The Mesozoic Basin-Mountain Coupling Process of the Southern East China Sea Shelf Basin and its Adjacent Land Area

Basin-mountain coupling is a key issue for basin formation and evolution. The analysis of basin-mountain coupling process, as well as quantitative or semiquantitative restoration of prototype basin and the evolution of continental margin, can be used to interpret the geological process of basin-range conversion and reconstruct early prototype basins, which is a difficult and leadin~ scientific oroblem of basin research.

Response of environmental sensitive grain size group in Core FJ04 from mud area in the north of East China Sea to East Asian winter monsoon evolvement

AMS14C dating and grain-size analysis for Core FJ04, located at mud area in the North of East China Sea provide us a high-resolution grain-size distribution curve varying with depth and time. This paper got environmental sensitive grain-size group by using standard deviation method, and proved that the selected sensitive grain-size group is an important proxy which can be used to reconstruct intensity of East Asian Winter Monsoon （EAWM）. Then we got reconstruction of EAWM evolvement since 3 ka B.P., which revealed two main phases： （1） 3 - 1.15ka B.P., relative weak EAWM with middle frequency fluctuation; （2） 1.15 - 0ka B.P., really strong EAWM with high frequency fluctuation. And 1.15 ka B.P. is a distinct turning point. During the whole period, 11 intense events of EAWM were recorded and correlated well with other climate records, but the response extent was different, which showed consistency of climate change and particularity of region response.

Abnormality of the monsoon wind in the sea area along the southeasterncoast of China and the response of the northern areaof the South China Sea during the ENSO events

-Variations of monsoon wind field in the sea area along the southeastern coast of China during the ENSO events and its influence on the sea level and sea surface temperature (SST) are explored mainly on the basis of the data of monthly mean wind at 850 hPa and five coastal stations during 1973-1987. The results from the analyses of the data and theoretical estimation show that the southwest wind anomalies appeared in the study area during the events, and northeast wind anomalies occurred in general before the events. With the coastline of the area being parallel basically to the direction of the wind, an Ekman transport will result in an accumulation of the water near the coast or a departure of the water from the coast. As a result , the sea level and SST there will be affected markedly. During the events, southwest wind will intensify in the summer, and northeast wind will weaken in the winter. Their total effect is that a large negative anomaly of the sea level and SST will occur. The estimations indicate that the monsoon wind is stronger in the summer and weaker in the winter than the normal by 1-1. 5 m/s during the events, and this anomaly will cause a decrease of the sea level by 7-11 cm . Changes of the wind field, therefore, is mainly responsible for a large negative anomalies of the sea level and SST there during the ENSO events.

Undrained shear strength evaluation for hydrate-bearing sediment overlying strata in the Shenhu area, northern South China Sea

The undrained shear strength of shallow strata is a critical parameter for safety design in deep-water operations.In situ piezocone penetration tests(CPTU) and laboratory experiments are performed at Site W18-19 in the Shenhu area, northern South China Sea, where China's first marine hydrate exploitation operation is due to be located. The validation of the undrained shear strength prediction model based on CPTU parameters. Different laboratory tests, including pocket penetrometer, torvane, miniature vane and unconsolidated undrained triaxial tests, are employed to solve empirical cone coefficients by statistical and mathematical methods. Finally, an optimized model is proposed to describe the longitudinal distribution of undrained shear strength in calcareous clay strata in the Shenhu area. Research results reveal that average empirical cone coefficients based on total cone resistance, effective resistance, and excess-pore pressure are 13.8, 4.2 and 14.4, respectively. The undrained shear strength prediction model shows a good fit with the laboratory results only within specific intervals based on their compaction degree and gas-bearing conditions. The optimized prediction model in piecewise function format can be used to describe the longitudinal distribution of the undrained shear strength for calcareous clay within all depth intervals from the mud-line to the upper boundary of hydrate-bearing sediments(HBS). The optimized prediction result indicates that the effective cone resistance model is suitable for very soft to firm calcareous clays,the excess-pore pressure model can depict the undrained shear strength for firm to very stiff but gas-free clays,while the total cone resistance model is advantageous for evaluating the undrained shear strength for very stiff and gassy clays. The optimized model in piecewise function format can considerably improve the adaptability of empirical models for calcareous clay in the Shenhu area. These results are significant for safety evaluations of proposed hydrate exploitation projects.

Basement of the South China Sea Area:Tracing the Tethyan Realm

The basement of the South China Sea（SCS）and adjacent areas can be divided into six divisions（regions）-Paleozoic Erathem graben-faulted basement division in Beibu Gulf,Paleozoic Erathem strike-slip pull-apart in Yinggehai waters,Paleozoic Erathem faulted-depression in eastern Hainan,Paleozoic Erathem rifted in northern Xisha（Paracel）,Paleozoic Erathem strike-slip extending in southern Xisha,and Paleozoic-Mesozoic Erathem extending in Nansha Islands（Spratly）waters.The Pre-Cenozoic basement in the SCS and Yunkai continental area are coeval within the Tethyan tectonic domain in the Pre-Cenozoic Period.They are formed on the background of the Paleo-Tethyan tectonic domain,and are important components of the Eastern Tethyan multi-island-ocean system.Three branches of the Eastern Paleo-Tethys tectonic domain,North Yunkai,North Hainan,and South Hainan sea basins,have evolved into the North Yunkai,North Hainan,and South Hainan suture zones, respectively.This shows a distinctive feature of localization for the Pre-Cenozoic basement.The Qiongnan（i.e.South Hainan）Suture Zone on the northern margin of the South China Sea can be considered the vestige of the principal ocean basin of Paleo-Tethys,and connected with the suture zone of the Longmucuo-Shuanghu belt-Bitu belt-Changning-Menglian-Bentong-Raub belt,the south extension of Bitu-Changning-Menglian-Ching Mai belt-Chanthaburi-Raub-Bentong belt on the west of South China Sea,and with the Lianhua-Taidong suture zone（a fault along the east side of Longitudinal Valley in Taiwan）-Hida LP/HT（low pressure-high temperature）metamorphic belt-Hida -marginal HP/LT metamorphic belt in southwestern Honshu of Japan,on the east of the South China Sea.The Qiongbei（North Hainan）suture zone may eastwards extended along the Wangwu-Wenjiao fault zone,and connects with the Lufeng-Dapu-Zhenghe-Shangyu（Lianhuashan）deep fault zone through the Pearl River Mouth Basin.The Meso-Tethys developed on the south of the South China Sea.The Nansha Trough may be considered the vestige of the northern shelf of the Meso-Tethys. The oceanic crust of the Meso-Tethys has southwards subducted along the subduction-collision-thrust southern margin of the Nansha Trough with a subduction-pole opposite to those of the Yarlung Zangbo-Mytkyina-Bago zone on the west of the South China Sea,and the Meso-Tethyan（e.g.Northern Chichibu Ocean of the Meso-Tethys）suture zone＂Butsozo tectonic line＂in the outer belt of the Jurassic-Early Cretaceous terrene group in southwest Japan,on the east of the South China Sea.

Types,Characteristics and Significances of Migrating Pathways of Gas-bearing Fluids in the Shenhu Area,Northern Continental Slope of the South China Sea

The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways（largescale faults, gas chimneys and mud diapirs） presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways（large-scale faults and mud diapirs） in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways（composed of gas chimneys） in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.

Characteristics of Clay Minerals in the Northern South China Sea and Its Implications for Evolution of East Asian Monsoon since Miocene

Clay mineral assemblages, crystallinity, chemistry, and micromorphology of clay particles in sediments from ODP Site 1146 in the northern South China Sea （SCS） were analyzed, and used to trace sediment sources and obtain proxy records of the past changes in the East Asian monsoon climate since the Miocene, based on a multi-approach, including X-ray diffraction （XRD） and scanning electron microscopy combined with energy dispersive X-ray spectrometry （SEM-EDS）. Clay minerals consist mainly of illite and smectite, with associated chlorite and kaolinite. The illite at ODP Site 1146 has very well-to-well crystallinity, and smectite has moderate-to-poor crystallinity. In SEM the smectite particles at ODP Site 1146 often appear cauliflower-like, a typical micromorphology of volcanic smecites. The smectite at ODP Site 1146 is relatively rich in Si element, but poor in Fe, very similar to the smectite from the West Philippine Sea. In contrast, the chemical composition of illite at ODP Site 1146 has no obvious differences from those of the Loess plateau, Yellow River, Yangtze River, and Pearl River. A further study on sediment source indicates that smectite originates mainly from Luzon, kaolinite from the Pearl River, and illite and chlorite from the Pearl River, Taiwan and/or the Yangtze River. The clay mineral assemblages at ODP Site 1146 were not only controlled by continental eathering regimes surrounding the SCS, but also by the changing strength of the transport processes. The ratios of （illite＋chlorite）/smectite at ODP Site 1146 were adopted as proxies for the East Asian monsoon evolution. Relatively higher ratios reflect strongly intensified winter monsoon relative to summer monsoon, in contrast, lower ratios indicate a strengthened summer monsoon relative to winter monsoon. The consistent variation of this clay proxy from those of Loess plateau, eolian deposition in the North Pacific, planktonic, benthic foraminifera, and black carbon in the SCS since 20 Ma shows that three profound shifts of the East Asian winter monsoon intensity, and aridity in the Asian inland and the intensity of winter monsoon relative to summer monsoon, occurred at about 15 Ma, 8 Ma, and the younger at about 3 Ma. The phased uplift of the Himalaya-Tibetan plateau may have played a significant role in strengthening the Asian monsoon at 15 Ma, 8 Ma, and 3 Ma.

Dynamics of picoplankton in the Nansha Islands area of the South China Sea

Dynamics of major picoplankton groups, Synechococcus (Syn), Prochlorococcus (Pro), picoeukaryotes (Euk) and heterotrophic bacteria (Bact) was investigated by flow cytometry for the first time in the Nansha Islands area in the South China Sea. Averaged over the whole investigation area, depth-weighted integrated cell abundance (DWA) of Syn, Pro, Euk and Bact was 1.6 (0.4-5.7)×103, 5.4 (0.1-7.3)×104, 0.7 (0.2-2.2)×103, and 2.3 (1.4-3.2)×105 cells/mL respectively. Picoautotrophic cell abundance was low in the northwest part of the Nansha Islands where surface water temperature was low and the upper mixed layer was shallow. Concurrently, a surface maximum vertical distribution pattern was observed in this area. While in the southeast and east zones where temperatures were relatively higher and nitraclines were deeper, picoplankton is abundant and a subsurface maximum around 50-75 m is observed. Coupling of horizontal and vertical distribution patterns of picoplankton abundance and hydrological status was found, suggesting a strong influence of currents and water column structure on picoplankton distribution in the investigation area. Contrary to that in the shelf water in the East China Sea, the relationship between Pro and Bact in the Nansha Islands area in the South China Sea was not significantly negative but weakly positive. Moreover, a similar distribution pattern of Syn and Pro was observed. Possible reasons for these differences in the two marine regimes were discussed.

The Relationship between Tectonic Subsidence and BSR of Upper Neogene in the Deep-Water Area of the Northern Continental Slope, South China Sea

BSR （Bottom Simulating Reflector） occurs widely in the strata since the late Miocene in the deep-water area of the northern continental slope of South China Sea （SCS）. It is an important seismic reference mark which identifies the gas hydrate and its distribution influenced by the tectonic movements. Single-point basin modeling was conducted using 473 points in the study area. To discuss the relationships between the tectonic subsidence and BSR, the volume and rate of tectonic subsidence in each geological time have been simulated. The results show that there are three tectonic accelerate subsidence processes in the study area since the late Miocene, especially since 1.8Ma the tectonic subsidence accelerates more apparently. Since the Late Miocene to Pleistocene, the rate of tectonic subsidence in deep-water underwent a transformation from weak to strong. The ratio of tectonic subsidence to the total subsidence was relatively high （65-70%）. Through the superposition of the BSR developed areas and the contours of tectonic subsidence in this area, it was discovered that more than 80% of BSR tend to be distributed at the slope break or depression-uplift structural transfer zone and the average tectonic subsidence rate ranges from 70 m/Ma to 125 m/Ma.

Coexistence of natural gas hydrate,free gas and water in the gas hydrate system in the Shenhu Area,South China Sea

Shenhu Area is located in the Baiyun Sag of Pearl River Mouth Basin,which is on the northern continental slope of the South China Sea.Gas hydrates in this area have been intensively investigated,achieving a wide coverage of the three-dimensional seismic survey,a large number of boreholes,and detailed data of the seismic survey,logging,and core analysis.In the beginning of 2020,China has successfully conducted the second offshore production test of gas hydrates in this area.In this paper,studies were made on the structure of the hydrate system for the production test,based on detailed logging data and core analysis of this area.As to the results of nuclear magnetic resonance(NMR)logging and sonic logging of Well GMGS6-SH02 drilled during the GMGS6 Expedition,the hydrate system on which the production well located can be divided into three layers:(1)207.8–253.4 mbsf,45.6 m thick,gas hydrate layer,with gas hydrate saturation of 0–54.5%(31%av.);(2)253.4–278 mbsf,24.6 m thick,mixing layer consisting of gas hydrates,free gas,and water,with gas hydrate saturation of 0–22%(10%av.)and free gas saturation of 0–32%(13%av.);(3)278–297 mbsf,19 m thick,with free gas saturation of less than 7%.Moreover,the pore water freshening identified in the sediment cores,taken from the depth below the theoretically calculated base of methane hydrate stability zone,indicates the occurrence of gas hydrate.All these data reveal that gas hydrates,free gas,and water coexist in the mixing layer from different aspects.

Environmental record from the mud area on the inner continental shelf of the East China Sea since the mid-Holocene

Paleoclimate record was revealed in Core MZ01 covering the mid-Holocene in age,located in the mud area of the inner continental shelf of the East China Sea. The ancient environment featured low-energy shallow sea shelf deposition formed mainly by coastal currents. The results show that temporal variation in geochemistry corresponds with the climate changes inferred from historical record. Relatively low MgO/Al 2 O 3,CaO/K 2 O and high Al 2 O 3 /Na 2 O,K 2 O/Na 2 O,MnO/CaO values reflected a warm and humid climate in general,and vice versa. Therefore,these chemical indices could be applied to identify the variation of palaeoclimate in eastern China. The authors reconstructed the history of mid-Holocene climatic variation of the inner continental shelf of the East China Sea. From 8 300 a BP to 4 200 a BP,the climate was moderately warm and humid. From 4 200 a BP to 2 000 a BP,the climate turned cool and dry,and the regional climate frequently fluctuated in alternation of cool-dry periods（3 700 a BP,2 850 a BP and 2 400 a BP） and warm-wet periods（3 250 a BP and 2 650 a BP） . After 2 000 a BP,the climate of the study area gradually turned warm again,while the Little Ice Age,a cold event centered at around 250 a BP was indicated by those geochemical indices as mentioned above.

STUDY OF WATER-TRANSPORT THROUGH SOME MAIN STRAITS IN THE EAST CHINA SEA AND SOUTH CHINA SEA

OCCAM global ocean model results were applied to calculate the monthly water transport through 7 straits around the East China Sea (ECS) and the South China Sea (SCS). Analysis of the features of velocity profiles and their variations in the Togara Strait, Luzon Strait and Eastern Taiwan Strait showed that: 1) the velocity profiles had striped pattern in the Eastern Taiwan Strait, where monthly flux varied from 22.4 to 28.1 Sv and annual mean was about 25.8 Sv; 2) the profiles of velocity in the Togara Strait were characterized by core structure, and monthly flux varied from 23.3 to 31.4 Sv, with annual mean of about 27.9 Sv; 3) water flowed from the SCS to the ECS in the Taiwan Strait, with maximum flux of 3.1 Sv in July and minimum of 0.9 Sv in November; 4) the flux in the Tsushima Strait varied by only about 0.4 Sv by season and its annual mean was about 2.3 Sv; 5) Kuroshio water flowed into the SCS in the Luzon Strait throughout the year and the velocity profiles were characterized by multi core structure. The flux in the Luzon Strait was minimum in June (about 2.4 Sv) and maximum in February (about 9.0 Sv), and its annual mean was 4.8 Sv; 6) the monthly flux in the Mindoro Strait was maximum in December (3.0 Sv) and minimum in June (only 0.1 Sv), and its annual mean was 1.3 Sv; 7) Karimata Strait water flowed into the SCS from May to August, with maximum inflow flux of about 0.75 Sv in June and flowed out from September to April at maximum outflow flux of 3.9 Sv in January. The annual mean flux was about 1.35 Sv.

Geoacoustic Inversion for Bottom Parameters in the Deep-Water Area of the South China Sea

Bottom acoustic parameters play an important role in sound field prediction. Acoustic parameters in deep water are not well understood. Bottom acoustic parameters are sensitive to the transmission-loss （TL） data in the shadow zone of deep water. We propose a multiple-step fill inversion method to invert sound speed, density and attenuation in deep water. Based on a uniform liquid hMf-space bottom model, sound speed of the bottom is inverted by using the long range TL at low frequency obtained in an acoustic propagation experiment conducted in the South China Sea （SCS） in summer 2014. Meanwhile, bottom density is estimated combining with the Hamilton sediment empirical relationship. Attenuation coefficients at different frequencies are then estimated from the TL data in the shadow zones by using the known sound speed and density as a constraint condition. The nonlinear relationship between attenuation coefficient and frequency is given in the end. Tile inverted bottom parameters can be used to forecast the transmission loss in the deep water area of SCS very we//.

Rates and fluxes of centennial-scale carbon storage in the fine-grained sediments from the central South Yellow Sea and Min-Zhe belt, East China Sea

The global carbon cycle has played a key role in mitigating global warming and climate change.Long-term natural and anthropogenic processes influence the composition,sources,burial rates,and fluxes of carbon in sediments on the continental shelf of China.In this study,the rates,fluxes,and amounts of carbon storage at the centennial scale were estimated and demonstrated using the case study of three fine-grained sediment cores from the central South Yellow Sea area(SYSA) and Min-Zhe belt(MZB),East China Sea.Based on the high-resolution temporal sequences of total carbon(TC)and total organic carbon(TOC)contents,we reconstructed the annual variations of historical marine carbon storage,and explored the influence of terrestrial and marine sources on carbon burial at the centennial scale.The estimated TC storage over 100 years was 1.18×10~8 t in the SYSA and 1.45×10~9 t in the MZB.The corrected TOC storage fluxes at the centennial scale ranged from 17 to 28 t/(km^2·a)in the SYSA and from 56 to 148 t/(km^2·a)in the MZB.The decrease of terrestrial materials and the increase of marine primary production suggest that the TOC buried in the sediments in the SYSA and MZB was mainly derived from the marine autogenetic source.In the MZB,two depletion events occurred in TC and TOC storage from 1985 to 1987 and 2003 to 2006,which were coeval with the water impoundment in the Gezhouba and Three Gorges dams,respectively.The high-resolution records of the carbon storage rates and fluxes in the SYSA and MZB reflect the synchronous responses to human activities and provide an important reference for assessing the carbon sequestration capacity of the marginal seas of China.

Distribution of Dissolved Inorganic Arsenic and Its Seasonal Variations in the Coastal Area of the East China Sea

Water samples were collected in the coastal area of the Changjiang Estuary on four cruises from August 2002 to May 2003. The seasonal variations of dissolved inorganic arsenic （DIAs） distributions were analyzed. The results showed that the distributions of DIAs were mainly influenced by Water （KSSW）. The concentration of the total dissolved the terrestrial input and the intrusion of the Kuroshio Subsurface inorganic arsenic （TDIAs） decreased consecutively from winter to summer, while it increased in autumn. The distributions of TDIAs showed some relationships with salinity and suspended particulate matter （SPM）. The relationships between DIAs speciation （including arsenite [ As（ Ⅲ ） ] and arsenate [ As（ Ⅴ ） ]）, biological activity and the availabilities of the phosphate were investigated in the study area for the cruise August 2002. The ratio of As （Ⅲ）/TDIAs increased with the decrease of phosphate concentrations. In the bottom water, the As（ Ⅲ ）/TDIAs ratio decreased with the increasing of N/P. The concentration of TDIAs decreased 28.7% approximately after the occurrence of harmful algal blooms （HAB） because of the uptake of arsenate by algae. Further study is needed about the arsenic source/sink relationships in their vertical or horizontal profiles and the uptake mechanism during the occurrence of harmful algal blooms.

Tidal analysis in the venturi-shaped area between Zhenhai and Shenjiamen in the East China Sea

In order to better understand the general tidal features in the venturi-shaped area between Zhenhai and Shenjiamen in the northern coastal region of Zhejiang Province in the East China Sea, the tidal data were obtained from both the three permanent tide stations of Zhenhai, Dinghai and Shenjiamen, and four temporary tide stations of Mamu, Chuanshan, Guoju and Liuheng, along with the current speed being observed at Luotou Waterway. Results from harmonic analysis show that: (1) The area was dominated by shallow water tides with irregular semi-diurnal features, and the smallest tidal range occurred in the area near a crossing line between Zhenhai and Dinghai stations, indicating that a tidal node existed in the southern Hangzhou Bay; (2) Formulae, HS2/HM2 >0.4 and gM2-(gK1+gO1)=270° (where H and g are harmonic constants), could be used as judging criteria for high and low tidal level diurnal inequalities; (3) The duration difference between ebb and flood tides could be roughly assessed by the ratio of HM4 vs. HM2; and the larger the ratio is, the bigger the duration difference is. At the same time, the duration period could be assessed by 2gM2-gM4, the epoch difference between M2 and M4 tidal constituents. If 2gM2-gM4 <180°, then the ebb duration is longer than the flood duration; if 180°< 2gM2-gM4 <360°, the result is reversed; (4) Taking Dinghai station as a center point, the highest tidal levels and the average high tidal levels, as well as the average tidal ranges at all stations became higher and larger both southeastwards and northwestwards, while the lowest tidal levels and the average low tidal levels appeared to be lower both southeastwards and northwestwards; and (5) The tidal patterns were not all in line with the tidal current patterns. As a conclusion, the smallest tidal range occurred in the narrow part of the venturi-shaped area. Along the both sides of the area, the highest tidal level and tidal range became higher and larger, while the lowest tidal level became lower with the increase of the distance from the narrow throat area. This is somehow different from the theory that the tidal level increases gradually when it moves towards the top narrow area of a V-shaped bay or estuary.

Simulation of the Accumulation Process of Biogenic Gas Hydrates in the Shenhu Area of Northern South China Sea

Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloor topographic highs. Many gas hydrate exploration examples abroad also indicate that the saturation of gas hydrates was higher at seafloor topographic highs. This work aims to understand why gas hydrates accumulated at topographic highs and why their saturation is higher.

The Combined Effect of Tibetan Plateau Uplift and Glacial-Interglacial Cycles on the Quaternary Evolution of the East Asian Monsoon: Evidence from South China Sea Sediments

The siliciclastic sediments of the uppermost section of 185 mcd （meters composite depth） from ODP Site 1146 on the northern continental slope of the South China Sea （SCS） were partitioned according to their sources using end-member modeling on grain-size data.The goal was to evaluate the evolution of the East Asian monsoon over the past 2 million years.The siliciclastic sediments were described as hybrids of four end-members,EM1,EM2,EM3,and EM4,with modal grain sizes of 8-22 μm,2-8 μm,31-125 μm,and 4-11 μm,respectively.EM1 and EM3 are interpreted as eolian dust and EM2 and EM4 as fluvial mud.The ratio of eolian dust to fluvial mud （（EM1＋EM3）/（EM2＋EM4）） is regarded as an indicator of the East Asian monsoon.The variation in this ratio not only shows periodical oscillations consistent with oxygen isotope stages,but also exhibits a phased increasing trend corresponding with the phased uplifts of the Tibetan Plateau,indicating that the evolution of the East Asian Monsoon was controlled not only by glacial-interglacial cycles,but also by the phased uplifts of the Tibetan Plateau during the Quaternary.

Comparison of air-sea CO2 flux and biological productivity in the South China Sea,East China Sea,and Yellow Sea:a three-dimensional physical-biogeochemical modeling study

Marginal seas play important roles in regulating the global carbon budget, but there are great uncertainties in estimating carbon sources and sinks in the continental margins. A Pacific basin-wide physical-biogeochemical model is used to estimate primary productivity and air-sea CO_2 flux in the South China Sea（SCS）, the East China Sea（ECS）, and the Yellow Sea（YS）. The model is forced with daily air-sea fluxes which are derived from the NCEP2 reanalysis from 1982 to 2005. During the period of time, the modeled monthly-mean air-sea CO_2 fluxes in these three marginal seas altered from an atmospheric carbon sink in winter to a source in summer. On annualmean basis, the SCS acts as a source of carbon to the atmosphere（16 Tg/a, calculated by carbon, released to the atmosphere）, and the ECS and the YS are sinks for atmospheric carbon（–6.73 Tg/a and –5.23 Tg/a, respectively,absorbed by the ocean）. The model results suggest that the sea surface temperature（SST） controls the spatial and temporal variations of the oceanic pCO_2 in the SCS and ECS, and biological removal of carbon plays a compensating role in modulating the variability of the oceanic pCO_2 and determining its strength in each sea,especially in the ECS and the SCS. However, the biological activity is the dominating factor for controlling the oceanic pCO_2 in the YS. The modeled depth-integrated primary production（IPP） over the euphotic zone shows seasonal variation features with annual-mean values of 293, 297, and 315 mg/（m^2·d） in the SCS, the ECS, and the YS, respectively. The model-integrated annual-mean new production（uptake of nitrate） values, as in carbon units, are 103, 109, and 139 mg/（m^2·d）, which yield the f-ratios of 0.35, 0.37, and 0.45 for the SCS, the ECS, and the YS, respectively. Compared to the productivity in the ECS and the YS, the seasonal variation of biological productivity in the SCS is rather weak. The atmospheric pCO_2 increases from 1982 to 2005, which is consistent with the anthropogenic CO_2 input to the atmosphere. The oceanic pCO_2 increases in responses to the atmospheric pCO_2 that drives air-sea CO_2 flux in the model. The modeled increase rate of oceanic pCO_2 is0.91 μatm/a in the YS, 1.04 μatm/a in the ECS, and 1.66 μatm/a in the SCS, respectively.

Geochemical characteristics of Oligocene-Miocene sediments from the deepwater area of the northern South China Sea and their provenance implications

Geochemical and detrital zircon U-Pb dating data for drilled sediments from the Baiyun deepwater area of the northern South China Sea demonstrate a change of sedimentary sources from the Oligocene to the Miocene.Zircon ages of the pre-rift Eocene sequences are dominated by Yanshanian ages with various peak values（110–115 Ma for U1435 and L21; 150 Ma for H1）, indicating local sediment supply from the pre-existing Mesozoic magmatic belt. For the Oligocene sediments in the northern part of the basin, the rare earth elements show different distribution characteristics, indicating sediment supply from the paleo-Zhujiang River（Pearl River）, as also confirmed by the multimodal zircon age spectra of the Lower Oligocene strata in Well X28. By contrast, a positive Eu anomaly characterizes sediments from the western and southern parts of the basin, indicating potential provenances from intermediate to basic volcanic rock materials. The Baiyun Movement at the end of the Oligocene contributed to a large-scale subsidence in the deepwater area and also a northward retreat of continental shelf break, leading to deepening depositional environment in the basin. As a result, all the detrital zircon ages of the Upper Oligocene strata from Wells X28, L13, and L21 share a similar distribution, implying the possible control of a common source like the Zhujiang River. During the Miocene, whereas sediments in the northern area were mainly sourced from the Zhujiang River Delta, and those in the southern deepwater area continued to be affected by basic volcanic activities, the Dongsha Uplift could have contributed as the main source to the eastern area.