This paper reports the synthesis and the nonlinear optical property of a series of new chromophores which contain furan ring as the only conjugation bridge for the first time. They are characterized by UV-VIS, FT-IR, ...This paper reports the synthesis and the nonlinear optical property of a series of new chromophores which contain furan ring as the only conjugation bridge for the first time. They are characterized by UV-VIS, FT-IR, 1H NMR, MS and elemental analysis. Their dipole moment and the first-order molecular hyperpolarizability (b) are calculated and compared with those of the analogues containing either benzene or thiophene as the conjugation bridge.展开更多
基金the National Natural Science Foundation of China(No.29774018) a grant from the National Key Fundamental Research Program of China.
文摘This paper reports the synthesis and the nonlinear optical property of a series of new chromophores which contain furan ring as the only conjugation bridge for the first time. They are characterized by UV-VIS, FT-IR, 1H NMR, MS and elemental analysis. Their dipole moment and the first-order molecular hyperpolarizability (b) are calculated and compared with those of the analogues containing either benzene or thiophene as the conjugation bridge.