The Two-Constant Cost Model and the Estimation of the Cost Performance Evolutions of the Proton Exchange Membrane Fuel Cell Power Generation

This paper aims at formulization and overview of the cost performance evolutions of proton exchange membrane (PEM) fuel cell power generation along with load and time. For this purpose, electricity-cost ratio (ECR) is proposed as the measuring parameter for the cost performance and a two-constant cost model is proposed to concisely describe the cost characteristic of the power generation as the opposite of a multi-constant cost model. Combination of the two-constant cost model and the ideal cell model developed recently produces an inclusive ECR equation that has three analytical expressions and thus allows of straight overviews of the cost performance evolutions in the working zones of the cells. The applications to real cells confirm the validity of the equation for operation optimization and technique evaluation of PEM fuel cells. And more insights into the cost performance evolutions are inferred by means of the equation to help promote the commercialization of PEM fuel cells.

Discrimination and Estimation of the Maximum Cost Performance of Proton Exchange Membrane Fuel Cell Power Generation with Seven Constants

This paper is dedicated to analytical expression of the maximum electricity-cost ratio (M-ECR) point of the proton exchange membrane (PEM) fuel cell power generation as the function of cell constants and cost constants. That is to formulize the maximum cost performance (MCP) magnitude and the optimal final operating (OFO) location in the working zone based on the five-constant ideal cell model and the two-constant cost model. The issues are well resolved by introducing the concepts of economic voltage and cost factor and describing the movement of the M-ECR point with cost factor. According to mathematical derivations, the movement can be described in the form of MCP and OFO curves. The derivations lead to a complete set of discriminants and criteria of the M-ECR point of PEM fuel cells that theoretically cover all of cell specialties and all of cost specialties. The discriminants and criteria may act as a general tool for the operation optimization of a diversity of PEM fuel cells and the economic viability estimation of the power generation.

Different dietary methionine to lysine ratios in the lactation diet:effects on the performance of sows and their offspring and methionine metabolism in lactating sows

Background:Over the last decade,the nutritional requirements of lactating modern genotype sows have increased.The current nutritional recommendations might be unable to meet the needs of increased litter size and milk production,and thus the nutritional requirements need to be re-evaluated.The current study was conducted to investigate the effects of dietary methionine to lysine(Met:Lys)ratios on the performance of and methionine metabolism in lactating sows.Results:During the 1st week of lactation,piglets reared on sows in the 0.37 to 0.57 Met:Lys ratio groups grew faster than those reared on sows in the control group(0.27)(P<0.01).The 0.37-ratio group showed increased levels of GSHPx in plasma during lactation(P<0.01)and decreased concentrations of urea nitrogen in the plasma of sows(P<0.05).Compared with the 0.27-ratio group,the levels of T-AOC and GSH-Px in the plasma and homocysteine in the milk of lactating sows were significantly increased in sows in the 0.47-ratio group(P<0.01).In sows fed a 0.57-ratio diet,the levels of glutathione and taurine in the plasma and milk were improved significantly during lactation.However,the content of TBARS in the blood(P<0.05 at day 7 and P=0.06 at weaning day)was increased(P<0.01).Moreover,there were linear increases in the levels of homocysteine in the blood and milk of sows during the lactation period(P<0.01)with increased dietary Met:Lys ratios in the lactation diet.Conclusions:The current study indicated that increasing the dietary Met:Lys ratio(0.37~0.57)in the lactation diet had no significant effect on the overall performance of sows or the colostrum and milk composition,but it increased piglet mean BW and piglet ADG during the first week of lactation.Increasing dietary methionine levels had no significant effect on antioxidant function in lactation sows,even though it increased levels of GSH and GSH-Px in the plasma of sows during lactation.However,the content of homocysteine in the plasma and milk increased during lactation due to a high level of dietary methionine.

Low-Cost Stormwater Filtration System to Improve Urban Water Quality: The Case of Addis Ababa, Ethiopia

Urbanization in developing countries often negatively impacts water re-sources by polluting surface waters. Addis Ababa, Ethiopia, is currently experiencing rapid urbanization accompanied by significant water shortages, unmanaged stormwater, and increasing river water pollution. To supplement the need for non-potable water and address stormwater runoff pollution, we constructed a low cost stormwater filtration system. The filtration system is comprised of a sedimentation area followed by three gravel grain sizes arranged horizontally from coarse to medium to fine filter media. We compared the quality of pretreatment water with post-treatment water by measuring physicochemical parameters, heavy metals and nutrients. We found that the filtration system reduced turbidity by 87%, TSS by 80%, Cu by 87% and Zn by 90%. Further, it positively increased the concentration of DO by 42%. However, the filtration system did not remove nitrates and nitrites. Implementing this system at outfalls in the rapidly expanding condominium housing areas can increase residents’ supply of non-potable water and reduce the amount of polluted stormwater entering nearby streams and rivers.

Applications of Compliance to Cost Ratio (C-CR) Analysis in the Determination of Optimum Mix of Insulating Bricks in Masonry

The scarcity of housing increases as population continues to rise all over the world. Despite government efforts at providing houses, yearly demand keeps on exceeding available houses and hence the hike in rent, the cost of erecting houses and the cost of building materials. This ultimately calls for a decisive solution. This study therefore applied compliance to cost ratio (C-CR) analysis in evaluating the optimum properties of fired ceramic bricks. The optimum mix proportions of waste glass (WG) and wood saw dust (WSD) in fired bricks, that will be suitable for housing constructions were hence determined. Fired clay brick samples which contained varied proportions of WG and WSD were examined for physical, mechanical and thermal properties in line with standard procedures. The results were compared with existing standards and property evaluation index, compliance level and C-CR were applied in analyzing the results obtained. It was observed that with increasing WG content, compliance level increased. Also, cost ratio and experimental cost of each brick sample trended upward. Sample with mix proportion;20 wt% WG, 5 wt% WSD and 75 wt% clay had compliance level of 94% and C-CR index of 7.81, hence chosen as optimum mix proportion for masonry bricks.

Experimental study on the shear performance of quasi-NPR steel bolted rock joints

Quasi-NPR(negative Poisson’s ratio)steel is a new type of super bolt material with high strength,high ductility,and a micro-negative Poisson’s effect.This material overcomes the contrasting characteristics of the high strength and high ductility of steel and it has significant energy-absorbing characteristics,which is of high value in deep rock and soil support engineering.However,research on the shear resistance of quasi-NPR steel has not been carried out.To study the shear performance of quasi-NPR steel bolted rock joints,indoor shear tests of bolted rock joints under different normal stress conditions were carried out.Q235 steel and#45 steel,two representative ordinary bolt steels,were set up as a control group for comparative tests to compare and analyze the shear strength,deformation and instability mode,shear energy absorption characteristics,and bolting contribution of different types of bolts.The results show that the jointed rock masses without bolt reinforcement undergo brittle failure under shear load,while the bolted jointed rock masses show obvious ductile failure characteristics.The shear deformation ca-pacity of quasi-NPR steel is more than 3.5 times that of Q235 steel and#45 steel.No fracture occurs in the quasi-NPR steel during large shear deformation and it can provide stable shear resistance.However,the other two types of control bolts become fractured under the same conditions.Quasi-NPR steel has significant energy-absorbing characteristics under shear load and has obvious advantages in terms of absorbing the energy released by shear deformation of jointed rock masses as compared with ordinary steel.In particular,the shear force plays a major role in resisting the shear deformation of Q235 steel and#45 steel,therefore,fracture failure occurs under small bolt deformation.However,the axial force of quasi-NPR steel can be fully exerted when resisting joint shear deformation;the steel itself does not break when large shear deformation occurs,and the supporting effect of the jointed rock mass is effectively guaranteed.

Effects of Filler-Asphalt Ratio on the Properties of Lignin and Polyester Fiber Reinforced SMPU/SBS Modified Asphalt Mortar

To understand the effects offiller-asphalt ratio on different properties of lignin and polyesterfiber reinforced shape memory polyurethane(SMPU)/styrene butadiene styrene(SBS)composite modified asphalt mortar(PSAM),as well as to reveal the reinforcing and toughening mechanisms of lignin and polyesterfibers on PSAM,SMPU,SBS and mineral powder werefirst utilized to prepare PSAM.Then the conventional,rheological and anti-cracking properties of ligninfiber reinforced PSAM(LFAM)and polyesterfiber reinforced PSAM(PFAM)at dif-ferentfiller-asphalt ratios were characterized.Test results indicate that the shear strength,deformation resistance and viscosity are increased after adding 0.8wt%ligninfiber or polyesterfiber and increasing thefiller-asphalt ratio from 0.8 to 1.2.The optimalfiller-asphalt ratio of 1.0 is proposed after comprehensive performance assessments of PSAM.Polyesterfiber shows a better reinforcing effect than ligninfiber,but its improvement in the thermal stability of PSAM is not significant at high temperatures.Additionally,the complex modulus,storage modulus,loss modulus and rutting resistance factor of PSAM are improved after adding ligninfiber and polyesterfiber,as well as show an increasing trend as thefiller-asphalt ratio is raised,but the phase angle is gradually decreased.Further,the increase of elastic components in PSAM effectively enhances the anti-deformation ability of PSAM at high temperatures,and polyesterfiber more obviously improves the high-temperature deformation resistance of PSAM than ligninfiber.Finally,the anti-cracking performance of PFAM and LFAM at low temperatures is reduced by 74.2%and 46.7%,respectively,as thefiller-asphalt ratio is raised from 0.8 to 1.2.The low-temperature anti-cracking performance of LFAM is lower than that of PFAM at the samefiller-asphalt ratio,even lower than that of PSA.Compared with ligninfiber,the anti-cracking performance and deformation resistance of PSAM at low temperature is more greatly enhanced by polyester fiber.

Effect of Refrigerant on the Performance of a C3/MRC Liquefaction Process

The Mixed Refrigerant(MR)component is an important factor influencing the performances of natural gas lique-faction processes.However,there is a lack of systematic research about the utilization of propane pre-cooled(C3/MRC).In this paper,this mixed refrigerant cycle liquefaction process is simulated using the HYSYS software and the main influential parameters involved in the process are varied to analyze their influence on the liquefaction rate and power consumption.The results show that an effective way for lowering the power consumption of the compressor consists of reducing the flow through the compressor through optimization of the percentage of mixed refrigerant.The power consumption of the compressor in the hybrid refrigeration process is affected by both flow and pressure ratios.Its specific power consumption can be reduced by increasing the flow and decreasing the pressure ratio at the same time.The increase in refrigerant pressure at the high-pressure end can significantly mitigate the energy loss of the heat exchanger and compressor.

Effects of Different Protein Energy Ratios on Fattening Performance,Slaughter Performance and Meat Quality of Pigs

[Objectives]Protein energy ratio refers to the proportional relationship between protein and energy levels in animal diets,i.e.,the grams of crude protein corresponding to every megacalorie of energy,which is generally expressed as CP:ME or CP:DE.This study was conducted to investigate the effects of different diets on fattening and slaughter performance and meat quality traits for"L(Large Yorkshire)×L(Landrace)"crossbred pigs.[Methods]Eighteen piglets of L×L crossbred with similar body weights about 51 kg were selected.The piglets were divided into 3 groups randomly and each group was assigned to 3 replicates with 2 piglets in a replicate.Group A was fed diet Ⅰ (control diet),group B was fed the same diet of group A in the first month of the trial but fed diet Ⅱ in second month,and group C consumed diet Ⅲ.All the pigs were fed in the same feeding condition for two months except the different diets during the trial.One pig in similar body weight from each replicate was slaughtered for the determination of slaughter performance and meat quality traits in the end of the trial.[Results]The average daily feed intake(ADFI)of pigs from group B was only(2.32±0.52)kg and significantly lower than those from group A and group C(P<0.05),but no difference was found in average daily gain(ADG) and feed/gain(P>0.05).Also,no differences occurred in the carcass length,back fat thickness,longissimus muscle (LM) area and dressing percentage(P>0.05).In addition,no differences were found in the meat quality traits of shear force,meat color,pH_(45 min),pH_(24 h) and cooking loss(P>0.05).However,the water-holding capacity of meat from group C was(2.58±0.02)ms and significantly lower than that of(2.80±0.20)ms from group A(P<0.05).Although the contents of glutamic acid and cystine in LM from group B was significantly lower than those from group A and group C(P<0.05),no differences occurred in the contents of other amino acids,the total amino acid and total flavor amino acid among the three groups(P>0.05).However,the inosine monophosphate content of LM from group C was only(331.80±11.53)mg/100 g and significantly lower than those of(361.00±6.36)and(366.37±4.80)mg/100 g from group A and B(P<0.05).Even though no differences were found in the contents of DM and CP in LM among the three groups of pigs,the content of intramuscular fat(IMF)in LM from group B and group C was increased by 45.6%and 46.58%respectively from that of group A(P<0.05),but no difference occurred between group B and C(P>0.05).[Conclusions]DietsⅡ and Ⅲ in this study caused no differences in fattening and slaughter performance of L×L crossbred pigs,but the effects on some meat traits were still significant,especially on the improvement of intramuscular fat in experimental pigs.Therefore,they could improve the meat quality of crossbred pigs to a certain extent.

Changshu textile machinery:Various motion devices show the cost performance

As a professional manufacturer of shedding devices and machines,Changshu Textile Machinery works Co.,Ltd.has been concentrating on research and development since it successfully developed the first ZED204 electronic dobby in China in 1993.Through technological innovation and process improvement,speed,reliability and cost performance of products have been obviously improved.Dobby,cam and jacquard are suitable for all kinds of mainstream looms in the international market.

Study for the Forming Principle of Logix Gear Tooth Profile and Its Mesh Performance

In recent years, a new type of gear named Logix gea r was developed. Actually, the tooth profile of this new type of gear is composed of lots of micro-segment involute curves, and on the profile, there exist lots of points, which their relative curvatures are equal to zero. This can result in the sliding coefficient smaller between two meshed Logix gears, and the mesh ch aracteristic becomes almost rolling transmission from sliding transmission accor dingly. So, this new type of gear has lots of advantages such as higher contact intensity, longer useful life and can easily realize power transfer of bigger tr ansmission ratio than standard involute gear. Study results showed that the cont act fatigue strength is 3 times larger, the bend fatigue strength is 2.5 times l arger, and the minimum tooth number can be decreased to 3, much smaller than tha t of standard involute gear. In this paper, following studies had been done: 1) The formation principle of Logix gear tooth profile was studied. The theoreti cal models describing the geometrical formations of this type of gear and its re lative Logix rack had been deduced. 2) While cutting a Logix gear, its tooth profile is decided by its normal tooth profile of Logix rack. Besides the basic parameters of standard involute gear, L ogix rack has its own specific parameters such as preliminary pressure angle, re lative pressure angle, and preliminary referential circle radius etc. So, the in fluence of connatural parameters of Logix rack on the tooth profile of Logix gea r had been farther studied. Reasonable selection for these parameters had been d iscussed. 3) Several kinds of transition curves for gear’s tooth profile had been introdu ced, its selection used by Logix gear had been described, and also its mathemati cal description model had been deduced. 4) The mesh theories of Logix gears had been developed. It had been proved that the transmission performance between Logix gears coincides with E-W theorem as that of ordinary standard involute gears. The formula calculating superposition coefficient was deduced according to its definition. Different from standard inv olute gears, the parameter of gear number has no effect on the superposition coe fficient of the Logix gears. Accordingly, bigger ratio transmission can be acqui red by means of decreasing the gear number, and its minimum gear number can be r eached to 3, much smaller than the minimum gear number of ordinary standard invo lute gear: 14～17. This is very important to realize the miniaturization of prod uction design. 5) The CAD special software was developed to design all kinds of Logix gears, an d a solid design example was offered. To sum up, by means of above study, the system info about Logix gear had been de veloped and enriched. This has most significant impact on its widely promotion a nd practical application, on the improvement of carrying capacity, miniaturizati on, and life of kinetic transmission products.

Optimization of the reflux ratio of benzene-toluene stage distillation columns by the Cuckoo algorithm

In this study, an enthalpy-concentration method was applied in order to model a steady state continuous benzene-toluene mixture distillation column. For a distillation tower such as the benzene- toluene splitter, there are relatively few degrees of freedom that can be manipulated in order to minimize the total annualized cost. The reflux ratio can influence the steady-state operating point and therefore influence the total annualized cost. The trade-offs between reflux ratios and total annualized cost were discussed. The Cuckoo optimization algorithm was applied to obtain a correlation for the optimum value of the reflux ratio as a power function of the economic parameters of energy price and capital cost. The results show that, at low energy price or high capital cost, the optimum reflux factor is high.

Effects of Dietary Concentrate to Forage Ratios on Production Performance and Serum Biochemical Indicators in Post-fattening Hainan Yellow Cattle

[Objective]The paper was to investigate the effects of dietary concentrate to forage ratios on production performance and serum bio-chemical indicators of post-fattening Hainan Yellow Cattle.[Method]Sixteen Hainan Yellow Cattles with the same genetic backgrounds and similar initial weight of(242.22 ±0.71 kg) were randomly divided into four treatments.Cattles were fed with diets of different concentrate to forage ratios(20:80, group Ⅰ;30:70, Group Ⅱ;40:60, group Ⅲ;50:50, group Ⅳ).The trial lasted 62 d.[Result]The daily gain in experimental group Ⅳ was significantly higher than that in experimental group Ⅱ(P<0.05), but the feed gain ratio in experimental group Ⅳ was lower than those in other ex-perimental groups(P>0.05).The feed intake in experimental group Ⅳ was also markedly higher than those in experimental groups Ⅰ and Ⅱ(P<0.05).Compared with the experimental group Ⅱ, the gross profit of experimental group Ⅳ was significantly promoted(P<0.05).The alanine aminotransferase and aspartate aminotransferase activities in experimental group Ⅱ were markedly higher than those in experimental groups Ⅰ, Ⅲ and Ⅳ.[Conclusion]When the dietary concentrate to forage ratios was 50∶50, the production performance of post-fattening Hainan Yellow Cattle was better.

Effects of Diets with Different Corn-to-Soybean Ratios on Performance of Lactational Rex Rabbits

[ Objective] To study the effects of diets with different com-to-soybean ratios on production performance of lactational Rex rabbits and select the best feed formula. [Method] A total of 80 lactational healthy Rex rabbits （similar age, body weight and delivery time） were randomly divided into five groups, 16 in each group. The Rex rabbits in group I were fed with corn-based meal diet, group II with soybean-based meal diet, group III with the developed corn-soybean meal diet, group IV with corn-soybean meal free diet, and group CK with conventional corn-soybean meal diet. During the lactation period, the changes in the lactation performance, growth rate of baby rabbits, weight and feed costs were observed. [ Result] The lactation performance of mother rabbits and the growth rate of baby rabbits in the experimental groups were similar to that in the control group. The weaning survival rate of the group III was the highest, but it was not significantly higher than that of the control group. The weaning survival rate of the other three groups was lower than that of the control group （P〈0.05）. The weight loss of mother rabbits in the group I, II and III was not significantly different from that of the control group, but the weight loss of the group IV was higher than that of the control group （ P 〈 0.01 ）. [ Conclusion] Diets with appropriate corn-to-soybean ratios not only reduce feed costs but also give the best feeding effects.

A novel model for cost performance evaluation of pulverized coal injected into blast furnace based on effective calorific value

The combustion process of pulverized coal injected into blast furnace involves a lot of physical and chemical reactions. Based on the combustion behaviors of pulverized coal, the conception of coal effective calorific value representing the actual thermal energy provided for blast furnace was proposed. A cost performance evaluation model of coal injection was built up for the optimal selection of various kinds of coal based on effective calorific value. The model contains two indicators: coal effective calorific value which has eight sub-indicators and coal injection cost which includes four sub-indicators. In addition, the calculation principle and application of cost performance evaluation model in a Chinese large-scale iron and steel company were comprehensively introduced. The evaluation results finally confirm that this novel model is of great significance to the optimal selection of blast furnace pulverized coal.

Effects of Feeding Time on the Growth Performance and Variation of RNA/DNA Ratio of the Chinese Soft-shelled Turtle, Pelodiscus sinensis

The present study was to investigate the effects of feeding time on growth of the Chinese soft-shelled turtle. The experiment was carried out with a photoperiod of 12L （light）： 12D （dark） with lights on at 06：00 and off at 18：00. Turtles were maintained at a temperature of 32 - 0.2 ℃ in tanks throughout the length of the experiment. The turtles in group 1 to group 6 were fed respectively at 00：00, 04：00, 08：00, 12：00, 16：00 and 20：00 with 60 turtles each （Initial body weight 88.27 - 0.09 g）. Acrophases of postprandial RNA/DNA ratio in liver in each group was shown between 5h and 7h after feeding. A positive linear correlation could be seen between specific growth rate （SGR） and RNA/ DNA：SGR=t.1586RNA/DNA-0.7097 （r = 0.9328, P = 0.0066）. The results indicated that the values at the acrophases of about 6h after feeding might be used as an instantaneous growth index in the Chinese soft-shelled turtle. The turtles in group 1 grew better than group 3, group 4, group 5, group 6, because they ate more, but they ate more and grew slower than group 2, whose feed conversion rate was also higher. Meanwhile, the SGR and feeding rate of turtles fed at 12：00 were the lowest from the six groups （P 〈 0.05）. Turtles fed in group 1, group 2 and group 6 developed more heavy final body weight （FBW）, higher feeding rate and SGR than the other three groups. This probably suggested that turtles fed in scotophase grew better than that fed at photophase in total.

Experimental Investigation on Combustion Performance of Solid Propellant Subjected to Erosion of Particles with Different Concentrations

A test device with rectangular channel is developed to study the combustion performance of solid propellant in high temperature particles erosion.The flowfields in this newdevice and a test device with circular channels are simulated numerically.The particle erosion experiments in these two devices are carried out under different particle concentrations.The results showthat the test device with rectangular channel can effectively improve the clarity and precision of combustion diagnosis image and can be used for research on combustion performance of solid propellant under lowconcentration particle erosion;the circular channel device has good particle convergent effect,provides high concentration particle erosion,and can be used for research on the combustion performance of solid propellant under high concentration particle erosion.The experiment data indicates that the propellant burning rate does not change obviously in lower particle concentration;the propellant with lower static burning rate increases remarkably under particle erosion,while the propellant with high static burning rate is not sensitive to the particle erosion.

Effect of Pelleted Total Mixed Ration with Different Concentrate-roughage Ratios on Production Performance and Serum Biochemical Parameters of Fattening Hainan Black Goats

[Objective] This paper was to study effects of pelleted total mixed ration with different concentrate-roughage ratios on production performance and serum biochemical parameters of fattening Hainan black goats.[Method] Thirty-six fattening Hainan black goats with the same genetic background and similar initial weight of(14.08±0.13) kg were randomly assigned into three treatments. Goats were fed with Juncao + concentrate(control group), pelleted total mixed ration I(concentrate: roughage 50 ∶50, group Ⅰ) and Ⅱ(concentrate: roughage 45∶55, group Ⅱ), respectively. The test lasted 45 d.[Result] The final weight, daily gain and feed intake of rams in experimental group Ⅰ were significantly higher than those of control group and experimental group Ⅱ(P<0.05);the final weight and daily gain of rams in experimental group Ⅰ were also markedly higher than those of experimental group Ⅱ(P<0.05);the feed/gain of rams in experimental group Ⅰ was significantly lower than those in control group and experimental group Ⅱ(P<0.05). The feed gain cost of rams in experimental group Ⅰ was markedly lower than that in experimental group Ⅱ( P<0.05), but was significantly higher than that in experimental group Ⅰ(P<0.05);the gross profit of rams in experimental group Ⅰ was significantly higher than those in control group and experimental group Ⅱ(P<0.05). Compared with control group and experimental group Ⅱ, the serum total protein and glucose lev-els in experimental group Ⅱ increased significantly(P<0.05), but the urea nitrogen content reduced(P>0.05).[Conclusion] When the concentrateroughage ratio of pelleted total mixed ration was 50∶50, the fattening effect of Hainan black goat was better, and the serum total protein and glucose levels were evidently improved.

The regulating effect of doping Cu on the catalytic performance of CO oxidative coupling to DMO on Pd_(x)Cu_(y)/GDY:A DFT study

Rely on the density functional theory(DFT)calculation,the catalytic performance of Pd_(x)Cu_(y)/GDY(x=1,2,3,4;x+y≤4)for CO oxidative coupling reaction was obtained.The Pdx/GDY(x=1,2,3,4)are not ideal catalyst for dimethyl oxalate(DMO)formation because byproduct dimethyl carbonate(DMC)is easily formed on Pd_(1)/GDY and Pd_(2)/GDY,and high activation energies are needed on Pd_(3)/GDY and Pd_(4)/GDY.Therefore the second metal Cu is doped to regulate the performance of Pdx/GDY(x=1,2,3,4).Doping Cu not only improve the activity of DMO formation,but more importantly,controlling the ratio of Cu:Pd can effectively regulate the selectivity of DMO.Thus taking into account the activity and selectivity of the reaction for the preparation of DMO by CO oxidative coupling,the Pd_(1)Cu_(1)/GDY and Pd_(1)Cu_(2)/GDY with the activation energies of 105.2 and 99.2 kJ mol^(-1)to generate DMO show excellent catalytic activity and high DMO selectivity,which are considered as good catalysts for CO oxidative coupling.The differential charge density analysis shows the decrease in the charge density of metal clusters is an important reason for improving the selectivity of the catalyst.

Energy and Cost Analyses of Solar Photovoltaic (PV) Microgeneration Systems for Different Climate Zones of Turkey

The environmental and energy problems that have arisen in Turkey because of the dramatically increase in energy consumption require the implementation of energy efficiency and microgeneration measures in the building sector which is the main sector of primary energy consumption. Since Turkey is highly dependent on exported energy resources, the basic energy policy approach is based on providing the supply security. In this regard, supporting for in situ energy production, encouraging the use of renewable energy sources and the systems such as microgeneration systems in order to meet the energy requirements of buildings would be considered as a key measure for resolving the energy related challenges of Turkey and dealing with the sustainability issues. Turkey’s geographical location has several advantages for extensive use of most of the renewable energy sources such as especially solar energy. However, this huge solar energy potential is not being used sufficiently in residential building sector which is responsible for the great energy consumption of Turkey. Therefore, this paper aims to introduce a study which investigates, on a life cycle basis, the environmental and the economic sustainability of solar Photovoltaic (PV) microgenerators to promote the implementation of this system as an option for the renovation of existing residential buildings in Turkey. In this study, main parameters which were related to the distribution of modules to be installed in flat roofs and facades and the evaluation of the PV systems were taken into account. The effect of these parameters on energy generation of PV systems was analyzed in a case study considering different climate zones of Turkey;and the decrease in the existing energy consumption of the reference building was calculated.