For a continuous, increasing function ω : R^+ →R^+/{0} of finite exponential type, this paper introduces the set Z(A, ω) of all x in a Banach space X for which the second order abstract differential equation ...For a continuous, increasing function ω : R^+ →R^+/{0} of finite exponential type, this paper introduces the set Z(A, ω) of all x in a Banach space X for which the second order abstract differential equation (2) has a mild solution such that [ω(t)]^-1u(t,x) is uniformly continues on R^+, and show that Z(A, ω) is a maximal Banach subspace continuously embedded in X, where A ∈ B(X) is closed. Moreover, A[z(A,ω) generates an O(ω(t)) strongly continuous cosine operator function family.展开更多
Backscattered fields from one-dimensional time-varying Gerstners sea surface are calculated utilising the secondorder small slope approximation. It is well known that spectral properties of the backscattered echoes re...Backscattered fields from one-dimensional time-varying Gerstners sea surface are calculated utilising the secondorder small slope approximation. It is well known that spectral properties of the backscattered echoes relate to the velocity of the small elementary scatterers on sea surface profiles. Therefore, modeling Doppler spectra from the ocean requires an accurate description of the sea surface motion. The profile of nonlinear Gerstners sea surface shows verticalskewness of sea waves, it is sharper at the crest and flatter at the trough than linear waves, and its maximum slope position is closer to the crest than to the trough. Furthermore, the horizontal component of the small elementary scatterers orbit velocity on the sea surface, which yields noticeable influence on Doppler spectra, can be obtained conveniently by Gerstners sea surface model. In this study the characteristics of Doppler spectra of backscattered fields from time-varying Gerstners sea surface are investigated and the dependences of the Doppler frequency and the Doppler bandwidth on the parameters, such as the wind speed, the radar frequency, the incident angle, etc. are discussed. It is shown that the Doppler bandwidth of microwave scattered fields from Gerstners sea surface is considerably broadened. For the case of high frequency backscattered fields, the values of the higher-order spectrum peaks are larger than those obtained by linear sea surface.展开更多
The following article has been retracted due to the investigation of complaints received against it. Title: A New Method of Construction of Robust Second Order Rotatable Designs Using Balanced Incomplete Block Designs...The following article has been retracted due to the investigation of complaints received against it. Title: A New Method of Construction of Robust Second Order Rotatable Designs Using Balanced Incomplete Block Designs Authors: Bejjam Re. Victorbabu, Kottapalli Rajyalakshmi. The above paper is a copy of Dr. Rabindra Nath Das’s former article, entitled '“Robust second order rotatable designs (Part I)”. The scientific community takes a very strong view on this matter and we solemnly withdrawn?the paper from the journal OJS. This paper published in OJS Vol.2 No.1, 39-47, 2012, has been retracted.展开更多
The following article has been retracted due to the investigation of complaints received against it. Title: A New Method of Construction of Robust Second Order Slope Rotatable Designs Using Pairwise Balanced Designs. ...The following article has been retracted due to the investigation of complaints received against it. Title: A New Method of Construction of Robust Second Order Slope Rotatable Designs Using Pairwise Balanced Designs. Authors: Bejjam Re. Victorbabu, Kottapalli Rajyalakshmi.The paper is a copy of Dr. Rabindra Nath Das’s former article, entitled “Slope rotatability with correlated errors (Vol. 54, pp. 57-70, 2003)” and “Robust second order rotatable designs (Part I)”. The scientific community takes a very strong view on this matter and we treat all unethical behavior such as plagiarism seriously. This paper published in OJSVol.2 No.3, 319-327, 2012, has been removed from this site.展开更多
A series of CdS nanoparticles with different surfaces were prepared by colloidal chemical method and reverse micelle method. Their second-order nonlinear optical (NLO) properties were experimentally studied in solutio...A series of CdS nanoparticles with different surfaces were prepared by colloidal chemical method and reverse micelle method. Their second-order nonlinear optical (NLO) properties were experimentally studied in solution by newly developed hyper-Rayleigh scattering (HRS) technique. The results show that 'per particle' first-order hyperpolarizability beta values are sensitive To the synthetic method and the surface chemical modification.展开更多
A previous study (Song. 2004. Geophys Res Lett, 31 (15):L15302) of the second-order solutions for random interracial waves is extended in a constant depth, two-layer fluid system with a rigid lid is extended into...A previous study (Song. 2004. Geophys Res Lett, 31 (15):L15302) of the second-order solutions for random interracial waves is extended in a constant depth, two-layer fluid system with a rigid lid is extended into a more general case of two-layer fluid with a top free surface. The rigid boundary condition on the upper surface is replaced by the kinematical and dynamical boundary conditions of a free surface, and the equations describing the random displacements of free surface, density-interface and the associated velocity potentials in the two-layer fluid are solved to the second order using the same expansion technology as that of Song (2004. Geophys Res Lett, 31 (15):L15302). The results show that the interface and the surface will oscillate synchronously, and the wave fields to the first-order both at the free surface and at the density-interface are made up of a linear superposition of many waves with different amplitudes, wave numbers and frequencies. The second-order solutions describe the second-order wave-wave interactions of the surface wave components, the interface wave components and among the surface and the interface wave components. The extended solutions also include special cases obtained by Thorpe for progressive interracial waves (Thorpe. 1968a.Trans R Soc London, 263A:563~614) and standing interracial waves (Thorpe. 1968b. J Fluid Mech, 32:489-528) for the two-layer fluid with a top free surface. Moreover, the solutions reduce to those derived for random surface waves by Sharma and Dean (1979.Ocean Engineering Rep 20) if the density of the upper layer is much smaller than that of the lower layer.展开更多
The adsorption capacities of new biomaterials derived from lemon leaf (Citrus sp.) toward fluoride ions have been explored by varying different physicochemical parameters such as pH, initial concentration, adsorbent d...The adsorption capacities of new biomaterials derived from lemon leaf (Citrus sp.) toward fluoride ions have been explored by varying different physicochemical parameters such as pH, initial concentration, adsorbent dose, contact time, stirring rate and temperature. The entire study was done through batch process. Maximum fluoride adsorption of 96.9% - 98.8% was achieved with an initial concentration of 10 mg/L. Langmuir isotherm model well expressed fluoride ad- sorption onto LLD-1, LLD-2 and LLD-3. According to correlation coefficient, the fluoride adsorption onto these 3 ad- sorbents was correlated well with pseudo-second-order kinetic model. From thermodynamic study, the spontaneous nature and feasibility of the adsorption process with negative enthalpy (ΔH0) value also supported the exothermic nature were shown. The rate of fluoride adsorption was mathematically described as a function of experimental parameters and was modeled through Box-Behnken (Response surface methodology). The results showed that the responses of fluoride adsorption were significantly affected by the quadratic term of pH, initial concentration, contact time and temperature and the statistical analysis was performed by ANOVA which indicated good correlation of experimental parameters.展开更多
The second-order optical nonlinearity of CdS nanoparticles with different diameters of 28.0, 30.0, 31.5, 50.0, and 91.0 A was studied by hyper-Rayleigh scattering technique. Results show that the first-order hyperpola...The second-order optical nonlinearity of CdS nanoparticles with different diameters of 28.0, 30.0, 31.5, 50.0, and 91.0 A was studied by hyper-Rayleigh scattering technique. Results show that the first-order hyperpolarizability P value per CdS partiele decreases as size is reduced to diameter of 31.5 A; however, as CdS size further decreases, this trend is reversed and (J value increases. Substantially, the normalized P value per CdS formula unit, β0, exhibits systematic enhancement with decreasing size. This phenomenon is interpreted in terms of a so-called surfaee contribution mechanism.展开更多
In this paper, α-times integrated C-regularized cosine functions and mild α-times integrated C-existence families of second order are introduced. Equivalences are proved among α-times integrated C-regularized cosin...In this paper, α-times integrated C-regularized cosine functions and mild α-times integrated C-existence families of second order are introduced. Equivalences are proved among α-times integrated C-regularized cosine function for a linear operator A, C-wellposed of (α+1)-times abstract Cauchy problem and mild a -times integrated C-existence family of second order for A when the commutable condition is satisfied. In addition, if A = C-1AC, they are also equivalent to A generating the α -times integrated C-regularized cosine function. The characterization of an exponentially bounded mild α -times integrated C-existence family of second order is given out in terms of a Laplace transform.展开更多
Despite the increased recognition of the nutritional value of the Oyster mushroom, coupled with its ability to tolerate a wide range of climatic conditions, its production is still at infancy stage with low adoption r...Despite the increased recognition of the nutritional value of the Oyster mushroom, coupled with its ability to tolerate a wide range of climatic conditions, its production is still at infancy stage with low adoption rate in Kenya. The low uptake could be attributed to the cost of spawns or lack of skills for spawns preparations coupled with poor knowledge on oyster mushroom consumption benefits. The objective of this study was to optimize Pleurotus ostreatus (Oyster mushroom) spawns production. To achieve the objective, the spawns propagation was optimized by varying the temperature level, sterilization time and culture media concentration in order to establish the feasible levels which minimized the days of mycelium full development using central composite designs. Based on the study findings, 26.29<span style="white-space:nowrap;">˚</span>C, 17.36 minutes and 60.95 g/L of temperature level, sterilization time and culture media concentration levels respectively minimized the days to full coverage of mycelium in a petri dish. Central composite designs for controlling temperature, sterilization time and culture media concentration were recommended for spawns maximum production. A further research on multiple response optimizations aimed at achieving resistance to bacterial diseases and yield by varying the strain in the culture were recommended.展开更多
The Junggar Basin is one of the major petroliferous basins with abundant oil and gas resources in onshore China.Around 2010 and thereafter,the hydrocarbon exploration for finding giant fields in the basin faced tough ...The Junggar Basin is one of the major petroliferous basins with abundant oil and gas resources in onshore China.Around 2010 and thereafter,the hydrocarbon exploration for finding giant fields in the basin faced tough difficulties:in the northwestern margin area,no significant breakthrough has been made for long since seeking to"escape from the step-fault zone and extend to the slope area";in the central part,the exploration for large lithologic-stratigraphic reservoirs stood still;since the discovery of the Kelameili gas field,no important achievement has been made in gas exploration.Under the guidance of"whole sag-oil-bearing"theory in the petroliferous basin,and based on the long-term study and thinking of the petroleum accumulation conditions and characteristics,the authors proposed several new concepts,i.e.,a"thrust-induced second-order fault step"hiding under the northwestern slope area;six"hydrocarbon migrationward surfaces"favorable for hydrocarbon accumulation;promising natural gas resource.These concepts have played an important role in the discoveries of Wells Mahu1 and Yanbei1 as well as the confirmation and expansion of Permian-Triassic billion-ton-scale petroliferous areas in Mahu.The fairway of new discoveries has also appeared for natural gas exploration in Wells Fu26,Gaotan1 and Qianshao2,suggesting that the surrounding regions of the highly matured source kitchen are of high possibility to form gas accumulations.展开更多
To obtain high-power semiconductor lasers with stable operation in a single longitudinal mode and improve the characteristics of the output beam,an end-emitting surface second-order metal grating distributed feedback(...To obtain high-power semiconductor lasers with stable operation in a single longitudinal mode and improve the characteristics of the output beam,an end-emitting surface second-order metal grating distributed feedback(DFB) laser emitting at around 940 nm is fabricated.The characteristics of the uncoated devices with and without gratings are tested under room temperature continuous-wave conditions without any temperature-control device and compared.The devices with gratings achieve high powers of up to 385 mW/facet and a small lateral far-field angle of 2.7° at 1.5 A,have only 4.13 nm/A wavelength-shift,and 0.09 nm spectral linewidth at 600 mA,and operate in a stable longitudinal mode.Devices without gratings operate in multimode,with a larger lateral far-field angle(7.3°) and spectral linewidth(1.3 nm),although with higher output powers.Because of the integration of second-order metal gratings and their very high coupling capability,the output beam quality is improved greatly,the lasing wavelength is stable and varies slowly with changes in injection current,while the spectrum is narrowed dramatically,and the far-field angles are greatly reduced.This opens the way for the realization of watt-scale power broad-stripe(>100 μm) surface second-order metal grating end and surface-emitting DFB lasers and arrays with single frequency,single mode operation and high output beam quality.展开更多
Consider the motion of immersed hypersurfaces driven by surface diffusion flow and give anlower bound on the life span of a smooth immersed solution, which depends only on how muchthe curvature of the initial surface ...Consider the motion of immersed hypersurfaces driven by surface diffusion flow and give anlower bound on the life span of a smooth immersed solution, which depends only on how muchthe curvature of the initial surface is concentrated in space.展开更多
The mechanism of a cycloaddition reaction between singlet methylidenesilene and ethylene has been investigated with MP2/6-31G^* and B3LYP/6-31G^* methods, including geometry optimization and vibrational analysis for...The mechanism of a cycloaddition reaction between singlet methylidenesilene and ethylene has been investigated with MP2/6-31G^* and B3LYP/6-31G^* methods, including geometry optimization and vibrational analysis for the involved stationary points on the potential energy surface. Energies of the involved conformers were calculated by CCSD(T)//MP2/6-31G* and CCSD(T)//B3LYP/6-31 G* methods, respectively. The results show that the dominant reaction pathway of the cycloaddition reaction is that a complex intermediate is firstly formed between the two reactants through a barrier-free exothermic reaction of 13.3 kJ/mol, and the complex is then isomefized to a four-membered ring product P2,1 via a transition state TS2.1 with a barrier of 32.0 kJ/mol.展开更多
The mechanism of cycloaddition reaction between singlet alkylidene carbene and ethylene has been investigated with second-order Moller-Plesset perturbation theory (MP2). By using 6–31G* basis, geometry optimization, ...The mechanism of cycloaddition reaction between singlet alkylidene carbene and ethylene has been investigated with second-order Moller-Plesset perturbation theory (MP2). By using 6–31G* basis, geometry optimization, vibrational analysis and energetics have been calculated for the involved stationary points on the potential energy surface. The results show that the title reaction has two major competition channels. An energy-rich intermediate (INT) is firstly formed between alkylidene carbene and ethylene through a barrier-free exothermic reaction of 63.62 kJ/mol, and the intermediate then isomerizes to a three-membered ring product (Pl) and a four-membered ring product (P2) via transition state TS1 and TS2, in which energy barriers are 47.00 and 51.02 kl/mol. respectively. PI is the main product.展开更多
The water surface wave radiation problem caused by multiple cylinders oscillating with identical frequency was solved in frequency domain by the boundary element method using simple Green's function in the inner w...The water surface wave radiation problem caused by multiple cylinders oscillating with identical frequency was solved in frequency domain by the boundary element method using simple Green's function in the inner water region combined with the eigenfunction expansions in the outer water region. The numerical method is suitable to the situation of constant depth of outer regions and complicated boundary conditions of inner region, while the oscillating modes, motion amplitudes and phases of the cylinders may be different from one another. The second order potential and hydrodynamic forces acting on each cylinder were evaluated completely by perturbation method. Compared with the case of single oscillating cylinder, hydrodynamic interference phenomena, such as wave resonance and negative added mass, of the radiation problem due to the oscillatory motions of multiple cylinders are identified which is of engineering importance to the design of moorings and other facilities involving multiple structures.展开更多
文摘For a continuous, increasing function ω : R^+ →R^+/{0} of finite exponential type, this paper introduces the set Z(A, ω) of all x in a Banach space X for which the second order abstract differential equation (2) has a mild solution such that [ω(t)]^-1u(t,x) is uniformly continues on R^+, and show that Z(A, ω) is a maximal Banach subspace continuously embedded in X, where A ∈ B(X) is closed. Moreover, A[z(A,ω) generates an O(ω(t)) strongly continuous cosine operator function family.
基金Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 40906088)the National Natural Science Foundation of China (Grant No. 60971067)Specialised Research Fund for the Doctoral Program of Higher Education (Grant No. 200804231021)
文摘Backscattered fields from one-dimensional time-varying Gerstners sea surface are calculated utilising the secondorder small slope approximation. It is well known that spectral properties of the backscattered echoes relate to the velocity of the small elementary scatterers on sea surface profiles. Therefore, modeling Doppler spectra from the ocean requires an accurate description of the sea surface motion. The profile of nonlinear Gerstners sea surface shows verticalskewness of sea waves, it is sharper at the crest and flatter at the trough than linear waves, and its maximum slope position is closer to the crest than to the trough. Furthermore, the horizontal component of the small elementary scatterers orbit velocity on the sea surface, which yields noticeable influence on Doppler spectra, can be obtained conveniently by Gerstners sea surface model. In this study the characteristics of Doppler spectra of backscattered fields from time-varying Gerstners sea surface are investigated and the dependences of the Doppler frequency and the Doppler bandwidth on the parameters, such as the wind speed, the radar frequency, the incident angle, etc. are discussed. It is shown that the Doppler bandwidth of microwave scattered fields from Gerstners sea surface is considerably broadened. For the case of high frequency backscattered fields, the values of the higher-order spectrum peaks are larger than those obtained by linear sea surface.
文摘The following article has been retracted due to the investigation of complaints received against it. Title: A New Method of Construction of Robust Second Order Rotatable Designs Using Balanced Incomplete Block Designs Authors: Bejjam Re. Victorbabu, Kottapalli Rajyalakshmi. The above paper is a copy of Dr. Rabindra Nath Das’s former article, entitled '“Robust second order rotatable designs (Part I)”. The scientific community takes a very strong view on this matter and we solemnly withdrawn?the paper from the journal OJS. This paper published in OJS Vol.2 No.1, 39-47, 2012, has been retracted.
文摘The following article has been retracted due to the investigation of complaints received against it. Title: A New Method of Construction of Robust Second Order Slope Rotatable Designs Using Pairwise Balanced Designs. Authors: Bejjam Re. Victorbabu, Kottapalli Rajyalakshmi.The paper is a copy of Dr. Rabindra Nath Das’s former article, entitled “Slope rotatability with correlated errors (Vol. 54, pp. 57-70, 2003)” and “Robust second order rotatable designs (Part I)”. The scientific community takes a very strong view on this matter and we treat all unethical behavior such as plagiarism seriously. This paper published in OJSVol.2 No.3, 319-327, 2012, has been removed from this site.
基金National Natural Science Foundation of China! (No.59582005)
文摘A series of CdS nanoparticles with different surfaces were prepared by colloidal chemical method and reverse micelle method. Their second-order nonlinear optical (NLO) properties were experimentally studied in solution by newly developed hyper-Rayleigh scattering (HRS) technique. The results show that 'per particle' first-order hyperpolarizability beta values are sensitive To the synthetic method and the surface chemical modification.
基金supported by the National Science Foundation for Distinguished Young Scholars of China under contract No.40425015the Cooperative Project of Chinese Academy Sciences and the China National 0ffshore 0il Corporation("Behaviours of internal waves and their roles on the marine stuctures").
文摘A previous study (Song. 2004. Geophys Res Lett, 31 (15):L15302) of the second-order solutions for random interracial waves is extended in a constant depth, two-layer fluid system with a rigid lid is extended into a more general case of two-layer fluid with a top free surface. The rigid boundary condition on the upper surface is replaced by the kinematical and dynamical boundary conditions of a free surface, and the equations describing the random displacements of free surface, density-interface and the associated velocity potentials in the two-layer fluid are solved to the second order using the same expansion technology as that of Song (2004. Geophys Res Lett, 31 (15):L15302). The results show that the interface and the surface will oscillate synchronously, and the wave fields to the first-order both at the free surface and at the density-interface are made up of a linear superposition of many waves with different amplitudes, wave numbers and frequencies. The second-order solutions describe the second-order wave-wave interactions of the surface wave components, the interface wave components and among the surface and the interface wave components. The extended solutions also include special cases obtained by Thorpe for progressive interracial waves (Thorpe. 1968a.Trans R Soc London, 263A:563~614) and standing interracial waves (Thorpe. 1968b. J Fluid Mech, 32:489-528) for the two-layer fluid with a top free surface. Moreover, the solutions reduce to those derived for random surface waves by Sharma and Dean (1979.Ocean Engineering Rep 20) if the density of the upper layer is much smaller than that of the lower layer.
文摘The adsorption capacities of new biomaterials derived from lemon leaf (Citrus sp.) toward fluoride ions have been explored by varying different physicochemical parameters such as pH, initial concentration, adsorbent dose, contact time, stirring rate and temperature. The entire study was done through batch process. Maximum fluoride adsorption of 96.9% - 98.8% was achieved with an initial concentration of 10 mg/L. Langmuir isotherm model well expressed fluoride ad- sorption onto LLD-1, LLD-2 and LLD-3. According to correlation coefficient, the fluoride adsorption onto these 3 ad- sorbents was correlated well with pseudo-second-order kinetic model. From thermodynamic study, the spontaneous nature and feasibility of the adsorption process with negative enthalpy (ΔH0) value also supported the exothermic nature were shown. The rate of fluoride adsorption was mathematically described as a function of experimental parameters and was modeled through Box-Behnken (Response surface methodology). The results showed that the responses of fluoride adsorption were significantly affected by the quadratic term of pH, initial concentration, contact time and temperature and the statistical analysis was performed by ANOVA which indicated good correlation of experimental parameters.
基金supposed by the National Natural Science Foundation of China(Nos.50202009,10074023)the National Postdoctoral Foundation(No.2002031222).
文摘The second-order optical nonlinearity of CdS nanoparticles with different diameters of 28.0, 30.0, 31.5, 50.0, and 91.0 A was studied by hyper-Rayleigh scattering technique. Results show that the first-order hyperpolarizability P value per CdS partiele decreases as size is reduced to diameter of 31.5 A; however, as CdS size further decreases, this trend is reversed and (J value increases. Substantially, the normalized P value per CdS formula unit, β0, exhibits systematic enhancement with decreasing size. This phenomenon is interpreted in terms of a so-called surfaee contribution mechanism.
基金This project is supported by the Natural Science Foundation of China and Science Development Foundation of the Colleges and University of Shanghai.
文摘In this paper, α-times integrated C-regularized cosine functions and mild α-times integrated C-existence families of second order are introduced. Equivalences are proved among α-times integrated C-regularized cosine function for a linear operator A, C-wellposed of (α+1)-times abstract Cauchy problem and mild a -times integrated C-existence family of second order for A when the commutable condition is satisfied. In addition, if A = C-1AC, they are also equivalent to A generating the α -times integrated C-regularized cosine function. The characterization of an exponentially bounded mild α -times integrated C-existence family of second order is given out in terms of a Laplace transform.
文摘Despite the increased recognition of the nutritional value of the Oyster mushroom, coupled with its ability to tolerate a wide range of climatic conditions, its production is still at infancy stage with low adoption rate in Kenya. The low uptake could be attributed to the cost of spawns or lack of skills for spawns preparations coupled with poor knowledge on oyster mushroom consumption benefits. The objective of this study was to optimize Pleurotus ostreatus (Oyster mushroom) spawns production. To achieve the objective, the spawns propagation was optimized by varying the temperature level, sterilization time and culture media concentration in order to establish the feasible levels which minimized the days of mycelium full development using central composite designs. Based on the study findings, 26.29<span style="white-space:nowrap;">˚</span>C, 17.36 minutes and 60.95 g/L of temperature level, sterilization time and culture media concentration levels respectively minimized the days to full coverage of mycelium in a petri dish. Central composite designs for controlling temperature, sterilization time and culture media concentration were recommended for spawns maximum production. A further research on multiple response optimizations aimed at achieving resistance to bacterial diseases and yield by varying the strain in the culture were recommended.
基金Supported by National Science and Technology Major Project(2017ZX5001).
文摘The Junggar Basin is one of the major petroliferous basins with abundant oil and gas resources in onshore China.Around 2010 and thereafter,the hydrocarbon exploration for finding giant fields in the basin faced tough difficulties:in the northwestern margin area,no significant breakthrough has been made for long since seeking to"escape from the step-fault zone and extend to the slope area";in the central part,the exploration for large lithologic-stratigraphic reservoirs stood still;since the discovery of the Kelameili gas field,no important achievement has been made in gas exploration.Under the guidance of"whole sag-oil-bearing"theory in the petroliferous basin,and based on the long-term study and thinking of the petroleum accumulation conditions and characteristics,the authors proposed several new concepts,i.e.,a"thrust-induced second-order fault step"hiding under the northwestern slope area;six"hydrocarbon migrationward surfaces"favorable for hydrocarbon accumulation;promising natural gas resource.These concepts have played an important role in the discoveries of Wells Mahu1 and Yanbei1 as well as the confirmation and expansion of Permian-Triassic billion-ton-scale petroliferous areas in Mahu.The fairway of new discoveries has also appeared for natural gas exploration in Wells Fu26,Gaotan1 and Qianshao2,suggesting that the surrounding regions of the highly matured source kitchen are of high possibility to form gas accumulations.
基金supported by the National Natural Science Foundation of China (90923037,61106068 and 61176045)
文摘To obtain high-power semiconductor lasers with stable operation in a single longitudinal mode and improve the characteristics of the output beam,an end-emitting surface second-order metal grating distributed feedback(DFB) laser emitting at around 940 nm is fabricated.The characteristics of the uncoated devices with and without gratings are tested under room temperature continuous-wave conditions without any temperature-control device and compared.The devices with gratings achieve high powers of up to 385 mW/facet and a small lateral far-field angle of 2.7° at 1.5 A,have only 4.13 nm/A wavelength-shift,and 0.09 nm spectral linewidth at 600 mA,and operate in a stable longitudinal mode.Devices without gratings operate in multimode,with a larger lateral far-field angle(7.3°) and spectral linewidth(1.3 nm),although with higher output powers.Because of the integration of second-order metal gratings and their very high coupling capability,the output beam quality is improved greatly,the lasing wavelength is stable and varies slowly with changes in injection current,while the spectrum is narrowed dramatically,and the far-field angles are greatly reduced.This opens the way for the realization of watt-scale power broad-stripe(>100 μm) surface second-order metal grating end and surface-emitting DFB lasers and arrays with single frequency,single mode operation and high output beam quality.
基金Project supported by the National Natural Science Foundation of China(No.10071067)and the Jiangsu Provincial Natural Science Foundation of China.
文摘Consider the motion of immersed hypersurfaces driven by surface diffusion flow and give anlower bound on the life span of a smooth immersed solution, which depends only on how muchthe curvature of the initial surface is concentrated in space.
基金Project supported by the Natural Science Foundation of Shandong Province of China (No. Y2002B07).
文摘The mechanism of a cycloaddition reaction between singlet methylidenesilene and ethylene has been investigated with MP2/6-31G^* and B3LYP/6-31G^* methods, including geometry optimization and vibrational analysis for the involved stationary points on the potential energy surface. Energies of the involved conformers were calculated by CCSD(T)//MP2/6-31G* and CCSD(T)//B3LYP/6-31 G* methods, respectively. The results show that the dominant reaction pathway of the cycloaddition reaction is that a complex intermediate is firstly formed between the two reactants through a barrier-free exothermic reaction of 13.3 kJ/mol, and the complex is then isomefized to a four-membered ring product P2,1 via a transition state TS2.1 with a barrier of 32.0 kJ/mol.
基金the Natural Science Foundation of Shandong Province of China (No. Y2002B07).
文摘The mechanism of cycloaddition reaction between singlet alkylidene carbene and ethylene has been investigated with second-order Moller-Plesset perturbation theory (MP2). By using 6–31G* basis, geometry optimization, vibrational analysis and energetics have been calculated for the involved stationary points on the potential energy surface. The results show that the title reaction has two major competition channels. An energy-rich intermediate (INT) is firstly formed between alkylidene carbene and ethylene through a barrier-free exothermic reaction of 63.62 kJ/mol, and the intermediate then isomerizes to a three-membered ring product (Pl) and a four-membered ring product (P2) via transition state TS1 and TS2, in which energy barriers are 47.00 and 51.02 kl/mol. respectively. PI is the main product.
文摘The water surface wave radiation problem caused by multiple cylinders oscillating with identical frequency was solved in frequency domain by the boundary element method using simple Green's function in the inner water region combined with the eigenfunction expansions in the outer water region. The numerical method is suitable to the situation of constant depth of outer regions and complicated boundary conditions of inner region, while the oscillating modes, motion amplitudes and phases of the cylinders may be different from one another. The second order potential and hydrodynamic forces acting on each cylinder were evaluated completely by perturbation method. Compared with the case of single oscillating cylinder, hydrodynamic interference phenomena, such as wave resonance and negative added mass, of the radiation problem due to the oscillatory motions of multiple cylinders are identified which is of engineering importance to the design of moorings and other facilities involving multiple structures.