China’s past economic growth has substantially relied on fossil fuels,causing serious air pollution issues.Decoupling economic growth and pollution has become the focus in developing ecological civilization in China....China’s past economic growth has substantially relied on fossil fuels,causing serious air pollution issues.Decoupling economic growth and pollution has become the focus in developing ecological civilization in China.We have analyzed the three-decade progress of air pollution controls in China,highlighting a strategic transformation from emission control toward air quality management.Emission control of sulfur dioxide(SO2)resolved the deteriorating acid rain issue in China in 2007.Since 2013,control actions on multiple precursors and sectors have targeted the reduction of the concentration of fine particulate matter(PM2.5),marking a transition to an air-quality-oriented strategy.Increasing ozone(O3)pollution further requires O3 and PM2.5 integrated control strategies with an emphasis on their complex photochemical interactions.Fundamental improvement of air quality in China,as a key indicator for the success of ecological civilization construction,demands the deep de-carbonization of China’s energy system as well as more synergistic pathways to address air pollution and global climate change simultaneously.展开更多
Increasing attention has been paid to air pollution control (APC) residues in China recently due to the rising proportion of waste incineration and the hazardous characteristics of the residues, among which heavy me...Increasing attention has been paid to air pollution control (APC) residues in China recently due to the rising proportion of waste incineration and the hazardous characteristics of the residues, among which heavy metal leaching toxicity plays an important role. Leaching behavior and potential risk of Pb and Zn in the APC residues from a Shanghai municipal solid waste (MSW) incinerator was studied, based on the leaching tests under different conditions and theoretical calculation using a geochemical thermodynamic equilibrium model MINTEQA2. Results showed that, extractant species and liquid to solid (L/S) ratio predominantly controlled the leaching toxicity of Pb and Zn, while ionic strength, vibration method and leaching time had less effect on the metals release. Leachate/final pH determined the metal leaching behavior, which changed the speciation of heavy metals in the extraction system. The equilibrium aqueous speciation, precipitation-dissolution of Pb and Zn was investigated according to the model computation, which was well in agreement with the experimental results.展开更多
With the rapid development of industry and energy,the emission of a large number of SO2 has brought serious harm to the global environment.This paper introduces several main SO2 control technologies and describes the ...With the rapid development of industry and energy,the emission of a large number of SO2 has brought serious harm to the global environment.This paper introduces several main SO2 control technologies and describes the progress of the advanced desulfurization technologies at home and abroad.At last,higher requirements on desulfurization technology are raised.展开更多
Air pollution control devices (APCDs) are installed at coal-fired power plants for air pollutant regulation. Selective catalytic reduction (SCR) and wet flue gas desulftLrization (FGD) systems have the co-benefi...Air pollution control devices (APCDs) are installed at coal-fired power plants for air pollutant regulation. Selective catalytic reduction (SCR) and wet flue gas desulftLrization (FGD) systems have the co-benefits of air pollutant and mercury removal. Configuration and operational conditions of APCDs and mercury speciation affect mercury removal efficiently at coal-fired utilities. The Ontario Hydro Method (OHM) recommended by the U.S. Environmental Protection Agency (EPA) was used to determine mercury speciation simultaneously at five sampling locations through SCR-ESP-FGD at a 190 MW unit. Chlorine in coal had been suggested as a factor affecting the mercury speciation in flue gas; and low-chlorine coal was purported to produce less oxidized mercury (Hg^2+) and more elemental mercury (Hg^0) at the SCR inlet compared to higher chlorine coal. SCR could oxidize elemental mercury into oxidized mercury when SCR was in service, and oxidation efficiency reached 71.0%. Therefore, oxidized mercury removal efficiency was enhanced through a wet FGD system. In the non-ozone season, about 89.5%-96.8% of oxidized mercury was controlled, but only 54.9%-68.8% of the total mercury was captured through wet FGD. Oxidized mercury removal efficiency was 95.9%-98.0%, and there was a big difference in the total mercury removal efficiencies from 78.0% to 90.2% in the ozone season. Mercury mass balance was evaluated to validate reliability of OHM testing data, and the ratio of mercury input in the coal to mercury output at the stack was from 0.84 to 1.08.展开更多
Since the implementation of the Action Plan for Air Pollution Prevention and Control , all regions of China have steadily promoted the prevention and control of air pollution and achieved results continuously. However...Since the implementation of the Action Plan for Air Pollution Prevention and Control , all regions of China have steadily promoted the prevention and control of air pollution and achieved results continuously. However, the atmospheric environment in key areas such as Beijing-Tianjin-Hebei region, the Yangtze River Delta region, and Fenwei Plain is still severe, and especially during the heating period heavy pollution occurs frequently, which has become the focus and difficulty of improving the quality of the atmospheric environment and is also the weakest link of China s air pollution control at present. How to alleviate air pollution, how to win the battle of pollution prevention and control, how to hold the fruits of the blue sky defense war, energy consumption is key.展开更多
Introduction: The Indian state of Uttar Pradesh (UP) for the past many years has been reported to have many cities with highly polluted air quality. The state has been taking meticulous steps in combating air pollutio...Introduction: The Indian state of Uttar Pradesh (UP) for the past many years has been reported to have many cities with highly polluted air quality. The state has been taking meticulous steps in combating air pollution in the form of action plans, introduced especially in its 17 non-attainment cities (NAC). To assess the progress and development of these action plans in UP, the present study has done an in-depth analysis and review of the state’s action plans and city micro action plans. Materials and Methods: In this research study, the analysis of the latest action plan reports, micro action plan reports as well as the recommendations for combating air pollution-related issues in the 17 NAC of the UP state has been well documented. Uttar Pradesh Pollution Control Board (UPPCB) has prepared these reports to highlight the progress of the plans in response to the growing air pollution in these cities. The information present in the reports has been used to further study sector-specific, category-specific action plans, institutional responsibility, and the present status of the action plans. Results: On average, the highest weightage in action plans was given to sector-specific categories such as Road dust and construction activities (24%). It was also observed that Urban local bodies (~50%) were majorly responsible to implement the action points and 56% of the action points were jointly implemented by multiple agencies.展开更多
The hourly and daily air quality concentration in the total air pollutant emission amount control zone is not sure to be continuously up to national ambient air quality standard, even though the total annual air pollu...The hourly and daily air quality concentration in the total air pollutant emission amount control zone is not sure to be continuously up to national ambient air quality standard, even though the total annual air pollutant emission is permitted under the total air pollutant emission amount control (TAPEAC) on the basis of A-value method. So the concept of the environmental quality guarantee ratio (EQGR) for TAPEAC is advanced in this paper and its quantitative formula is figured out for both hourly and daily EQGR. It is concluded that the EQGR is related with the yearly arrangement of A-value besides the pollutant type. According to the meteorological data in a lower area along Yangtze River in 2000, the yearly A-value trend is analyzed. Based on the data, the hourly EQGR of SO 2 and NO 2 is respectively 97.4% and 90.2%, and daily EQGR respectively 90.2% and 79.5%.展开更多
The research aimed to apply phytoindication for controlling air pollution with chlorine and lead in Yerevan. The research was performed between 2005 and 2008.5 arboreous species were studied: Robinia pseudoacacia L.,...The research aimed to apply phytoindication for controlling air pollution with chlorine and lead in Yerevan. The research was performed between 2005 and 2008.5 arboreous species were studied: Robinia pseudoacacia L., Fraxinus excelsior L., Populus alba L., Morus alba L. and Uitis vinifera L.. The research showed that arboreous plants growing in the city accumulate chlorine and lead. Chlorine concentrations in all 5 species varied from 0.50% to 1.77%, and the maximum value was found in Robiniapseudoacacia L., exceeding the control by 3.6 times. As for the level of lead in plants, the concentration varied between 1.64-7.65 mg/kg, and the maximum rate exceeds the background (2.0 mg/kg) by 3.8 times. The authors produced a schematic map of chlorine distribution all over the city, territory, and detected the most polluted zones. According to the data the autbtors collected, only 3 of 5 studied species displayed high intake rate and tolerance to lead and chlorine pollution: Robinia pseudoacacia L.. Fraxinus excelsior L. and Populus alba L. Thus, the authors advise these species for planting in Yerevan. The results of this research were used by the Municipality of Yerevan for functional tree planting in the city.展开更多
The spatial spillover of air pollution in Beijing-Tianjin-Hebei region makes the territorial governance model inefficient.At the same time,it is facing the contradiction between environmental governance and economic d...The spatial spillover of air pollution in Beijing-Tianjin-Hebei region makes the territorial governance model inefficient.At the same time,it is facing the contradiction between environmental governance and economic development.So far,there is still no regional long-term mechanism for coordinated governance of air pollution.Ecological compensation theory is becoming an effective guiding theory to coordinate economic and environmental benefits.There is relatively little research on ecological compensation mechanism in the coordinated control of regional air pollution.Ecological compensation mechanism is an effective tool to promote air pollution control.At the same time,regional cooperation can realize the efficient control of air pollution.Scientifically constructing the cross regional cooperative control model of Beijing,Tianjin and Hebei is a favorable way to implement comprehensive control of air pollution.This paper discusses the necessity of ecological compensation mechanism for regional coordinated control of air pollution.Referring to practical experience of provinces and cities that have implemented the ecological compensation mechanism for air pollution control,and the effective way to distribute the compensation amount,compensation subject and compensation standard determination method that can be implemented in Beijing-Tianjin-Hebei region are analyzed,further proposing an effective way to establish an ecological compensation mechanism for regional air pollution collaborative control according to its reality.展开更多
At present,China’s atmospheric environmental protection work has achieved initial results,but environmental protection is facing increasing pressure,and the environmental situation is still not optimistic.In response...At present,China’s atmospheric environmental protection work has achieved initial results,but environmental protection is facing increasing pressure,and the environmental situation is still not optimistic.In response to the call of the state,efforts have been intensified in environmental protection and ecological civilization construction,and supply-side structural reform has been actively promoted,and the Implementation Plan for Tianjin’s Comprehensive Discharge of Industrial Pollution Sources to Meet Standards has been promoted.When the total amount of pollutants discharged in key areas far exceeds the environmental capacity,regional heavy pollution weather will still occur once adverse meteorological conditions are encountered.In accordance with the Law of the People’s Republic of China on the Prevention and Control of Atmospheric Pollution,when the deterioration of air quality to a certain extent,to protect public health,key gas related industries should carry out emergency emission reduction in accordance with the local emergency plan while the local government starts the emergency response of heavy pollution weather.Direct economic loss of emergency response to heavy pollution weather is enormous.On the basis of meeting the total amount of emissions required by the state,the project aims to achieve the effect of"emission reduction and production increase"by precise emission reduction according to local characteristics.展开更多
The COVID-19 lockdowns led to abrupt reductions in human-related emissions worldwide and had an unintended impact on air quality improvement.However,quantifying this impact is difficult as meteorological conditions ma...The COVID-19 lockdowns led to abrupt reductions in human-related emissions worldwide and had an unintended impact on air quality improvement.However,quantifying this impact is difficult as meteorological conditions may mask the real effect of changes in emissions on the observed concentrations of pollutants.Based on the air quality and meteorological data at 35 sites in Beijing from 2015 to 2020,a machine learning technique was applied to decouple the impacts of meteorology and emissions on the concentrations of air pollutants.The results showed that the real(“deweathered”)concentrations of air pollutants(expect for O 3)dropped significantly due to lockdown measures.Compared with the scenario without lockdowns(predicted concentrations),the observed values of PM_(2.5),PM_(10),SO_(2),NO_(2),and CO during lockdowns decreased by 39.4%,50.1%,51.8%,43.1%,and 35.1%,respectively.In addition,a significant decline for NO_(2)and CO was found at the background sites(51%and 37.8%)rather than the traffic sites(37.1%and 35.5%),which is different from the common belief.While the primary emissions reduced during the lockdown period,episodic haze events still occurred due to unfavorable meteorological conditions.Thus,developing an optimized strategy to tackle air pollution in Beijing is essential in the future.展开更多
A synergistic pathway is regarded as a critical measure for tackling the intertwined challenges of climate change and air pollution in China. However, there is as yet no indicator that can comprehensively reflect such...A synergistic pathway is regarded as a critical measure for tackling the intertwined challenges of climate change and air pollution in China. However, there is as yet no indicator that can comprehensively reflect such synergistic effects;hence, existing studies lack a consistent framework for comparison. Here, we introduce a new synergistic indicator defined as the pollutant generation per gross domestic product (GDP) and adopt an integrated analysis framework by linking the logarithmic mean Divisia index (LMDI) method, response surface model (RSM), and global exposure mortality model (GEMM) to evaluate the synergistic effects of carbon mitigation on both air pollutant reduction and public health in China. The results show that synergistic effects played an increasingly important role in the emissions mitigation of SO_(2), NOx, and primary particulate matter with an aerodynamic diameter no greater than 2.5 μm (PM2.5), and the synergistic mitigation of pollutants respectively increase from 3.1, 1.4, and 0.3 Mt during the 11th Five-Year Plan (FYP) (2006–2010) to 5.6, 3.7, and 1.9 Mt during the 12th FYP (2011–2015). Against the non-control scenario, synergistic effects alone contributed to a 15% reduction in annual mean PM2.5 concentration, resulting in the prevention of 0.29 million (95% confidential interval: 0.28–0.30) PM2.5-attributable excess deaths in 2015. Synergistic benefits to air quality improvement and public health were remarkable in the developed and population-dense eastern provinces and municipalities. With the processes of urbanization and carbon neutrality in the future, synergistic effects are expected to continue to increase. Realizing climate targets in advance in developed regions would concurrently bring strong synergistic effects to air quality and public health.展开更多
Research and development of efficient, economical and resource-based flue gas desulfurization technology has always been a hot spot in the field of air pollution control. Molecular sieve materials have been paid atten...Research and development of efficient, economical and resource-based flue gas desulfurization technology has always been a hot spot in the field of air pollution control. Molecular sieve materials have been paid attention to by SO<sub>2</sub> adsorbent researchers due to their huge specific surface area. In this paper, 13X zeolite was modified with Cu(NO<sub>3</sub>) <sub>2</sub>·3H<sub>2</sub>O to obtain 13x-Xwt %CuO (calculated by the amount of CuO loaded). The adsorption time and capacity of SO<sub>2</sub> penetration sorbent and the isothermal curve of N<sub>2</sub> adsorption-desorption were studied. The results are as follows: 13X-3wt%CuO has the best adsorption effect, the penetration adsorption time is 110 min, the penetration adsorption capacity is 43.41 mg·g<sup>-1</sup>, the saturation adsorption capacity is 49.27 mg·g<sup>-1</sup>;The amount of CuO loading has a great influence on the adsorption effect of modified 13X molecular sieve on SO<sub>2</sub>. SEM and BET characterization showed that CuO modification did not change the external morphology of 13X molecular sieve, changed the pore size, but did not block the original channel of the molecular sieve, before and after modification belong to the type I adsorption isothermal curve. The pore size distribution and type of molecular sieve, as well as the content and type of alkali metal cations jointly control the adsorption process of SO<sub>2</sub> by 13X-xwt %CuO. XPS characterization showed that Cu(NO<sub>3</sub>) <sub>2</sub> decomposed into CuO and Cu<sub>2</sub>O during roasting at 450°C, CuO/Cu<sub>2</sub>O ≈ 1.5. The R<sup>2</sup> values of the quasi-second-order kinetic models obtained from the 13X-Xwt %CuO particle diffusion kinetic models were all above 0.99, indicating that the quasi-second-order kinetic equations were more relevant. Particle diffusion dynamics model in fitting results show that the adsorption process can be divided into two stages, the first phase of surface adsorption and diffusion rate in the granules common control process, more accurate dynamics model of the secondary in the second phase particle diffusion rate control stage, mainly for the micropore adsorption or chemical adsorption, quasi level 2 dynamic model conformity of variation;C is a constant not equal to 0, indicating that the adsorption of SO<sub>2</sub> is not completely through the form of intra-particle diffusion, and a small amount of chemisorption exists. And it is the compound effect of multiple adsorption mechanisms.展开更多
Air pollution poses a critical threat to public health and environmental sustainability globally, and Nigeria is no exception. Despite significant economic growth and urban development, Nigeria faces substantial air q...Air pollution poses a critical threat to public health and environmental sustainability globally, and Nigeria is no exception. Despite significant economic growth and urban development, Nigeria faces substantial air quality challenges, particularly in urban centers. While outdoor air pollution has received considerable attention, the issue of indoor air quality remains underexplored yet equally critical. This study aims to develop a reliable, cost-effective, and user-friendly solution for continuous monitoring and reporting of indoor air quality, accessible from anywhere via a web interface. Addressing the urgent need for effective indoor air quality monitoring in urban hospitals, the research focuses on designing and implementing a smart indoor air quality monitoring system using Arduino technology. Employing an Arduino Uno, ESP8266 Wi-Fi module, and MQ135 gas sensor, the system collects real-time air quality data, transmits it to the ThingSpeak cloud platform, and visualizes it through a user-friendly web interface. This project offers a cost-effective, portable, and reliable solution for monitoring indoor air quality, aiming to mitigate health risks and promote a healthier living environment.展开更多
Man made activities are changing environment of our planet earth.Various methods are used to reduce the environmental pollution.In this paper the methods of air/water/soil pollution mitigation/reduction using electrom...Man made activities are changing environment of our planet earth.Various methods are used to reduce the environmental pollution.In this paper the methods of air/water/soil pollution mitigation/reduction using electromagnetic fields is discussed.Air/water/soil contains ions and the energy transfer for living organisms takes place by ion exchange processes.Ions are affected by electric/magnetic fields.Many investigators展开更多
Due to the high viscosity of magnetorheological(MR)fluid,eliminating air pockets dissolved in the fluid is very difficult,which results in a force lag phenomenon.In order to evaluate the performance of a semi-active c...Due to the high viscosity of magnetorheological(MR)fluid,eliminating air pockets dissolved in the fluid is very difficult,which results in a force lag phenomenon.In order to evaluate the performance of a semi-active control system based on the MR damper considering the trapped air effect,a performance test on a MR damper is carried out under different loading cases,and the influence of the input current,excitation amplitude and frequency on the force lag phenomenon is analyzed.A concise and efficient parametric model,combining the simple Bouc-Wen model and a spring with small stiffness,is proposed to portray the experimental characteristics of the MR damper with force lag,and then the response analysis of the semi-active controlled single-degree-of-freedom(SDOF)structure is performed using the classic clipped-optimal control strategy based on acceleration feedback.Numerical results show that the trapped air in the MR fluid can weaken the control effect of the MR damper,and the performance of the semi-active control system will be reduced more obviously and become close to the passive-off control with the increasing content of air trapped in the MR fluid.展开更多
Air pollution is a hot issue studied by scholars all over the world.Academic circles generally believe that socio-economic factors such as extensive economic growth,unbalanced proportion of industrial structure and un...Air pollution is a hot issue studied by scholars all over the world.Academic circles generally believe that socio-economic factors such as extensive economic growth,unbalanced proportion of industrial structure and unreasonable energy consumption structure are the main"culprits"of serious air pollution in China.Therefore,the relationship between air pollution and socio-economic growth has very important theoretical and practical significance for air pollution prevention and control and promoting the sustainable and healthy development of cities.Through literature research and summary methods,this paper studies the severity and harmfulness of air pollution in China,and deeply studies the research progress of socio-economic influencing factors of air pollution,environmental Kuznets curve hypothesis of air pollution,decoupling relationship between air pollution and socio-economic growth,so as to provide useful reference for the prevention and control of air pollution.展开更多
A novel bioactive foam emulsion bioreactor for benzene,toluene and xylene(BTX)contaminated air streams treatment has been developed.The gas-liquid interfacial area by biocompatible foam and driving force for mass tran...A novel bioactive foam emulsion bioreactor for benzene,toluene and xylene(BTX)contaminated air streams treatment has been developed.The gas-liquid interfacial area by biocompatible foam and driving force for mass transfer by a water immiscible organic phase were increased in this reactor.The effect of several parameters such as gas residence time,oxygen content,and organic phase concentration on bioreactor performance was studied. Experimental results showed an average elimination capacity(EC)of 220 g·m3·h -1with removal efficiency(RE) of 89.59%for BTX inlet concentration of 1 g·m3at 15 s gas residence time in the bioreactor.The statistical developed model predicted that the maximum elimination capacity of the reactor for BTX could be reached to 423.45 g·m3·h -1.Continues operation of the bioreactor with high EC and RE was demonstrated by optimizing the operational parameters of the bioreactor.Overall the results suggest that the bioreactor developed can be very effective systems to treat BTX vapors.展开更多
The direct sulfation of limestone from different sources in Iran was studiedin a thermogravimetric analyzer under atmospheric pressure. All limestone samples tested have higherthan 97% CaCO_3. Experimental conditions ...The direct sulfation of limestone from different sources in Iran was studiedin a thermogravimetric analyzer under atmospheric pressure. All limestone samples tested have higherthan 97% CaCO_3. Experimental conditions were as follows: particle size levels ranging from 1.6 μmto 7.8 μm, four level reaction temperatures (700℃, 750℃, 800℃ and 850℃), and two SO_2concentrations (2.4 x 10^(-3) and 3.2 x 10^(-3) mol · mol^(-1)). The particle size and temperatureshowed dominant influences on the rate and level of conversion while the effect of SO_2concentration was weak. The shrinking core model can be used to describe the behavior of thesulfation process. The reaction kinetics and diffusion mechanism are both important in controllingthe rate of the process. The two key parameters of the model, chemical rate constant K_s andeffective diffusion coefficient D_(eff) were obtained. Model predictions are in good agreement withthe experimental data.展开更多
Activated red mud(RM)has been proved to be a promising base material for the selective catalysis reduction(SCR)of NOx.The inherent low reducibility and acidity limited its low-temperature activity.In this work,molybde...Activated red mud(RM)has been proved to be a promising base material for the selective catalysis reduction(SCR)of NOx.The inherent low reducibility and acidity limited its low-temperature activity.In this work,molybdenum oxide,tungsten oxide,and cerium oxide were used to reconfigure the redox sites and acid sites of red mud based catalyst.When activated red mud was reconfigured by cerium-tungsten oxide(Ce-W@RM),the NOx conversion kept above 90%at 219-480℃.The existence of Ce^(3+)/Ce^(4+) redox electron pairs provided more surface adsorbed oxygen(O_(α)) and served as a redox cycle.Positive interactions between Ce,W species and Fe oxide in red mud occurred,which led to the formation of unsaturated chemical bond and promoted the activation of adsorbed NH_(3) species.WO_(3) and Ce_(2)(WO_(4))_(3)(formed by solid-state reaction between Ce and W species)could provide more Brønsted acid sites(W-O modes of WO_(3),W=O or W-O-W modes of Ce_(2)(WO_(4))_(3)).CeO_(2) species could provide more Lewis acid sites.The Langmuir-Hinshelwood(L-H)routes and Eley-Rideal(E-R)routes occurred in the low-temperature SCR reaction on the Ce-W@RM surface.NH_(4)^(+) species on Brønsted acid sites,NH_(3) species on Lewis acid sites,bidentate nitrate and bridging nitrate species were key active intermediates species.展开更多
基金the National Key Research Development Program of China(2016YFC0208901 and 2017YFC0212100)the National Natural Science Foundation of China(71722003 and 71690244)。
文摘China’s past economic growth has substantially relied on fossil fuels,causing serious air pollution issues.Decoupling economic growth and pollution has become the focus in developing ecological civilization in China.We have analyzed the three-decade progress of air pollution controls in China,highlighting a strategic transformation from emission control toward air quality management.Emission control of sulfur dioxide(SO2)resolved the deteriorating acid rain issue in China in 2007.Since 2013,control actions on multiple precursors and sectors have targeted the reduction of the concentration of fine particulate matter(PM2.5),marking a transition to an air-quality-oriented strategy.Increasing ozone(O3)pollution further requires O3 and PM2.5 integrated control strategies with an emphasis on their complex photochemical interactions.Fundamental improvement of air quality in China,as a key indicator for the success of ecological civilization construction,demands the deep de-carbonization of China’s energy system as well as more synergistic pathways to address air pollution and global climate change simultaneously.
基金The Key Project of Shanghai Council of Science and Technology(No. 032312043)
文摘Increasing attention has been paid to air pollution control (APC) residues in China recently due to the rising proportion of waste incineration and the hazardous characteristics of the residues, among which heavy metal leaching toxicity plays an important role. Leaching behavior and potential risk of Pb and Zn in the APC residues from a Shanghai municipal solid waste (MSW) incinerator was studied, based on the leaching tests under different conditions and theoretical calculation using a geochemical thermodynamic equilibrium model MINTEQA2. Results showed that, extractant species and liquid to solid (L/S) ratio predominantly controlled the leaching toxicity of Pb and Zn, while ionic strength, vibration method and leaching time had less effect on the metals release. Leachate/final pH determined the metal leaching behavior, which changed the speciation of heavy metals in the extraction system. The equilibrium aqueous speciation, precipitation-dissolution of Pb and Zn was investigated according to the model computation, which was well in agreement with the experimental results.
文摘With the rapid development of industry and energy,the emission of a large number of SO2 has brought serious harm to the global environment.This paper introduces several main SO2 control technologies and describes the progress of the advanced desulfurization technologies at home and abroad.At last,higher requirements on desulfurization technology are raised.
基金supported by the U.S.Agency for International Development (USAID) cooperation agreement(No.486-A-00-06-000140-00)
文摘Air pollution control devices (APCDs) are installed at coal-fired power plants for air pollutant regulation. Selective catalytic reduction (SCR) and wet flue gas desulftLrization (FGD) systems have the co-benefits of air pollutant and mercury removal. Configuration and operational conditions of APCDs and mercury speciation affect mercury removal efficiently at coal-fired utilities. The Ontario Hydro Method (OHM) recommended by the U.S. Environmental Protection Agency (EPA) was used to determine mercury speciation simultaneously at five sampling locations through SCR-ESP-FGD at a 190 MW unit. Chlorine in coal had been suggested as a factor affecting the mercury speciation in flue gas; and low-chlorine coal was purported to produce less oxidized mercury (Hg^2+) and more elemental mercury (Hg^0) at the SCR inlet compared to higher chlorine coal. SCR could oxidize elemental mercury into oxidized mercury when SCR was in service, and oxidation efficiency reached 71.0%. Therefore, oxidized mercury removal efficiency was enhanced through a wet FGD system. In the non-ozone season, about 89.5%-96.8% of oxidized mercury was controlled, but only 54.9%-68.8% of the total mercury was captured through wet FGD. Oxidized mercury removal efficiency was 95.9%-98.0%, and there was a big difference in the total mercury removal efficiencies from 78.0% to 90.2% in the ozone season. Mercury mass balance was evaluated to validate reliability of OHM testing data, and the ratio of mercury input in the coal to mercury output at the stack was from 0.84 to 1.08.
基金Supported by Special Project for Research on Prevention and Control of Air Pollution from Fire Coal in 2018 of Ministry of Ecology and Environment of the People’s Republic of China(2018A030)National Natural Science Foundation of China(41771498)
文摘Since the implementation of the Action Plan for Air Pollution Prevention and Control , all regions of China have steadily promoted the prevention and control of air pollution and achieved results continuously. However, the atmospheric environment in key areas such as Beijing-Tianjin-Hebei region, the Yangtze River Delta region, and Fenwei Plain is still severe, and especially during the heating period heavy pollution occurs frequently, which has become the focus and difficulty of improving the quality of the atmospheric environment and is also the weakest link of China s air pollution control at present. How to alleviate air pollution, how to win the battle of pollution prevention and control, how to hold the fruits of the blue sky defense war, energy consumption is key.
文摘Introduction: The Indian state of Uttar Pradesh (UP) for the past many years has been reported to have many cities with highly polluted air quality. The state has been taking meticulous steps in combating air pollution in the form of action plans, introduced especially in its 17 non-attainment cities (NAC). To assess the progress and development of these action plans in UP, the present study has done an in-depth analysis and review of the state’s action plans and city micro action plans. Materials and Methods: In this research study, the analysis of the latest action plan reports, micro action plan reports as well as the recommendations for combating air pollution-related issues in the 17 NAC of the UP state has been well documented. Uttar Pradesh Pollution Control Board (UPPCB) has prepared these reports to highlight the progress of the plans in response to the growing air pollution in these cities. The information present in the reports has been used to further study sector-specific, category-specific action plans, institutional responsibility, and the present status of the action plans. Results: On average, the highest weightage in action plans was given to sector-specific categories such as Road dust and construction activities (24%). It was also observed that Urban local bodies (~50%) were majorly responsible to implement the action points and 56% of the action points were jointly implemented by multiple agencies.
文摘The hourly and daily air quality concentration in the total air pollutant emission amount control zone is not sure to be continuously up to national ambient air quality standard, even though the total annual air pollutant emission is permitted under the total air pollutant emission amount control (TAPEAC) on the basis of A-value method. So the concept of the environmental quality guarantee ratio (EQGR) for TAPEAC is advanced in this paper and its quantitative formula is figured out for both hourly and daily EQGR. It is concluded that the EQGR is related with the yearly arrangement of A-value besides the pollutant type. According to the meteorological data in a lower area along Yangtze River in 2000, the yearly A-value trend is analyzed. Based on the data, the hourly EQGR of SO 2 and NO 2 is respectively 97.4% and 90.2%, and daily EQGR respectively 90.2% and 79.5%.
文摘The research aimed to apply phytoindication for controlling air pollution with chlorine and lead in Yerevan. The research was performed between 2005 and 2008.5 arboreous species were studied: Robinia pseudoacacia L., Fraxinus excelsior L., Populus alba L., Morus alba L. and Uitis vinifera L.. The research showed that arboreous plants growing in the city accumulate chlorine and lead. Chlorine concentrations in all 5 species varied from 0.50% to 1.77%, and the maximum value was found in Robiniapseudoacacia L., exceeding the control by 3.6 times. As for the level of lead in plants, the concentration varied between 1.64-7.65 mg/kg, and the maximum rate exceeds the background (2.0 mg/kg) by 3.8 times. The authors produced a schematic map of chlorine distribution all over the city, territory, and detected the most polluted zones. According to the data the autbtors collected, only 3 of 5 studied species displayed high intake rate and tolerance to lead and chlorine pollution: Robinia pseudoacacia L.. Fraxinus excelsior L. and Populus alba L. Thus, the authors advise these species for planting in Yerevan. The results of this research were used by the Municipality of Yerevan for functional tree planting in the city.
基金Supported by Beijing Natural Science Foundation Project(9192002)Key Projects of Beijing Social Science Foundation(19YJA002)。
文摘The spatial spillover of air pollution in Beijing-Tianjin-Hebei region makes the territorial governance model inefficient.At the same time,it is facing the contradiction between environmental governance and economic development.So far,there is still no regional long-term mechanism for coordinated governance of air pollution.Ecological compensation theory is becoming an effective guiding theory to coordinate economic and environmental benefits.There is relatively little research on ecological compensation mechanism in the coordinated control of regional air pollution.Ecological compensation mechanism is an effective tool to promote air pollution control.At the same time,regional cooperation can realize the efficient control of air pollution.Scientifically constructing the cross regional cooperative control model of Beijing,Tianjin and Hebei is a favorable way to implement comprehensive control of air pollution.This paper discusses the necessity of ecological compensation mechanism for regional coordinated control of air pollution.Referring to practical experience of provinces and cities that have implemented the ecological compensation mechanism for air pollution control,and the effective way to distribute the compensation amount,compensation subject and compensation standard determination method that can be implemented in Beijing-Tianjin-Hebei region are analyzed,further proposing an effective way to establish an ecological compensation mechanism for regional air pollution collaborative control according to its reality.
文摘At present,China’s atmospheric environmental protection work has achieved initial results,but environmental protection is facing increasing pressure,and the environmental situation is still not optimistic.In response to the call of the state,efforts have been intensified in environmental protection and ecological civilization construction,and supply-side structural reform has been actively promoted,and the Implementation Plan for Tianjin’s Comprehensive Discharge of Industrial Pollution Sources to Meet Standards has been promoted.When the total amount of pollutants discharged in key areas far exceeds the environmental capacity,regional heavy pollution weather will still occur once adverse meteorological conditions are encountered.In accordance with the Law of the People’s Republic of China on the Prevention and Control of Atmospheric Pollution,when the deterioration of air quality to a certain extent,to protect public health,key gas related industries should carry out emergency emission reduction in accordance with the local emergency plan while the local government starts the emergency response of heavy pollution weather.Direct economic loss of emergency response to heavy pollution weather is enormous.On the basis of meeting the total amount of emissions required by the state,the project aims to achieve the effect of"emission reduction and production increase"by precise emission reduction according to local characteristics.
基金This work was supported by the National Natural Science Foundation of China(Grant number 42077204)the National Key Research and Development Project(Grant number 2017YFC0210103)with data support provided by the National Earth System Science Data Center,National Science&Technology Infrastructure of China(http://www.geodata.cn).
文摘The COVID-19 lockdowns led to abrupt reductions in human-related emissions worldwide and had an unintended impact on air quality improvement.However,quantifying this impact is difficult as meteorological conditions may mask the real effect of changes in emissions on the observed concentrations of pollutants.Based on the air quality and meteorological data at 35 sites in Beijing from 2015 to 2020,a machine learning technique was applied to decouple the impacts of meteorology and emissions on the concentrations of air pollutants.The results showed that the real(“deweathered”)concentrations of air pollutants(expect for O 3)dropped significantly due to lockdown measures.Compared with the scenario without lockdowns(predicted concentrations),the observed values of PM_(2.5),PM_(10),SO_(2),NO_(2),and CO during lockdowns decreased by 39.4%,50.1%,51.8%,43.1%,and 35.1%,respectively.In addition,a significant decline for NO_(2)and CO was found at the background sites(51%and 37.8%)rather than the traffic sites(37.1%and 35.5%),which is different from the common belief.While the primary emissions reduced during the lockdown period,episodic haze events still occurred due to unfavorable meteorological conditions.Thus,developing an optimized strategy to tackle air pollution in Beijing is essential in the future.
基金supported by the National Natural Science Foundation of China(72025401,71974108,and 72140003)the Tsinghua University-INDITEX Sustainable Development Fund.
文摘A synergistic pathway is regarded as a critical measure for tackling the intertwined challenges of climate change and air pollution in China. However, there is as yet no indicator that can comprehensively reflect such synergistic effects;hence, existing studies lack a consistent framework for comparison. Here, we introduce a new synergistic indicator defined as the pollutant generation per gross domestic product (GDP) and adopt an integrated analysis framework by linking the logarithmic mean Divisia index (LMDI) method, response surface model (RSM), and global exposure mortality model (GEMM) to evaluate the synergistic effects of carbon mitigation on both air pollutant reduction and public health in China. The results show that synergistic effects played an increasingly important role in the emissions mitigation of SO_(2), NOx, and primary particulate matter with an aerodynamic diameter no greater than 2.5 μm (PM2.5), and the synergistic mitigation of pollutants respectively increase from 3.1, 1.4, and 0.3 Mt during the 11th Five-Year Plan (FYP) (2006–2010) to 5.6, 3.7, and 1.9 Mt during the 12th FYP (2011–2015). Against the non-control scenario, synergistic effects alone contributed to a 15% reduction in annual mean PM2.5 concentration, resulting in the prevention of 0.29 million (95% confidential interval: 0.28–0.30) PM2.5-attributable excess deaths in 2015. Synergistic benefits to air quality improvement and public health were remarkable in the developed and population-dense eastern provinces and municipalities. With the processes of urbanization and carbon neutrality in the future, synergistic effects are expected to continue to increase. Realizing climate targets in advance in developed regions would concurrently bring strong synergistic effects to air quality and public health.
文摘Research and development of efficient, economical and resource-based flue gas desulfurization technology has always been a hot spot in the field of air pollution control. Molecular sieve materials have been paid attention to by SO<sub>2</sub> adsorbent researchers due to their huge specific surface area. In this paper, 13X zeolite was modified with Cu(NO<sub>3</sub>) <sub>2</sub>·3H<sub>2</sub>O to obtain 13x-Xwt %CuO (calculated by the amount of CuO loaded). The adsorption time and capacity of SO<sub>2</sub> penetration sorbent and the isothermal curve of N<sub>2</sub> adsorption-desorption were studied. The results are as follows: 13X-3wt%CuO has the best adsorption effect, the penetration adsorption time is 110 min, the penetration adsorption capacity is 43.41 mg·g<sup>-1</sup>, the saturation adsorption capacity is 49.27 mg·g<sup>-1</sup>;The amount of CuO loading has a great influence on the adsorption effect of modified 13X molecular sieve on SO<sub>2</sub>. SEM and BET characterization showed that CuO modification did not change the external morphology of 13X molecular sieve, changed the pore size, but did not block the original channel of the molecular sieve, before and after modification belong to the type I adsorption isothermal curve. The pore size distribution and type of molecular sieve, as well as the content and type of alkali metal cations jointly control the adsorption process of SO<sub>2</sub> by 13X-xwt %CuO. XPS characterization showed that Cu(NO<sub>3</sub>) <sub>2</sub> decomposed into CuO and Cu<sub>2</sub>O during roasting at 450°C, CuO/Cu<sub>2</sub>O ≈ 1.5. The R<sup>2</sup> values of the quasi-second-order kinetic models obtained from the 13X-Xwt %CuO particle diffusion kinetic models were all above 0.99, indicating that the quasi-second-order kinetic equations were more relevant. Particle diffusion dynamics model in fitting results show that the adsorption process can be divided into two stages, the first phase of surface adsorption and diffusion rate in the granules common control process, more accurate dynamics model of the secondary in the second phase particle diffusion rate control stage, mainly for the micropore adsorption or chemical adsorption, quasi level 2 dynamic model conformity of variation;C is a constant not equal to 0, indicating that the adsorption of SO<sub>2</sub> is not completely through the form of intra-particle diffusion, and a small amount of chemisorption exists. And it is the compound effect of multiple adsorption mechanisms.
文摘Air pollution poses a critical threat to public health and environmental sustainability globally, and Nigeria is no exception. Despite significant economic growth and urban development, Nigeria faces substantial air quality challenges, particularly in urban centers. While outdoor air pollution has received considerable attention, the issue of indoor air quality remains underexplored yet equally critical. This study aims to develop a reliable, cost-effective, and user-friendly solution for continuous monitoring and reporting of indoor air quality, accessible from anywhere via a web interface. Addressing the urgent need for effective indoor air quality monitoring in urban hospitals, the research focuses on designing and implementing a smart indoor air quality monitoring system using Arduino technology. Employing an Arduino Uno, ESP8266 Wi-Fi module, and MQ135 gas sensor, the system collects real-time air quality data, transmits it to the ThingSpeak cloud platform, and visualizes it through a user-friendly web interface. This project offers a cost-effective, portable, and reliable solution for monitoring indoor air quality, aiming to mitigate health risks and promote a healthier living environment.
文摘Man made activities are changing environment of our planet earth.Various methods are used to reduce the environmental pollution.In this paper the methods of air/water/soil pollution mitigation/reduction using electromagnetic fields is discussed.Air/water/soil contains ions and the energy transfer for living organisms takes place by ion exchange processes.Ions are affected by electric/magnetic fields.Many investigators
基金The National Science Fund for Distinguished Young Scholars(No.51625803)China and Korea International Cooperation Project of the National Key Research and Development Program(No.2016YEE0119700)+3 种基金the Fundamental Research Funds for the Central Universities(No.3205008102)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(No.CE02-2-33)Research and Innovation Project for College Graduates of Jiangsu Province(No.KYLX15_0088,KYLX16_0255)the State Foundation for Studying Abroad,China
文摘Due to the high viscosity of magnetorheological(MR)fluid,eliminating air pockets dissolved in the fluid is very difficult,which results in a force lag phenomenon.In order to evaluate the performance of a semi-active control system based on the MR damper considering the trapped air effect,a performance test on a MR damper is carried out under different loading cases,and the influence of the input current,excitation amplitude and frequency on the force lag phenomenon is analyzed.A concise and efficient parametric model,combining the simple Bouc-Wen model and a spring with small stiffness,is proposed to portray the experimental characteristics of the MR damper with force lag,and then the response analysis of the semi-active controlled single-degree-of-freedom(SDOF)structure is performed using the classic clipped-optimal control strategy based on acceleration feedback.Numerical results show that the trapped air in the MR fluid can weaken the control effect of the MR damper,and the performance of the semi-active control system will be reduced more obviously and become close to the passive-off control with the increasing content of air trapped in the MR fluid.
基金Supported by Humanities and Social Sciences Project of the Ministry of Education“Relationship between Haze Pollution and Socio-economic Growth:Research on Three Dimensions Spatial-temporal Feature,Decoupling Effect and Collaborative Governance”(21YJCZH016).
文摘Air pollution is a hot issue studied by scholars all over the world.Academic circles generally believe that socio-economic factors such as extensive economic growth,unbalanced proportion of industrial structure and unreasonable energy consumption structure are the main"culprits"of serious air pollution in China.Therefore,the relationship between air pollution and socio-economic growth has very important theoretical and practical significance for air pollution prevention and control and promoting the sustainable and healthy development of cities.Through literature research and summary methods,this paper studies the severity and harmfulness of air pollution in China,and deeply studies the research progress of socio-economic influencing factors of air pollution,environmental Kuznets curve hypothesis of air pollution,decoupling relationship between air pollution and socio-economic growth,so as to provide useful reference for the prevention and control of air pollution.
文摘A novel bioactive foam emulsion bioreactor for benzene,toluene and xylene(BTX)contaminated air streams treatment has been developed.The gas-liquid interfacial area by biocompatible foam and driving force for mass transfer by a water immiscible organic phase were increased in this reactor.The effect of several parameters such as gas residence time,oxygen content,and organic phase concentration on bioreactor performance was studied. Experimental results showed an average elimination capacity(EC)of 220 g·m3·h -1with removal efficiency(RE) of 89.59%for BTX inlet concentration of 1 g·m3at 15 s gas residence time in the bioreactor.The statistical developed model predicted that the maximum elimination capacity of the reactor for BTX could be reached to 423.45 g·m3·h -1.Continues operation of the bioreactor with high EC and RE was demonstrated by optimizing the operational parameters of the bioreactor.Overall the results suggest that the bioreactor developed can be very effective systems to treat BTX vapors.
文摘The direct sulfation of limestone from different sources in Iran was studiedin a thermogravimetric analyzer under atmospheric pressure. All limestone samples tested have higherthan 97% CaCO_3. Experimental conditions were as follows: particle size levels ranging from 1.6 μmto 7.8 μm, four level reaction temperatures (700℃, 750℃, 800℃ and 850℃), and two SO_2concentrations (2.4 x 10^(-3) and 3.2 x 10^(-3) mol · mol^(-1)). The particle size and temperatureshowed dominant influences on the rate and level of conversion while the effect of SO_2concentration was weak. The shrinking core model can be used to describe the behavior of thesulfation process. The reaction kinetics and diffusion mechanism are both important in controllingthe rate of the process. The two key parameters of the model, chemical rate constant K_s andeffective diffusion coefficient D_(eff) were obtained. Model predictions are in good agreement withthe experimental data.
基金supported by the National Natural Science Foundation of China(21906090)the National Key Research and Development Program(2017YFC0210200,2017YFC0212800)Primary Research&Development Project of Shandong Province(2018GSF117034,2019JZZY020305).
文摘Activated red mud(RM)has been proved to be a promising base material for the selective catalysis reduction(SCR)of NOx.The inherent low reducibility and acidity limited its low-temperature activity.In this work,molybdenum oxide,tungsten oxide,and cerium oxide were used to reconfigure the redox sites and acid sites of red mud based catalyst.When activated red mud was reconfigured by cerium-tungsten oxide(Ce-W@RM),the NOx conversion kept above 90%at 219-480℃.The existence of Ce^(3+)/Ce^(4+) redox electron pairs provided more surface adsorbed oxygen(O_(α)) and served as a redox cycle.Positive interactions between Ce,W species and Fe oxide in red mud occurred,which led to the formation of unsaturated chemical bond and promoted the activation of adsorbed NH_(3) species.WO_(3) and Ce_(2)(WO_(4))_(3)(formed by solid-state reaction between Ce and W species)could provide more Brønsted acid sites(W-O modes of WO_(3),W=O or W-O-W modes of Ce_(2)(WO_(4))_(3)).CeO_(2) species could provide more Lewis acid sites.The Langmuir-Hinshelwood(L-H)routes and Eley-Rideal(E-R)routes occurred in the low-temperature SCR reaction on the Ce-W@RM surface.NH_(4)^(+) species on Brønsted acid sites,NH_(3) species on Lewis acid sites,bidentate nitrate and bridging nitrate species were key active intermediates species.