Drift Mobility, Diffusion Coefficient of Randomly Moving Charge Carriers in Metals and Other Materials with Degenerated Electron Gas

In this short review some aspects of applications of free electron theory on the ground of the Fermi statistics will be analyzed. There it is an intention to attempt somebody’s attention to problems in widespread literature of interpretation of conductivity of metals, superconductor in the normal state and semiconductors with degenerated electron gas. In literature there are many cases when to these materials the classical statistics is applied. It is well known that the electron heat capacity and thermal noise (and as a consequence the electrical conductivity) are determined by randomly moving electrons, which energy is close to the Fermi energy level, and the other part of electrons, which energy is well below the Fermi level can not be scattered and change its energy. Therefore there was tried as simple as possible on the ground of Fermi distribution, and on random motion of charge carriers, and on the well known experimental results to take general expressions for various kinetic parameters which are applicable for materials both without and with degenerated electron gas. It is shown, that drift mobility of randomly moving charge carriers, depending on the degree degeneracy, can considerably exceed the Hall mobility. Also it is shown that the Einstein relation between the diffusion coefficient and the drift mobility of charge carriers is valid even in the case of degeneracy. There also will be presented the main kinetic parameter values for different metals.

Modeling of Ions Mobility in Plasma Like Concept and Transfer Processes in Electrolyte Solutions

Plasma like concept of ions in electrolyte solutions is accepted as a basis for development of equation mobility for transfer processes （viscosity, diffusion, thermal conductivity and electrical conductivity）. The examples of isomorphism of dissipative processes are given in the article. The integrated assessment equation of transfer properties is developed based on the ion-dipole, dipole-dipole and ion-ion interactions and the force of liquid dielectric resistance to oscillating solvated particles. It is shown that the estimated magnitude of viscosity, diffusion, electrical conductivity and thermal conductivity are comparable with the current knowledge and experimental values in a wide range of electrolyte concentrations.

Phase field calculation of interface mobility in a ternary alloy

A novel approach based on the quantitative phase field model was proposed to calculate the interface mobility and applied to the α/β interface of a ternary Ti-6Al-4V alloy.Phase field simulations indicate that the higher interface mobility leads to the faster transformation rate,but only a unique value of interface mobility matches the diffusion equation under the diffusion-controlled condition.By comparing the transformation kinetics from phase field simulations with that from classical diffusion equation,the interface mobility at different temperatures can be obtained.The results show that the calculated interface mobility increases with increasing temperature and accords with Arrhenius equation very well.

Enhanced efficiency and stability of perovskite solar cells by 2D perovskite vapor-assisted interface optimization

Organic–inorganic perovskites solar cells(PSCs)have attracted great attention due to their rapid progress in power conversion efficiency(PCE).However,there is still an enormous challenge to achieve both high efficiency and stability devices as the decomposition of perovskite materials under humid and light conditions.Herein,we demonstrate that high efficiency and stability of PSCs can be obtained by the reaction of three-dimensional(3D)perovskite with 1,4-butanediamine iodide(BEAI2)vapor.The incorporation of BEAI2 intensively promotes the crystallization of perovskite film with large grain size(~500 nm).Further characterization reveals that the post-treatment perovskite film delivered low interface trap density with long carrier lifetime(>200 ns),long carrier diffusion length(>600 nm)and large carrier mobility(>1.5 cm^2 V-1S-1).Solar cells employing such post-treatment films demonstrated 19.58%PCE without hysteresis.Moreover,the post-treatment devices can retain over 90%original efficiencies stored under ambient atmospheric conditions and exhibit better stability under 85℃and continuous illumination as a two-dimensional(2D)perovskite thin layer is formed on the surface/or at the grain boundaries of 3D perovskite.This study offers an effective way to obtain PSCs with high efficiency and stability.

Methodical Approach to the Development of a Radar Sensor Model for the Detection of Urban Traffic Participants Using a Virtual Reality Engine

New approaches for testing of autonomous driving functions are using Virtual Reality (VR) to analyze the behavior of automated vehicles in various scenarios. The real time simulation of the environment sensors is still a challenge. In this paper, the conception, development and validation of an automotive radar raw data sensor model is shown. For the implementation, the Unreal VR engine developed by Epic Games is used. The model consists of a sending antenna, a propagation and a receiving antenna model. The microwave field propagation is simulated by a raytracing approach. It uses the method of shooting and bouncing rays to cover the field. A diffused scattering model is implemented to simulate the influence of rough structures on the reflection of rays. To parameterize the model, simple reflectors are used. The validation is done by a comparison of the measured radar patterns of pedestrians and cyclists with simulated values. The outcome is that the developed model shows valid results, even if it still has deficits in the context of performance. It shows that the bouncing of diffuse scattered field can only be done once. This produces inadequacies in some scenarios. In summary, the paper shows a high potential for real time simulation of radar sensors by using ray tracing in a virtual reality.

QUANTUM MECHANICAL MODEL AND SIMULATION OF GaAs/AlGaAs QUANTUM WELL INFRARED PHOTODETECTOR-Ⅱ ELECTRICAL ASPECTS

A complete quantum mechanical model for GaAs/AlGaAs quantum well infrared photodetectors(QWIPs) was presented. The photocurrent was investigated by the optical transition(absorption coefficient)between the ground state and the excited states due to the nonzero component of the radiation field along the sample growth direction. By studying the inter diffusion of the Al atoms across the GaAs/AlGaAs heterointer faces, the mobility of the drift diffusion carriers in the excited states was calculated. As a result, the measurement results of the dark current and the photocurrent spectra are explained theoretically.

Mobility of large clusters on a semiconductor surface:Kinetic Monte Carlo simulation results

The mobility of clusters on a semiconductor surface for various values of cluster size is studied as a function of temperature by kinetic Monte Carlo method. The cluster resides on the surface of a square grid. Kinetic processes such as the diffusion of single particles on the surface, their attachment and detachment to/from clusters, diffusion of particles along cluster edges are considered. The clusters considered in this study consist of 150-6000 atoms per cluster on average. A statistical probability of motion to each direction is assigned to each particle where a particle with four nearest neighbors is assumed to be immobile. The mobility of a cluster is found from the root mean square displacement of the center of mass of the cluster as a function of time. It is found that the diffusion coefficient of clusters goes as D = A（T）Na where N is the average number of particles in the cluster, A（T） is a temperature-dependent constant and a is a parameter with a value of about -0.64 〈 a 〈 -0.75. The value of a is found to be independent of cluster sizes and temperature values （170-220 K） considered in this study. As the diffusion along the perimeter of the cluster becomes prohibitive, the exponent approaches a value of -0.5. The diffusion coefficient is found to change by one order of magnitude as a function of cluster size.

Development and Use of Rural Finance: A Case Study of Village A in Sichuan Province

Mobile finance plays a great role in solving problems of rural finance,such as insufficient physical outlets and excessive high transaction cost. Based on the field survey data of Village A in Sichuan Province,analysis and study were carried out on the development and use of rural mobile finance. The results indicated that the degree of use of rural mobile finance is not high. Mobile finance is mainly used in the young and the middle aged people with high educational level,engaged in non-agricultural industry,and with lower middle income. The business is single and mainly concentrated in shopping and transfer of account.

Cooperative Sensing and Distributed Control of a Diffusion Process Using Centroidal Voronoi Tessellations

This paper considers how to use a group of robots to sense and control a diffusion process.The diffusion process is modeled by a partial differential equation (PDE),which is a both spatially and temporally variant system.The robots can serve as mobile sensors,actuators,or both.Centroidal Voronoi Tessellations based coverage control algorithm is proposed for the cooperative sensing task.For the diffusion control problem,this paper considers spraying control via a group of networked mobile robots equipped with chemical neutralizers,known as smart mobile sprayers or actuators,in a domain of interest having static mesh sensor network for concentration sensing.This paper also introduces the information sharing and consensus strategy when using centroidal Voronoi tessellations algorithm to control a diffusion process.The information is shared not only on where to spray but also on how much to spray among the mobile actuators.Benefits from using CVT and information consensus seeking for sensing and control of a diffusion process are demonstrated in simulation results.

Kinetic modeling of high-temperature oxidation of pure Mg

A variety of experimental tracer diffusivities of Mg and O in magnesium oxide available in the literature were first assessed.Atomic mobilities including bulk and short-circuit diffusion of Mg and O were then obtained by means of the CALPHAD(Calculation of Phase Diagram)approach.Afterwards,the diffusion-controlled kinetic model of oxidation in a gas-MgO-Mg environment was developed based on the moving boundary model and Fick's law,coupling with the modified thermodynamic description of MgO.A mathematical expression for parabolic rate constant kp of the oxide scale was derived for magnesia and correlated with the thermodynamic and diffusion kinetic information.The evaluated kp results were in line with the experimental data.Finally,the oxidation process of pure magnesium at 673 K was model-predicted,and the predicted evolution of the oxide thicknesses agreed very well with the experimental data.It was indicated that the grain boundaries diffusion of magnesium cations predominated the high temperature oxidation process.

Implanting a preferential solid electrolyte interphase layer over anode electrode of lithium ion batteries for highly enhanced Li^+ diffusion properties

The lithium-ion batteries are recognized as the most promising energy storage system,but it still does not meet the power requirements of electric vehicle batteries owing to low volumetric energy density with the traditional graphite electrode system.In this study,we report the development of a novel electrode system fabricated by implantation of a solid electrolyte interphase(SEI)layer on the graphite surface.The SEI-implanted graphite electrode is made using a lithium bis(trifluoromethanesulfonyl)imide(LiTFSI)-based electrolyte and cycled with a lithium tetrafluoroborate LiBF4-based electrolyte.This new electrode system shows significantly enhanced electrochemical properties owing to the rapid and efficient diffusion of Li ions through the SEI layer between the electrolyte and electrode.This graphite electrode with its pre-formed SEI layer achieves a reversible capacity of 357 mAh g^-1 at 0.5 C after 50 cycles,which is significantly higher than that of commercial lithium-ion battery systems constructed with LiPF6(312mAh g^-1).The resulting unique electrode system could present a new avenue in SEI research for highperformance lithium-ion batteries.

A short review on diffusion coefficients in magnesium alloys and related applications

To have a better understand on the change of microstructure via kinetics, the diffusion behavior of Mg alloys is of special interest to researchers. Meanwhile, diffusion coefficients of Mg based alloys can explain and represent their diffusion behavior well. The evolution of experimental and calculated methods for detecting and extracting diffusion coefficients was discussed briefly. The reasonable diffusion data, especially self-diffusion coefficients, impurity diffusion coefficients and inter-diffusion coefficients of Mg alloys, were reviewed in detail serving to design the Mg alloys with higher accuracy. Then the practical applications of diffusion coefficients of Mg alloys were summarized,including diffusional mobility establishing, precipitation simulation and mechanical properties prediction.

An Improved Cooperative Team Spraying Control of a Diffusion Process With a Moving or Static Pollution Source

This paper is concerned with a control problem of a diffusion process with the help of static mesh sensor networks in a certain region of interest and a team of networked mobile actuators carrying chemical neutralizers.The major contribution of this paper can be divided into three parts:the first is the construction of a cyber-physical system framework based on centroidal Voronoi tessellations(CVTs),the second is the convergence analysis of the actuators location,and the last is a novel proportional integral(PI)control method for actuator motion planning and neutralizing control(e.g.,spraying)of a diffusion process with a moving or static pollution source,which is more effective than a proportional(P)control method.An optimal spraying control cost function is constructed.Then,the minimization problem of the spraying amount is addressed.Moreover,a new CVT algorithm based on the novel PI control method,henceforth called PI-CVT algorithm,is introduced together with the convergence analysis of the actuators location via a PI control law.Finally,a modified simulation platform called diffusion-mobile-actuators-sensors-2-dimension-proportional integral derivative(Diff-MAS2D-PID)is illustrated.In addition,a numerical simulation example for the diffusion process is presented to verify the effectiveness of our proposed controllers.

Carrier diffusion coefficient is independent of defects in CH_(3)NH_(3)PbBr_(3) single crystals:Direct evidence

Organolead halide perovskite solar cells have attracted extensive interests in recent years. Thanks to innovations in materials process and technology, the power conversion efficiency (PCE) of perovskites-based solar cells increases from 3.8% to 25.2%[1–4].In evaluating the quality of perovskite materials, a few key photophysical properties such as the lifetime, mobility and diffusion length of photogenerated carriers are usually measured.

Imperfect Trapping in a Random Walk with Both Species Mobile

It is presented here a continuous time random walk model for diffusion mediated reactions with both species mobile. The random walk is carried out over an infinite homogeneouos lattice. They are calculated the probability density for the time of reaction of a pair, the reaction rate and the time evolution of the concentration of the majority species. Analytical results are obtained in the Fourier-Laplace transform representation. Known results for a fixed trap are reobtained with appropriate marginal probabilities. It is thus justified Smoluchowski’s original approximation considering the trap at a fixed position and the majority species diffusing with a coefficient sum of the individual coefficients. The results obtained are illustrated by a one dimensional model with bias.

Transport of Electrons in Donor-Doped Silicon at Any Degree of Degeneracy of Electron Gas

The general expressions, based on the Fermi distribution of the free electrons, are applied for calculation of the kinetic coefficients in donor-doped silicon at arbitrary degree of the degeneracy of electron gas under equilibrium conditions. The classical statistics lead to large errors in estimation of the transport parameters for the materials where Fermi level is located high above the conduction band edge unless the effective density of randomly moving electrons is introduced. The obtained results for the diffusion coefficient and drift mobility are discussed together with practical approximations applicable for non-degenerate electron gas and materials with arbitrary degree of degeneracy. In particular, the drift mobility of randomly moving electrons is found to depend on the degree of degeneracy and can exceed the Hall mobility considerably. When the effective density is introduced, the traditional Einstein relation between the diffusion coefficient and the drift mobility of randomly moving electrons is conserved at any level of degeneracy. The main conclusions and formulae can be applicable for holes in acceptor-doped silicon as well.

Reverse Direction Micellar Electrokinetic Capillary Chromatography, Hydrostatic Flow Injection and Diffusional Injection Analysis： An Experimental Work

Separation was reported by Dunn, Hankins and Ghowsi for the case that ions incapillary electrophoresis move opposite to electroosmosis and ions move faster than flow finally they get separated and reach the detector. Similar mode for electrokinetic chromatography is reported for p-xylene and toluene separation, which is called reverse direction MECC （micellar electrokinetic capillary chromatography）. The effect of injection time on separation in reverse direction micellar electrokinetic capillary chromatography is investigated. In this study, hydrostatic and diffusion injection were studied.

Epidemic-Like Proximity-Based Traffic Offloading

Cellular networks are overloaded due to the mobile traffic surge,and mobile social networks(MSNets) can be leveraged for traffic offloading.In this paper,we study the issue of choosing seed users for maximizing the mobile traffic offloaded from cellular networks.We introduce a gossip-style social cascade(GSC) model to model the epidemic-like information diffusion process in MSNets.For static-case and mobile-case networks,we establish an equivalent view and a temporal mapping of the information diffusion process,respectively.We further prove the submodularity in the information diffusion and propose a greedy algorithm to choose the seed users for traffic offloading,yielding a sub-optimal solution to the NP-hard traffic offloading maximization(TOM) problem.Experiments are carried out to study the offloading performance,illustrating that the greedy algorithm significantly outperforms the heuristic and random algorithms,and user mobility can help further reduce cellular load.

Technology Sub-diffusions:Consumptive Motivations for Mobile Phone Calls and Digital Services

Digital services interfaced with mobile phone lines are gradually being regarded as a core product in this modern age due to the high transmission speed of mobile technology.The research in this paper is based on the concept of product inter-dependence and actively explores the different consumptive motivations between the consumers' behavior of phone-call users and those who use digital services.This study also attempts to use a modifi ed diffusion model to estimate the consumers' collective behavior with a longitudinal approach.In this study,it can be inferred that psychological consumer motivations should dominate marketing policies.Thus,it was found that digital service users have more self-motivation and autonomy when adopting a new product because they have significantly higher innovative at-tributes than the segment of phone-call users.With these findings,we claim that we have discovered an unprec-edented concept for marketing managers who welcome the challenges of mobile digital services in the future.

基于“三焦生精”理论治疗成人原发免疫性血小板减少症

原发免疫性血小板减少症是一种免疫介导的以血小板减少为主要特征的疾病,归属于中医“紫癜病”范畴,临床多从火热亢盛、气虚失摄、脾不统血、肾虚火旺等方面论治。三焦理论始于《黄帝内经》,三焦具有通行原气,运化水液两大基本功能,该文首先对“三焦生精”的理论内涵进行阐述,其次基于“三焦生精”理论探讨原发免疫性血小板减少症的病机及治法,最后通过对一则验案进一步分析,以期为临床治疗原发免疫性血小板减少症拓宽思路。