The process of emulsifier-free copolymerization of the Styrene-Butyl Acrylate-K_sS_sO_s-water in the presence of Barium Sulfate(BS)powder was investigated under varied conditions within the range of BS powder quantity...The process of emulsifier-free copolymerization of the Styrene-Butyl Acrylate-K_sS_sO_s-water in the presence of Barium Sulfate(BS)powder was investigated under varied conditions within the range of BS powder quantity,initiator concentration and reaction temperature.Experimental results showed that the rate of polymerization is proportional to 0.3-power of the BS quantity and 1.3-power of the initiator concentration.There is a linear relationship of 2/3-power for the conversion and time.A process for the polymerization is propose to explain the experimental results.展开更多
Evolution of spatial distribution of charged particulates under the action of an external force is investigated. It is found that starting from a homogeneous Maxwellian distribution of particulates, clusters can form ...Evolution of spatial distribution of charged particulates under the action of an external force is investigated. It is found that starting from a homogeneous Maxwellian distribution of particulates, clusters can form and aggregate. The evolution process, as well as the asymptotic number and configuration of the clusters formed, depends strongly on the strength of the external force. The particulates in most of the final clusters are in the crystal state, as can also be deduced from the corresponding velocity and auto-correlation functions.展开更多
Based on the time-convolutionless master-equation approach, the entropic uncertainty in the presence of quantum memory is investigated for a two-atom system in two dissipative cavities. We find that the entropic uncer...Based on the time-convolutionless master-equation approach, the entropic uncertainty in the presence of quantum memory is investigated for a two-atom system in two dissipative cavities. We find that the entropic uncertainty can be controlled by the non-Markovian effect and the atom-cavity coupling. The results show that increasing the atom-cavity coupling can enlarge the oscillating frequencies of the entropic uncertainty and can decrease the minimal value of the entropic uncertainty. Enhancing the non-Markovian effect can reduce the minimal value of the entropic uncertainty. In particular, if the atom-cavity coupling or the non-Markovian effect is very strong, the entropic uncertainty will be very dose to zero at certain time points, thus Bob can minimize his uncertainty about Alice's measurement outcomes,展开更多
Using bis(p-methoxyphenyl)telluroxide(BMPTO)as the catalyst, phenylsulphonyl acetonitrile condensed easily with aromatic aldehydes at room temperature to give -cyano- ,β-unsaturated sulphones in high yields.
Terbium can form a ternary complex having a ratio of 1:1:1 with acetylacetone and EDTA. By adding cetyl pyridinium chloride into the above system, a marked enhancement of fluorescence intensity is observed and the ter...Terbium can form a ternary complex having a ratio of 1:1:1 with acetylacetone and EDTA. By adding cetyl pyridinium chloride into the above system, a marked enhancement of fluorescence intensity is observed and the ternary complex becomes more stable than before. For analytical application, the derivative spectrofluorimetric method has high sensitivity and the effect of foreign ions is very low. The optimum conditions were obtained. The calibration graph is linear over 5~100μg/mL.展开更多
To investigate soapless emulsion copolymerization in the presence of a solid phase, copolymerization experiments were carried out for the styrene-butyl acrylate-K_2S_2O_8-water system by using barium sulfate powder,wh...To investigate soapless emulsion copolymerization in the presence of a solid phase, copolymerization experiments were carried out for the styrene-butyl acrylate-K_2S_2O_8-water system by using barium sulfate powder,which is assumed to be chemically inert.Reaction conditions were varied with respect to barium sulfate powder quantity,initiator concen- tration and temperature.These factors were investigated with respect to the effect on reaction rate and conversion,polymer particle number and diameter,and latex stability.展开更多
Tb(111) and Ca(11) ion equilibria in the presence of glutamic acid and glutamine were studied by potentiometric titration at 37'C and an ionic strength of 0. 15mol/L(NaCl) .The stability constants for Tb(111) and ...Tb(111) and Ca(11) ion equilibria in the presence of glutamic acid and glutamine were studied by potentiometric titration at 37'C and an ionic strength of 0. 15mol/L(NaCl) .The stability constants for Tb(111) and Ca(11)complexes in the systems were obtained. The species and their distribution in the systems were discussed.展开更多
The reaction of phenylethyne with 2,4-pentanedione in the presence of manganese(Ⅲ) acetate and oxygen at room tempraure gave 4-acetyl-5-benzoyl-3-methyl-1, 2-dioxolan-3-ol, 2-acetyl-3-benzoloxirane and 3-acety-2-meth...The reaction of phenylethyne with 2,4-pentanedione in the presence of manganese(Ⅲ) acetate and oxygen at room tempraure gave 4-acetyl-5-benzoyl-3-methyl-1, 2-dioxolan-3-ol, 2-acetyl-3-benzoloxirane and 3-acety-2-methyl-phenylfuran展开更多
The derivative fluorimetric characteristics of Tb—SDS and Tb—SDS—phenanthroline systems have been studied. The optimum conditions were obtained. The 2nd—derivative spectrofluorimetric method in the systems has bee...The derivative fluorimetric characteristics of Tb—SDS and Tb—SDS—phenanthroline systems have been studied. The optimum conditions were obtained. The 2nd—derivative spectrofluorimetric method in the systems has been applied to the determination of trace amounts of terbium, in rare earth ore and their oxides. The results are satisfactory.展开更多
The active intermediate'carbon radical' was detected by the spin—trapping reagent (POBN) during the debromination of Ph_2CHBr in the presence of viologen derivatives as electron—transfer catalysts(ETC).
Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosp...Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosphate or media owing to adsorption Silicate can also enhance the peak current of Cu(II). The enhancing power phosphate,carbonate, and silicate is 33, 26, and 8.9 times, respectively.展开更多
This study explored the internal mechanism of the effect of mindfulness on life satisfaction from the perspective of logotherapy theory and achievement attribution theory.We recruited 1021 college students using a com...This study explored the internal mechanism of the effect of mindfulness on life satisfaction from the perspective of logotherapy theory and achievement attribution theory.We recruited 1021 college students using a combination of random sampling and cluster sampling.They completed the relevant questionnaire.The results showed that,from the perspective of logotherapy theory,wefind that the presence of meaning in life is an important intermediary between mindfulness and life satisfaction.From the perspective of achievement attribution theory,we found that internal control was an important intermediary between mindfulness and life satisfaction.In addition,we also found the chain mediating path that mindfulness positively predicted life satisfaction by influencing internal control and then influencing the presence of meaning in life.This study proves for thefirst time that the theory of logotherapy and achievement attribution explain the internal mechanism of the relation of mindfulness on life satisfaction.This study provides an important reference for how to effectively improve life satisfaction from the perspective of mindfulness.展开更多
The reaction of m-dimethoxybenzene with crotonic acid in the presence of PPA affords an unexpected compound,which has been proved to be a dimer by H-NMR and MS.The x-ray struc- tural analysis has the same result.The p...The reaction of m-dimethoxybenzene with crotonic acid in the presence of PPA affords an unexpected compound,which has been proved to be a dimer by H-NMR and MS.The x-ray struc- tural analysis has the same result.The phenomenon has not been reported.展开更多
The Conservation Voltage Reduction (CVR) is a technique that aims to achieve the decrease of power consumption as a result of voltage reduction. The customer is supplied with the lowest possible voltage level compatib...The Conservation Voltage Reduction (CVR) is a technique that aims to achieve the decrease of power consumption as a result of voltage reduction. The customer is supplied with the lowest possible voltage level compatible with the stipulated level by the regulatory agency. International Standards ANSI C84.1-2006 and IEEE std 1250-1995 specify the range of supply voltage to electronics equipment from 0.9 to 1.05 pu of nominal voltage. To analyse the CVR effect in distribution systems with different load characteristics (residential, commercial, industrial or a combination of these), mathematical load models are used. Typically, these equipment/load models are used to analyse load aggregation without any consideration of its nonlinearity characteristics. Aiming to analyse the nonlinear characteristics and its consequences, this paper presents a discussion of the neglected variables as well as the results of a set of measurements of nonlinear loads. Different mathematical models are applied to obtain them for each load. Using these models the load aggregation is evaluated. It is presented that although the models show adequate results for individual loads, the same does not occur for aggregated models if the harmonic contribution is not considered. Consequently, to apply the load model in CVR it is necessary to consider the harmonics presence and the model has to be done using only the fundamental frequency data. The discussion about the causes is done and the models are compared with the measurements.展开更多
The analysis of company data useful for economic decisions,if not interpreted in an overall view of the company situation,can lead to wrong conclusions.This is the case when a company has to choose between several sal...The analysis of company data useful for economic decisions,if not interpreted in an overall view of the company situation,can lead to wrong conclusions.This is the case when a company has to choose between several sales options for one or more products in the presence of a limiting factor.The continuation of the investigation often denies the initial analysis.Not everything is as it appears,therefore,at the beginning of the deepening of the data useful for economic decisions.As it is well known,the choices of profitability concerning the planning of the sale of company products take place,at least in the majority of cases,through the determination of the contribution margin,i.e.the profitability margin connected to the individual goods/services sold by the companies(selling price net of variable costs).The contribution margin can be determined with four objectives:(1)Determination of the yield of the single product,net of variable costs only.In this case,the margin defines unitary,from net product yield to unitary contribution margin.(2)Determination of the return on total sales of an individual product,net of variable costs.In this hypothesis,reference is made to the first level(or gross)contribution margin.(3)Determination of the ability of the individual product to contribute to the coverage of fixed costs common to the company.This margin is determined net of special product variable and fixed costs.This aggregate is defined as a Level II(or semi-gross)margin.(4)Determination of the useful value in the planning choices in case of presence of scarce productive factors.In this case,it must identify the so-called unitary margin for low factor.Here we will only deal with the problem of the use of the contribution margin in the presence of rare factors.To complete the analysis,below are some very brief considerations regarding,respectively,the unitary,level I,and level II contribution margin in order to better understand where the problem of the most convenient choice of income is located in the event of the presence of rare production factors,especially in an environment characterized by a plurality of sales options.展开更多
Unsteady MHD natural convective heat and mass transfer flow through a semi-infinite vertical porous plate in a rotating system have been investigated with the combined Soret and Dufour effects in the presence of Hall ...Unsteady MHD natural convective heat and mass transfer flow through a semi-infinite vertical porous plate in a rotating system have been investigated with the combined Soret and Dufour effects in the presence of Hall current and constant heat flux. It is considered that the porous plate is subjected to constant heat flux. The obtained non-dimensional, non-similar coupled non-linear and partial differential equations have been solved by explicit finite difference technique. Numerical solutions for velocities, temperature and concentration distributions are obtained for various parameters by the above mentioned technique. The local and average shear stresses, Nusselt number as well as Sherwood number are also investigated. The stability conditions and convergence criteria of the explicit finite difference scheme are established for finding the restriction of the values of various parameters to get more accuracy. The obtained results are illustrated with the help of graphs to observe the effects of various legitimate parameters.展开更多
文摘The process of emulsifier-free copolymerization of the Styrene-Butyl Acrylate-K_sS_sO_s-water in the presence of Barium Sulfate(BS)powder was investigated under varied conditions within the range of BS powder quantity,initiator concentration and reaction temperature.Experimental results showed that the rate of polymerization is proportional to 0.3-power of the BS quantity and 1.3-power of the initiator concentration.There is a linear relationship of 2/3-power for the conversion and time.A process for the polymerization is propose to explain the experimental results.
基金Supported by the Natural Science Foundation of Zhejiang Province under Grant No LY15A050001the National Natural Science Foundation of China under Grant Nos 11247007 and 11374262the Open Fund of the State Key Laboratory of High-Field Laser Physics at SIOM
文摘Evolution of spatial distribution of charged particulates under the action of an external force is investigated. It is found that starting from a homogeneous Maxwellian distribution of particulates, clusters can form and aggregate. The evolution process, as well as the asymptotic number and configuration of the clusters formed, depends strongly on the strength of the external force. The particulates in most of the final clusters are in the crystal state, as can also be deduced from the corresponding velocity and auto-correlation functions.
基金Supported by the Science and Technology Plan of Hunan Province under Grant No 2010FJ3148the National Natural Science Foundation of China under Grant No 11374096the Doctoral Science Foundation of Hunan Normal University
文摘Based on the time-convolutionless master-equation approach, the entropic uncertainty in the presence of quantum memory is investigated for a two-atom system in two dissipative cavities. We find that the entropic uncertainty can be controlled by the non-Markovian effect and the atom-cavity coupling. The results show that increasing the atom-cavity coupling can enlarge the oscillating frequencies of the entropic uncertainty and can decrease the minimal value of the entropic uncertainty. Enhancing the non-Markovian effect can reduce the minimal value of the entropic uncertainty. In particular, if the atom-cavity coupling or the non-Markovian effect is very strong, the entropic uncertainty will be very dose to zero at certain time points, thus Bob can minimize his uncertainty about Alice's measurement outcomes,
文摘Using bis(p-methoxyphenyl)telluroxide(BMPTO)as the catalyst, phenylsulphonyl acetonitrile condensed easily with aromatic aldehydes at room temperature to give -cyano- ,β-unsaturated sulphones in high yields.
基金Project supported by the National Natural Science Foundation of China
文摘Terbium can form a ternary complex having a ratio of 1:1:1 with acetylacetone and EDTA. By adding cetyl pyridinium chloride into the above system, a marked enhancement of fluorescence intensity is observed and the ternary complex becomes more stable than before. For analytical application, the derivative spectrofluorimetric method has high sensitivity and the effect of foreign ions is very low. The optimum conditions were obtained. The calibration graph is linear over 5~100μg/mL.
文摘To investigate soapless emulsion copolymerization in the presence of a solid phase, copolymerization experiments were carried out for the styrene-butyl acrylate-K_2S_2O_8-water system by using barium sulfate powder,which is assumed to be chemically inert.Reaction conditions were varied with respect to barium sulfate powder quantity,initiator concen- tration and temperature.These factors were investigated with respect to the effect on reaction rate and conversion,polymer particle number and diameter,and latex stability.
文摘Tb(111) and Ca(11) ion equilibria in the presence of glutamic acid and glutamine were studied by potentiometric titration at 37'C and an ionic strength of 0. 15mol/L(NaCl) .The stability constants for Tb(111) and Ca(11)complexes in the systems were obtained. The species and their distribution in the systems were discussed.
文摘The reaction of phenylethyne with 2,4-pentanedione in the presence of manganese(Ⅲ) acetate and oxygen at room tempraure gave 4-acetyl-5-benzoyl-3-methyl-1, 2-dioxolan-3-ol, 2-acetyl-3-benzoloxirane and 3-acety-2-methyl-phenylfuran
基金Project supported by the National Natural Science Foundation of China
文摘The derivative fluorimetric characteristics of Tb—SDS and Tb—SDS—phenanthroline systems have been studied. The optimum conditions were obtained. The 2nd—derivative spectrofluorimetric method in the systems has been applied to the determination of trace amounts of terbium, in rare earth ore and their oxides. The results are satisfactory.
文摘The active intermediate'carbon radical' was detected by the spin—trapping reagent (POBN) during the debromination of Ph_2CHBr in the presence of viologen derivatives as electron—transfer catalysts(ETC).
文摘Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosphate or media owing to adsorption Silicate can also enhance the peak current of Cu(II). The enhancing power phosphate,carbonate, and silicate is 33, 26, and 8.9 times, respectively.
基金supported by the General Program of the National Social Science Foundation of China(19BSH114)。
文摘This study explored the internal mechanism of the effect of mindfulness on life satisfaction from the perspective of logotherapy theory and achievement attribution theory.We recruited 1021 college students using a combination of random sampling and cluster sampling.They completed the relevant questionnaire.The results showed that,from the perspective of logotherapy theory,wefind that the presence of meaning in life is an important intermediary between mindfulness and life satisfaction.From the perspective of achievement attribution theory,we found that internal control was an important intermediary between mindfulness and life satisfaction.In addition,we also found the chain mediating path that mindfulness positively predicted life satisfaction by influencing internal control and then influencing the presence of meaning in life.This study proves for thefirst time that the theory of logotherapy and achievement attribution explain the internal mechanism of the relation of mindfulness on life satisfaction.This study provides an important reference for how to effectively improve life satisfaction from the perspective of mindfulness.
文摘The reaction of m-dimethoxybenzene with crotonic acid in the presence of PPA affords an unexpected compound,which has been proved to be a dimer by H-NMR and MS.The x-ray struc- tural analysis has the same result.The phenomenon has not been reported.
文摘The Conservation Voltage Reduction (CVR) is a technique that aims to achieve the decrease of power consumption as a result of voltage reduction. The customer is supplied with the lowest possible voltage level compatible with the stipulated level by the regulatory agency. International Standards ANSI C84.1-2006 and IEEE std 1250-1995 specify the range of supply voltage to electronics equipment from 0.9 to 1.05 pu of nominal voltage. To analyse the CVR effect in distribution systems with different load characteristics (residential, commercial, industrial or a combination of these), mathematical load models are used. Typically, these equipment/load models are used to analyse load aggregation without any consideration of its nonlinearity characteristics. Aiming to analyse the nonlinear characteristics and its consequences, this paper presents a discussion of the neglected variables as well as the results of a set of measurements of nonlinear loads. Different mathematical models are applied to obtain them for each load. Using these models the load aggregation is evaluated. It is presented that although the models show adequate results for individual loads, the same does not occur for aggregated models if the harmonic contribution is not considered. Consequently, to apply the load model in CVR it is necessary to consider the harmonics presence and the model has to be done using only the fundamental frequency data. The discussion about the causes is done and the models are compared with the measurements.
文摘The analysis of company data useful for economic decisions,if not interpreted in an overall view of the company situation,can lead to wrong conclusions.This is the case when a company has to choose between several sales options for one or more products in the presence of a limiting factor.The continuation of the investigation often denies the initial analysis.Not everything is as it appears,therefore,at the beginning of the deepening of the data useful for economic decisions.As it is well known,the choices of profitability concerning the planning of the sale of company products take place,at least in the majority of cases,through the determination of the contribution margin,i.e.the profitability margin connected to the individual goods/services sold by the companies(selling price net of variable costs).The contribution margin can be determined with four objectives:(1)Determination of the yield of the single product,net of variable costs only.In this case,the margin defines unitary,from net product yield to unitary contribution margin.(2)Determination of the return on total sales of an individual product,net of variable costs.In this hypothesis,reference is made to the first level(or gross)contribution margin.(3)Determination of the ability of the individual product to contribute to the coverage of fixed costs common to the company.This margin is determined net of special product variable and fixed costs.This aggregate is defined as a Level II(or semi-gross)margin.(4)Determination of the useful value in the planning choices in case of presence of scarce productive factors.In this case,it must identify the so-called unitary margin for low factor.Here we will only deal with the problem of the use of the contribution margin in the presence of rare factors.To complete the analysis,below are some very brief considerations regarding,respectively,the unitary,level I,and level II contribution margin in order to better understand where the problem of the most convenient choice of income is located in the event of the presence of rare production factors,especially in an environment characterized by a plurality of sales options.
文摘Unsteady MHD natural convective heat and mass transfer flow through a semi-infinite vertical porous plate in a rotating system have been investigated with the combined Soret and Dufour effects in the presence of Hall current and constant heat flux. It is considered that the porous plate is subjected to constant heat flux. The obtained non-dimensional, non-similar coupled non-linear and partial differential equations have been solved by explicit finite difference technique. Numerical solutions for velocities, temperature and concentration distributions are obtained for various parameters by the above mentioned technique. The local and average shear stresses, Nusselt number as well as Sherwood number are also investigated. The stability conditions and convergence criteria of the explicit finite difference scheme are established for finding the restriction of the values of various parameters to get more accuracy. The obtained results are illustrated with the help of graphs to observe the effects of various legitimate parameters.