Hydrothermal Synthesis and Crystal Structure of a Square Grid Coordination Copper(II) Polymer from 1,4-Bis(imidazole-1-ylmethyl)benzene

The title compound [Cu（bix）2（NO3）z·H2P]n 1 （bix = 1,4-bis（imidazole-1-ylme-thyl） benzene） has been synthesized by hydrothermal method. Its crystal structure is of monoclinic, space group P1^- with a = 8.3075（13）, b = 9.4725（13）, c = 10.0192（13） A, α = 91.088（4）, β = 104.063（6）, γ = 101.88（1）, V = 746.5（3） A^3, Z = 1, C28H30N10O7Cu1, Mr = 682.16, Dc = 1.518 g/cm^3, μ = 0.796 mm^-1, F（000） = 353, the final R = 0.0535 and wR = 0.0996 for 2921 observed reflections with I 〉 2σ（I）. Each bix ligand binds two Cu（Ⅱ） ions to form a 2-D（4,4） square grid layer, which is connected by hydrogen bonds showing large channels occupied by solvated water molecules and nitrate anions.

Square Grid结构无线传感网数据传输的源路由策略分析

无线传感网中的汇聚传输模式使得靠近汇聚点的节点承担了较多的数据转发业务,导致这些节点能量很快耗尽,造成网络节点负载分布不均衡。针对这种汇聚传输问题,结合规则拓扑结构的对称性和预知性,提出基于Square Grid规则拓扑结构中分析典型源路由策略,设计一种计算路由节点负载分布的转发指数,并依据该转发指数分析各路由策略负载性能的方法。通过Mathematica绘制各路由节点负载分布图并对比各路由策略的转发指数,实验结果验证了Balancing Forwarding路由策略的节点具有较均衡的负载分布。该方法能有效地应用于评价路由策略的优劣。

An Improved Algorithm of Grounding Grids Corrosion Diagnosis Based on Total Least Square Method

A new model considering corrosion property for grounding grids diagnosis is proposed,which provides reference solutions of ambiguous branches.The constraint total least square method based on singular value decomposition is adopted to improve the effectiveness of grounding grids' diagnosis algorithm.The improvement can weaken the influence of the model's error,which results from the differences between design paper and actual grid.Its influence on touch and step voltages caused by the interior resistance of conductors is taken into account.Simulation results show the validity of this approach.

Electrochemical Machining Analysis on Grid Cathode Composed of Square Cells

During the electrochemical machining (ECM), the cathodes designed by the existing methods are mainly unitary cathodes, which can be only used to produce the workpieces with the same shapes. However, there are few researches on designing cathodes for machining the different workpieces with the different surfaces. This paper presents the grid cathode composed of the square cells to produce the workpieces with different shapes. Three types of the square cells, 2.5 mm′2.5 mm, 3 mm′3 mm, and 4 mm′4 mm, are utilized to construct the plane, the slant, and the blade cathode. The material of the cathode and the anode is CrNi 18 Ti 9 , and the ingredient of electrolyte is 15% NaCl and 15% NaNO 3 . The machining equilibrium machining current and time are acquired and analyzed, the machining process and the workpiece quality are compared between using the grid cathode and the unitary cathode. Moreover, the machining errors on the workpiece surface are measured and analyzed, and the error reasons are traced and discussed to obtain the better surface quality of the workpiece. The experiment and analysis results show that the grid cathode can be used to manufacture the workpieces with complex shapes in certain range of the error. The workpiece quality improves with the size of the square cell being reduced, and if the square element is small enough, the workpiece quality is almost equal to the one machined by the unitary cathode. The proposed research realizes a single cathode machining the different workpieces with the different surfaces.

INFLUENCE OF SERIES OF SQUARE GRIDS ON FRACTAL DIMENSIONS-A Case Study of Mountains of China's Mainland

MANDELBROT enunciated the uncertainty of the length of a coastline in his paper "How long is the coastline of Britain?" published in Science in 1967. The fractal concept was presented for the first time in that paper and has been applied to many fields ever since. Although fractal dimensions of lots of phenomena were calculated by the box-counting method,the quantitative influence of series of square grids on them is ignored. The issue is systematically discussed as a case study of the mountains of China′s Mainland in this paper. And some significant conclusions are drawn as follows: 1) Although the fractal character objectively exists in the mountains of China′s Mainland,and it does not vary with the changes of series of square grids,the fractal dimensions of the mountains of China′s Mainland are different with these changes. 2) The fractal dimensions of the mountains of China′s Mainland vary with the average lengths of sides of series of square grids. The fractal dimension of the mountains of China′s Mainland is the function of the average length of side of square grid. They conform to the formula D=f(r) (where D is the fractal dimension,and r is the average length of side of square grid). 3) Different dots of data collection can affect the fractal dimension of the mountains of China′s Mainland. 4) The same range of length of side of square grid and dots of data collection can ensure the comparison of fractal dimensions of the mountains of China′s Mainland. The research is helpful to get the more understanding of fractal and fractal dimension,and ensure that the fractal studies would be scientific.

Comparative Analysis of Equal and Unequal Grounding Grid Configurations by Compression Ratio and Least Square Curve Fitting Techniques

The primary aim of the power system grounding is to safeguard the person and satisfying the performance of the power systemtomaintain reliable operation.With equal conductor spacing grounding grid design,the distribution of the current in the grid is not uniform.Hence,unequal grid conductor span in which grid conductors are concentrated more at the periphery is safer to practice than equal spacing.This paper presents the comparative analysis of two novel techniques that create unequal spacing among the grid conductors:the least-square curve fitting technique and the compression ratio techniquewith equal grid configuration for both square and rectangular grids.Particle Swarm Optimization(PSO)is adopted for finding out one optimal feasible solution among many feasible solutions of equal grid configuration for both square and rectangular grids.Comparative analysis is also carried out between square and rectangular grids using the least square curve fitting technique as it results in only one unequal grid configuration.Simulation results are obtained by theMATLAB software developed.Percentage of improvement in ground potential rise,step voltage,touch voltage,and grid resistancewith variation in compression ratios are plotted.

Grid Convergence Property of Three-Dimensional Measurement-Integrated Simulation for Unsteady Flow behind a Square Cylinder with Karman Vortex Street

The purpose of this study was to clarify grid convergence property of three-dimensional measurement-integrated (3D-MI) simulation for a flow behind a square cylinder with Karman vortex street. Measurement-integrated (MI) simulation is a kind of the observer in the dynamical system theory by using CFD scheme as a mathematical model of the system. In a former study, two-dimensional MI (2D-MI) simulation with a coarse grid system showed a fairly good result in comparison with a 2D ordinary (2D-O) simulation, but the results were degraded with grid refinement. In this study, 3D-MI simulation and three-dimensional ordinary (3D-O) simulation were performed with three grid systems of different grid resolutions, and their grid convergence properties were compared. As a result, all 3D-MI simulations reproduced the vortex shedding frequency identical to that of the experiment, and the flow fields obtained were very close, within 5% difference between the results, while the results of the 3D-O simulations showed variation of the solution under convergence. It is shown that the grid convergence property of 3D-MI simulation is monotonic and better than that of 3D-O simulation, whereas those of 2D-O and 2D-MI simulations for streamwise velocity fluctuation are divergent. The solution of 3D-MI simulation with a relatively coarse grid system properly reproduces the basic three-dimensional structure of the wake flow as well as the drag and lift coefficients.

Local geoid height approximation and interpolation using moving least squares approach

In this paper an introduction of the moving least squares approach is presented in the context of data approximation and interpolation problems in Geodesy.An application of this method is presented for geoid height approximation and interpolation using different polynomial basis functions for the approximant and interpolant,respectively,in a regular grid of geoid height data in the region 16.0417°≤φ≤47.9583°and 36.0417°≤λ≤69.9582°,with increment 0.0833°in both latitudal and longitudal directions.The results of approximation and interpolation are then compared with the geoid height data from GPS-Levelling approach.Using the standard deviation of the difference of the results,it is shown that the planar interpolant,with reciprocal of distance as weight function,is the best choice in this local approximation and interpolation problem.

High-Dimensional Regression on Sparse Grids Applied to Pricing Moving Window Asian Options

The pricing of moving window Asian option with an early exercise feature is considered a challenging problem in option pricing. The computational challenge lies in the unknown optimal exercise strategy and in the high dimensionality required for approximating the early exercise boundary. We use sparse grid basis functions in the Least Squares Monte Carlo approach to solve this “curse of dimensionality” problem. The resulting algorithm provides a general and convergent method for pricing moving window Asian options. The sparse grid technique presented in this paper can be generalized to pricing other high-dimensional, early-exercisable derivatives.

不同容量下并网模式交流微电网短路故障早期检测与区域定位

随着分布式电源(distributed generation,DG)的容量变化,微电网原有的供电结构发生改变,使得潮流大小、方向和功率结构发生变化,对快速检测和定位微电网中的短路故障区域提出了挑战。在MATLAB/Simulink中搭建低压交流微电网模型;通过高尺度小波能量谱算法对微电网与大电网公共连接点(point of common coupling,PCC)处检测到的电流进行分解,提取适应不同容量情况的短路故障特征值,实现了不同容量下微电网短路故障的早期检测;利用小波能量谱特征结合基于正交最小二乘法(orthogonal least square,OLS)的径向基函数(radial basis function,RBF)神经网络算法提出一种适用于不同容量微电网的短路故障区域定位方法,并进行仿真验证;在此基础上设计并网模式微电网短路故障保护硬件系统,并进行实验验证。结果表明,所设计的保护系统能够快速、准确地同时实现并网模式下交流微电网短路故障的早期检测与区域定位。

方格上的乌托邦:建筑标准化思想向未来城市的延伸

建筑标准化思想虽因现实建造而生,但也在众多空想城市中频现其身。在城市空间里,它时而反映政治控制,时而体现技术统治,即:既属于技术,也属于观念。建筑标准化的一些基本特征如统一性、高效性、畅达性、秩序性,不断被乌托邦建筑师利用和追求,或偶尔回避,经常以不同方式表现其存在。在传统标准化技术支持下的乌托邦城市,不仅普遍使用类似方格网这样的简单线性形式,还充当着工业时代线性建造逻辑的代表;而新型标准化正走向非线性的未来。

近代粤西广州湾的空间形态演变研究

广州湾(现湛江市)于1899年被强租。早期法国计划在麻斜河口分设东西军营以加强军事控制,并在东岸着重建设麻斜新城与赤坎埠争利,失败后转回西岸发展白雅特城。套用东南亚的管治经验,白雅特城由法国人主导进行政治控制,赤坎埠由华商精英主导进行商业经营,广州湾开始较为稳定发展并演进为双核主体空间结构。白雅特城采用轴线控制的方格网格局以彰显控制权威;赤坎埠因发展时序建成四个组团,空间呈现多元拼贴特征,二者共同建构了湛江历史城区的底图。

三层正放四角锥预应力网架稳定性分析

网架以其优良的工程性能成为大跨度结构的首选结构类型之一。为改善传统网架结构在大跨度条件下变形大、用钢量大的缺陷,文中通过对网架施加预应力的方式,达到增强结构整体刚度和承载能力的目的。预应力的施加必然会对网架的稳定性能造成影响,其中支承形式对网架结构的稳定性影响较大。并通过对网架施加不同预应力后进行稳定性分析,得到不同预应力布索方式对网架稳定性影响,为网架的实际工程建设提供参考。

基于ico_HEALPix网格的超高阶地球重力场建模方法

本文针对传统地理网格数据剖分的重力场模型构建在高纬度区域出现数据冗余的问题,将分层等积等纬度像素化(HEALPix)网格结构引入地球重力场解算中,提出了利用二十面体HEALPix(ico_HEALPix)网格的超高阶地球重力场建模方法,实现了全球3600阶次球谐位系数的高效构建,同时针对ico_HEALPix网格在球谐分析过程中法矩阵不是严格块对角化结构的问题,设计了迭代算法,有效提高模型构建的精度。试验表明,ico_HEALPix网格数据在数据量小于地理网格500万的前提下,通过迭代方法构建的全球地球重力场模型精度可达到优于地理网格的效果,球谐位系数误差阶RMS提升1~2个数量级,还解决了地理网格南北极点畸变和数据冗余的问题,提高了网格的数据利用率。

Integrative square-grid triboelectric nanogenerator as a vibrational energy harvester and impulsive force sensor

A square-grid triboelectric nanogenerator （SG-TENG） is demonstrated for harvesting vibrational energy and sensing impulsive forces. Each square of the three-dimensional （3D）-printed square grid is filled with an aluminum （A1） ball. The grid structure allows the SG-TENG to harvest vibrational energy over a broad bandwidth and operate at different vibrational angles. The most striking feature of the SG-TENG is its ability of being scaled and integrated. After connecting two SG-TENGs in parallel, the open-circuit voltage and short-circuit current are significantly increased over the full vibrational frequency range. Being integrated with a table tennis racket, the SG-TENG can harvest the vibrational energy from hitting a ping pong ball using the racket, where a direct hit by the racket generates an average output voltage of 10,9 ~ 0.6 V and an average output current of 0.09 ± 0.02 boA. Moreover, the SG-TENG integrated into a focus mitt can be used in various combat sports, such as boxing and taekwondo, to monitor the frequency and magnitude of the punches or kicks from boxers and other practitioners. The collected data allow athletes to monitor their status and improve their performance skills. This work demonstrates the enormous potential of the SG-TENG in energy harvesting and sensing applications.

Synthesis of two lanthanide clusters Ln^(Ⅲ)_(4)(Gd_(4) and Dy_(4)) with [2×2] square grid shape:Magnetocaloric effect and slow magnetic relaxation behaviors

Two isostructural tetranuclear lanthanide clusters named [Ln_(4)(L)_(4)(CH_(3) O)_(4)]·CH_(3) OH(Ln=Gd(Ⅲ) for 1,Dy(Ⅲ) for 2,H_(2) L=N’-(2-hydroxy-3-methoxybenzylidene)-6-(hydroxymethyl) picolinohydrazide) were successfully isolated by using a polydentate Schiff based ligand and Ln(Ⅲ) nitrate salts.The structures of 1 and 2 were characterized by X-ray structural analyses,they are held by four double deprotonated ligands L2-.In them all the lanthanide ions are eight-coordinated and distributed over four vertices of a parallelogram,presenting a Ln4 cluster with a strict [2 × 2] square grid pattern.The details of magnetic analysis show that 1 displays weak anti-ferromagnetic exchange between neighboring Gd(Ⅲ) ions through carboxylate oxygen and methanol oxygen ligand atoms.Furthermore,1 exhibits significant magnetocaloric effect with the maximum entropy change-ΔSm value of 28.5 J/(kg K) for ΔH=7.0 T at 2.0 K.For compound 2,remarkable slow magnetic relaxation behaviors are observed in the presence of zero magnetic field with τ0=1.02 × 10^(-6) s and energy barrier ΔE/kB=43.24 K.

基于自适应栅格聚类的轻量化车辆检测算法

提出了一种自适应栅格聚类的轻量化车辆检测算法。采用半径滤波和最小二乘法对原始点云进行噪声点去除和地面拟合处理,采用最大最小值栅格化和自适应栅格聚类算法生成若干个聚类目标,使用多层感知机网络对聚类目标进行二分类。在KITTI数据集上进行训练和验证算法实验,结果表明:算法在不同场景下具有环境适应性,与其他3D检测算法相比,车辆识别准确率平均提高了7.95%。

基于CASS的土方量计算方法对比分析

文章基于CASS软件详细地阐述了断面法、方格网法、等高线法和三角网法(DTM)计算土方量的方法和原理以及各方法在土方计算中存在的问题,总结了各方法的优缺点,对4种方法的应用场景、适用情况、精度等进行归纳和对比,为工程土方量计算的用户提供参考。

分布式新能源接入电网的电能质量异常监测方法研究

电网电能质量易受到分布式新能源接入电网的冲击。冲击会破坏电压数据的完整性从而无法确定监测阈值,导致监测时间长、准确率低。为此,对分布式新能源接入电网的电能质量异常监测方法进行了研究。构建最小二乘支持向量机模型,通过综合学习粒子群算法确定模型超参数,利用优化后模型填补电压信号缺失数据。采用小波变换提取电能质量数据分布特征,获取每层能量分布与标准信号能量分布的差值。引入樽海鞘群优化算法优化反向传播(BP)神经网络初始权值和监测阈值,将差值输入训练完成的BP神经网络中,实现电能质量异常监测。试验结果表明,所提方法的查准率和查全率在95%以上、训练时间和测试时间在15 ms左右。该方法可准确、高效地监测到异常数据,从而保证电网的稳定运行。