Three kinds of lower rank bituminous coals from Yanzhou mine and Tengxian mine from Shandong Province were treated and hydrogenated in the study. The test re- sults show that the performance of hydrogenation liquefact...Three kinds of lower rank bituminous coals from Yanzhou mine and Tengxian mine from Shandong Province were treated and hydrogenated in the study. The test re- sults show that the performance of hydrogenation liquefaction of the pretreated coals is improved markedly. Under the test condition of H2 initial pressure 8.2 MPa, addition of FeSO4·7H2O and S as catalyst, final reacting temperature 400 ℃ and reacting time 1.5 h, the oil yield of pretreated YZ1 coal is 69.76% compared with 62.53% of oil yield of un- treated YZ1. Seminally the oil yield of pretreated YZ2 coal is 55.43% compared with 20.88% of untreated YZ2 coal. The results of tests also prove that the improving degree of hydrogenation liquefaction of the pretreated coals is related with radiation duration when the radiation frequency and radiation power of ultrasonic wave are fixed.展开更多
The recent progress of non-covalent associative structure of coal, and the mechanisms of the CS2/NMP (1:1 by volume) mixed solvent and the additive addition enhancing the extraction yield of coals were reviewed, and t...The recent progress of non-covalent associative structure of coal, and the mechanisms of the CS2/NMP (1:1 by volume) mixed solvent and the additive addition enhancing the extraction yield of coals were reviewed, and the aggregation behavior of coal in solid and solution states were presented, and the aggregation behavior of coal in solid and solution states were introduced in this paper. Coal extraction and swelling in organic solvents at room temperature were the most useful methods to understand the associative structure of coal. CS2/NMP (1:1 by volume) is a unique solvent to give high extraction yields for some bituminous coals. Some additives can dissociate the stronger interactions among coal molecules and enhance the extraction yields of coal in the mixed solvent.展开更多
文摘Three kinds of lower rank bituminous coals from Yanzhou mine and Tengxian mine from Shandong Province were treated and hydrogenated in the study. The test re- sults show that the performance of hydrogenation liquefaction of the pretreated coals is improved markedly. Under the test condition of H2 initial pressure 8.2 MPa, addition of FeSO4·7H2O and S as catalyst, final reacting temperature 400 ℃ and reacting time 1.5 h, the oil yield of pretreated YZ1 coal is 69.76% compared with 62.53% of oil yield of un- treated YZ1. Seminally the oil yield of pretreated YZ2 coal is 55.43% compared with 20.88% of untreated YZ2 coal. The results of tests also prove that the improving degree of hydrogenation liquefaction of the pretreated coals is related with radiation duration when the radiation frequency and radiation power of ultrasonic wave are fixed.
基金Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of MOE and the Natural Scientific Foundation of Anhui Education Department (2003kj052)
文摘The recent progress of non-covalent associative structure of coal, and the mechanisms of the CS2/NMP (1:1 by volume) mixed solvent and the additive addition enhancing the extraction yield of coals were reviewed, and the aggregation behavior of coal in solid and solution states were presented, and the aggregation behavior of coal in solid and solution states were introduced in this paper. Coal extraction and swelling in organic solvents at room temperature were the most useful methods to understand the associative structure of coal. CS2/NMP (1:1 by volume) is a unique solvent to give high extraction yields for some bituminous coals. Some additives can dissociate the stronger interactions among coal molecules and enhance the extraction yields of coal in the mixed solvent.
