LiMn_(2)O_(4)(LMO)electrochemical lithium-ion pump has gained widespread attention due to its green,high efficiency,and low energy consumption in selectively extracting lithium from brine.However,collapse of crystal s...LiMn_(2)O_(4)(LMO)electrochemical lithium-ion pump has gained widespread attention due to its green,high efficiency,and low energy consumption in selectively extracting lithium from brine.However,collapse of crystal structure and loss of lithium extraction capacity caused by Mn dissolution loss limits its industrialized application.Hence,a multifunctional coating was developed by depositing amorphous AlPO_(4)on the surface of LMO using sol-gel method.The characterization and electrochemical performance test provided insights into the mechanism of Li^(+)embedment and de-embedment and revealed that multifunctional AlPO_(4)can reconstruct the physical and chemical state of LMO surface to improve the interface hydrophilicity,promote the transport of Li^(+),strengthen cycle stability.Remarkably,after 20 cycles,the capacity retention rate of 0.5AP-LMO reached 93.6%with only 0.147%Mn dissolution loss.The average Li^(+)release capacity of 0.5AP-LMO//Ag system in simulated brine is 28.77 mg/(g h),which is 90.4%higher than LMO.Encouragingly,even in the more complex Zabuye real brine,0.5AP-LMO//Ag can still maintain excellent lithium extraction performance.These results indicate that the 0.5AP-LMO//Ag lithium-ion pump shows promising potential as a Li^(+)selective extraction system.展开更多
The nanofluid and porous medium together are able to fulfill the requirement of high cooling rate in many engineering problems.So,here the impact of various shapes of nanoparticles on unsteady stagnation-point flow of...The nanofluid and porous medium together are able to fulfill the requirement of high cooling rate in many engineering problems.So,here the impact of various shapes of nanoparticles on unsteady stagnation-point flow of Cu-H_(2)O nanofluid on a flat surface in a porous medium is examined.Moreover,the thermal radiation and viscous dissipation effects are considered.The problem governing partial differential equations are converted into self-similar coupled ordinary differential equations and those are numerically solved by the shooting method.The computed results can reveal many vital findings of practical importance.Firstly,dual solutions exist for decelerating unsteady flow and for accelerating unsteady and steady flows,the solution is unique.The presence of nanoparticles affects the existence of dual solution in decelerating unsteady flow only when the medium of the flow is a porous medium.But different shapes of nanoparticles are not disturbing the dual solution existence range,though it has a considerable impact on thermal conductivity of the mixture.Different shapes of nanoparticles act differently to enhance the heat transfer characteristics of the base fluid,i.e.,the water here.On the other hand,the existence range of dual solutions becomes wider for a larger permeability parameter related to the porous medium.Regarding the cooling rate of the heated surface,it rises with the permeability parameter,shape factor(related to various shapes of Cu-nanoparticles),and radiation parameter.The surface drag force becomes stronger with the permeability parameter.Also,with growing values of nanoparticle volume fraction,the boundary layer thickness(BLT)increases and the thermal BLT becomes thicker with larger values of shape factor.For decelerating unsteady flow,the nanofluid velocity rises with permeability parameter in the case of upper branch solution and an opposite trend for the lower branch is witnessed.The thermal BLT is thicker with radiation parameter.Due to the existence of dual solutions,a linear stability analysis is made and it is concluded that the upper branch and unique solutions are stable solutions.展开更多
With the help of skew-symmetric differential forms, the hidden properties of the mathematical physics equations that describe discrete quantum transitions and emergence the physical structures are investigated. It is ...With the help of skew-symmetric differential forms, the hidden properties of the mathematical physics equations that describe discrete quantum transitions and emergence the physical structures are investigated. It is shown that the mathematical physics equations possess a unique property. They can describe discrete quantum transitions, emergence of physical structures and occurrence observed formations. However, such a property possesses only equations on which no additional conditions, namely, the conditions of integrability, are imposed. The intergrability conditions are realized from the equations themselves. Just under realization of integrability conditions double solutions to the mathematical physics equations, which describe discrete transitions and so on, are obtained. The peculiarity consists in the fact that the integrability conditions do not directly follow from the mathematical physics equations;they are realized under the description of evolutionary process. The hidden properties of differential equations were discovered when studying the integrability of differential equations of mathematical physics that depends on the consistence between the derivatives in differential equations along different directions and on the consistence of equations in the set of equations. The results of this work were obtained with the help of skew-symmetric differential forms that possess a nontraditional mathematical apparatus such as nonidentical relations, degenerate transformations and the transition from nonintegrable manifolds to integrable structures. Such results show that mathematical physics equations can describe quantum processes.展开更多
This study examined the effects of mental imagery in the solution-focused approach by evaluating the impact of positive self-image about the future on emotional states using the time machine question (which is a quest...This study examined the effects of mental imagery in the solution-focused approach by evaluating the impact of positive self-image about the future on emotional states using the time machine question (which is a questioning technique used in the solution-focused approach). We compared the change in the emotional state of 270 participants, using the Japanese version of the Positive and Negative Affect Schedule (PANAS), before and after the intervention. The intervention conditions included: verbal description of one’s positive future on a worksheet (the language description condition), and imagining one’s positive future (the imagery condition). The results of the experiment showed that after the intervention, the scores of the imagery group on the positive and negative affect scales of the PANAS were significantly higher and lower, respectively, than those of the language description group. We also found that the amount of change in the scores of the positive and negative affect scales of the PANAS was significantly larger in the imagery group as compared to the language description group. These results indicate that interventions involving the imagining of one’s future via the time machine question of the solution-focused approach have a more direct impact on emotional states than interventions using a language description. This suggests that mental imagery plays an important role in interventions carried out within the framework of the solution-focused approach.展开更多
基金supported by the National Natural Science Foundation of China(21908082,22278426,and 22178154)the Jiangsu Funding Program for Excellent Postdoctoral Talent(2022ZB629)+1 种基金the Natural Science Foundation of Jiangsu Province(BK20221367)the China Postdoctoral Science Foundation(2021M701472)。
文摘LiMn_(2)O_(4)(LMO)electrochemical lithium-ion pump has gained widespread attention due to its green,high efficiency,and low energy consumption in selectively extracting lithium from brine.However,collapse of crystal structure and loss of lithium extraction capacity caused by Mn dissolution loss limits its industrialized application.Hence,a multifunctional coating was developed by depositing amorphous AlPO_(4)on the surface of LMO using sol-gel method.The characterization and electrochemical performance test provided insights into the mechanism of Li^(+)embedment and de-embedment and revealed that multifunctional AlPO_(4)can reconstruct the physical and chemical state of LMO surface to improve the interface hydrophilicity,promote the transport of Li^(+),strengthen cycle stability.Remarkably,after 20 cycles,the capacity retention rate of 0.5AP-LMO reached 93.6%with only 0.147%Mn dissolution loss.The average Li^(+)release capacity of 0.5AP-LMO//Ag system in simulated brine is 28.77 mg/(g h),which is 90.4%higher than LMO.Encouragingly,even in the more complex Zabuye real brine,0.5AP-LMO//Ag can still maintain excellent lithium extraction performance.These results indicate that the 0.5AP-LMO//Ag lithium-ion pump shows promising potential as a Li^(+)selective extraction system.
文摘The nanofluid and porous medium together are able to fulfill the requirement of high cooling rate in many engineering problems.So,here the impact of various shapes of nanoparticles on unsteady stagnation-point flow of Cu-H_(2)O nanofluid on a flat surface in a porous medium is examined.Moreover,the thermal radiation and viscous dissipation effects are considered.The problem governing partial differential equations are converted into self-similar coupled ordinary differential equations and those are numerically solved by the shooting method.The computed results can reveal many vital findings of practical importance.Firstly,dual solutions exist for decelerating unsteady flow and for accelerating unsteady and steady flows,the solution is unique.The presence of nanoparticles affects the existence of dual solution in decelerating unsteady flow only when the medium of the flow is a porous medium.But different shapes of nanoparticles are not disturbing the dual solution existence range,though it has a considerable impact on thermal conductivity of the mixture.Different shapes of nanoparticles act differently to enhance the heat transfer characteristics of the base fluid,i.e.,the water here.On the other hand,the existence range of dual solutions becomes wider for a larger permeability parameter related to the porous medium.Regarding the cooling rate of the heated surface,it rises with the permeability parameter,shape factor(related to various shapes of Cu-nanoparticles),and radiation parameter.The surface drag force becomes stronger with the permeability parameter.Also,with growing values of nanoparticle volume fraction,the boundary layer thickness(BLT)increases and the thermal BLT becomes thicker with larger values of shape factor.For decelerating unsteady flow,the nanofluid velocity rises with permeability parameter in the case of upper branch solution and an opposite trend for the lower branch is witnessed.The thermal BLT is thicker with radiation parameter.Due to the existence of dual solutions,a linear stability analysis is made and it is concluded that the upper branch and unique solutions are stable solutions.
文摘With the help of skew-symmetric differential forms, the hidden properties of the mathematical physics equations that describe discrete quantum transitions and emergence the physical structures are investigated. It is shown that the mathematical physics equations possess a unique property. They can describe discrete quantum transitions, emergence of physical structures and occurrence observed formations. However, such a property possesses only equations on which no additional conditions, namely, the conditions of integrability, are imposed. The intergrability conditions are realized from the equations themselves. Just under realization of integrability conditions double solutions to the mathematical physics equations, which describe discrete transitions and so on, are obtained. The peculiarity consists in the fact that the integrability conditions do not directly follow from the mathematical physics equations;they are realized under the description of evolutionary process. The hidden properties of differential equations were discovered when studying the integrability of differential equations of mathematical physics that depends on the consistence between the derivatives in differential equations along different directions and on the consistence of equations in the set of equations. The results of this work were obtained with the help of skew-symmetric differential forms that possess a nontraditional mathematical apparatus such as nonidentical relations, degenerate transformations and the transition from nonintegrable manifolds to integrable structures. Such results show that mathematical physics equations can describe quantum processes.
文摘This study examined the effects of mental imagery in the solution-focused approach by evaluating the impact of positive self-image about the future on emotional states using the time machine question (which is a questioning technique used in the solution-focused approach). We compared the change in the emotional state of 270 participants, using the Japanese version of the Positive and Negative Affect Schedule (PANAS), before and after the intervention. The intervention conditions included: verbal description of one’s positive future on a worksheet (the language description condition), and imagining one’s positive future (the imagery condition). The results of the experiment showed that after the intervention, the scores of the imagery group on the positive and negative affect scales of the PANAS were significantly higher and lower, respectively, than those of the language description group. We also found that the amount of change in the scores of the positive and negative affect scales of the PANAS was significantly larger in the imagery group as compared to the language description group. These results indicate that interventions involving the imagining of one’s future via the time machine question of the solution-focused approach have a more direct impact on emotional states than interventions using a language description. This suggests that mental imagery plays an important role in interventions carried out within the framework of the solution-focused approach.
