Formation,evolution,reconstruction of black shales and their influence on shale oil and gas resource

Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.

Geochemical prerequisites for the formation of oil and gas accumulation zones in the South Turgay basin,Kazakhstan

This study predicts favorable oil and gas source-rock formation conditions in the Aryskum Depression of the South Turgay Basin,Kazakhstan.This study assesses the thermal maturity and characteristics of organic matter by determining its environmental conditions using data from geochemical analysis of core(pyrolysis)and oil(biomarkers and carbon isotopic compositions)samples.According to the geochemical parameters obtained by pyrolysis,the oil generation potential of the original rocks of most studied samples varies from poor to rich.The facies–genetic organic matter is predominantly humic and less frequently humus–sapropel,indicating organic matter accumulation in the studied samples were under moderately reducing conditions(kerogenⅢand Ⅱ types)and coastal–marine environments(kerogen typeⅠ).The carbon isotopic compositions of oils derived from the Jurassic deposits of the Aryskum Depression also indicate the sapropelic and mixed humic–sapropelic type of organic matter(kerogenⅡandⅠ).Biomarker analysis of oils indicates original organic matter formation in an anoxic environment.

Stress corrosion cracking behavior of buried oil and gas pipeline steel under the coexistence of magnetic field and sulfate-reducing bacteria

Magnetic field and microorganisms are important factors influencing the stress corrosion cracking(SCC)of buried oil and gas pipelines. Once SCC occurs in buried pipelines, it will cause serious hazards to the soil environment. The SCC behavior of X80 pipeline steel under the magnetic field and sulfate-reducing bacteria(SRB) environment was investigated by immersion tests, electrochemical tests, and slow strain rate tensile(SSRT) tests. The results showed that the corrosion and SCC sensitivity of X80 steel decreased with increasing the magnetic field strength in the sterile environment. The SCC sensitivity was higher in the biotic environment inoculated with SRB, but it also decreased with increasing magnetic field strength, which was due to the magnetic field reduces microbial activity and promotes the formation of dense film layer. This work provided theoretical guidance on the prevention of SCC in pipeline steel under magnetic field and SRB coexistence.

Risk assessment of oil and gas investment environment in countries along the Belt and Road Initiative

With the implementation of the Belt and Road Initiative, China is deepening its cooperation in oil and gas resources with countries along the Initiative. In order to better mitigate risks and enhance the safety of investments, it is of significant importance to research the oil and gas investment environment in these countries for China's overseas investment macro-layout. This paper proposes an indicator system including 27 indicators from 6 dimensions. On this basis, game theory models combined with global entropy method and analytic hierarchy process are applied to determine the combined weights, and the TOPSIS-GRA model is utilized to assess the risks of oil and gas investment in 76 countries along the Initiative from 2014 to 2021. Finally, the GM(1,1) model is employed to predict risk values for 2022-2025. In conclusion, oil and gas resources and political factors have the greatest impact on investment environment risk, and 12 countries with greater investment potential are selected through cluster analysis in conjunction with the predicted results. The research findings may provide scientific decisionmaking recommendations for the Chinese government and oil enterprises to strengthen oil and gas investment cooperation with countries along the Belt and Road Initiative.

Miscibility of light oil and flue gas under thermal action

The miscibility of flue gas and different types of light oils is investigated through slender-tube miscible displacement experiment at high temperature and high pressure.Under the conditions of high temperature and high pressure,the miscible displacement of flue gas and light oil is possible.At the same temperature,there is a linear relationship between oil displacement efficiency and pressure.At the same pressure,the oil displacement efficiency increases gently and then rapidly to more than 90% to achieve miscible displacement with the increase of temperature.The rapid increase of oil displacement efficiency is closely related to the process that the light components of oil transit in phase state due to distillation with the rise of temperature.Moreover,at the same pressure,the lighter the oil,the lower the minimum miscibility temperature between flue gas and oil,which allows easier miscibility and ultimately better performance of thermal miscible flooding by air injection.The miscibility between flue gas and light oil at high temperature and high pressure is more typically characterized by phase transition at high temperature in supercritical state,and it is different from the contact extraction miscibility of CO_(2) under conventional high pressure conditions.

Discovery and inspiration of large-and medium-sized glutenite-rich oil and gas fields in the eastern South China Sea:An example from Paleogene Enping Formation in Huizhou 26 subsag,Pearl River Mouth Basin

Based on the practice of oil and gas exploration in the Huizhou Sag of the Pearl River Mouth Basin,the geochemical indexes of source rocks were measured,the reservoir development morphology was restored,the rocks and minerals were characterized microscopically,the measured trap sealing indexes were compared,the biomarker compounds of crude oil were extracted,the genesis of condensate gas was identified,and the reservoir-forming conditions were examined.On this basis,the Paleogene Enping Formation in the Huizhou 26 subsag was systematically analyzed for the potential of oil and gas resources,the development characteristics of large-scale high-quality conglomerate reservoirs,the trapping effectiveness of faults,the hydrocarbon migration and accumulation model,and the formation conditions and exploration targets of large-and medium-sized glutenite-rich oil and gas fields.The research results were obtained in four aspects.First,the Paleogene Wenchang Formation in the Huizhou 26 subsag develops extensive and thick high-quality source rocks of semi-deep to deep lacustrine subfacies,which have typical hydrocarbon expulsion characteristics of"great oil generation in the early stage and huge gas expulsion in the late stage",providing a sufficient material basis for hydrocarbon accumulation in the Enping Formation.Second,under the joint control of the steep slope zone and transition zone of the fault within the sag,the large-scale near-source glutenite reservoirs are highly heterogeneous,with the development scale dominated hierarchically by three factors(favorable facies zone,particle component,and microfracture).The(subaqueous)distributary channels near the fault system,with equal grains,a low mud content(<5%),and a high content of feldspar composition,are conducive to the development of sweet spot reservoirs.Third,the strike-slip pressurization trap covered by stable lake flooding mudstone is a necessary condition for oil and gas preservation,and the NE and nearly EW faults obliquely to the principal stress have the best control on traps.Fourth,the spatiotemporal configuration of high-quality source rocks,fault transport/sealing,and glutenite reservoirs controls the degree of hydrocarbon enrichment.From top to bottom,three hydrocarbon accumulation units,i.e.low-fill zone,transition zone,and high-fill zone,are recognized.The main area of the channel in the nearly pressurized source-connecting fault zone is favorable for large-scale hydrocarbon enrichment.The research results suggest a new direction for the exploration of large-scale glutenite-rich reservoirs in the Enping Formation of the Pearl River Mouth Basin,and present a major breakthrough in oil and gas exploration.

Influence of lithospheric thickness distribution on oil and gas basins,China seas and adjacent areas

The distribution of oil and gas resources is intricately connected to the underlying structure of the lithosphere.Therefore,investigating the characteristics of lithospheric thickness and its correlation with oil and gas basins is highly important.This research utilizes recently enhanced geological–geophysical data,including topographic,geoid,rock layer thickness,variable rock layer density,and interface depth data.Employing the principles of lithospheric isostasy and heat conduction,we compute the laterally varying lithospheric thickness in the China seas and adjacent areas.From these results,two pivotal parameters for different types of oil and gas basins were statistically analyzed:the minimum lithospheric thickness and the relative fluctuation in lithospheric thickness.A semiquantitative analysis was used to explore the connection between these parameters and the hydrocarbon abundance within the oil and gas basins.This study unveils distinct variations in lithospheric thickness among basins,with oil and gas rich basins exhibiting a thicker lithosphere in the superimposed basins of central China and a thinner lithosphere in the rift basins of eastern China.Notably,the relative fluctuations in lithospheric thickness in basins demonstrate significant disparities:basins rich in oil and gas often exhibit greater thickness fluctuations.Additionally,in the offshore basins of China,a conspicuous negative linear correlation is observed between the minimum lithospheric thickness and the relative fluctuation in lithospheric thickness.This study posits that deep-seated thermal upwelling results in lithospheric undulations and extensional thinning in oil and gas basins.Concurrently,sustained deep-seated heat influences sedimentary materials in basins,creating favorable conditions for oil and gas generation.The insights derived from this study contribute to a quantitative understanding of the intricate relationships between deep lithospheric structures and oil and gas basins.These findings provide valuable guidance for future oil and gas exploration in the studied areas.

Energy Saving Analysis of Coal Gas Resource Utilization in Iron and Steel Enterprises

The article discusses the preparation of a gas balance sheet,as well as the recovery,storage,transporta-tion,and use of gas.An analysis was conducted on the occurrence and consumption quotas of various gas media,and specific energy-saving measures were elaborated for each process.This provides a theoretical reference for saving gas and reducing energy consumption in steel enterprises.

Evaluation of the oil and gas preservation conditions, source rocks, and hydrocarbongenerating potential of the Qiangtang Basin: New evidence from the scientific drilling project

The Qiangtang Basin of the Tibetan Plateau,located in the eastern Tethys tectonic domain,is the largest new marine petroliferous region for exploration in China.The scientific drilling project consisting primarily of well QK-1 and its supporting shallow boreholes for geological surveys(also referred to as the Project)completed in recent years contributes to a series of new discoveries and insights into the oil and gas preservation conditions and source rock evaluation of the Qiangtang Basin.These findings differ from previous views that the Qiangtang Basin has poor oil and gas preservation conditions and lacks high-quality source rocks.As revealed by well QK-1 and its supporting shallow boreholes in the Project,the Qiangtang Basin hosts two sets of high-quality regional seals,namely an anhydrite layer in the Quemo Co Formation and the gypsum-bearing mudstones in the Xiali Formation.Moreover,the Qiangtang Basin has favorable oil and gas preservation conditions,as verified by the comprehensive study of the sealing capacity of seals,basin structure,tectonic uplift,magmatic activity,and groundwater motion.Furthermore,the shallow boreholes have also revealed that the Qiangtang Basin has high-quality hydrocarbon source rocks in the Upper Triassic Bagong Formation,which are thick and widely distributed according to the geological and geophysical data.In addition,the petroleum geological conditions,such as the type,abundance,and thermal evolution of organic matter,indicate that the Qiangtang Basin has great hydrocarbon-generating potential.

Influence of the Moho surface distribution on the oil and gas basins in China seas and adjacent areas

Owing to the strategic significance of national oil and gas resources,their exploration and production must be prioritized in China.Oil and gas resources are closely related to deep crustal structures,and Moho characteristics influence oil and gas distribution.Therefore,it is important to study the relationship between the variation of the Moho surface depth undulation and hydrocarbon basins for the future prediction of their locations.The Moho depth in the study area can be inverted using the Moho depth control information,the Moho gravity anomaly,and the variable density distribution calculated by the infinite plate.Based on these results,the influences of Moho characteristics on petroleum basins were studied.We found that the Moho surface depth undulation deviation and crustal thickness undulation deviation in the hydrocarbon-rich basins are large,and the horizontal gradient deviation of the Moho surface shows a positive linear relationship with oil and gas resources in the basin.The oil-bearing mechanism of the Moho basin is further discussed herein.The Moho uplift area and the slope zone correspond to the distribution of oil and gas fields.The tensile stress produced by the Moho uplift can form tensile fractures or cause tensile fractures on the surface,further developing into a fault or depression basin that receives deposits.The organic matter can become oil and natural gas under suitable chemical and structural conditions.Under the action of groundwater or other dynamic forces,oil and natural gas are gradually transported to the uplift or the buried hill in the depression zone,and oil and gas fields are formed under the condition of good caprock.The research results can provide new insights into the relationship between deep structures and oil and gas basins as well as assist in the strategic planning of oil and gas exploration activities.

The gradual subduction-collision evolution model of Proto-South China Sea and its control on oil and gas

This study involved outcrop,drilling,seismic,gravity,and magnetic data to systematically document the geological records of the subduction process of Proto-South China Sea(PSCS)and establish its evolution model.The results indicate that a series of arc-shaped ophiolite belts and calcalkaline magmatic rocks are developed in northern Borneo,both of which have the characteristics of gradually changing younger from west to east,and are direct signs of subduction and collision of PSCS.At the same time,the subduction of PSCS led to the formation of three accretion zones from the south to the north in Borneo,the Kuching belt,Sibu belt,and Miri belt.The sedimentary formation of northern Borneo is characterized by a three-layer structure,with the oceanic basement at the bottom,overlying the deep-sea flysch deposits of the Rajang–Crocker group,and the molasse sedimentary sequence that is dominated by river-delta and shallow marine facies at the top,recording the whole subduction–collision–orogeny process of PSCS.Further,seismic reflection and tomography also confirmed the subduction and collision of PSCS.Based on the geological records of the subduction and collision of PSCS,combined with the comprehensive analysis of segmented expansion and key tectonic events in the South China Sea,we establish the“gradual”subduction-collision evolution model of PSCS.During the late Eocene to middle Miocene,the Zengmu,Nansha,and Liyue–Palawan blocks were separated by West Baram Line and Balabac Fault,which collided with the Borneo block and Kagayan Ridge successively from the west to the east,forming several foreland basin systems,and PSCS subducted and closed from the west to the east.The subduction and extinction of PSCS controlled the oil and gas distribution pattern of southern South China Sea(SSCS)mainly in three aspects.First,the“gradual”closure process of PSCS led to the continuous development of many large deltas in SSCS.Second,the deltas formed during the subduction–collision of PSCS controlled the development of source rocks in the basins of SSCS.Macroscopically,the distribution and scale of deltas controlled the distribution and scale of source rocks,forming two types of source rocks,namely,coal measures and terrestrial marine facies.Microscopically,the difference of terrestrial higher plants carried by the delta controlled the proportion of macerals of source rocks.Third,the difference of source rocks mainly controlled the distribution pattern of oil and gas in SSCS.Meanwhile,the difference in the scale of source rocks mainly controlled the difference in the amount of oil and gas discoveries,resulting in a huge amount of oil and gas discoveries in the basin of SSCS.Meanwhile,the difference of macerals of source rocks mainly controlled the difference of oil and gas generation,forming the oil and gas distribution pattern of“nearshore oil and far-shore gas”.

Analysis of the world deepwater oil and gas exploration situation

The global trends in deepwater oil and gas exploration,characteristics of deepwater oil and gas discovery,and layout of deepwater oil and gas exploration business by seven major international oil companies are systematically analyzed using commercial databases(e.g.S&P Global and Rystad)and public information of oil companies.The deepwater area is currently the most important domain for global oil and gas exploration and discovery,with the most discoveries and reserves in passive continental margin basins.The deepwater discoveries have the greatest contribution to the total newly discovered oil and gas reserves in the sea areas,with an increasing number of lithological reservoirs discovered,and oil and gas discoveries mainly distributed in the Mesozoic–Cenozoic.The seven major international oil companies are widely active in various aspects of deepwater oil and gas exploration and development,and play a leading role.Based on years of theoretical understanding of global oil and gas geology and resource evaluation,it is proposed that favorable deepwater exploration areas in the future will mainly focus on three major areas:the Atlantic coast,the Indian Ocean periphery,and the Arctic Ocean periphery.Six suggestions are put forward for expanding overseas deepwater oil and gas exploration business:first,expand the sources for obtaining multi-user seismic data and improve the scientific selection of deepwater exploration areas;second,increase efforts to obtain deepwater exploration projects in key areas;third,adopt various methods to access into/exit from resource licenses flexibly;fourth,acquire licenses with large equity and operate in“dual-exploration”model;fifth,strengthen cooperation with leading international oil companies in deepwater technology;and sixth,improve business operation capabilities and gradually transform from“non-operators”to“operators”.

Quantitative research of the liquid film characteristics in upward vertical gas, oil and water flows

The study of liquid film characteristics in multiphase flow is a very important research topic, however,the characteristics of the liquid film around Taylor bubble structure in gas, oil and water three-phase flow are not clear. In the present study, a novel liquid film sensor is applied to measure the distributed signals of the liquid film in three-phase flow. Based on the liquid film signals, the liquid film characteristics including the structural characteristics and the nonlinear dynamics characteristics in three-phase flows are investigated for the first time. The structural characteristics including the proportion, the appearance frequency and the thickness of the liquid film are obtained and the influences of the liquid and gas superficial velocities and the oil content on them are investigated. To investigate the nonlinear dynamics characteristics of the liquid film with the changing flow conditions, the entropy analysis is introduced to successfully uncover and quantify the dynamic complexity of the liquid film behavior.

The accumulation characteristics and exploration potential of oil and gas in the back-arc basin of Japan under the background of high heat flow

The Sea of Japan is located in the southeast margin of Eurasia, in the triangle area of the western Pacific Ocean. Due to the interaction of the Pacific plate, Eurasian plate and Philippine plate, its tectonic environment is complex, forming a typical trench-arc-basin system. At present, 148 oil and gas fields have been discovered in Japan, with an oil and gas resource of 255.78×10^(6) t, showing a good prospect for oil and gas exploration. Based on the previous research and the recently collected geological and geophysical data, the characteristics of tectonic-sedimentary evolution and geothermal field in the basins around the Sea of Japan are analyzed. The results show that the tectonic evolution of the basin is mainly controlled by plate subduction and back-arc oceanic crust expansion, and it mainly undergone four tectonic-sedimentary evolution stages: Subduction period, basin development period, subsidence period and compression deformation period. The overall heat flow value of Japan Sea is high, and it is distributed annularly along Yamato Ridge. The geothermal heat flow value is about 50–130 MW/m^(2), and the average heat flow is75.9±19.8 MW/m^(2), which has a typical “hot basin ”. The high heat flow background provides unique thermal evolution conditions for hydrocarbon generation, which leads to the high temperature and rapid evolution. The authors summarized as “early hydrocarbon generation, rapid maturity and shallow and narrow hydrocarbon generation window”. The type of oil and gas is mainly natural gas, and it mainly distributed in Neogene oil and gas reservoirs. The trap types are mainly structural traps, lithologic traps and composite traps. In addition, the pre-Neogene bedrock oil and gas reservoirs also show a good exploration prospect. The resource prospecting indicates that Niigata Basin, Ulleung Basin and kitakami Basin are the main target areas for future exploration and development.

Geological characteristics of unconventional tight oil reservoir (10^(9) t): A case study of Upper Cretaceous Qingshankou Formation, northern Songliao Basin, NE China

The Daqing exploration area in the northern Songliao Basin has great potential for unconventional oil and gas resources,among which the total resources of tight oil alone exceed 109 t and is regarded as an important resource base of Daqing oilfield.After years of exploration in the Qijia area,Songliao Basin,NE China,tight oil has been found in the Upper Cretaceous Qingshankou Formation.To work out tight oil’s geological characteristics,taking tight oil in Gaotaizi oil layers of the Upper Cretaceous Qingshankou Formation in northern Songliao Basin as an example,this paper systematically analyzed the geological characteristics of unconventional tight oil in Gao3 and Gao4 layers of the Qijia area,based on the data of the geological survey,well drilling journey,well logging,and test.It is that three sets of hydrocarbon source rocks(K2qn1,K2qn2+3,and K2n1)develop in the examined area,and exhibit excellent type I and II kerogens,high organic matter abundance,and moderate maturity.The reservoir is generally composed of thin-bedded mudstone,siltstone,and sandstone,and presents poor porosity(average 8.5 vol.%)and air permeability(average 4 mD).The main reservoir space primarily includes intergranular pores,secondary soluble pores,and intergranular soluble pores.Three types of orifice throats were identified,namely fine throat,extra-fine throat,and micro-fine throat.The siltstone is generally oil-bearing,the reservoirs with slime and calcium become worse oil-bearing,and the mudstone has no obvious oil-bearing characteristics.The brittleness indices of the sandstone in the tight oil reservoir range from 40%to 60%,and those of the mudstone range from 40%to 45%,indicating a better brittleness of the tight oil reservoir.Based on the study of typical core hole data,this paper gives a comprehensive evaluation of the properties of the tight oil and establishes a tight oil single well composite bar chart as well as the initial evaluation system with the core of properties in the tight oil reservoir.This study has theoretical guiding significance and practical application value for tight oil exploration and evaluation in the Qijia area.

Hydrocarbon gas huff-n-puff optimization of multiple horizontal wells with complex fracture networks in the M unconventional reservoir

The oil production of the multi-fractured horizontal wells(MFHWs) declines quickly in unconventional oil reservoirs due to the fast depletion of natural energy. Gas injection has been acknowledged as an effective method to improve oil recovery factor from unconventional oil reservoirs. Hydrocarbon gas huff-n-puff becomes preferable when the CO_(2) source is limited. However, the impact of complex fracture networks and well interference on the EOR performance of multiple MFHWs is still unclear. The optimal gas huff-n-puff parameters are significant for enhancing oil recovery. This work aims to optimize the hydrocarbon gas injection and production parameters for multiple MFHWs with complex fracture networks in unconventional oil reservoirs. Firstly, the numerical model based on unstructured grids is developed to characterize the complex fracture networks and capture the dynamic fracture features.Secondly, the PVT phase behavior simulation was carried out to provide the fluid model for numerical simulation. Thirdly, the optimal parameters for hydrocarbon gas huff-n-puff were obtained. Finally, the dominant factors of hydrocarbon gas huff-n-puff under complex fracture networks are obtained by fuzzy mathematical method. Results reveal that the current pressure of hydrocarbon gas injection can achieve miscible displacement. The optimal injection and production parameters are obtained by single-factor analysis to analyze the effect of individual parameter. Gas injection time is the dominant factor of hydrocarbon gas huff-n-puff in unconventional oil reservoirs with complex fracture networks. This work can offer engineers guidance for hydrocarbon gas huff-n-puff of multiple MFHWs considering the complex fracture networks.

Formation damage mechanism and control strategy of the compound function of drilling fluid and fracturing fluid in shale reservoirs

For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid.With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface,fracture closure and rock powder blocking,the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid.The formation damage mechanism during drilling and completion process in shale reservoir is revealed,and the protection measures are raised.The drilling fluid can deeply invade into the shale formation through natural and induced fractures,erode shale minerals and weaken the mechanical properties of shale during the drilling process.In the process of hydraulic fracturing,the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale,results in fracture closure and rock powder shedding,and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures.The damage can yield significant conductivity decrease of fractures,and restrict the high and stable production of shale oil and gas wells.The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section,forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface,strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid,optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection.

Purification of Produced Water from a Sour Oilfield in South Kuwait. 1. Oil-Water Separation and Industrial Salt Production

Produced water from an oil extraction site in South Kuwait was sampled after primary oil – water separation had been carried out. The produced water was filtered through a mixture of activated charcoal and esterified cellulosic material gained from spent coffee grounds as a tertiary adsorption treatment. The earth-alkaline metal ions and heavy metals were separated from the de-oiled produced water by addition of either sodium or potassium hydroxide in the presence of carbon dioxide or by direct addition of solid sodium carbonate. The resulting filtrate gave salt of industrial purity upon selective crystallization on evaporation.

Purification of Produced Water from a Sour Oilfield in South Kuwait. 2. Oil-Water Separation and Crystallization of Calcium Carbonate

Oil-water separation for produced water (PW) originating from an oil extraction site in South Kuwait was carried out using bleached, esterified cellulosic material from used coffee grounds. Thereafter, earth-alkaline metal ions, specifically calcium ions, of the de-oiled PW were removed by precipitation with sodium carbonate to give access to pure sodium chloride as industrial salt from the remaining PW. While the purity of the precipitated calcium carbonate (CaCO3) depends on the precipitation conditions, CaCO3 of up to 95.48% purity can be obtained, which makes it a salable product. The precipitation of CaCO3 decreases the amount of calcium ions in PW from 11,300 ppm to 84 ppm.

Model and methods for comprehensive measurement of the low-carbon status of China's oil and gas enterprises

This paper establishes a model that would allow China＇s oil and gas enterprises to scientifically evaluate and measure their low-carbon level and status. It considers various characteristics of China＇s oil and gas enterprises and the implications of low-carbon development, and is based on an overall analysis of factors that influence the reduction of carbon emissions. In view of low-carbon economic theories and the general principles of an evaluation index system, a comprehensive system for measuring the low-carbon status of China＇s oil and gas enterprises has been developed. This measurement system is comprised of four main criteria （energy structure, energy utilization, carbon emissions and utilization, and low carbon management） as well as thirty indexes. By the Delphi method and the analytical hierarchy process （AHP）, the weight of the rules hierarchy and indexes hierarchy were determined. The standardized indexes were then integrated using a linear weighted sum formula, and a comprehensive formula for index measurement was established. Taking into account the status of low- carbon development in the petroleum and petrochemical industry at home and abroad, an evaluation criterion is proposed comprising four levels： ideal low-carbon, economical low-carbon, medium-carbon and high-carbon, whose values were organized within the settings of [0, 1].