang-hien stage formed during late Miocene-Pliocene or Piiocene-early Pleistocene period and probably ended prior to 2.2-2.6 Ma based on ESR dating. After the Tang-hien stage, the incision and aggradation of the river formed six stream terraces with heights of 3-5 m, 8-12 m, 22-24 m, 28-38 m, 50-62 m and 80-85 m above the river bottom, respectively. The dating results of the alluvium sediments suggest that these terraces were formed during Holocene, 20-23 ka B.P., 110-120 ka B.P., 200-240 ka B.P., 840-1200 ka B.P. or ~450 ka B.P. and 1600-1800 ka B.P. or -1100 ka B.P., respectively. These results indicate that episodic incision of the river, which controls the formation of the scenery in the Yuntaishan World Geopark, was mainly influenced by the periodic dry-wet climate change during late Cenozoic mountain uplift.

Impacts of the north migration of China＇s rice production on its ecosystem service value during the last three decades (1980-2014)

The ecosystem services value （ESV） of rice system has received increasing attention in agricultural policy decision. Over the last three decades, China＇s rice production presented an obviously trend that moving towards north locations. However, the impacts of this migration on the ESV of rice production have not been well documented. In this paper, we analyzed the change of the ESV of rice production in China under ＂north migration＂ and ＂no migration＂ scenarios during 1980-2014 based on long-term historical data. The results showed that both the positive and negative ESVs of rice production were lower under ＂north migration＂ than under ＂no migration＂ scenarios. The total ESV during 1980-2014 was reduced by 15.8%. ＂North migration＂ significantly reduced the area-scaled ESV since the early 1990s; while its impact on yield-scaled ESV was not significant. The effects of＂north migration＂ on ESV showed great spatial variation. The greatest reduction in total and area-scaled ESV was observed in south locations. While the yield-scaled ESVs of most south locations were enhanced under ＂north migration＂ scenario. These results indicated that ＂north migration＂ has generated adverse effects on the ESV of rice production. An adjustment in the spatial distribution is essential to protecting the non-production benefits of rice ecosystem.

Porosity model and pore evolution of transitional shales:an example from the Southern North China Basin

The evolution of shale reservoirs is mainly related to two functions:mechanical compaction controlled by ground stress and chemical compaction controlled by thermal effect.Thermal simulation experiments were conducted to simulate the chemical compaction of marine-continental transitional shale,and X-ray diffraction(XRD),CO2 adsorption,N2 adsorption and high-pressure mercury injection(MIP)were then used to characterize shale diagenesis and porosity.Moreover,simulations of mechanical compaction adhering to mathematical models were performed,and a shale compaction model was proposed considering clay content and kaolinite proportions.The advantage of this model is that the change in shale compressibility,which is caused by the transformation of clay minerals during thermal evolution,may be considered.The combination of the thermal simulation and compaction model may depict the interactions between chemical and mechanical compaction.Such interactions may then express the pore evolution of shale in actual conditions of formation.Accordingly,the obtained results demonstrated that shales having low kaolinite possess higher porosity at the same burial depth and clay mineral content,proving that other clay minerals such as illite-smectite mixed layers(I/S)and illite are conducive to the development of pores.Shales possessing a high clay mineral content have a higher porosity in shallow layers(<3500 m)and a lower porosity in deep layers(>3500 m).Both the amount and location of the increase in porosity differ at different geothermal gradients.High geothermal gradients favor the preservation of high porosity in shale at an appropriate Ro.The pore evolution of the marine-continental transitional shale is divided into five stages.Stage 2 possesses an Ro of 1.0%-1.6%and has high porosity along with a high specific surface area.Stage 3 has an Ro of 1.6%-2.0%and contains a higher porosity with a low specific surface area.Finally,Stage 4 has an Ro of 2.0%-2.9%with a low porosity and high specific surface area.

Earthquake-induced Soft-sediment Deformation Structures in the Dengfeng Area,Henan Province,China:Constraints on Qinling Tectonic Evolution during the Early Cambrian

Soft-sediment deformation structures are abundant in the Cambrian Zhushadong and Mantou formations of the Dengfeng area, Henan Province, China. Soft-sediment deformation structures of the Zhushadong Formation consist of fluidized deformation, synsedimentary faults, seismo-folds and plastic deformation; the Mantou Formation is dominated by small-scale horst faults, intruded dikes, fluidized veins, and seismo-cracks. These structures are demonstrated to be earthquake-related by analysis of trigger mechanisms, and may indicate the activity of the Qinling tectonic belt during the early Cambrian. Furthermore, the assemblages of soft-sediment deformation structures altered with time： large-scale, intense deformation in the Zhushadong Formation alters to small-scale, weak deformation in the Mantou Formation. This striking feature may have been caused by changes in hypocentral depth from deep-focus to shallow-focus earthquakes, indicating that the Qinling tectonic belt developed from the subduction of the Shangdan Ocean to the extension of the Erlangping back-arc basin. This study suggests that soft-sediment deformation structures can be used to reveal the activity of a tectonic belt, and, more importantly, changes in deformation assemblages can track the evolution of a tectonic belt.

Structural Geochemical Study of the Yuxi Fold-Thrust Belt in the Southern North China Plate

The Yuxi （豫西） fold-thrust fracture belt is part of the gigantic fold-thrust fracture belt that extends NW in the southern North China plate. The contents of major elements of tectonites were analyzed by ICP-AES. The analysis of chemical compositions and new stress minerals indicates： extending from the surrounding country rocks to the center of the fracture belt, the Fe2O3 content gradually increases while the FeO content gradually decreases; regular increase, decrease or peak changes are shown for chemical compositions like SiO2, Al2O3, Fe2O3, MgO, CaO, FeO, loss on ignition, TIO：, K2O, Na2 O, etc.. New stress minerals are developed for the south branch and few for the north branch. The characteristics of chemical compositions and new stress minerals of the thrust fracture demonstrate that the fracture belt has undergone a process from a closed reducing environmental system to a relatively open. oxidizing environmental system, andcompressive fractures have resulted from compression in the late stages of evolution, and the dynamothermal metamorphism and thrusting intensities are different between the south and north branches of the belt, which is strong for the south branch but relatively weak for the north branch.

Weakening of Winter North Atlantic Oscillation Signal in Spring Precipitation over Southern China

In this study,the relationship between the North Atlantic Oscillation （NAO） in winter （DecemberFebruary） and the precipitation over southem China （SCP） in the following spring （March-May） was investigated.Results showed an interdecadal change,from strong to weak connection,in their connection.Before the early 1980s,they were highly correlated,with a strong （weak） winter NAO followed by an increased （decreased） spring SCP.However,after the early 1980s,their relationship was weakened significantly.This unstable relationship may be linked to the climatological change of East Asian jet.Before the early 1980s,the wave train along the Asian jet propagated the NAO signal eastward to East Asia and affected local upper-tropospheric atmospheric circulation.A strong NAO in winter led to an anomalous anticyclonic circulation at the south side of 30°N in East Asia in spring,resulting in an increase of SCP.In contrast,after the early 1980s,the wave train pattern along the Asian jet extended eastward due to strengthening of the climatological East Asian jet.Correspondingly,the NAO-related East Asian atmospheric circulations in the upper troposphere shifted eastward,thereby weakening the linkage between the spring SCP and the winter NAO.