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Effects of the Adjustment of Energy Structure on 24-h Average of NO_2 Concentration in Different Regions of Urumqi City in Winter
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作者 Nuorsaolie Jiang Wei 《Meteorological and Environmental Research》 CAS 2013年第5期26-29,共4页
[ Objective] The study aimed to discuss the effects of the adjustment of energy structure on daily average concentration of NO2 in different regions of Urumqi city in winter. [ Method] The changes of daily average con... [ Objective] The study aimed to discuss the effects of the adjustment of energy structure on daily average concentration of NO2 in different regions of Urumqi city in winter. [ Method] The changes of daily average concentration of NO2 in different areas of Urumqi City from January to February ( NO2 pollution was most serious) before and after the implementation of the project "changing coal to gas" were analyzed. [ Result] After the implementation of the project, daily average concentration of NO2 in different areas of Urumqi City was increased due to the rapid increase of ve- hicle quantity, but there were certain differences in the increase among various regions. From south to north, daily average concentration of NO2 in winter was decreased gradually, that is, daily average concentration of NO2 was the highest in the south area, while in the north area, it didn't change significantly before and after the implementation of the project, but it was still high. Therefore, the local government should pay more attention to pollution NO2 during environmental management process. [ Conclusion] The research could provide scientific references for the control of atmospheric pollution in future. 展开更多
关键词 Changing coal to gas vehicle exhaust Air pollution Spatial distribution NO2 concentration China
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Estimation of Total Emission of VOCs Discharged by Afforesting Vegetation and Its Impacts on Ozone Concentration in Nanjing
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作者 Chen Feng Yu Shuyue +7 位作者 Luo Wei Pei Yuxin Shen Shaohua Tang Jing Xu Shuyan Zhan Yintian Zeng Chen Zhu Weihan 《Meteorological and Environmental Research》 CAS 2016年第3期10-14,共5页
Based on Guenther light-temperature model , annual emission of VOCs discharged by plants in Nanjing was estimated, and the impacts of VOCs discharged by afforesting vegetation in the city on ozone concentration was an... Based on Guenther light-temperature model , annual emission of VOCs discharged by plants in Nanjing was estimated, and the impacts of VOCs discharged by afforesting vegetation in the city on ozone concentration was analyzed. The results show that annual emission of VOCs dis- charged by plants in Nanjing is about 0.004 9 Tg C. The annual emmisions of isoprene, monoterpene and other VOCs account for 18.0%, 25.9% and 56.1% of total emission of VOCs respectively. VOCs discharged by afforesting vegetation in Nanjing has the greatest impact on average con- centration of ozone in winter. 展开更多
关键词 Total emission of vocs Ozone concentration IMPACTS Guenther light-temperature model NANJinG China
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The Impact of Traffic Emission on Air Quality in an Urban Environment
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作者 Hesham A. Al-Jeelani 《Journal of Environmental Protection》 2013年第2期205-217,共13页
Study of the impact of traffic emissions on air quality around the Haram Mosque in Makkah, Saudi Arabia, was conducted experimentally, numerically and statistically. Experimental study was performed to measure existin... Study of the impact of traffic emissions on air quality around the Haram Mosque in Makkah, Saudi Arabia, was conducted experimentally, numerically and statistically. Experimental study was performed to measure existing air quality. Numerical study was done to model the extent of air movement and pollutant dispersion within and around the Haram area. Statistical study was conducted to determine correlation coefficients, auto-correlation and time lags of each pollutant. Pollutant measurements were carried out using an air quality mobile laboratory at three sites. Numerical calculations were made using an ISC-AERMOD dispersion model. Concentrations of traffic emissions including nitrogen dioxide (NO2), sulfur dioxide (SO2), carbon monoxide (CO), ozone (O3) and airborne particulate material under 10 μm diameter (PM10) are presented and analyzed. The calculated concentrations are validated by comparing with observed values at the three sites. The results indicate good agreement between calculated concentrations and observed values, which demonstrate satisfactory model performance. Results show that the Haram area is experiencing high concentrations of dust. High buildings around the Haram Mosque act as flow obstacles. Mean pollutant dispersion was toward the south and southeast during January and June. Highest mean concentrations were observed in January and June. 展开更多
关键词 Air Quality POLLUTANT concentration Field Experiment Power PLANT vehicle TRAFFIC
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结合大气污染特征的VOCs聚集区识别方法
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作者 陆秋琴 田园 黄光球 《重庆理工大学学报(自然科学)》 CAS 北大核心 2024年第3期308-317,共10页
为实现VOCs聚集区的精准感知识别,提出一种结合大气污染特征的VOCs聚集区识别方法。首先,划分区域网格,利用IDW空间插值方法得到VOCs网格数据集;其次,利用HYSPLIT计算后向气团运动轨迹并引入VGG提取轨迹特征,同数据集输入TCN-BiLSTM模型... 为实现VOCs聚集区的精准感知识别,提出一种结合大气污染特征的VOCs聚集区识别方法。首先,划分区域网格,利用IDW空间插值方法得到VOCs网格数据集;其次,利用HYSPLIT计算后向气团运动轨迹并引入VGG提取轨迹特征,同数据集输入TCN-BiLSTM模型,预测各网格VOCs浓度;最后,根据预测结果进行聚集区识别。以西安市碑林区为例,对VOCs浓度值进行预测,并将聚集区识别结果可视化。结果表明:该组合预测模型能够有效提高识别精度,VOCs浓度预测结果的MAE、MSE、RMSE、R2分别为6.657、103.657、10.181、0.976,预测效果优于对比模型。消融实验证明考虑气团污染特征能提高VOCs预测准确性,实现VOCs聚集区的精准感知识别。 展开更多
关键词 vocs聚集 污染区域识别 浓度预测 大气污染特征 深度学习
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Measurement of in-vehicle volatile organic compounds under static conditions 被引量:28
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作者 YOU Ke-wei GE Yun-shan +4 位作者 HU Bin NING Zhan-wu ZHAO Shou-tang ZHANG Yan-ni XIE Peng 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第10期1208-1213,共6页
The types and quantities of volatile organic compounds (VOCs) inside vehicles have been determined in one new vehicle and two old vehicles under static conditions using the Thermodesorber-Gas Chromatograph/Mass Spec... The types and quantities of volatile organic compounds (VOCs) inside vehicles have been determined in one new vehicle and two old vehicles under static conditions using the Thermodesorber-Gas Chromatograph/Mass Spectrometer (TD-GC/MS). Air sampling and analysis was conducted under the requirement of USEPA Method TO-17. A room-size, environment test chamber was utilized to provide stable and accurate control of the required environmental conditions (temperature, humidity, horizontal and vertical airflow velocity, and background VOCs concentration). Static vehicle testing demonstrated that although the amount of total volatile organic compounds (TVOC) detected within each vehicle was relatively distinct (4940 μg/m^3 in the new vehicle A, 1240 μg/m^3 in used vehicle B, and 132 μg/m^3 in used vehicle C), toluene, xylene, some aromatic compounds, and various C7-C12 alkanes were among the predominant VOC species in all three vehicles tested. In addition, tetramethyl succinonitrile, possibly derived from foam cushions was detected in vehicle B. The types and quantities of VOCs varied considerably according to various kinds of factors, such as, vehicle age, vehicle model, temperature, air exchange rate, and environment airflow velocity. For example, if the airflow velocity increases from 0.1 m/s to 0.7 m/s, the vehicle's air exchange rate increases from 0.15 h^-1 to 0.67 h^-1, and in-vehicle TVOC concentration decreases from 1780 to 1201 μg/m^3. 展开更多
关键词 volatile organic compounds vocs in-vehicle trim material static conditions
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Assessment of UAV Based Vegetation Indices for Nitrogen Concentration Estimation in Spring Wheat 被引量:2
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作者 Olga S. Walsh Sanaz Shafian +7 位作者 Juliet M. Marshall Chad Jackson Jordan R. McClintick-Chess Steven M. Blanscet Kristin Swoboda Craig Thompson Kelli M. Belmont Willow L. Walsh 《Advances in Remote Sensing》 2018年第2期71-90,共20页
Unmanned Aerial Vehicles (UAVs) have become increasingly popular in recent years for agricultural research. High spatial and temporal resolution images obtained with UAVs are ideal for many applications in agriculture... Unmanned Aerial Vehicles (UAVs) have become increasingly popular in recent years for agricultural research. High spatial and temporal resolution images obtained with UAVs are ideal for many applications in agriculture. The objective of this study was to evaluate the performance of vegetation indices (VIs) derived from UAV images for quantification of plant nitrogen (N) concentration of spring wheat, a major cereal crop worldwide. This study was conducted at three locations in Idaho, United States. A quadcopter UAV equipped with a red edge multispectral sensor was used to collect images during the 2016 growing season. Flight missions were successfully carried out at Feekes 5 and Feekes 10 growth stages of spring wheat. Plant samples were collected on the same days as UAV image data acquisition and were transferred to lab for N concentration analysis. Different VIs including Normalized Difference Vegetative Index (NDVI), Red Edge Normalized Difference Vegetation Index (NDVIred edge), Enhanced Vegetation Index 2 (EVI2), Red Edge Simple Ratio (SRred edge), Green Chlorophyll Index (CIgreen), Red Edge Chlorophyll Index (CIred edge), Medium Resolution Imaging Spectrometer (MERIS) Terrestrial Chlorophyll Index (MTCI) and Red Edge Triangular Vegetation Index (core only) (RTVIcore) were calculated for each flight event. At Feekes 5 growth stage, red edge and green based VIs showed higher correlation with plant N concentration compare to the red based VIs. At Feekes 10 growth stage, all calculated VIs showed high correlation with plant N concentration. Empirical relationships between VIs and plant N concentration were cross validated using test data sets for each growth stage. At Feekes 5, the plant N concentration estimated based on NDVIred edge showed one to one correlation with measured N concentration. At Feekes 10, the estimated and measured N concentration were highly correlated for all empirical models, but the model based on CIgreen was the only model that had a one to one correlation between estimated and measured plant N concentration. The observed high correlations between VIs derived from UAV and the plant N concentration suggests the significance of VIs deriving from UAVs for within-season N concentration monitoring of agricultural crops such as spring wheat. 展开更多
关键词 Unmanned AERIAL vehicleS and Systems (UAV) VEGETATION indices (VIs) Plant NITROGEN concentration
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湘潭市城区夏季VOCs光化学损耗特征及来源解析
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作者 何立志 谢诚 肖正辉 《环境科学与技术》 CAS CSCD 北大核心 2024年第3期101-110,共10页
挥发性有机物(VOCs)化学活性差异较大,如仅通过观测浓度开展VOCs来源解析将降低活性较强物种的贡献,不利于以缓解臭氧(O_(3))污染为目的的VOCs减排。为有效降低光化学损耗对于VOCs来源解析的影响,文章通过光化学老化方法估算湘潭市城区... 挥发性有机物(VOCs)化学活性差异较大,如仅通过观测浓度开展VOCs来源解析将降低活性较强物种的贡献,不利于以缓解臭氧(O_(3))污染为目的的VOCs减排。为有效降低光化学损耗对于VOCs来源解析的影响,文章通过光化学老化方法估算湘潭市城区夏季VOCs的初始浓度,矫正光化学损耗的影响,进而利用正交矩阵因子分解模型(PMF)开展VOCs来源解析研究。研究结果表明,观测期间湘潭市城区夏季VOCs平均观测浓度为(23.90±5.79)×10^(-9)(体积浓度,下同),初始浓度为(31.28±15.17)×10^(-9)。其中烯烃变化最大,是观测浓度的4.33倍,其次是芳香烃(1.87倍)。白天光化学平均总消耗量为14.66×10^(-9),以烯烃光化学消耗量为主,占总消耗量的70.7%。初始浓度、O_(3)和气温的日变化趋势基本一致,15时达到最大值,光化学损耗量也处于最大小时值(22.69×10^(-9))。O_(3)污染日烯烃和芳香烃光化学损失大于非污染日,烯烃和芳香烃的光化学损失是臭氧生成的重要来源。湘潭市城区夏季VOCs初始浓度PMF源解析结果显示工业源的贡献占比最高,观测浓度结果显示二次转化是最高的贡献源类。 展开更多
关键词 vocs 初始浓度 光化学损耗 来源解析
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VOCs监测技术及BP神经网络预测模型在船舶涂装车间的应用
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作者 韩立新 张耀元 《材料保护》 CAS CSCD 2024年第5期184-190,共7页
VOCs污染问题是我国环境保护遇到的最大问题之一。控制和减少VOCs的排放,既是日趋严格的环保标准的要求,也是建设船舶行业绿色生产体系的内在需求。不同环境下的VOCs监测,其内涵、监测项目、监测方法等存在差异又极易混淆。梳理了VOCs... VOCs污染问题是我国环境保护遇到的最大问题之一。控制和减少VOCs的排放,既是日趋严格的环保标准的要求,也是建设船舶行业绿色生产体系的内在需求。不同环境下的VOCs监测,其内涵、监测项目、监测方法等存在差异又极易混淆。梳理了VOCs监测和浓度分布的有关概念,结合某船厂涂装车间的具体工况,给出了船舶涂装车间排放VOCs的监测方案以及VOCs监测场景下的PID检测器技术应用和在线监测系统的构成,采用神经网络方法构建了监测点VOCs数据与涂装车间空间中任一点VOCs数据之间的关系模型,为实现互联互通绿色制造车间提供了数据支撑。 展开更多
关键词 vocs监测 船舶涂装车间 vocs浓度分布 PID检测器 BP神经网络
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嘉兴市大气VOCs特征及其对臭氧生成的影响研究
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作者 陈建挺 富英杰 熊传芳 《绿色科技》 2024年第6期104-110,共7页
为研究嘉兴市大气VOCs特征及其对臭氧生成的影响,采集了2022年1月、4月、7月和10月大气中114种VOCs物种,分析VOCs的浓度分布与组成特征,估算其臭氧生成潜势(OFP)。结果表明:嘉兴市大气VOCs平均体积浓度为38.74×10^(-9),OVOCs占比最... 为研究嘉兴市大气VOCs特征及其对臭氧生成的影响,采集了2022年1月、4月、7月和10月大气中114种VOCs物种,分析VOCs的浓度分布与组成特征,估算其臭氧生成潜势(OFP)。结果表明:嘉兴市大气VOCs平均体积浓度为38.74×10^(-9),OVOCs占比最高,各组分的体积浓度都在冬季呈现最高值。OPF均值为256.76μg/m^(3),芳香烃在各季节的OFP都最大,对OFP贡献最大的物种为甲苯、间/对—二甲苯、乙烯、丙烯、乙醛等,削减机动车排放和溶剂使用是嘉兴市控制O_(3)污染的关键。通过计算X/E(间/对—二甲苯和乙苯的体积浓度之比)和T/B(甲苯和苯的体积浓度之比),得出气团存在长距离传输现象,且受到溶剂挥发等VOCs排放源的影响更显著。 展开更多
关键词 vocs 臭氧 臭氧生成潜势 体积浓度 嘉兴市
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车内VOCs及气味的管控措施研究
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作者 吴峰 《汽车零部件》 2024年第3期90-93,102,共5页
车内空气质量近年来日益受到汽车行业和消费者的关注。概述了挥发性有机物(VOCs)和气味的区别和联系,以及其他国家关于VOCs的法规;分析讨论了VOCs在车辆、零部件、材料维度的管理方法,VOCs整车检测的数据一致性处理方法,整车VOCs限值目... 车内空气质量近年来日益受到汽车行业和消费者的关注。概述了挥发性有机物(VOCs)和气味的区别和联系,以及其他国家关于VOCs的法规;分析讨论了VOCs在车辆、零部件、材料维度的管理方法,VOCs整车检测的数据一致性处理方法,整车VOCs限值目标向零部件的分解。最后,提出了在生产环境、工艺等方面对VOCs和气味的管控措施。 展开更多
关键词 车内空气质量 vocs 新车异味 检测一致性 管控措施
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Deflection and stress of hollow CRCP slab under concentrated vehicle load 被引量:2
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作者 陈小兵 黄晓明 +1 位作者 丁建明 童金虎 《Journal of Southeast University(English Edition)》 EI CAS 2011年第2期213-216,共4页
Based on the equivalence principle of deflection and stress, the concentrated vehicle load which acts on the center of continuously reinforced concrete pavement (CRCP) is translated into the equivalent half-wave sin... Based on the equivalence principle of deflection and stress, the concentrated vehicle load which acts on the center of continuously reinforced concrete pavement (CRCP) is translated into the equivalent half-wave sine load by the Fourier transform. On the basis of this transform and the small deflection theory of elastic thin plates, the deflection and stress formulae of CRCP under the concentrated vehicle load with a hollow foundation are put forward. The sensitivity of parameters is analyzed. The results show that maximum deflection is directly proportional to the concentrated vehicle load and the slab width, and inversely proportional to the lateral bending stiffness and slab thickness. The effects of slab width and thickness are significant with regard to maximum deflection. Maximum stress is directly proportional to the concentrated vehicle load and the slab width as well as inversely proportional to slab thickness. The effect of slab thickness is significant with regard to maximum stress. According to the calculation results, the most effective measure to reduce maximum deflection and stress is to increase slab thickness. 展开更多
关键词 concentrated vehicle load equivalence principle half-wave sine load elastic thin plates hollow continuouslyreinforced concrete pavement slab deflection and stressformulae slab thickness
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基于K-CNN-BiLSTM的关联区域VOCs浓度时空关联预测 被引量:6
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作者 黄光球 王瑞泽 陆秋琴 《安全与环境学报》 CAS CSCD 北大核心 2023年第4期1336-1348,共13页
为了提升关联区域内VOCs浓度预测精度,基于深度学习理论构造了K-CNN-BiLSTM时空关联预测模型。同时,为了实现VOCs精细化治理,首先对研究区域进行了网格划分,采用IDW进行空间插值,计算整理得到VOCs的网格数据集。其次使用KNN算法计算空... 为了提升关联区域内VOCs浓度预测精度,基于深度学习理论构造了K-CNN-BiLSTM时空关联预测模型。同时,为了实现VOCs精细化治理,首先对研究区域进行了网格划分,采用IDW进行空间插值,计算整理得到VOCs的网格数据集。其次使用KNN算法计算空间相关性筛选得到空间相关矩阵,按照时序排列拼接成时空类图。然后将时空类图输入CNN模型中提取局部时空特征,最后将提取的时空特征送入双向LSTM中进行全局预测。以西安市某区为例,对VOCs浓度进行预测,并将预测结果进行时空分布可视化。结果表明:模型具备单步预测和多步预测能力,同时与CNN-BiLSTM、CNN-LSTM和LSTM相比考虑了VOCs浓度数据的时空关联性,预测精度更高;平均均方根误差(RMSE)、平均绝对值误差(MAE)和平均绝对百分比误差(MAPE)分别为6.352、5.442和10.252%,均优于对比模型。 展开更多
关键词 环境工程学 vocs浓度预测 KNN CNN-BiLSTM 时空关联
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基于SOF-FTIR的机场VOCs污染排放监测分析 被引量:3
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作者 韩昕 李相贤 +5 位作者 高闽光 魏秀丽 童晶晶 李胜 叶树彬 李妍 《量子电子学报》 CAS CSCD 北大核心 2019年第1期101-107,共7页
为了研究机场排放对环境大气的影响,在2014年12月10日到16日,采用掩日通量遥测傅里叶红外技术(SOF-FTIR)对北京首都国际机场的乙烯(C_2H_4)、己烷(C_6H_(14))和一氧化碳(CO)排放进行了研究.分析了三种组份的特征浓度值及其变化趋势,结... 为了研究机场排放对环境大气的影响,在2014年12月10日到16日,采用掩日通量遥测傅里叶红外技术(SOF-FTIR)对北京首都国际机场的乙烯(C_2H_4)、己烷(C_6H_(14))和一氧化碳(CO)排放进行了研究.分析了三种组份的特征浓度值及其变化趋势,结果表明三者的特征浓度值变化趋势上具有高度相关性;机场乙烯的平均柱浓度为13.18 ppm,己烷的平均柱浓度为97.82 ppm,一氧化碳的平均柱浓度为3065.56 ppm.通过结合国际民航组织发布的测量数据,得到该机场乙烯和己烷的排放量分别达到碳氢化合物排放总量的3.32%和66.96%.文章结果表明,掩日通量遥测FTIR技术与ICAO的数据具有较好的一致性,为评估飞机排放提供数据支撑. 展开更多
关键词 光谱学 Sof-FTIR 飞机尾气 特征浓度 挥发性有机物
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便携式气相色谱-质谱联用仪用于测定环境中VOCs的可靠性研究
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作者 李学辉 李亚飞 +2 位作者 于志强 马俊刚 陈希尧 《绿色科技》 2023年第22期102-108,共7页
针对环境空气中VOCs成分较复杂,现场采样后在实验室用大型仪器分析费时且成本高,同时也为满足环境监测系统对VOCs能实时监测的要求;采用便携式气相色谱-质谱联用仪分析了52种VOCs混合标气,从定性准确性、定量重复性、灵敏度、线性相关... 针对环境空气中VOCs成分较复杂,现场采样后在实验室用大型仪器分析费时且成本高,同时也为满足环境监测系统对VOCs能实时监测的要求;采用便携式气相色谱-质谱联用仪分析了52种VOCs混合标气,从定性准确性、定量重复性、灵敏度、线性相关性、色谱柱的温度控制稳定性、色谱柱程序升温重复性等方面进行了分析,试验结果表明:便携式气相色谱-质谱联用仪的技术指标满足国家相关计量法规中的要求,能很好地用于分析环境中不同浓度VOCs;便携式气相色谱-质谱联用仪可用于对环境中VOCs实时监测,为政府监管平台提供技术支持。 展开更多
关键词 便携式 定性准确性 定量重复性 灵敏度 线性 稳定性 vocs
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影响低温等离子体降解VOCs因素的研究进展 被引量:2
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作者 岳晓刚 米俊锋 杜胜男 《应用化工》 CAS CSCD 北大核心 2023年第3期898-903,共6页
随着生态环境越来越重要,由于挥发性有机物(VOCs)对人类健康和生存环境有着重大的影响,因此大气污染防治也变得十分重要。归纳了目前几种降解VOCs的技术及优缺点,包括冷凝技术、吸附技术、催化燃烧技术、光催化技术等。主要针对低温等... 随着生态环境越来越重要,由于挥发性有机物(VOCs)对人类健康和生存环境有着重大的影响,因此大气污染防治也变得十分重要。归纳了目前几种降解VOCs的技术及优缺点,包括冷凝技术、吸附技术、催化燃烧技术、光催化技术等。主要针对低温等离子体技术介绍其降解VOCs的技术原理,并对其影响因素进行了综述,突出了反应物初始浓度和电源参数对其影响的重要性。对低温等离子体技术未来发展方向进行了展望。 展开更多
关键词 vocs 初始浓度 相对湿度 电源参数 vocs成分 反应器参数
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机动车尾气VOCs排放特征及影响因素研究进展
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作者 高鑫 荆博宇 +2 位作者 吴琳 刘可欣 毛洪钧 《环境科学与技术》 CAS CSCD 北大核心 2023年第11期69-78,共10页
机动车尾气排放是城市大气挥发性有机物(VOCs)的重要来源之一,深入了解机动车尾气VOCs排放特征及其影响因素可以为其污染治理提供重要理论依据。台架试验和车载测试是研究尾气污染物排放特征的关键方法,该文主要综述了机动车尾气VOCs的... 机动车尾气排放是城市大气挥发性有机物(VOCs)的重要来源之一,深入了解机动车尾气VOCs排放特征及其影响因素可以为其污染治理提供重要理论依据。台架试验和车载测试是研究尾气污染物排放特征的关键方法,该文主要综述了机动车尾气VOCs的实验研究进展,阐述了不同测试方法下的机动车尾气VOCs排放特征,对比了不同研究得到的VOCs排放因子及组分特征,包括燃料与车辆类型、排放标准、运行工况、启动方式、累计行驶里程及燃油组分等不同因素对VOCs排放的影响,并提出OVOCs组分的分析测定、机动车驾驶行为减排和生物质燃料的应用是未来研究重点关注的方向。 展开更多
关键词 vocs 机动车尾气 排放因子 组分特征 影响因素
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Establishment and Evaluation of a Method for Analyzing Atmospheric Volatile Organic Compounds
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作者 孙扬 王跃思 +2 位作者 修天阳 王迎红 徐新 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2007年第4期679-687,共9页
An automated cumulative sampling system and a method that combines a two-step cryo-concentrated system and gas chromatography/mass spectrometry (CCS-GC/MS) are introduced. The method is evaluated by a set of special... An automated cumulative sampling system and a method that combines a two-step cryo-concentrated system and gas chromatography/mass spectrometry (CCS-GC/MS) are introduced. The method is evaluated by a set of special experiments and the results are presented. The lowest measurement detection limit was expanded from 10^-6 nmol mol^-1 to 10^-12 nmol mol^-1 by using CCS-GC/MS instead of the simpler method of gas chromatography/mass spectrometry (GC/MS), with the average responsible factor of 39 object compounds being 2.9 × 10^-12. When the volume of air sample reached 1000 cm^3, the lowest detection limit reached up to 7 × 10^-12-40 × 10^-12 nmol mol^-1. The CCS-GC/MS method can potentially identify all objective chemical species in an atmospheric sample, with an average 2.5 s bias error of retention time for 39 gas chromatography (GC) peaks. Within the range 0-400×10^-9 nmol mol^-1, the concentration of 39 kinds of objective compounds can be individually calculated very accurately by a standard curve [average r^2 (coefficient of determination) value of above 0.99]. The recovery efficiency was 88%-111%, with an average of 100.8% ±5.6%. The bias error of precision was 2%-14%, with an average of 6.6%. 展开更多
关键词 ATMOSPHERE cryo-concentration volatile organic compounds vocs EVALUATION bias error
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求解装卸油中VOCs排放量的离散差分进化算法
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作者 梁颖 白云云 +1 位作者 高绪春 刘洁莹 《计算机与数字工程》 2023年第11期2505-2510,2514,共7页
针对油罐装卸油作业过程中VOCs的排放量难以测算的问题,以油气扩散分布机理与罐体呼气理论为基础,使用空间与时间的离散化的数值方法,用有限差分进化方法求解摩尔流扩散方程、气体动量方程,依照液面处与罐顶的特殊边界条件,建立实时监... 针对油罐装卸油作业过程中VOCs的排放量难以测算的问题,以油气扩散分布机理与罐体呼气理论为基础,使用空间与时间的离散化的数值方法,用有限差分进化方法求解摩尔流扩散方程、气体动量方程,依照液面处与罐顶的特殊边界条件,建立实时监测算法模型。判断算法的稳定性,并对全过程进行程序开发简化计算过程。经现场实验表明,该算法的结果与以往经验公式相比可降低误差达76.1%。 展开更多
关键词 离散差分 装卸油 vocs 模型 浓度
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固定污染源烟气排放VOCs自动监测方法研究 被引量:1
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作者 王昕 《环境科学与管理》 CAS 2023年第5期141-145,共5页
大气污染威胁人类生命健康,且固定污染源烟气排放VOCs监测性能过差,为了合理防控大气污染,提出固定污染源烟气排放VOCs自动监测方法。分析固定污染源VOCs监测管理现状,了解监测固定污染源VOCs的重要性,并以低温浓缩-气相色谱/质谱法为例... 大气污染威胁人类生命健康,且固定污染源烟气排放VOCs监测性能过差,为了合理防控大气污染,提出固定污染源烟气排放VOCs自动监测方法。分析固定污染源VOCs监测管理现状,了解监测固定污染源VOCs的重要性,并以低温浓缩-气相色谱/质谱法为例,从选择仪器与试剂和优化液氮低温浓缩两方面入手,验证固定污染源VOCs混合标气在冷凝状态下的监测效果。实验结果表明,固定污染源VOCs混合标气中各废气挥发性有机物的监测率均不低于95%,低温浓缩-气相色谱/质谱法对固定污染源烟气排放VOCs的监测性能较强。 展开更多
关键词 vocs 挥发性有机物 低温浓缩-气相色谱/质谱法 液氮低温浓缩 线性回归
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湿度对低浓度VOCs活性炭吸附影响的研究
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作者 李善淇 羌宁 《中国环保产业》 2023年第11期69-74,共6页
以甲苯为目标污染物,通过测定不同温度和湿度条件下活性炭吸附平衡线,研究不同浓度甲苯气体在不同湿度和温度条件下吸附容量的变化情况,进而梳理出可更直观反映湿度、温度对吸附容量影响的表征方式并研究了待吸附气体调温、调湿参数优... 以甲苯为目标污染物,通过测定不同温度和湿度条件下活性炭吸附平衡线,研究不同浓度甲苯气体在不同湿度和温度条件下吸附容量的变化情况,进而梳理出可更直观反映湿度、温度对吸附容量影响的表征方式并研究了待吸附气体调温、调湿参数优化的方法。结果表明,总体而言,水蒸气对VOCs吸附具有抑制作用;气相浓度越低,吸附容量受湿度的影响越大;对于含湿量较高的有机气体,提高吸附温度有利于保持吸附容量;采用绝对湿度与吸附容量的关系图能更直观地表示湿度、温度对吸附容量的影响,有利于确定待吸附气体的调温、调湿预处理工艺的目标参数。 展开更多
关键词 低浓度vocs 温度 湿度 吸附容量 影响程度表征方式
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