On the Thermal Fatigue of a Room-Cured Neat Epoxy and Its Composite

An experimental investigation is conducted to evaluate the potential degradation in the mechanical properties of an epoxy resin and unidirectional glass fiber-reinforced epoxy (GFRE) as a result of exposure to fluctuating temperature. A commonly used room-cured epoxy resin and the GFRE are subjected to various numbers of thermal cycles (up to 1000 heating/cooling cycles). Mechanical tests are conducted to examine the influence of thermal cycles on the stiffness, ultimate strength and strain of the resin and its GFRE. The Fourier transform-Raman spectroscopy (FT-Raman) is conducted to investigate the influence of the thermal cycles on the resulting chemical changes and curing degree of the resin. In addition, the Differential Scanning Calorimetry (DSC) analysis is conducted to investigate the variation in the glass transition temperature (Tg) of the resin as a function of the applied thermal cycles.

Preparation and mechanical properties of carbon/carbon composites with high textured pyrolytic carbon matrix

Short carbon fiber felts with an initial porosity of 89.5% were deposited by isobaric, isothermal chemical vapor infiltration using natural gas as carbon source. The bulk density of the deposited carbon/carbon （C/C） composites was 1.89 g/cm3 after depositing for 150 h. The microstructure and mechanical properties of the C/C composites were studied by polarized light microscopy, X-ray diffraction, scanning electron microscopy and three-point bending test. The results reveal that high textured pyrolytic carbon is deposited as the matrix of the composites, whose crystalline thickness and graphitization degree highly increase after heat treatment. A distinct decrease of the flexural strength and modulus accompanied by the increase of the toughness of the C/C composites is found to be correlated with the structural changes in the composites during the heat treatment process.

Investigation on the Factors Influencing the Synthesis of Butyl Polyglycosides and Its Synthesis Kinetics

[ Objective ] The paper was to study the factors influencing the synthesis of butyl polyglycosides and its synthesis kineties. [ Method ] In the synthesis process of alkyl polyglycosides by transglyeosidation method, p-toluenesulfonie acid and stearie acid were used as composite catalyst, intermediate product butyl polyglycosides was prepared via reactive distillation technology. [ Result ] The suitable preparation conditian of butyl polyglyeasides was as follows： catalyst usage, 1.2 g（ p-toluenesulfoni ：stearie acid = 6：1 ） ; reaction temperature, 110 ℃ ; the ratio of butanol and glucose, 8： 1. The results showed that the larger the molar ratio of butanol and glucose was,the more the butyl monoside content was, and the less the polymerizatian degree of butyl glyeasides was. The catalyst usage and reaction temperature had little influence on the component of butyl polyglyeesides. With the increase of catalyst usage or reaction temperature,the reaction time was shortened dramatically. The kinetic equation for the synthesis of butyl glueeside was finally obtained as follows： -dCA/dt =0.163 7exp（ -1. 968×10^3/RT）CA -0.003 49 exp （ -2.727×10^3/RT） Ce. [ Conclusionl The suitable condition for the preparation of butyl polyglyeasides and its synthesis kinetic equation obtained in the study could provide theoretical basis for the synthesis of long-chain alkyl polyglyeasides.

Bending stress of rolling element in elastic composite cylindrical roller bearing

A new structure design method of elastic composite cylindrical roller bearing is proposed, in which PTFE is embedded into a hollow cylindrical rolling element, according to the principle of creative combinations and through innovation research on cylindrical roller bearing structure. In order to systematically investigate the inner wall bending stress of the rolling element in elastic composite cylindrical roller bearing, finite element analysis on different elastic composite cylindrical rolling elements was conducted. The results show that, the bending stress of the elastic composite cylindrical rolling increases along with the increase of hollowness with the same filling material. The bending stress of the elastic composite cylindrical rolling element decreases along with the increase of the elasticity modulus of the material under the same physical dimension. Under the same load, on hollow cylindrical rolling element, the maximum bending tensile stress values of the elastic composite cylindrical rolling element after material filling at 0° and 180° are 8.2% and 9.5%, respectively, lower than those of the deep cavity hollow cylindrical rolling element. In addition, the maximum bending-compressive stress value at 90° is decreased by 6.1%.

Consolidation analysis of composite foundation with partially penetrated cement fly-ash gravel(CFG) piles under changing permeable boundary conditions

Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the underlying untreated stratum. Due to the changing permeability property of CFG piles, the whole consolidation process of the composite ground with CFG piles was divided into two stages, i.e., the early stage(permeable CFG pile bodies) and the later stage(impermeable pile bodies). Then, the consolidation equation of the composite foundation with CFG piles was established by using the Terzaghi one-dimensional consolidation theory. Consequently, the unified formula to calculate the excess pore water pressure was derived with the specific solutions for the consolidation degree of composite ground, reinforced area and underlying stratum under instant load obtained respectively. Finally, combined with a numerical example, influencing rules by main factors(including the replacement rate m, the treatment depth h1, the permeability coefficient Ks1, Kv2 and compression modulus Es1, Es2 of reinforced area and underlying stratum) on the consolidation property of composite ground with CFG piles were discussed in detail. The result shows that the consolidation velocity of underlying stratum is slower than that of the reinforced area. However, the consolidation velocity of underlying stratum is slow at first then fast as a result of the transferring of effective stress to the underlying stratum during the dissipating process of excess pore water pressure.

Raman spectroscopy investigation of structural and textural change in C/C composites during braking

The microstructure and texture of C/C composites with a resin-derived carbon, a rough laminar （RL） pyrocarbon and a smooth laminar pyrocarbon, before and after braking tests, were investigated by Raman spectroscopy. The full width at half maximum （FWHM） of the D-band indicates the amount of defects in the in-plane lattice, while the G-to-D band intensity （peak area） ratios （lC/ID） is used to evaluate the degree of graphitization. The results show that the FWHM of D-band of sample with RL pyrocarbon changes greatly from 36 cm-1 to 168 cm 1 after braking tests, which indicates that a large number of lattice defects are produced on its wear surface. However, the graphitization degree of resin-derived carbon sample rises significantly, because the IC/1D increases from 0.427 to 0.928. Braking tests under normal loading conditions, involving high temperature and high pressure, produce a lot of lattice defects on the wear surface, and induce the graphitization of the surface. Sample with RL pyrocarbon having a low hardness is easy to deform, and has the most lattice defects on the wear surface after braking. While raw materials with resin-derived carbon have the lowest graphitization degree which rises greatly during braking.

Analysis of Hydration Mechanism and Microstructure of Composite Cementitious Materials for Filling Mining

To obtain the compositions and microstructure of hydration products of cementitious material in different hydration ages and its growth law of filling strength, the optimal proportion of composite cementitious material was determined according to the chemical composition of cement clinker which was composed of the Portland cement 32.5R, CSA 42.5 sulphoaluminate cement and two gypsum（CS）. The characterization of composite cementitious materials in different hydration ages was conducted by NMR, XRD and SEM techniques. The mechanism of hydration was explored. It is shown that the compressive strength of the test block increases gradually with the increase of hydration age. The microstructure of composite cementitious material can be changed from Al-O octahedron into Al-O tetrahedron in the hydration process. The hydrated alkali alumi niumsilicate formed with Si-O tetrahedron and Al-O tetrahedron. The degree of polymerization of Si-O tetrahedron gradually increased, and the structural strength of cementitious materials continued to increase. The diffraction peak of clinker minerals gradually decreased with the extension of hydration age. The CaSO4 completely hydrated to produce Aft during hydration which resulted in high early strength of cementitious material. The early hydration product of composite cementitious materials was Aft with a needle bar structure. The main middle and last hydration products were CSH gel and CH gel with dense prismatic shape. The microscopic pore of composite cementitious material gradually decreased and improved the later strength of filling block. The strong support was provided for mined-out area.

Effects of curing age on compressive and tensile stress-strain behaviors of ecological high ductility cementitious composites

To obtain the design parameters of the structure made by ecological high ductility cementitious composites(Eco-HDCC),the effects of curing age on the compressive and tensile stress-strain relationships were studied.The reaction degree of fly ash,non-evaporable water content and the pH value in pore solution were calculated to reveal the mechanical property.The results indicate that as the curing age increases,the peak compressive strength,peak compressive strain and ultimate tensile strength of Eco-HDCC increase.However,the ultimate compressive strain and ultimate tensile strain of Eco-HDCC decrease with the increase in curing age.Besides,as the curing age increases,the reaction degree of fly ash and non-evaporable water content in Eco-HDCC increase,while the pH value in the pore solution of Eco-HDCC decreases.Finally,the simplified compressive and tensile stress-strain constitutive relationship models of Eco-HDCC with a curing age of 28 d were suggested for the structure design safety.

Rapid chemical vapor infiltration of C/C composites

With liquid petrol gas(LPG)as carbon source,carbon felt as porous perform and hydrogen as diluent,C/C composites were fast fabricated by using a multi-physics field chemical vapor infiltration(MFCVI)process in a self-made furnace.A set of orthogonal experiments were carried out to optimize parameters in terms of indices of density and graphitization degree.The results show the optimal indices can be achieved under the conditions of temperature 650℃,LPGconcentration 80%,gas flux 60 mL/s, total pressure 20 kPa,infiltration time 15 h.The verification experiment proves the effectiveness of the orthogonal experiments. Under the optimal conditions,the graphitization degree of 75%and bulk density of 1.69 g/cm are achieved with a uniform density distribution.At the same time,a new structure is obtained.

Three vertex degree correlations of fixed act-size collaboration networks

A rate equation approach was presented for the exact computation of the three vertex degree correlations of the fixed act-size collaboration networks.Measurements of the three vertex degree correlations were based on a rate equation in the continuous degree and time approximation for the average degree of the nearest neighbors of vertices of degree k,with an appropriate boundary condition.The rate equation proposed can be generalized in more sophisticated growing network models,and also extended to deal with related correlation measurements.Finally,in order to check the theoretical prediction,a numerical example was solved to demonstrate the performance of the degree correlation function.

Toward a more open and collaborative climate change policy framework in Hong Kong and Macao within the Guangdong-Hong Kong-Macao Greater Bay Area

The special administrative regions of Hong Kong and Macao enjoy a high degree of autonomy from the national policy system in devising their local policies,including measures related to climate change.Hong Kong and Macao each have their own climate change policies,some aspects of which are more advanced than policies in China's Mainland.While their high degree of policy autonomy has advantages,this has also isolated them from China's larger environmental management and practices that continue to advance at scale.This paper reviews the climate change policies of the two special administrative regions and analyzes their strengths and innovations,particularly in adaptation.It also identifies areas where there could be closer engagement,collaboration,and capacity-building with the China's Mainland,which has the potential for greater positive impacts,especially on a regional basis.

含初始损伤饱水花岗岩的冲击破坏规律

为研究饱水和初始损伤对冲击荷载下花岗岩宏观和微观破坏特征的影响,开展了X射线衍射、霍普金森和扫描电镜试验,利用分形维数对花岗岩的破碎块度和断口形貌进行了分析,探讨了图像放大倍数对分形维数的影响,分析了冲击荷载下饱水后花岗岩的微观致裂机制。结果表明:饱水后花岗岩中角闪石、钠长石、微斜长石和石英的占比减少,高岭石占比显著提高;随着初始损伤的增大,花岗岩的动态峰值应力逐渐减小,而破碎程度和块度分形维数逐渐增大,且初始损伤对块度分形维数的影响大于饱水的影响;随着初始损伤的增加,断口出现更多的微裂纹和碎屑,断口图像的分形维数也逐渐增加;放大倍数在400~3200范围内时,断口图像分形维数随着图像放大倍数的增大而增加,超过3200后,分形维数减小。

Multi-scale collaborative design method for macroscopic thermal optimization and mesoscopic woven structure of hypersonic vehicle's TOCMC leading edge

A new thermal protection design method for hypersonic vehicle's leading edge is proposed, which can effectively reduce temperature of the leading edge without additional cooling measures. This method reduces the leading-edge's temperature by the multi-scale collaborative design of the macroscopic thermal optimization and the mesoscopic woven structures of Three-dimensional Orthogonal Woven Ceramic Matrix Composites(TOCMC). The macroscopic thermal optimization is achieved by designing different mesoscopic woven structures in different regions to create combined heat transfer channels to dredge the heat. The combined heat transfer channel is macroscopically represented by the anisotropic thermal conductivity of TOCMC. The thermal optimization multiple linear regression model is established to optimize the heat transport channel, which predicts Theoretical Optimal Thermal Conductivity Configuration(TOTCC) in different regions to achieve the lowest leading-edge temperature. The function-oriented mesostructure design method is invented to design the corresponding mesostructure of TOCMC according to the TOTCC, which consists of universal thermal conductivity prediction formulas for TOCMC. These universal formulas are firstly derived based on the thermal resistance network method, which is verified by experiments with an error of 6.25%. The results show that the collaborative design method can effectively reduce the leading edge temperature by about 12.8% without adding cooling measures.

Atmospheric Deposition-Carried Pb, Zn, and Cd from a Zinc Smelter and Their Effect on Soil Microorganisms

Dust emissions from smelters, as a major contributor to heavy metal contamination in soils, could severely influence soil quality. Downwind surface soils within 1.5 km of a zinc smelter, which was active for 10 years but ceased in 2000, in Magu Town, Cuizhou Province, China were selected to examine Pb, Zn, and Cd concentrations and their fractionation along a distance gradient from a zinc smelter, and to study the possible effects of Pb, Zn, and Cd accumulation on soil microorganisms by comparing with a reference soil located at a downwind distance of 10 km from the zinc smelter. Soils within 1.5 km of the zinc smelter accumulated high levels of heavy metals Zn （508 mg kg^-1）, Pb （95.6 mg kg^-1）, and Cd （5.98 mg kg^-1） with low ratios of Zn/Cd （59.1-115） and Pb/Cd （12.4-23.4）. Composite pollution indices （CPIs） of surface soils （2.52-15.2） were 3 to 13 times higher than the reference soils. In metal accumulated soils, exchangeable plus carbonate-bound fractions accounted for more than 10% of the total Zn, Pb, and Cd. The saturation degree of metals （SDM） in soils within 1.5 km of the smelter （averaging 1.25） was six times higher than that of the reference soils （0.209）. A smaller soil microbial biomass was found more frequently in metal accumulated soils （85.1-438 μg C g^-1） than in reference soils （497 μg C g^-1）, and a negative correlation （P 〈 0.01） of soil microbial biomass carbon to organic carbon ratio （Cmic/Corg） with SDM was observed. Microbial consumption of carbon sources was more rapid in contaminated soils than in reference soils, and a shift in the substrate utilization pattern was apparent and was negatively correlated with SDM （R = -0.773, P 〈 0.01）. Consequently, dust deposited Pb, Zn, and Cd in soils from zinc smelting were readily mobilized, and were detrimental to soil quality mainly in respect of microbial biomass .

Bilateral Collaborative Optimization for Cloud Manufacturing Service

Manufacturing service composition of the supply side and scheduling of the demand side are two important components of Cloud Manufacturing,which directly affect the quality of Cloud Manufacturing services.However,the previous studies on the two components are carried out independently and thus ignoring the internal relations and mutual constraints.Considering the two components on both sides of the supply and the demand of Cloud Manufacturing services at the same time,a Bilateral Collaborative Optimization Model of Cloud Manufacturing(BCOM-CMfg)is constructed in this paper.In BCOM-CMfg,to solve the manufacturing service scheduling problem on the supply side,a new efficient manufacturing service scheduling strategy is proposed.Then,as the input of the service composition problem on the demand side,the scheduling strategy is used to build the BCOM-CMfg.Furthermore,the Cooperation Level(CPL)between services is added as an evaluation index in BCOM-CMfg,which reveals the importance of the relationship between services.To improve the quality of manufacturing services more comprehensively.Finally,a Self-adaptive Multi-objective Pigeon-inspired Optimization algorithm(S-MOPIO)is proposed to solve the BCOM-CMfg.Simulation results show that the BCOM-CMfg model has advantages in reliability and cost and S-MOPIO can solve BCOM-CMfg effectively.

An investigation of weed seed banks reveals similar potential weed community diversity among three different farmland types in Anhui Province, China

Crop type is one of main factors influencing weed community structure. However, the identity of weed communities associated with the cultivation of different crops in farmlands remains largely unclear. A field survey of weed seed banks was conducted in 2 280 fields at 228 sites of 62 locations representing three different types of farmland(95 paddy, 73 summer-ripe, and 60 autumn-ripe farmlands) along the bank of the Yangtze River in Anhui Province, China. A total of 43 families and 174 species of weeds were found in these weed seed banks. A comparison of the composition of weed groups in the seed banks showed that the species number and density percentage of grass, sedge and broadleaf weed groups were similar among the different types of farmland. The seed banks of all three farmland types shared 71 common weed species, accounting for 40.80% of the total number of species. These common weeds, which were both associated and not associated with crops, accounted for 91.71% of the total dominance degree among all farmland types. The crop-associated weed species were distributed in all soil layers of each farmland type. The Shannon-Wiener index H′(description of species diversity which is more sensitive to dense species) and Pielou's evenness index J(description of species evenness) in summer-ripe farmland were similar to those in autumn-ripe farmland but differed from those in paddy farmland. However, the Simpson's index D(description of species diversity which is more sensitive to sparse species) was similar among all three farmland types. The results of similarity comparison indicated that although the aboveground weed community differed among the different cropping patterns, the weed species composition in the soil seed bank was still similar. Consequently, our results demonstrate that after the implementation of long-term monoculture patterns, weed species compositions in the soil seed bank in different farmlands become homogenized regardless of the crop type.

Some Results on Generalized Degree Distance

In [1], Hamzeh, Iranmanesh and Hossein-Zadeh and M. V. Diudea recently introduced the generalized degree distance of graphs. In this paper, we present explicit formulas for this new graph invariant of the Cartesian product, composition, join, disjunction and symmetric difference of graphs and introduce generalized and modified generalized degree distance polynomials of graphs, such that their first derivatives at x = 1 are respectively, equal to the generalized degree distance and the modified generalized degree distance. These polynomials are related to Wiener-type invariant polynomial of graphs.

3D Simulation of Storm Surge Disaster Based on Scenario Analysis

The occurrence of storm surge disaster is often accompanied with floodplain, overflow, dike breach and other complex phenomena, while current studies on storm surge flooding are more concentrated on the 1D/2D numerical simulation of single disaster scenario(floodplain, overflow or dike breach), ignoring the composite effects of various phenomena. Therefore, considering the uncertainty in the disaster process of storm surge, scenario analysis was firstly proposed to identify the composite disaster scenario including multiple phenomena by analyzing key driving forces, building scenario matrix and deducing situation logic. Secondly, by combining the advantages of k-ω and k-ε models in the wall treatment, a shear stress transmission k-ω model coupled with VOF was proposed to simulate the 3D flood routing for storm surge disaster. Thirdly, risk degree was introduced to make the risk analysis of storm surge disaster. Finally, based on the scenario analysis, four scenarios with different storm surge intensity(100-year and 200-year frequency) were identified in Tianjin Binhai New Area. Then, 3D numerical simulation and risk map were made for the case.

基于比较研究的华中三省产业结构与低碳经济的关系分析

为了促进中部地区的崛起,实现经济低碳化发展与产业优化转型,研究产业结构与低碳经济之间的相互关系具有重要意义。论文以河南、湖北和湖南三省为研究对象,运用熵值-Topsis法对2007—2022年三省的产业结构与低碳经济指标进行综合测评,并基于脱钩理论与协同学理论,运用Tapio脱钩模型和复合系统协同度模型对2008—2022年三省各自的脱钩状态与协同效应演化进行科学分析。结果表明:(1)研究期内,华中三省的产业结构综合指数和低碳经济综合指数不断提高,整体发展趋势良好。(2)大多数年份三省都处于相对脱钩状态,产业结构综合指数增长速度低于低碳经济综合指数增长速度;湖北率先达到理想的扩张负脱钩状态,湖南次之。(3)2008—2022年三省的协同效应一直较弱,且都具有一定的波动性特征;整体来看,湖北的协同水平略高于河南和湖南。

以需求为导向的专业学位研究生协同培养机制优化研究——基于教育、科技、人才一体化的视角

深化专业学位研究生培养机制改革是新时代研究生教育分类发展的核心主题。本研究以教育、科技、人才一体化为视角,通过考察我国经济强省和教育大省的专业学位研究生教育发展,总结特点和经验,以期为全国专业学位研究生教育高质量发展提供实践经验。研究发现,专业学位研究生培养主要瓶颈是过度指标考核及学术导向,导致校企联合培养质量打折扣;行业企业参与联合培养成本高、供需错位,导致动力性不强;专业学位点及课程教学内容设置滞后,难以跟上生产实践需要;多元主体协同松散,治理机制不健全,导致难以支撑“有组织育人”。分类发展背景下专业学位研究生培养亟待服务于国家和区域发展战略需求,优化政校院企多元主体协同新机制,以教育为主体深化分类培养改革,以科技为支撑促进科教深度融合,以人才为支点强化人才能力导向,以产业为依托深化区域产教融合,以制度为保障优化多元主体组织架构,强化教育、科技、人才一体化的支撑作用,打造专业学位研究生教育高质量发展新局面。