Fabrication of UV-Curing Linalool-Polysiloxane Hybrid Films with High Refractive Index and Transparency

In this article,a series of high refractive indices(1.50-1.53)thiol phenyl polysiloxane(TPS)were synthesized via hydrolytic sol-gel reaction.The Fourier transform infrared spectra(FT-IR)and nuclear magnetic resonance spectra(NMR)results showed that TPS conformed to the predicted structures.Natural terpene linalool was exploited as photocrosslinker to fabricate UV-curing linalool-polysiloxane hybrid films(LPH)with TPS via photoinitiated thiol-ene reaction.LPH rapidly cured under UV irradiation at the intensity of 80 mW/cm^(2) in 30 s,exhibiting good UV-curing properties.The optical transmittance of LPH in the wavelength of 300-800 nm was over 90%,exhibiting good optical transparency.The water contact angle and water vapor permeability results showed that the introduction of phenyl groups enhance the hydrophobicity and water vapor barrier properties of LPH.The results indicated the potential of LPHs in the applications of optical functional coatings.

Fabrication, Structure and Optical Properties of Zr4+ Doped Ba（Mg, Ta） O3 Transparent Ceramics with High Refractive Index

Novel transparent ceramics of Zr4+ doped Ba(Mg,Ta)O3(BMT)with a high refractive index of 2.037 at 587.56 nm were successfully fabricated via high temperature solid-state-reaction sintering method.To make it transparent,the pure cubic Ba(Zr,Mg,Ta)O3 phases(BZMT)were realized in advance by skillfully modulating the lattice structure of BMT from trigonal symmetric to cubic symmetric through doping Zr4+ into the lattice of BMT crystal.Highly optical transmittance of 74% at 650 n,,which hit the upper limit of the theory,was achieved for BZMT.Both abbe number of 23.4 and the bandgap Eg of 3.22 eV have been calculated.

Qualitative Analysis of Relationship between Refractive Index and Atomic Parameters of Solid Materials

The refractive index is one of the important parameters describing the optical properties of solid materials. However, it is difficult to obtain a quantitative relation between the refractive index and the structure and composition of materials. A qualitative relation between the refractive index and some atomic parameters of materials was proposed and demonstrated by some oxide optical crystals. A parameter P=r~-/F=r~-/(r~+ΔxD) is defined, in which Δx is the difference of the electronegativities between cations and anions in the materials and r~+ and r~- are the radii of cations and anions respectively. On the other hand, the factor D was introduced to describe the effect of mass difference of the ions. It is demonstrated by both theoretical discussion and experimental data that refractive index is a decreasing function of parameter P. The relation may be useful for the investigation of optical materials.

Analysis of optical properties of bio-smoke materials in the 0.25–14 μm band

At present, research into optical properties of bio-smoke materials mostly concentrates on single band or single germplasm. Herein, we measured the spectral reflectance of three eukaryotic bio-smoke materials and three prokaryotic bio-smoke materials in the waveband from 0.25 μm to 14μm. Based on the Kramers-Kroning algorithm, the complex refractive index m(λ) was calculated and the Fourier-transform infrared(FTIR) spectra of materials were analyzed. The results show that n(λ) of bio-smoke materials varies between 1.1-2, and n(λ) values in the visible light to near-infrared wavebands are significantly larger than those in other wavebands. The k(λ) of bio-smoke materials varies between 0-0.4.At 6-6.5 μm, k(λ) of prokaryotic materials is 3 times that of eukaryotic materials, which is caused by C=O stretching vibration of amide I and C-N stretching vibration of amide Ⅱ in proteins. At 2.5-3 μm and 9.75 μm, k(λ) values of eukaryotic bio-smoke materials are nearly 2 times that of prokaryotic ones. The absorption peak at 2.5-3 μm is mainly triggered by C-H stretching vibration in lipid and O-H stretching vibration in bound water. The absorption peak at 9.75 μm is mainly caused by symmetric stretching vibration of PO2-in nucleic acids.

How to realize a negative refractive index material at the atomic level in an optical frequency range?

The theoretical mechanism for realizing a negative refractive index material in an optical frequency range with an atomic gas system of electromagnetically induced transparency (EIT) is studied. It is shown that under certain conditions such a dense gas can exhibit simultaneously negative permittivity and negative permeability, and negligibly small loss.

Stopband Phenomena in the Passband of Left-Handed Metamaterials

Stopband phenomena are reported in the passband of left-handed metamaterials. The samples with linear defect are designed by removing one layer of split ring resonators （SRRs）. It is shown that the left-handed transmission peaks have a distinct transform with the relative deviation of the SRRs centre from the wire centre 8, from a single left-handed peak, double left-handed peaks with different magnitude to no transmission peak, i.e. left-handed properties of metamaterials disappear. Numerical simulation shows that the change of 8 makes the effective permeability shift at a frequency range, where stopband occurs. It is thought that the stopband in left-handed passband is due to the symmetry breaking between SRRs and wires in the metamaterials.

Inversion Methods of Optical Constants of Semitransparent Solid Materials from Transmittance Spectrograms

The direct calculation models of spectral transmittance of single and double slabs consisted of semitransparent solid materials were developed based on ray trace method, and a new inversion method of optical constants （k is extinction coefficient and n is refractive index ） of materials was proposed based on transmittance spectrograms of double slabs. Differences between the new method and two others currently used methods were studied, and application range of methods was also investigated. Optical constants of selenide glass attained in references were selected as true values, and spectral transmittances of glass simulated based on direct calculation model were regarded as experimental values. Optical constants of selenide glass were achieved by inverse models. Influences of measurement error on inverse results were also determined. The results showed that ： （ 1 ） based on transmittance spectrograms of double slabs in which thickness of single slab is the same, the new proposed method can attain optical constants of materials; （2） the effect of optical constants n and k on three inversion methods are urgent larger, but inversed calculation precision of optical constants are higher in most application ranges ; （ 3 ） the influence of measurement errors existed in experimental datum on the inverse precision of three methods are urgent distinctness.

Negative Refractive Index Metamaterial Structure Using SRR by Incidenting the Light Horizontally

Metamaterial structure based on split ring resonators (SRR) is proposed in order to produce a negative refractive index. For this structure we have used a new approach, instead of applying light perpendicularly incident. We apply horizontally incident input waves. A model of SRR is used to understand the behavior and its affects. We calculate the S-parameters using S-parameter analysis and the results for transmission, refractive index, permeability and permittivity of the structure is induced. The negative refractive index is found to be significantly dependent upon the width of the continuous wire as well as gap between resonators. Moreover, we study the effect of lattice constant on the electromagnetic response of the structure. It is expected that this work will provide useful information for design and fabrication of metamaterials with negative refractive index for in-plane applications.

Investigation of Negative Refraction Phenomenon for Au Nanowires Array Tuning with Index of Filling Material

Negative refraction performance of Au nanowires arrays-based metamaterials was explored by means of finite difference and time domain (FDTD) algorithm for the purpose of providing flexible design freedom of the negative index metamaterials (NIMs) working in visible regime from nanofabrication point of view. Tuning performance of the nanowires for negative refraction was analyzed by use of varying refractive index of filling materials among the metallic nanowires. Computational numerical simulation and analyses were carried out. The performance of negative refraction was compared by optimization of the structures. By optimizing the nanowires radius, E-field intensity was calculated in the case that the refractive index of filling material is changeable. The calculated refraction angles illustrate a relationship between the refraction angle and the index of filling material. Our computational results demonstrate that effective value of the negative refractive index strongly depends on the refractive index of the filling material when other parameters are fixed.

Electrodynamic Analysis of Dissipative Electromagnetic Materials Based on Fractional Derivative

The generalized Lagrangian is defined in a dissipative electromagnetic medium on the basis of the combination of dynamical analysis and fractional derivative. Lorentz medium models are obtained by formulating relevant Euler-Lagrange equations. The invariance is obtained subsequently by investigating the invariance of time variation in the system, and then the relation between the related Hamiltonian and electromagnetic energy density is investigated. Canonical equations are obtained eventually. The electrodynamic interpretation on dissipative electromagnetic systems is revealed.

Coherently induced grating in refractive index enhanced medium

We demonstrate a scheme for coherently induced grating based on a mixture of two three-level atomic species interacting with two standing-wave fields. As a result of interaction between the absorptive and amplified Raman resonances, the refractive index of the medium can be enhanced and modulated periodically. Then a sinusoidal grating, which can diffract the probe field into high-order directions, is coherently formed in the medium. The proposed scheme is theoretically investigated in a mixture of atomic isotopes of rubidium. The results show that the diffraction efficiency depends strongly on the two two-photon detunings of the two Raman transitions and the intensities of the two driving standing-wave fields. The proposed electromagnetically induced grating scheme may be applied to the all-optical switching and beam splitting in optical networking and communication.

Negative refractive index in a four-level atomic system

A closed four-level system in atomic vapour is proposed, which is made to possess left handedness by using the technique of quantum coherence. The density matrix method is utilized in view of the rotating-wave approximation and the effect of a local field in dense gas. The numerical simulation result shows that the negative permittivity and the negative permeability of the medium can be achieved simultaneously （i.e. the left handedness） in a wider frequency band under appropriate parameter conditions. Furthermore, when analysing the dispersion property of the left-handed material, we can find that the probe beam propagation can be controlled from superluminal to subluminal, or vice versa via changing the detuning of the probe field.

High index of refraction via quantum interference in a three-level system of Er^3＋-doped yttrium aluminium garnet crystal

A simple three-level system is proposed to produce high index of refraction with zero absorption in an Er^3＋-doped yttrium aluminium garnet （YAG） crystal, which is achieved for a probe field between the excited state 4I13/2 and ground state 4I15/2 by adjusting a strong coherent driving field between the upper excited state 4I11/2 and 4I15/2. It is found that the changes of the frequency of the coherent driving field and the concentration of Er^3＋ ions in the YAG crystal can maximize the index of refraction accompanied by vanishing absorption. This result could be useful for the dispersion compensation in fibre communication, laser particle acceleration, high precision magnetometry and so on.

Optical Waveguide Property of Nd-doped Laser Materials Nd_xY_(1-x)Al_3(BO_3) _4 and Nd∶MgO∶LiNbO_3

Lanthanide has attracted much attention in the field of optical communications in recent years. Some property analyses on optical waveguide of Nd doped crystal Nd x Y 1-x A1 3(BO 3) 4 and Nd∶MgO∶LiNbO 3 are made in this paper, followed by introduction of the methods of experimentation and theoretical calculation for the planar optical waveguides. The refractive index profiles of the optical waveguides are analyzed. The above work offers useful information for study on new type materials for optical communications.

Quantized Energy Momentum and Wave for an Electromagnetic Pulse—A Single Photon inside Negative Refractive Indexed Media

An Electromagnetic (EM) radiation in dispersion less free space vacuum is represented by a photon, with corpuscular and wave nature. The discussions, for the past century aimed at the nature of photon inside a media having dispersion in the refraction property, other than free space. What about its nature if the space be of refractive index which is negative, is discussed in this paper. We call mechanical momentum, wave-momentum, and try to match our present theories with intriguing property of this ‘photon’ or pulse carrying EM energy packet, and more so we try to find its property energy, momentum inside a media a positive refractive media, and if the media show a negative refractive index behavior, then these queries are profound, and suitable explanations to these classical concepts of corpuscular-wave nature of photon inside these media are quest for the scientists dealing with these materials having negative index of refraction. Here some of this counterintuitive nature of corpuscular-wave nature of photon inside negative indexed material is brought out, with possible ‘new definition’ of its ‘wave-momentum’, the concept of ‘reactive energy’ inside negative indexed material, along with possible ‘new wave equation’. These definitions and expressions of ‘wave-momentum’ and ‘reactive energy’ pertaining to negative indexed material are new and discussed and derived by classical means.

Optical Negative-Index Metamaterial Using CSRR by Incidenting the Light Horizontally at Near-Infrared Domain

Metamaterial structure based on cascaded split ring resonators (CSRR) is proposed in order to produce a negative refractive index in terahertz regime at near-infrared range. We have incident light horizontally instead of incidenting it perpendicular. We have measured the negative refractive index, permeability and permittivity by using the S-parameter analysis. Furthermore, it is found out that negative refractive index, permeability and permittivity are dependent upon the width of the wire and the gap between resonators at near-infrared range. This work will be helpful for the fabrication and design of double negative metamaterials structure having negative permeability, permittivity and negative refractive index for in plane applications.

Aberration-free two-thin-lens systems based on negative-index materials

Since the complete correction of all five monochromatic Seidel aberrations for a singlet lens with random shape or a two-thin-lens system is unprocurable merely by using the conventional positive-index materials both in theory and practice, this paper proposes that when one or both of the two lenses is/are made from negative-index materials, an imaging system composed of a pair of spherical thin lenses is possible to form a real image, in air, free from all five monochromatic Seidel aberrations. The calculated numerical solutions to the structural parameters of such lens systems possessing superior performance are provided and examples of them are illustrated for the given combinations of the two lenses＇ refractive indices, including an ultimately-remote imaging system.

新型电介质:Metamaterials(特异材料)与光子晶体材料

作者对目前国际研究热点的Metamaterials(有特异材料,奇异材料,超常材料,左手性材料,负折射率材料,异向材料,元材料等多种中文译名)与光子晶体材料(即光子带隙材料、电磁波带隙材料)的原理与构成方法作了基本的介绍.作者还讨论了这两类新型电介质的共性问题与个性问题.并且讨论与介绍了这两类新型电介质材料的实现方法与应用前景,同时就这两类材料在微波频段的应用与制备技术作了专门的讨论.

基于激光反射和折射测量透明液体折射率

设计了一个基于激光反射测量透明液体折射率的实验。实验测量装置由升降台、容器、光屏、激光、移测显微镜构成。激光以小角度照射容器底部,光屏接收反射的激光,移测显微镜确定容器的位置。在确定容器的初始位置后,往容器中加适量的透明液体,再缓慢下降容器。在容器下降的过程中,当容器底部、液面反射的激光与空容器时底部反射的激光照射光屏同一位置时分别确定容器的位置。最后,根据移测显微镜确定的这三个位置就可计算得到透明液体的折射率。这种测量方法的原理简单、易懂,实验易演示,可以提升实验教学效果。

基于线阵CCD的折射率和浓度测量装置

本文提出了一种结合激光器和线阵CCD的折射率测量方法,利用光线穿过平行板介质时产生横向位移的特性,实现对透明介质折射率和浓度的高效、准确测量。装置采用红色点状激光器作为稳定光源,并通过衰减片削弱光强,利用旋转平台精确调整入射角,最后用线阵CCD传感器捕捉光斑位置变化,再录入Matlab程序中,实现对介质折射率以及透明液体浓度的实时测量。