Re-Os Age of Cu-Ni Ores from the Huangshandong Cu-Ni Sulfide Deposit in the East Tianshan Mountains and Its Implication for Geodynamic Processes

An isochron age of 282±20 (95% conf. limit) Ma of the sulfide ores in the Huangshandong Cu-Ni sulfide deposit, the East Tianshan Mountains has been obtained through Re-Os isotopic measurement. The age implies that the Cu-Ni sulfide deposit and other related deposits in the same area occurred in a Permian extensional environment of post-collision instead of Devonian-Early Carboniferous ophiolite-related oceanic or island arc environments inferred before. It shares the same ages with the orogenic and epithermal gold deposit systems in the same area. An initial 187Os/188Os ratio of 0.25±0.04 (1σ) and a γos value of 99 on average display the participation of large quantities of crustal components into the rock-forming and ore-forming system during mineralization and magmatic emplacement.

REE Characteristics of the Kalatongke Cu-Ni Deposit, Xinjiang, China

On the basis of the study on the REE geochemistry of the ore minerals and host rocks of the Kalatongke Cu-Ni deposit, Xinjiang, it is indicated that the major ore minerals, sulfides, were sourced from the host mafic-ultramafic magma. Characterized by low REE content of sulfide, such a Cu-Ni sulfide deposit occurring in the orogen is obviously different from that on the margin of the craton. Because the mafic-ultramafic rocks from the Cu-Ni sulfide deposit occurring in the orogen is water-rich and the REEs of some sulfides show a particular 'multiple-bending' pattern, which suggests coexistence of multiple liquid phases (fluid and melt), the sulfide melt possibly contains a great deal of hydrothermal fluids and increasingly developed gases and liquid-rich ore-forming fluids after the main metallogenic epoch (magmatic segregation stage).

Geochemistry of Ore-bearing Lamprophyre from the Cu-Ni Deposit in Dhi Samir,Yemen

Magmatic Cu-Ni sulfide deposits are generally associated with mafic-ultramafic rocks and it has not been reported that lamprophyre is one of the surrounding rocks of Cu-Ni sulfide deposits.The Dhi Samir deposit in Yemen,however,is a rare example of Cu-Ni deposits which are hosted in lamprophyre dikes.In this paper,comprehensive research is made on petrology,petrochemistry and isotope geochemistry for Cu-Ni-bearing rocks in the Dhi Samir area and the results show that dark rocks related to Cu-Ni orebodies are sodium-weak potassium and belong to calc-alkaline series lamprophyre,especially camptonite,characterized by enriched alkali,iron and titanium.In these rocks large-ion-lithophile elements are obviously concentrated,while high field strength elements slightly depleted,showing clear negative anomalies of Ta and Nb,and weak deficiency of Ti.TheΣREE is very high（225.67-290.05 ppm） and the REE partition curves are flat and right-inclined,featuring a LREE-enriched pattern with low negative Eu anomalies.Study of magmatic source areas indicates that the rocks have low（87Sr/86Sr） and highεNd（t）,and the magmas were probably derived from the enriched mantle I（EM-I） end-member.Based on the LA-ICPMS on zircon U-Pb isotope dating,the lamprophyre in the Dhi Samir mining area has an age of 602±2.6 Ma,indicating that the rock was formed in the late Proterozoic and in an intraplate setting due to magmatism of an extensional environment in the post-Pan-Africa orogeny.

First Report of Zircon U-Pb Ages from Lubei Cu-Ni Sulfide Deposit in East Tianshan of Central Asian Orogenic Belt, NW China

Objective The East Tianshan mafic-ultramafic rocks belt mainly produced in the eastern Jueluotage belt is an important part of the Central Asia Orogenic Belt （CAOB）. The well- known deposits including Huangshan, Huangshandong, Tulaergen, Hulu, Xiangshan were have been consecutively discovered in this belt （Duan Xingxing et al., 2016）. The new discovery of the Lubei Cu-Ni sulfide deposit in recent years, which locates in the west of Jueluotage belt, has great significance to the westward extension of the East Tianshan Cu-Ni metallogenic belt. To determine whether the mineralization age of the Lubei Cu-Ni sulfide deposit is consistent with other typical deposits, this study conducted zircon U-Pb geochronology on the diorite from the Lubei Cu-Ni sulfide deposit in order to provide new information for further exploring direction of Cu-Ni prospecting in East Tianshan.

Rhenium-Osmium Isotope Constraints on the Origin of the Tianyu Cu-Ni Deposit in the East Tianshan Orogenic Belt, Xinjiang, NW China

The Tianyu Cu-Ni sulfide deposit occurs in the north margin of the Central Tianshan Arc in East Tianshan orogenic belt, Xinjiang, NW China. The intrusions consist of gabbro, peridotite, and olivine pyroxenite. The peridotite and pyroxenite are the main host rock for the Cu-Ni ores. Rhenium and osmium isotopic analyses of Ni-and Cu-bearing sulfide minerals from the deposit have been used to determine the source of osmium, and by inference, the sources of ore metals. Sulfide ore samples have Os and Re concentrations varying in the ranges 1.85 to 4.58 ppb and 93.56 to 146.00 ppb, respectively. An initial ^(187)Os/^(188)Os ratio ranges from 0.86 to 1.23 for the ores and the γOs values from 592 to 2227. Osmium isotopic data suggest that the Tianyu intrusion and associated Cu-Ni mineralization has derived from crustal-contaminated mantle melts. The intrusions early show island-arc geochemical signatures, which indicate that the Hulu mafic–ultramafic intrusions, along with the Cu-Ni deposit, formed as a result of subduction of oceanic crust in the Early Permian.

Geochemical Characteristics,Genesis of Concealed Cu-rich Ore Body in the Jinchuan Deposit,Northwestern China,and Its Prospecting

The Jinchuan deposit is hosted by the olivine-rich ultramafic rock body, which is the thirdlargest magmatic sulfide Ni-Cu deposit in the world currently being exploited. Seeking new relaying resources in the deep and the border of the deposit becomes more and more important. The ore body, ore and geochemistry characteristics of the concealed Cu-rich ore body are researched. Through spatial analysis and comparison with the neighboring II1 main ore body, the mineralization rule of the concealed Cu-rich ore body is summed up. It is also implied that Cu-rich magma may exist between Nirich magma and ore pulp during liquation differentiation in deep-stage chambers, which derives from deep-mantle Hi-MgO basalt magma. It is concluded that the type of ore body has features of both magmatic liquation and late reconstruction action. It has experienced three stages： deep liquation and pulsatory injection of the Cu- and PPGE-rich magma, concentration of tectonic activation, and the later magma hydrothermal superimposition. In addition, the Pb and S isotopes indicate the magma of I6 concealed Cu-rich ore body originates predominantly from mantle; however, it is interfused by minute crust material. Finally, it is inferred that the genesis of the Cu-Ni sulfide deposit is complex and diverse, and the prospect of seeking new deep ore bodies within similar deposits is promising, especially Cu-rich ore bodies.

汉南杂岩余家山铜镍矿成矿时代与岩浆源区性质研究——来自锆石U-Pb测年和Lu-Hf同位素的制约

汉南杂岩余家山铜镍矿位于望江山基性岩体的西南部,地处扬子克拉通北缘西端。矿区内出露的岩体成岩成矿时代和源区性质不明,从而影响了对本矿床成因的认识。本文分析了矿区内出露的典型含矿岩体和围岩的LA-ICP-MS锆石U-Pb年代学和原位Lu-Hf同位素数据,结果表明其成矿时代接近或稍晚于约(791±4)Ma,成岩时代约为(808±7)Ma。且含矿岩体的εHf(t)值在+9.5^+10.9之间,平均值为+10.7,一阶段Hf模式年龄为924~974 Ma;围岩的εHf(t)值在+8.7^+11.1之间,平均值为+9.9,一阶段Hf模式年龄为927~1018 Ma。结合前人研究成果表明,余家山铜镍矿基性岩体由中元古代晚期至新元古代早期亏损地幔物质部分熔融生成,可能形成于活动大陆边缘环境。

Phase Equilibria Constraints on Relations of Ore-bearing Intrusions with Flood Basalts in the Panxi Region,Southwestern China

There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province （LIP）; namely, small ultramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element （PGE）-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis （Q-PI-OI-Opx-Cpx system） has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts （including high-Ti, low-Ti and alkali basalts）, respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and low-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limahe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basalts. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.

The Gaojiacun Mafic-Ultramafic Complex(Sichuan,SW China):Neoproterozoic Magmatic Activity at the Western Margin of the Yangtze Craton

The Neoproterozoic Gaojiacun intrusive complex （GIC） is composed of one big intrusion （ca. 9 × 7.5 km） and numerous satellite intrusions, emplaced in the low-grade schists of the Neoproterozoic Yanbian Group. The main intrusion is concentrically zoned, with peridotite bodies ＋ leucogabbroids in its core （inner zone） and the sequence： olivine hornblende gabbronorite - porphyric pyroxene hornblende gabbronorite （transitional zone） - pyroxene hornblende gabbronorite ＋ hornblende gabbro ＋ diorite （outer zone）, towards the margins. The satellite intrusions are composed either of a single rock type （peridotite, gabbro, diorite or granite） or of different rock types （peridotite ＋ diorite ＋ granite）. Upper crustal contamination is evidenced by the occurrence of numerous metamorphic enclaves, migmatites and mixed rocks in the outer zone of the main intrusion and in the satellite intrusions. Hornblende （often oikocrystic） is present in all mafic and ultramafic rocks. Cu-Ni （-PGE） deposits occur in several satellite intrusions, hosted in peridotite. The geochemical and mineralogical features of GIC support the presence of a subduction zone at the western edge of the Yangtze Craton. A feederrelated genesis of the satellite intrusions is inferred.

Mafic-ultramafic magma activity and copper-nickel sulfide metallogeny during Paleozoic in the Eastern Kunlun Orogenic Belt,Qinghai Province,China

The Eastern Kunlun Orogenic Belt(EKOB)has a complex geological structure and diverse magmatic activities,which are closely related to the Qaidam Basin and the Tethys tectonic evolution.There are at least 3 stages mafic-ultramafic rocks occurred in the Early Paleozoic in EKOB.The first stage is the Later-Silurian to Early Devonian,represented by the giant Xiarihamu super large magmatic Cu-Ni deposit,containing about 1.18 million metric tons(Mt)of nickel with average grades of 0.65%Ni,and its age of ore-forming pyroxene peridotite is 411 Ma;The second stage is the Early Carboniferous,represented by the large Shitoukengde magmatic Cu-Ni sulfide deposit,and its ore-forming age of the olivine websterite is 334 Ma;The third stage of mafic-ultramafic rocks occurred mainly during the Middle-Late Triassic,represented by Xiaojianshan,Lalinggaoli,and Kaimuqi complexes,and no economical ore bodies have been found in this period.The authors summarized the difference between the ore-bearing and the nonmineralized mafic-ultramafic rocks in the EKOB.The olivine of the ore-bearing complexes contains higher MgO and SiO2 content but lower FeO and CaO contents,and the clinopyroxene of ore-bearing complexes contains lower FeO and CaO contents.Crustal sulfur contamination is key to the formation of the giant Xiarihamu Ni deposit,and crustal sulfur contamination degree of the giant magmatic Ni deposit is higher than that of large Ni deposit.The above indicators could guide the exploration and evaluation of similar deposits in the EKOB.

Interfacial tension studies between Fe-Cu-Ni sulfide and halo-norilsk basalt slag system

The interfacial tension of the matte/halo-Norilsk basalt slag systems of FeS-Cu2S-Ni3S2 and FeO-FeS were investigated using the sessile drop technique. The results indicate that interfacial tension decreases with increasing copper and nickel contents in the matte of FeS-Cu2S-Ni3S2 system while it increases with increasing oxygen content in the matte of FeO-FeS system. It is inferred from these results that two conditions are critical for the formation of giant Cu-Ni sulfide deposits. One is that ma-fic-ultramafic parent magma of sulfide deposits should be rich in copper and nickel where due to the low interfacial tension, it is difficult to form sulfide droplet in the early stage of magma evolution. In other words, sulfide liquid conglomeration occurs more difficultly. The other condition is that the magma emplacement should be shallow; and a lot of faults occur in the magma emplacement field. Since oxygen content is high in the environment, interfacial tension is high, which helps sulfide liquid conglomeration and consequently Cu-Ni sulfide deposits form.