For a long time,most studies about pyrite have focused on sediments while only a few have focused on pyrite in water.In this study,a method that combines the scanning electron microscopy(SEM)and the energy dispersive ...For a long time,most studies about pyrite have focused on sediments while only a few have focused on pyrite in water.In this study,a method that combines the scanning electron microscopy(SEM)and the energy dispersive X-ray spectrometry(EDS)was used to compare pyrite particles suspended in water to those in associated bottom sediments,both obtained from the mixing zone of the Yangtze Estuary.It was found that the pyrite particles in the two media have similar morphologies and size distributions.The particle morphology mainly includes two types,single crystal and aggregate,and the particle size mainly ranges from 0.5 to 2μm.The pyrite particles in water exhibit an increase in relative content towards the sea,and their transport and deposit processes are mainly affected by hydrodynamic conditions.It is concluded that the pyrite particles in the suspended matter mainly derived from the resuspension of sediments,which are products of the early diagenesis.Precursor minerals may appear during the formation of pyrite,but are generally restricted by the diagenetic environment and local microenvironment.展开更多
In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang （Yangtze） Estuary, the contents of heavy metals （Zn,...In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang （Yangtze） Estuary, the contents of heavy metals （Zn, Pb, Cd, Co and Ni） have been analyzed. During a tidal cycle, the average contents of heavy metals are in the order of Zn〉Ni〉Pb〉Co〉〉Cd. The average contents in ebb tide are generally higher than that in flood tide. However, at the inshore Sta. 11, influenced by the contamination from the nearby waste treatment plant, the average contents of Zn and Ni in flood tide are higher than those in ebb fide and at the offshore Sta. 10, the content of Cd in flood tide higher than that in ebb tide due to marine-derived materials. The five heavy metals, mainly terrigenous, are transported towards east-northeast, and settle down with suspended matters in the area between Sta. 11 and Sta. 10. Influenced by marine-derived materials, the flux value of Cd does not alter significantly with obviously changing in flux direction towards northwest. The source of heavy metals, the salinity of water and the concentration of suspended matters are the main factors controlling the content distributions of heavy metals during a tidal cycle. There is a positive correlation between the contents of heavy metals （Zn, Pb, Co and Ni） and the salinity of water, while the opposite correlation between the contents and the concentrations of suspended matters. Because of marine-derived materials, the content of Cd is not correlated with the concentration of suspended matters and the salinity of water.展开更多
Temporal and spatial distribution of biogenic （BSi） and lithogenic （LSi） silica were studied in the Changjiang （Yangtze River） Estuary and its adjacent area. The annual average BSi and LSi concentrations were （...Temporal and spatial distribution of biogenic （BSi） and lithogenic （LSi） silica were studied in the Changjiang （Yangtze River） Estuary and its adjacent area. The annual average BSi and LSi concentrations were （1.714-1.79） #mol/L and （0.564-1.41） mmol/L, respectively. Both BSi and LSi were high ii~. tbe inshore ar- eas, where they received terrigenous discharge from the Changjiang, and decreased towards the offshore region. BSi and LSi were most abundant at the near bottom layer due to the high sedimentation rates and resuspension of sediment. Diatom blooms occurred in summer with high Chl a concentration in the sur- face layer, which induced that BSi in the surface layer during summer was obviously higher than that in the surface layer of other seasons. LSi concentration was maximal in autumn and spring and minimum in summer, associated with the seasonal variation of SPM values. Drifting investigation and mesocosm exper- iments were conducted during dinoflagellate bloom, aiming to understand the effect of nutrients on BSi by changing the phytoplankton composition. The results show that the low dissolved inorganic phosphorus concentration and high molar ratio of N/P （dissolved inorganic nitrogen vs. dissolved inorganic phospho- rus）, were the important factors for decreasing diatom biomass in the study area, and it would subsequently decrease the BSi concentration in aquatic ecosystem.展开更多
Based on the principle of conservative matter removal in estuary,a new method is proposed for estimating the ratio of sediment resuspension in estuaries with fine suspended sediments in the turbidity maximum zone(TMZ)...Based on the principle of conservative matter removal in estuary,a new method is proposed for estimating the ratio of sediment resuspension in estuaries with fine suspended sediments in the turbidity maximum zone(TMZ) of the Changjiang(Yangtze) estuary during 2005.Results show that there was a range of 18.7%±27.9% to 73.9%±22.5% per annum of total suspended particulate matter(SPM),with an average of 49.2%.Nearly half of the particulate matter in the TMZ originates from sediment resuspension.This indicates that sediment resuspension is one of the major mechanisms involved in formation of the TMZ.Compared with traditional method for calculating these ratios in the estuary,this new method evaluates the dynamic variation of SPM content carried by river runoff from the river mouth to the ocean.The new method produced more reliable results than the traditional one and could produce a better estimation of resuspension flux for particulate matter in estuaries.展开更多
This paper reports the relationship between the biogeochemical characteristics of C. N. P and flocculation and settling of suspended materials in the Changjiang Estuary. Regional activities of bacteria and the plankto...This paper reports the relationship between the biogeochemical characteristics of C. N. P and flocculation and settling of suspended materials in the Changjiang Estuary. Regional activities of bacteria and the plankton and biogeochemical processes at the water-particle interface under some environmental conditions are quite variable. This leads to the transition of material phase with speciation variation of elements C. N. P. in the transfer processes. Therefore, the composition and reactivity of particle surface and dissolved constituent are modified, affecting the stability of the particulate dispersion system. In summer, the concentration of NO3 and PO4 are positively correlated with turbidity, while the weight percentage of PON, POC and PP are negatively correlated with turbidity. When particles in the river move seaward, two zones can be distinguished: i) zone with maximum flocculation speed, in salinity 0. 1～2. 0 ;ii) zone with huge coagulating particles netting and high turbidity at the bottom, in salinity 2～11.The highest values of C/N in particles (or the low valley of C. E. C.of particle surface) appear in the two zones. These results demonstrate that the biogeochemical action is one of the major factors and mechanisms to dominate the flocculation of particles in the Changjiang Estuary.展开更多
基金the National Natural Science Foundation of China(NSFC)who organized the public survey cruise in the Yangtze River Estuary in March 2015,with special thanks to the crew of the R/V Run Jiang No.1 for kindly assisting in sediment sampling on the cruiseThis study was funded by the NSFC(No.41676036)and the National Key R&D Program of China(No.2016YFA0600904).
文摘For a long time,most studies about pyrite have focused on sediments while only a few have focused on pyrite in water.In this study,a method that combines the scanning electron microscopy(SEM)and the energy dispersive X-ray spectrometry(EDS)was used to compare pyrite particles suspended in water to those in associated bottom sediments,both obtained from the mixing zone of the Yangtze Estuary.It was found that the pyrite particles in the two media have similar morphologies and size distributions.The particle morphology mainly includes two types,single crystal and aggregate,and the particle size mainly ranges from 0.5 to 2μm.The pyrite particles in water exhibit an increase in relative content towards the sea,and their transport and deposit processes are mainly affected by hydrodynamic conditions.It is concluded that the pyrite particles in the suspended matter mainly derived from the resuspension of sediments,which are products of the early diagenesis.Precursor minerals may appear during the formation of pyrite,but are generally restricted by the diagenetic environment and local microenvironment.
基金The National Natural Science Foundation of China under contract No.41076022the National Basic Research Program(973Program)of China under contract No.2002CB412400
文摘In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang （Yangtze） Estuary, the contents of heavy metals （Zn, Pb, Cd, Co and Ni） have been analyzed. During a tidal cycle, the average contents of heavy metals are in the order of Zn〉Ni〉Pb〉Co〉〉Cd. The average contents in ebb tide are generally higher than that in flood tide. However, at the inshore Sta. 11, influenced by the contamination from the nearby waste treatment plant, the average contents of Zn and Ni in flood tide are higher than those in ebb fide and at the offshore Sta. 10, the content of Cd in flood tide higher than that in ebb tide due to marine-derived materials. The five heavy metals, mainly terrigenous, are transported towards east-northeast, and settle down with suspended matters in the area between Sta. 11 and Sta. 10. Influenced by marine-derived materials, the flux value of Cd does not alter significantly with obviously changing in flux direction towards northwest. The source of heavy metals, the salinity of water and the concentration of suspended matters are the main factors controlling the content distributions of heavy metals during a tidal cycle. There is a positive correlation between the contents of heavy metals （Zn, Pb, Co and Ni） and the salinity of water, while the opposite correlation between the contents and the concentrations of suspended matters. Because of marine-derived materials, the content of Cd is not correlated with the concentration of suspended matters and the salinity of water.
基金The National Natural Sciences Foundation of China under contract Nos 40925017 and 40876054the Ministry of Science&Technology of P.R.China under contract Nos 2011CB409802 and 2001CB409703
文摘Temporal and spatial distribution of biogenic （BSi） and lithogenic （LSi） silica were studied in the Changjiang （Yangtze River） Estuary and its adjacent area. The annual average BSi and LSi concentrations were （1.714-1.79） #mol/L and （0.564-1.41） mmol/L, respectively. Both BSi and LSi were high ii~. tbe inshore ar- eas, where they received terrigenous discharge from the Changjiang, and decreased towards the offshore region. BSi and LSi were most abundant at the near bottom layer due to the high sedimentation rates and resuspension of sediment. Diatom blooms occurred in summer with high Chl a concentration in the sur- face layer, which induced that BSi in the surface layer during summer was obviously higher than that in the surface layer of other seasons. LSi concentration was maximal in autumn and spring and minimum in summer, associated with the seasonal variation of SPM values. Drifting investigation and mesocosm exper- iments were conducted during dinoflagellate bloom, aiming to understand the effect of nutrients on BSi by changing the phytoplankton composition. The results show that the low dissolved inorganic phosphorus concentration and high molar ratio of N/P （dissolved inorganic nitrogen vs. dissolved inorganic phospho- rus）, were the important factors for decreasing diatom biomass in the study area, and it would subsequently decrease the BSi concentration in aquatic ecosystem.
基金Supported by National Natural Science Foundation of China for Creative Research Groups(No.41121064) and NSFC(No.41176138)the Program from Three Gorges Engineering Construction Committee of the State Council,China(No.SX2004-010)
文摘Based on the principle of conservative matter removal in estuary,a new method is proposed for estimating the ratio of sediment resuspension in estuaries with fine suspended sediments in the turbidity maximum zone(TMZ) of the Changjiang(Yangtze) estuary during 2005.Results show that there was a range of 18.7%±27.9% to 73.9%±22.5% per annum of total suspended particulate matter(SPM),with an average of 49.2%.Nearly half of the particulate matter in the TMZ originates from sediment resuspension.This indicates that sediment resuspension is one of the major mechanisms involved in formation of the TMZ.Compared with traditional method for calculating these ratios in the estuary,this new method evaluates the dynamic variation of SPM content carried by river runoff from the river mouth to the ocean.The new method produced more reliable results than the traditional one and could produce a better estimation of resuspension flux for particulate matter in estuaries.
文摘This paper reports the relationship between the biogeochemical characteristics of C. N. P and flocculation and settling of suspended materials in the Changjiang Estuary. Regional activities of bacteria and the plankton and biogeochemical processes at the water-particle interface under some environmental conditions are quite variable. This leads to the transition of material phase with speciation variation of elements C. N. P. in the transfer processes. Therefore, the composition and reactivity of particle surface and dissolved constituent are modified, affecting the stability of the particulate dispersion system. In summer, the concentration of NO3 and PO4 are positively correlated with turbidity, while the weight percentage of PON, POC and PP are negatively correlated with turbidity. When particles in the river move seaward, two zones can be distinguished: i) zone with maximum flocculation speed, in salinity 0. 1～2. 0 ;ii) zone with huge coagulating particles netting and high turbidity at the bottom, in salinity 2～11.The highest values of C/N in particles (or the low valley of C. E. C.of particle surface) appear in the two zones. These results demonstrate that the biogeochemical action is one of the major factors and mechanisms to dominate the flocculation of particles in the Changjiang Estuary.
