On the basis of the second order solution of two-dimensional random gravity waves in finite uniform depth,which is rederived by a perturbation expansion method,the analytical expression of the second order spectrum is...On the basis of the second order solution of two-dimensional random gravity waves in finite uniform depth,which is rederived by a perturbation expansion method,the analytical expression of the second order spectrum is strictly deduced, and for infinite depth, the correct form of the kernel function is given for each octant do main.In fact,the present study improves and corrects the generally accepted results obtained by Tick展开更多
The equations of the second and third order derivative curves of time with respect to potential for a reversible process in adsorption chronopotentiometry are derived and experimentally verified.
In this parer, applications of the fractional calculus to the form (Az 2+Bz+C)ψ 2+(Dz+G)ψ 1+Eψ=f and the partial differential equation 2μz 2(Az 2+Bz+C)+(Dz+G)μz+δμ(z,t)=M 2μT 2+NμT, where ψ 1...In this parer, applications of the fractional calculus to the form (Az 2+Bz+C)ψ 2+(Dz+G)ψ 1+Eψ=f and the partial differential equation 2μz 2(Az 2+Bz+C)+(Dz+G)μz+δμ(z,t)=M 2μT 2+NμT, where ψ 1= d ψ d z and ψ 2= d 2ψ d z 2 are presented.展开更多
In this paper,a 13-node pyramid spline element is derived by using the tetrahedron volume coordinates and the B-net method,which achieves the second order completeness in Cartesian coordinates.Some appropriate example...In this paper,a 13-node pyramid spline element is derived by using the tetrahedron volume coordinates and the B-net method,which achieves the second order completeness in Cartesian coordinates.Some appropriate examples were employed to evaluate the performance of the proposed element.The numerical results show that the spline element has much better performance compared with the isoparametric serendipity element Q20 and its degenerate pyramid element P13 especially when mesh is distorted,and it is comparable to the Lagrange element Q27.It has been demonstrated that the spline finite element method is an efficient tool for developing high accuracy elements.展开更多
The title compound of isonicotinato lead（Ⅱ） [Pb（C5H4NCOO）2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead（Ⅱ） ion adopts 4-coordinate geometry. Atomic charge dist...The title compound of isonicotinato lead（Ⅱ） [Pb（C5H4NCOO）2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead（Ⅱ） ion adopts 4-coordinate geometry. Atomic charge distributions indicate that during forming the title compound, each isonicotinic acid ion transfers -0.452 e to lead（Ⅱ） ion. The electronic spectra calculations show that there exist two absorption bands and the electronic transitions are mainly derived from the contribution of intraligand π→π^＊ transition and ligand-to-metal charge transfer （LMCT） transition. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between property and temperature have also been obtained. The calculation of the second order optical nonlinearity was carried out, and the molecular hyperpolarizability was 3.62365^＊10^-30 esu.展开更多
In classical study on generalized viscoelastic fluid, the momentum equation was derived by considering the fractional constitutive model, while the energy equation was ignored its effect. This paper presents an invest...In classical study on generalized viscoelastic fluid, the momentum equation was derived by considering the fractional constitutive model, while the energy equation was ignored its effect. This paper presents an investigation for the magnetohydrodynamic(MHD) flow and heat transfer of an incompressible generalized Burgers' fluid due to an exponential accelerating plate with the effect of the second order velocity slip. The energy equation and momentum equation are coupled by the fractional Burgers' fluid constitutive model. Numerical solutions for velocity, temperature and shear stress are obtained using the modified implicit finite difference method combined with the G1-algorithm,whose validity is confirmed by the comparison with the analytical solution. Our results show that the influences of the fractional parameters α and β on the flow are opposite each other, which is just like the effects of the two parameters on the temperature. Moreover, the impact trends of the relaxation time λ_1 and retardation time λ_3 on the velocity are opposite each other. Increasing the boundary parameter will promote the temperature, but has little effect on the temperature boundary layer thickness.展开更多
With a new approach,the general current expressions of two typical second order catalytic reactions are obtained for disk,hemispherical and spherical microelectrodes under steady-state conditions.This approach is base...With a new approach,the general current expressions of two typical second order catalytic reactions are obtained for disk,hemispherical and spherical microelectrodes under steady-state conditions.This approach is based on the concept of reaction layer.For the second order EC' reactions,we also discussed how it is possible to observe pseudo-first order or second order behavior.This consideration allows the study of the fast chemical reactions and systems where the bulk concentrations of the reactants are nearly equal.Regeneration of Fe^(3+)(EDTA) with H_2O_2 was selected as an example of a rapid catalytic reaction.展开更多
文摘On the basis of the second order solution of two-dimensional random gravity waves in finite uniform depth,which is rederived by a perturbation expansion method,the analytical expression of the second order spectrum is strictly deduced, and for infinite depth, the correct form of the kernel function is given for each octant do main.In fact,the present study improves and corrects the generally accepted results obtained by Tick
文摘The equations of the second and third order derivative curves of time with respect to potential for a reversible process in adsorption chronopotentiometry are derived and experimentally verified.
文摘In this parer, applications of the fractional calculus to the form (Az 2+Bz+C)ψ 2+(Dz+G)ψ 1+Eψ=f and the partial differential equation 2μz 2(Az 2+Bz+C)+(Dz+G)μz+δμ(z,t)=M 2μT 2+NμT, where ψ 1= d ψ d z and ψ 2= d 2ψ d z 2 are presented.
基金The project was supported by the National Natural Science Foundation of China(11001037,11102037,11072156)the Fundamental Research Funds for the Central Universities of China(DUT10ZD112,DUT10JS02)
文摘In this paper,a 13-node pyramid spline element is derived by using the tetrahedron volume coordinates and the B-net method,which achieves the second order completeness in Cartesian coordinates.Some appropriate examples were employed to evaluate the performance of the proposed element.The numerical results show that the spline element has much better performance compared with the isoparametric serendipity element Q20 and its degenerate pyramid element P13 especially when mesh is distorted,and it is comparable to the Lagrange element Q27.It has been demonstrated that the spline finite element method is an efficient tool for developing high accuracy elements.
基金This work was supported by the Natural Science Foundation of Shandong Province (No. Y2002B06)
文摘The title compound of isonicotinato lead（Ⅱ） [Pb（C5H4NCOO）2] has been optimized at B3LYP/LANL2DZ level of theory and calculated results show that the lead（Ⅱ） ion adopts 4-coordinate geometry. Atomic charge distributions indicate that during forming the title compound, each isonicotinic acid ion transfers -0.452 e to lead（Ⅱ） ion. The electronic spectra calculations show that there exist two absorption bands and the electronic transitions are mainly derived from the contribution of intraligand π→π^＊ transition and ligand-to-metal charge transfer （LMCT） transition. The thermodynamic properties of the title compound at different temperatures have been calculated and corresponding relations between property and temperature have also been obtained. The calculation of the second order optical nonlinearity was carried out, and the molecular hyperpolarizability was 3.62365^＊10^-30 esu.
基金Supported by the National Natural Science Foundations of China under Grant Nos.21576023,51406008the National Key Research Program of China under Grant Nos.2016YFC0700601,2016YFC0700603,and 2016YFE0115500
文摘In classical study on generalized viscoelastic fluid, the momentum equation was derived by considering the fractional constitutive model, while the energy equation was ignored its effect. This paper presents an investigation for the magnetohydrodynamic(MHD) flow and heat transfer of an incompressible generalized Burgers' fluid due to an exponential accelerating plate with the effect of the second order velocity slip. The energy equation and momentum equation are coupled by the fractional Burgers' fluid constitutive model. Numerical solutions for velocity, temperature and shear stress are obtained using the modified implicit finite difference method combined with the G1-algorithm,whose validity is confirmed by the comparison with the analytical solution. Our results show that the influences of the fractional parameters α and β on the flow are opposite each other, which is just like the effects of the two parameters on the temperature. Moreover, the impact trends of the relaxation time λ_1 and retardation time λ_3 on the velocity are opposite each other. Increasing the boundary parameter will promote the temperature, but has little effect on the temperature boundary layer thickness.
基金Project supported by the National Natural Science Foundation of ChinaChangchun Institute of Applied Chemistry of Chinese Academy of Sciences.
文摘With a new approach,the general current expressions of two typical second order catalytic reactions are obtained for disk,hemispherical and spherical microelectrodes under steady-state conditions.This approach is based on the concept of reaction layer.For the second order EC' reactions,we also discussed how it is possible to observe pseudo-first order or second order behavior.This consideration allows the study of the fast chemical reactions and systems where the bulk concentrations of the reactants are nearly equal.Regeneration of Fe^(3+)(EDTA) with H_2O_2 was selected as an example of a rapid catalytic reaction.
