Rare earth luminescence has attracted widespread attention for several decades, among which nearinfrared(NIR) light-related up-conversion luminescence and NIR-Ⅱ luminescence are widely used in the biomedical field. T...Rare earth luminescence has attracted widespread attention for several decades, among which nearinfrared(NIR) light-related up-conversion luminescence and NIR-Ⅱ luminescence are widely used in the biomedical field. The NIR-related luminescence is widely studied due to the excellent performance, such as good biocompatibility, deep tissue penetration depth, low self-fluorescence and minimal light damage to organisms. In this review, we mainly introduce the mechanism for rare earth up-conversion luminescence, NIR-Ⅱ luminescence and conclude their advantages compared with traditional luminescence.These excellent priorities provide the basis for NIR-related luminescence bioimaging in vivo. Additionally,we hilglight the scheme for the sensitive detection of substances in organisms and various methods for biological therapy. In spite of the existing research, it is outlined that NIR-related luminescence has great potential to be applied in different aspects, expanding perspectives and future challenges of research in related fields. Based on the current scientific achievements, this review can provide reference for research in the areas mentioned above, expand the research direction and arouse a broad interest in different disciplines to pay attention to rare earth luminescence.展开更多
This paper is centered on the extent to which contemporary Chinese science fiction is related to ancient Chinese mythologies according to the previous scholarly discussion and how these ancient mythologies are utilize...This paper is centered on the extent to which contemporary Chinese science fiction is related to ancient Chinese mythologies according to the previous scholarly discussion and how these ancient mythologies are utilized specifically in the futuristic narratives of modern Chinese science fiction.By referring to academic dialogues,this paper argues that ancient mythologies can be recreated in modern science fiction and create modern mythologies in futuristic narratives to present or deal with modern human fears.Based on this argument,this paper then continues to explore what kinds of modern mythologies science fiction might deliver.The Chinese film The Wandering Earth(2019)will be discussed in terms of its mythological symbols and metaphors.This paper proposes a new approach through which to reconnect past stories with futuristic narratives and builds a frame in which to contextualize ancient mythologies in contemporary Chinese culture.展开更多
Due to 4f electron characteristics and alternation valence, cerium involved in an oxidation-reduction reaction in plant, closely relating to photosynthesis. Our studies proved that cerium could promote photosynthesis ...Due to 4f electron characteristics and alternation valence, cerium involved in an oxidation-reduction reaction in plant, closely relating to photosynthesis. Our studies proved that cerium could promote photosynthesis and greatly improve spinach growth. However, the mechanism of promoting energy transfer and conversion by cerium remains unclear. Here we reported that the effects of Ce^3＋ on energy transfer and oxygen evolution in photosystem Ⅱ （PS Ⅱ ） isolated from spinach, which was related to 4f electron characteristics and alternation valence in Ce molecule. The methods of absorption spectrum, fluorescence spectrum were used in the research. Results showed that Ce^3＋ treatment at low concentration could suitably change PS Ⅱ mieroenvironment, increase the absorbance of visible light, improve the energy transfer among amino acids within PS Ⅱ protein-pigment complex, and accelerate energy transport from tyrosine residue to chlorophyll a. In summary, the photochemical activity of PS Ⅱ （fluorescence quantum yield） and its oxygen evolving rate were enhanced by Ce^3＋.展开更多
UV-Vis spectroscopy was used to directly determine the concentration of Eu（ Ⅱ） during electroreduction of Eu （ Ⅲ ） in hydrochloric acid medium. Electroreduction was carried out in a flow type electrolyzer with g...UV-Vis spectroscopy was used to directly determine the concentration of Eu（ Ⅱ） during electroreduction of Eu （ Ⅲ ） in hydrochloric acid medium. Electroreduction was carried out in a flow type electrolyzer with glassy carbon cathode at the constant potential of - 800 mV vs. Ag/AgCl. The effects of oxygen and concentration of hydrochloric acid on the system were investigated. For 0.01 mol· L^-1 hydrochloric acid, calibration curves for Eu （Ⅱ） absorption bands at 248 and 320 nm were constructed. Molar absorption coefficients were estimated to be 2016 and 648 L· mol^-1·cm^-1, respectively. The absorbance strongly decreased with decrease in pH of the solution, whereas concentration of chloride had only a negligible effect.展开更多
Satellite-to-Satellite Tracking in low-low model （SST-Ⅱ） is a new technique to resolve the series of problems met in the determination of the earth＇s gravity field. As the key technique of SST-Ⅱ, KBR can get SST-...Satellite-to-Satellite Tracking in low-low model （SST-Ⅱ） is a new technique to resolve the series of problems met in the determination of the earth＇s gravity field. As the key technique of SST-Ⅱ, KBR can get SST-Ⅱ measurements directly. So the KBR performance analysis is the first step in SST-Ⅱ design. In this paper, assuming that the satellite pairs of SST-Ⅱ are in near circle polar orbits, the spectrum relationship between the earth gravity field and KBR is established using analytic method. And then some examples are analyzed, the suggestions and conclusions are drawn from these examples. The research results could be taken as a reference for future satellite gravity project of China.展开更多
基金Financial support from the National Natural Science Foundation of China(NSFC,Nos.51972076,52272144,22205048)the Heilongjiang Provincial Natural Science Foundation of China(No.JQ2022E001)+3 种基金the Natural Science Foundation of Shandong Province(No.ZR2020ZD42)Project funded by China Postdoctoral Science Foundation(No.2022M710931)the Fundamental Research Funds for the Central Universitiesthe Special Scientific Research Starting Foundation for Young teachers of Zhengzhou University(No.32213226).
文摘Rare earth luminescence has attracted widespread attention for several decades, among which nearinfrared(NIR) light-related up-conversion luminescence and NIR-Ⅱ luminescence are widely used in the biomedical field. The NIR-related luminescence is widely studied due to the excellent performance, such as good biocompatibility, deep tissue penetration depth, low self-fluorescence and minimal light damage to organisms. In this review, we mainly introduce the mechanism for rare earth up-conversion luminescence, NIR-Ⅱ luminescence and conclude their advantages compared with traditional luminescence.These excellent priorities provide the basis for NIR-related luminescence bioimaging in vivo. Additionally,we hilglight the scheme for the sensitive detection of substances in organisms and various methods for biological therapy. In spite of the existing research, it is outlined that NIR-related luminescence has great potential to be applied in different aspects, expanding perspectives and future challenges of research in related fields. Based on the current scientific achievements, this review can provide reference for research in the areas mentioned above, expand the research direction and arouse a broad interest in different disciplines to pay attention to rare earth luminescence.
文摘This paper is centered on the extent to which contemporary Chinese science fiction is related to ancient Chinese mythologies according to the previous scholarly discussion and how these ancient mythologies are utilized specifically in the futuristic narratives of modern Chinese science fiction.By referring to academic dialogues,this paper argues that ancient mythologies can be recreated in modern science fiction and create modern mythologies in futuristic narratives to present or deal with modern human fears.Based on this argument,this paper then continues to explore what kinds of modern mythologies science fiction might deliver.The Chinese film The Wandering Earth(2019)will be discussed in terms of its mythological symbols and metaphors.This paper proposes a new approach through which to reconnect past stories with futuristic narratives and builds a frame in which to contextualize ancient mythologies in contemporary Chinese culture.
基金Project supported by the National Natural Science Foundation of China (20671067, 30470150)
文摘Due to 4f electron characteristics and alternation valence, cerium involved in an oxidation-reduction reaction in plant, closely relating to photosynthesis. Our studies proved that cerium could promote photosynthesis and greatly improve spinach growth. However, the mechanism of promoting energy transfer and conversion by cerium remains unclear. Here we reported that the effects of Ce^3＋ on energy transfer and oxygen evolution in photosystem Ⅱ （PS Ⅱ ） isolated from spinach, which was related to 4f electron characteristics and alternation valence in Ce molecule. The methods of absorption spectrum, fluorescence spectrum were used in the research. Results showed that Ce^3＋ treatment at low concentration could suitably change PS Ⅱ mieroenvironment, increase the absorbance of visible light, improve the energy transfer among amino acids within PS Ⅱ protein-pigment complex, and accelerate energy transport from tyrosine residue to chlorophyll a. In summary, the photochemical activity of PS Ⅱ （fluorescence quantum yield） and its oxygen evolving rate were enhanced by Ce^3＋.
基金Project supported by Japan Society for the Promotion of Science （JSPS）
文摘UV-Vis spectroscopy was used to directly determine the concentration of Eu（ Ⅱ） during electroreduction of Eu （ Ⅲ ） in hydrochloric acid medium. Electroreduction was carried out in a flow type electrolyzer with glassy carbon cathode at the constant potential of - 800 mV vs. Ag/AgCl. The effects of oxygen and concentration of hydrochloric acid on the system were investigated. For 0.01 mol· L^-1 hydrochloric acid, calibration curves for Eu （Ⅱ） absorption bands at 248 and 320 nm were constructed. Molar absorption coefficients were estimated to be 2016 and 648 L· mol^-1·cm^-1, respectively. The absorbance strongly decreased with decrease in pH of the solution, whereas concentration of chloride had only a negligible effect.
基金Project supported by the National Natural Science Foundation of China (No.40374006 , No.40304001) the Foundation for Ph.D project of ChineseMinistry of Education (No.20020486003) .
文摘Satellite-to-Satellite Tracking in low-low model （SST-Ⅱ） is a new technique to resolve the series of problems met in the determination of the earth＇s gravity field. As the key technique of SST-Ⅱ, KBR can get SST-Ⅱ measurements directly. So the KBR performance analysis is the first step in SST-Ⅱ design. In this paper, assuming that the satellite pairs of SST-Ⅱ are in near circle polar orbits, the spectrum relationship between the earth gravity field and KBR is established using analytic method. And then some examples are analyzed, the suggestions and conclusions are drawn from these examples. The research results could be taken as a reference for future satellite gravity project of China.
