Physical and mechanical properties and microstructures of submarine soils in the Yellow Sea

In recent years,the exploration of seabed has been intensified,but the submarine soils of silt and sand in the Yellow Sea area have not been well investigated so far.In this study,the physical and mechanical properties of silt and sand from the Yellow Sea were measured using a direct shear apparatus and their microstructures were observed using a scanning electron microscope.The test results suggest that the shear strength of silt and sand increases linearly with the increase of normal stress.Based on the direct shear test,the scanning electron microscope was used to observe the section surface of sand.It is observed that the section surface becomes rough,with many“V”‐shaped cracks.Many particles appear on the surface of the silt structure and tend to be disintegrated.The X‐ray diffraction experiment reveals that the sand and silt have different compositions.The shear strength of sand is slightly greater than that of silt under high stress,which is related to the shape of soil particles and the mineral composition.These results can be a reference for further study of other soils in the Yellow Sea;meanwhile,they can serve as soil parameters for the stability and durability analyses of offshore infrastructure construction.

Physical and Chemical Properties of Horns Sheaths Particles for the Manufacture of Composite Materials

Salvaged cow horns from slaughterhouses have been transformed into fine particles for a physical characterization that has led us to determine the humidity rate (2.34% ± 0.054%), the actual density situated between 0.586 g/cm3 and 0.732 g/cm3, the swelling rate (12%), and one chemical characterization that permitted us to determine the rate of dry matters (97.05%), of mineral matters (2.5%), of protein matters (94.52%). From these weak values, it can easily be seen that cow horn case doesn’t absorb much water and improve the mechanical characteristics of the composite;the high rate of protein shows that keratin which is the structural molecule favors its gripping as reinforcing element in the manufacturing of composite materials.

Assessment of the Variations in Soil Physicochemical Parameters of the Natural Forest and Plantations in Orumba North Local Government Area, Anambra State, Nigeria

Soil physicochemical parameters are the physical and chemical characteristics of soil such as pH, bulk density, organic carbon, nitrogen content, and nutrient levels at different soil depths. These parameters vary from one vegetation to the other and from one soil to the other. The study assessed the variations in soil physicochemical parameters of the natural forest and plantations in Agu Eke (Eke bush) in Etti village, Nanka and Umunnebo village, Ufuma both located in Orumba North Local Government Area, Anambra State. The experimental research design and stratified random sampling methods were used for the study and a total of 12 soil samples were collected at 30 cm depth from the selected locations of natural forest, cashew and palm plantations. The samples were analyzed using laboratory Varian AA240 Atomic Absorption Spectrophotometer, after which the result was subjected to statistical analysis—Analysis of Variance (ANOVA). The study found that there was no significant difference (variation) between the moisture contents of natural forests and the plantations;that is, the moisture contents were the same. It was also found that there was no significant variation between the bulk densities of the natural forest, oil plantation, and cashew plantation, meaning that the bulk densities were significantly the same. However, there were significant variations in nitrogen, potassium and phosphates, with p-values: sig = .000 < .05, sig = .010 < .05 and sig = .000 < .05, respectively. That is, the nitrogen and phosphate contents of the natural forest significantly vary more than those of the oil palm and cashew plantations, which probably means that by reducing natural forest to plantation, the nitrogen and phosphate contents of the natural forest reduced from what it used to be when the lands were mere forests. This shows that plantations do not have the same function of maintaining or improving soil quality as natural forests. The study recommended adopting a sustainable plantation agricultural system, such as using diverse nutrient sources (manure and compost), in order to maintain the desired soil quality.

Impact of mica on geotechnical behavior of weathered granitic soil using macro and micro investigations

The micaceous weathered granitic soil(WGS)is frequently encountered in civil engineering worldwide,unfortunately little information is available regarding how mica affects the physico-mechanical behaviors of WGS.This study prepares reconstituted WGS with different mica contents by removing natural mica in theWGS,and then mixes it with commercial mica powders.The geotechnical behavior as well as the microstructures of the mixtures are characterized.The addition of mica enables the physical indices of WGS to be specific combinations of coarser gradation and high permeability but high Atterberg limits.However,high mica content in WGS was found to be associated with undesirable mechanical properties,including increased compressibility,disintegration,and swelling potential,as well as poor compactability and low effective frictional angle.Microstructural analysis indicates that the influence of mica on the responses of mixtures originates from the intrinsic nature of mica as well as the particle packing being formed withinWGS.Mica exists in the mixture as stacks of plates that form a spongy structure with high compressibility and swelling potential.Pores among the plates give the soil high water retention and high Atterberg limits.Large pores are also generated by soil particles with bridging packing,which enhances the permeability and water-soil interactions upon immersion.This study provides a microlevel understanding of how mica dominates the behavior of WGS and provides new insights into the effective stabilization and improvement of micaceous soils.

Digital mapping of soil physical and mechanical properties using machine learning at the watershed scale

Knowledge about the spatial distribution of the soil physical and mechanical properties is crucial for soil management,water yield,and sustainability at the watershed scale;however,the lack of soil data hinders the application of this tool,thus urging the need to estimate soil properties and consequently,to perform the spatial distribution.This research attempted to examine the proficiency of three machine learning methods(RF:Random Forest;Cubist:Regression Tree;and SVM:Support Vector Machine)to predict soil physical and mechanical properties,saturated hydraulic conductivity(Ks),Cohesion measured by fall-cone at the saturated(Psat)and dry(Pdry)states,hardness index(HI)and dry shear strength(SS)by integrating environmental variables and soil features in the Zayandeh-Rood dam watershed,central Iran.To determine the best combination of input variables,three scenarios were examined as follows:scenarioⅠ,terrain attributes derivative from a digital elevation model(DEM)+remotely sensed data;scenarioⅡ,covariates of scenarioⅠ+selected climatic data and some thematic maps;scenarioⅢ,covariates in scenarioⅡ+intrinsic soil properties(Clay,Silt,Sand,bulk density(BD),soil organic matter(SOM),calcium carbonate equivalent(CCE),mean weight diameter(MWD)and geometric weight diameter(GWD)).The results showed that for Ks,Psat Pdry and SS,the best performance was found by the RF model in the third scenario,with R2=0.53,0.32,0.31 and 0.41,respectively,while for soil hardness index(HI),Cubist model in the third scenario with R2=0.25 showed the highest performance.For predicting Ks and Psat,soil characteristics(i.e.clay and soil SOM and BD),and land use were the most important variables.For predicting Pdry,HI,and SS,some topographical characteristics(Valley depth,catchment area,mltiresolution of ridge top flatness index),and some soil characteristics(i.e.clay,SOM and MWD)were the most important input variables.The results of this research present moderate accuracy,however,the methodology employed provides quick and costeffective information serving as the scientific basis for decision-making goals.

GIS-Based Assessment of Soil Chemical and Physical Properties as a Basis for Land Reclamation in Toshka Area, Aswan, EGYPT

The accurate assessment of soil properties is a crucial factor for composing and implementing reclamation plans. The main objective of this study was to evaluate soil chemical and physical properties and calculate the chemical and fertility index for assisting land reclamation in Toshka area. The Toshka area is located between latitudes 31°32'N and 31°36'N and longitudes 32°40'E and 32°60'E. GIS was used to select 16 sites. The results revealed the soil has undesirable characteristics. The soil pH ranged from slightly alkaline to moderately alkaline. Furthermore, it was characterized as saline (with a ECe of 4.65 - 11.45 dS⋅m−1) and moderately calcareous soil (with CaCO3 at 11.85% - 17.20%). The soil had a low soil organic matter content which did not exceed 0.18%. The soil was dominated by a sandy loam texture (62.50%) followed by a sandy clay loam texture (18.75%). The bulk density, total soil porosity and saturated hydraulic conductivity values varied with 1.38 - 1.55 Mg⋅cm−3, 41.85% - 48.45% and 1.20 - 3.34 cm⋅h−1, respectively. The chemical index ranged from low to moderate quality. The correlations between the parameters osculated between negative and positive. Therefore, the soil may be reclaimed if the soil properties are improved and crop selection is optimized for this soil.

Effects of Poplar Plantations on the Physical and Chemical Properties of Soils:A Case Study in the North China Plain

In recent years, large areas of farmland in the North China Plain have been converted into short-rotation poplar plantations. To analyze the impacts of poplar plantations on soil, 22 soil samples were collected and assayed from the soil profiles of a corn field and a poplar plantation. The results showed that the average soil moisture content of the soil profile in the poplar field was 2.6 percent lower than that of the arable land. The maximum dif- ference in soil moisture content was found in the upper 0-10 cm of topsoil. Soil organic matter and nitrogen, phosphorus and potassium in the cornfield were significantly higher than in the poplar field. Higher nutrient content in the corn field may result from higher fertilizer inputs and the practice of returning straw to the cropped field. The analysis also showed no significant increase in soil organic matter content in deeper soil layers of the poplar field, which means that the conditions are not favorable for the formation of soil organic matter, or that soil organic matter needs a longer time to develop. Elements such as magnesium, iron, manganese and copper in both the corn field and the poplar field had a tendency to accumulate with increasing soil depth. Magnesium, iron, manganese and copper in the 0-80 cm soil layer of the poplar field were higher than those of the cornfield, but the situation was reversed at depths greater than 80 cm. It is concluded that poplar trees consume a large amount of soil moisture and soil nutrients. Local governments should prevent the development of new plantations of fast-growing trees in farmland and help farmers to recover their farmland from forestry plantations.

Responses of microbial activities and soil physical-chemical properties to the successional process of biological soil crusts in the Gurbantunggut Desert,Xinjiang

Biological soil crusts （BSCs） are capable of modifying nutrient availability to favor the establishment of biogeochemical cycles. Microbial activities serve as critical roles for both carbon and nutrient transformation in BSCs. However, little is known about microbial activities and physical-chemical properties of BSCs in the Gurbantunggut Desert, Xinjiang, China. In the present research, a sampling line with 1-m wide and 20-m long was set up in each of five typical interdune areas selected randomly in the Gurbantunggut Desert. Within each sampling line, samples of bare sand sheet, algal crusts, lichen crusts and moss crusts were randomly collected at the depth of 0-2 cm. Varia- tions of microalgal biomass, microbial biomass, enzyme activities and soil physical-chemical properties in different succession of BSCs were analyzed. The relationships between microalgal biomass, microbial biomass, enzymatic activities and soil physical-chemical properties were explored by stepwise regression. Our results indicate that micro- algal biomass, microbial biomass and most of enzyme activities increased as the BSCs developed and their highest values occurred in lichen or moss crusts. Except for total K, the contents of most soil nutrients （organic C, total N, total P, available N, available P and available K） were the lowest in the bare sand sheet and significantly increased with the BSCs development, reaching their highest values in moss crusts. However, pH values significantly decreased as the BSCs developed. Significant and positive correlations were observed between chlorophyll a and microbial biomass C. Total P and N were positively associated with chlorophyll a and microbial biomass C, whereas there was a significant and negative correlation between microbial biomass and available P. The growth of cyanobacteria and microorganism contributed C and N in the soil, which offered substrates for enzyme activities thus increasing enzyme activities. Probably, improvement in enzyme activities increased soil fertility and promoted the growth of cyanobacteria, eukary- otic algae and heterotrophic microorganism, with the accelerating succession of BSCs. The present research found that microalgal-microbial biomass and enzyme activities played important roles on the contents of nutrients in the successional stages of BSCs and helped us to understand developmental mechanism in the succession of BSCs.

Effects of Different Application Amounts of Potassium Fulvate on Yield and Quality of Tomato and Soil Physical and Chemical Properties

This study was conducted to study the optimum dosage of potassium ful- vate （PF） on greenhouse tomato, the effects of different amounts of PF on yield and quality of greenhouse tomato and soil physical and chemical properties were investigated by a field plot experiment. The results showed that the bottom applica- tion of PF increased tomato yield, plant dry matter weight and root dry matter weight by 14.0%, 14.4 and 50.6%, respectively; Vc and soluble sugar content of tomato increased by 1＆5% and 10.0%, respectively; and soil bulk density de- creased by 3.6%, and CEC increased by 5.0%. All the indexes increased with the increase of PF application amount, and reached the maximum value when the PF application rate was 4 500 kg/hm2. In consideration of the cost of fertilizer and all indexes, the optimum dosaqe of PF fertilizer was 4 500 kg/hm2.

Establishment and verification of prediction models for evaluating the physical and chemical properties of soilless substrates

In soilless culture,a suitable mixed substrate that provides a balanced and stable rhizosphere environment is vital for promoting plant growth.The present study was undertaken to establish seven prediction models of physical and chemical properties,including bulk density(DB),total porosity(TP),water-holding porosity(WHP),air porosity(AP),WHP/AP,electrical conductivity(EC)and cation exchange capacity(CEC)of mixed substrate based on regression equations of measured values from 76 substrate combinations.These seven models were verified using the measured values of 12 mixed substrates,and the average relative prediction errors(REs)were all less than 10%.A comprehensive property prediction model was established by weighted summation of the seven models of physical and chemical properties.According to the set values of DB,TP,WHP,AP,WHP/AP,EC and CEC,the comprehensive property model predicted the six mixture proportions of mixed-substrate,as verified using the measured values.This study is the first to establish prediction models for the physical and chemical properties of mixed substrates.The comprehensive property model could be used to evaluate the physical and chemical properties of commercial mixed substrates,and to provide the optimal mixture substrate formulations according to the setting property value of production requirement.

Analysis of the Engineering Restoration Effect of Abandoned Yongledian Quarry in Beijing City Based on Soil Physical and Chemical Properties

The improvement of the soil physical and chemical properties is the most important foundation for mine ecological restoration.The experiment is aimed at undisturbed area,restored area,and damaged area of abandoned Yongledian Quarry in Beijing.Through determination and analysis of soil physical and chemical properties,it shows that there are significant differences in the composite effects of soil physical and chemical properties between restored area,and undisturbed area,damaged area,and engineering restoration effectively improves the composite effects of soil physical and chemical properties in the restored area.The single factor hypothesis test shows that soil pH value,organic matter,alkali-hydrolyzable nitrogen,and total nitrogen traits are the key targets to be restored in this mining area.

Soil Physical and Chemical Properties of Pure Pinus massoniana and Its Mixed Forests in Different Ages in Southern Guangxi

Six forest stands of 59,34 and 24 year-old Pinus massoniana forests and their mixed forests were selected at the Experimental Center of Tropical Forestry of Chinese Academy of Forestry,and 20 m × 20 m plot was set up and soil samples were taken from 0-60 cm soil layers,to analyze the changes of soil nutrient content under different forest stands and forest ages. The results showed that soil moisture and the bulk density in the mesophytic forest land were higher than those of other forest lands. The highest soil porosity value was observed in the early forest land. Soil p H of different forest was 4. 45-4. 75,indicating the variation was small. Besides,it indicated that the mixed forest was more able to increase the soil fertility than the pure forest because that the variation of soil acidity,organic matter content and total P and K in 34 and24 year-old mixed forests were higher than those in pure forests of the same year old. However,the content of soil available P and K decreased with the increase of soil depth,and varied in terms of forest ages. From the changes of soil indicators in different forest lands,soil nutrients in the 34 year-old P. massoniana forest was superior to that of other forest stands.

Soil Physical and Chemical Properties of Five Subtropical Forests in Lingao of Hainan

With 5 types of typical forests as research object, the physical and chemical properties of different types of forests were analyzed by sample plot investigation method. The results showed that： the soil total porosity was the highest in the Casuarina equisetifolia forest （46.168%）, but the lowest in the Encalyptus robusta forest （39.46%）. The soil capillary porosity was the highest in the Acacia mangium forest （22.57%）, but the lowest in the secondary forest （18.95%）. The soil water content was the highest in the C. equisetifolia forest, with a mean value of 27.85%, but the lowest in the secondary forest, with a mean value of 4.34%. The soil pH values were in the range of 4.81-6.59, the soils in the A. mangium forest, C. equisetifolia forest and E. robusta forest were strongly acidic （pH 4.5-5.5）, and the soils in the secondary forest and C. nucifera forest were weakly acidic. The soils had organic matter contents in the range of 0.34-28.68 g/kg, and showed an order of A. mangium forest〉C. equisetifolia forest〉E. robusta forest〉secondary forest〉C. nucifera forest, with a decreasing trend with the soil depth increasing. The soil total N contents were in the range of 0.10-1.63 g/kg, the A. mangium forest showed the highest soil total N contents, while the C. nucifera forest exhibited the lowest soil total N contents; the soil total P contents were in the range of 0.21-1.74 g/kg, and the E. robusta forest had the highest soil total P contents; and the soil total K contents were in the range of 0.16-2.15 g/kg, and the A. mangium forest exhibited the highest soil total K contents. The soil available P contents were in the range of 0.98-132.46 mg/kg; and the secondary forests had the highest soil available P contents; and the soil rapidly available K contents were in the range of 3.03-27.35 mg/kg, and the C. nucifera forest exhibited the highest soil rapidly available K contents. The soil ammonium N contents were in the range of 1.38-5.15 mg/kg, and the nitrate N contents were in the range were in the range of 0.56 -3.51 mg/kg. The A. mangium forest showed the highest soil nitrate N contents （with a mean value of 2.29 mg/kg） and ammonium N contents （with a mean value of 3.93 mg/kg）. For the same forest type, with the increase of soil depth, the nitrate nitrogen and ammonium nitrogen content also showed a decreasing trend.

The Effect of Some Soil Physical and Chemical Properties on Soil Aggregate Stability in Different Locations in Sulaimani and Halabja Governorate

Some soil properties were studied in relation soil aggregate along a climatologically region and different crop land use in the Northeast of Sulaimani City/Kurdistan Region of Iraq. Five locations were selected along these regions ranging from semiarid to sub-humid climatologically conditions. The soil physical, chemical properties, aggregate stability and size distribution were analyzed. A mean-weight-diameter (MWD) value was determined on 5 soils, which was the sum of the percentage of soil on each sieve (6, 3, 1.5, 0.75, 0.375 and 0.125 mm). The results of the measurements could evaluated with linear correlation coefficients for the relationships between aggregate stability (MWD) and soil physical and chemical properties of the different crop land use. The correlation coefficient for the relationship between aggregate stability and organic matter was highly significant (P < 0.0l%) which is in agreement with the findings of [1]. Generally large aggregates (large 6, 3, 3 - 1.5 mm) were present in highest proportions in the most semiarid of the studied areas. Aggregates 0.75 - 0.125 mm were positively correlated to fine, very fine sand and silt fractions and to organic matter. Stability of aggregates showed a positive correlation with clay content and organic matter content, while the carbonate content was strongly correlated with aggregate stability. The land use history affecting soil overlaps the pattern of climatological situations and cultivated crop lands and has to be taken into account. Aggregate size distribution and stability can be used as indicator of soil conservation and productivity.

Effects of Green Manure Mixed Cropping Patterns on Physical and Chemical Properties of Soil and Economic Characters of Flue-cured Tobacco

[Objective] The aim was to clear the suitable green manure cropping pat- terns in Xiangxi tobacco-planting areas. [Method] 8 treatments were set to study the effects of the monoculture and mixed cropping of common vetch （Vicia gigantea Bge.）, perennial ryegrass （Lofium） and rapeseed （Brassica campestris L.） on physi- cal and chemical properties of soil and economic characters of flue-cured tobacco. [Result] （1） Green manure turnover can reduce soil bulk density by 1.08%-8.62%, and the effect of green manure mixed cropping pattern was the best. （2） Green manure turnover also can increase the soil nutrient, soil organic matter, total nitro- gen （N）, total phosphorus （P）, total potassium （K）, alkali-hydrolyzale N, rapidly available P and rapidly available K by 1.44%-6.10%, 0.01-0.12 g/kg, 1.89%- 11.32%, 0.12%-3.56%, 1.06%-11.76%, 0.04%-18.93% and 0.98%-23.12%, respec- tively, and the effect of the monoculture of common vetch was the best.（3） The overall change of soil pH was not obvious.（4）Green manure turnover can increase the yield and output of flue-cured tobacco, and the effect of the monoculture of common vetch was the best. [Conclusion] The monoculture of common vetch can be generalized in the dry land of Xiangxi tobacco-planting areas.

Classification and Distribution of Common Aroma Components in Tobacco Leaf Based on Their Physical and Chemical Properties

[Objective] This study was aimed to find a new method for the classification of common aroma components in tobacco leaves. [Method] Sixty-four common aroma components in tobacco leaves were classified by cluster analysis based on their relative molecular weight. The contents and distribution of aroma components in another 71 C3F and 64 B2F tobacco leaf samples were analyzed by using the new method. [Result] The 64 common aroma components were divided into three categories trough the cluster analysis based on their molecular weight. CategoryⅠ consisted of 12 aroma components which had high molecular weight（281.308±21.536on average） and high boiling point（371.311±29.904 ℃ on average）. Category Ⅱ included 27 components which had low molecular weight（103.722 ± 13.115 on average） and low boiling point（176.132±42.342 ℃ on average）. Category Ⅲ included 25components which had middle molecular weight（175.393 ± 24.906 on average） and middle boiling point（250.562±45.431 ℃ on average）. The content of high-molecularweight aroma components in middle leaves（547.344±224.391 μg/g） was much higher than that in upper leaves（477.549±182.066 μg/g）. The content of low-molecularweight aroma component in middle leaves（17.468±3.459 μg/g） was also significantly higher than that in upper leaves（15.936±3.456 μg/g）. The content of middle-molecular-weight aroma component in middle leaves（44.931 ±8.953 μg/g） was extremely significantly higher than that in upper leaves（37.997±6.042 μg/g）. [Conclusion] This study proposed a new way to classify the aroma components in flue-cured tobacco leaves using the relative molecular weight as the index, which will provide theoretical reference for developing special tobacco leaves.

Ecological effect of the plantation of Sabina vulgaris in the Mu Us Sandy Land,China

Vegetation restoration through artificial plantation is an effective method to combat desertification,especially in arid and semi-arid areas.This study aimed to explore the ecological effect of the plantation of Sabina vulgaris on soil physical and chemical properties on the southeastern fringe of the Mu Us Sandy Land,China.We collected soil samples from five depth layers(0-20,20-40,40-60,60-80,and 80-100 cm)in the S.vulgaris plantation plots across four plantation ages(4,7,10,and 16 years)in November 2019,and assessed soil physical(soil bulk density,soil porosity,and soil particle size)and chemical(soil organic carbon(SOC),total nitrogen(TN),available nitrogen(AN),available phosphorus(AP),available potassium(AK),cation-exchange capacity(CEC),salinity,p H,and C/N ratio)properties.The results indicated that the soil predominantly consisted of sand particles(94.27%-99.67%),with the remainder being silt and clay.As plantation age increased,silt and very fine sand contents progressively rose.After 16 years of planting,there was a marked reduction in the mean soil particle size.The initial soil fertility was low and declined from 4 to 10 years of planting before witnessing an improvement.Significant positive correlations were observed for the clay,silt,and very fine sand(mean diameter of 0.000-0.100 mm)with SOC,AK,and p H.In contrast,fine sand and medium sand(mean diameter of 0.100-0.500 mm)showed significant negative correlations with these indicators.Our findings ascertain that the plantation of S.vulgaris requires 10 years to effectively act as a windbreak and contribute to sand fixation,and needs 16 years to improve soil physical and chemical properties.Importantly,these improvements were found to be highly beneficial for vegetation restoration in arid and semi-arid areas.This research can offer valuable insights for the protection and restoration of the vegetation ecosystem in the sandy lands in China.

Effect of fire severity on physical and biochemical soil properties in Zagros oak(Quercus brantii Lindl.)forests in Iran

Fire affects the physical and chemical properties and soil biological activity of natural ecosystems. This study was conducted in the Miyan Tang region, Ilam Province in western Iran. The study site was 110 hectares, where we sampled soils in areas that were classified by fire severity： low （LS）, high （HS） and medium severity （MS）, and unburned （UB）, which served as the control. In each severity class, 25 transect points were randomly selected for measurement. Around each transect plot center, 3 soil samples were selected randomly and soils collected from the 0 to 20 cm depth were combined into a composite sample that was used in laboratory analysis to represent conditions at that point. Plots in the UB and LS fire classes had similar soil conditions and had higher values of factors such as saturated moisture, organic carbon, carbon dioxide, and silt and clay content. In contrast, plots in the HS and MS fire severity classes were clustered in the positive direction along the first axis that represented gradients in soil acidity, electrical conductivity, cation exchange capacity, accessible phosphorus, accessible potassium, bulk density, and sand. Soil attributes were similar in areas of HS and MS fire severity classes, whereas soil conditions in the LS class and UB controls were most similar. Fire in the LS areas either did not significantly alter the physicalchemical soil properties and microbial basal respiration, or soils were able to recover quickly after being burned.

Preparation of Manganese Oxide and Its Adsorption Properties

The in-situ oxidation of manganese sulfate solution with H2O_(2),sodium hypochlorite,potassium permanganate and oxygen as oxidants was investigated by means of SEM,EDS,XRD,BET and infrared analysis,and the effects of different oxidants on the morphology,phase composition,surface properties and specific surface area of manganese oxides were investigated.The experimental results show that the diameter of manganese oxide particles prepared with H_(2)O_(2)is the smallest,about 50 nm,and the specific surface area is the largest,63.8764 m^(2)/g.It has the advantages of abundant surface hydroxyl groups,no introduction of other impurities and large adsorption potential.It is most suitable to be used as an oxidant for oxidizing manganese sulfate solution to prepare manganese oxide by in-situ oxidation.Nano manganese oxide prepard by H_(2)O_(2)in-situ oxidation method is used as adsorbent to adsorb cobalt and nickel impurities in manganese sulfate.When the reaction pH is 6,the reaction time is 30min and the amount of adsorbent is 1.0 g,the adsorption rates of cobalt and nickel impurities in 100ml manganese sulfate solution are 97.59%and 97.67%,respectively.The residual amounts of cobalt and nickel meet the industrial process standard of first-class products(Co,Ni w/%≤0.005)of high-purity manganese sulfate(Hg/t4823-2015)for batteries.The study plays a guiding role in the preparation and regulation of manganese oxide,and provides a new method with high efficiency,purity and adsorbent availability for the preparation of high-purity manganese sulfate solution.

Shear resistance characteristics and influencing factors of root-soil composite on an alpine metal mine dump slope with different recovery periods

Artificial vegetation restoration is the main measure for vegetation restoration and soil and water conservation in alpine mine dumps on the Qinghai-Tibet Plateau,China.However,there are few reports on the dynamic changes and the influencing factors of the soil reinforcement effect of plant species after artificial vegetation restoration under different recovery periods.We selected dump areas of the Delni Copper Mine in Qinghai Province,China to study the relationship between the shear strength and the peak displacement of the root-soil composite on the slope during the recovery period,and the influence of the root traits and soil physical properties on the shear resistance characteristics of the root-soil composite via in situ direct shear tests.The results indicate that the shear strength and peak displacement of the rooted soil initially decreased and then increased with the increase of the recovery period.The shear strength of the rooted soil and the recovery period exhibited a quadratic function relationship.There is no significant function relationship between the peak displacement and the recovery period.Significant positive correlations(P<0.05)exists between the shear strength of the root-soil composite and the root biomass density,root volume density,and root area ratio,and they show significant linear correlations(P<0.05).There are no significant correlations(P>0.05)between the shear strength of the root-soil composite and the root length density,and the root volume ratio of the coarse roots to the fine roots.A significant negative linear correlation(P<0.05)exists between the peak displacement of the rooted soil and the coarse-grain content,but no significant correlations(P>0.05)with the root traits,other soil physical property indices(the moisture content and dry density of the soil),and slope gradient.The coarse-grain content is the main factor controlling the peak displacement of the rooted soil.